Abstract: Most Decision Support Systems (DSS) for waste
management (WM) constructed are not widely marketed and lack
practical applications. This is due to the number of variables and
complexity of the mathematical models which include the
assumptions and constraints required in decision making. The
approach made by many researchers in DSS modelling is to isolate a
few key factors that have a significant influence to the DSS. This
segmented approach does not provide a thorough understanding of
the complex relationships of the many elements involved. The
various elements in constructing the DSS must be integrated and
optimized in order to produce a viable model that is marketable and
has practical application. The DSS model used in assisting decision
makers should be integrated with GIS, able to give robust prediction
despite the inherent uncertainties of waste generation and the plethora
of waste characteristics, and gives optimal allocation of waste stream
for recycling, incineration, landfill and composting.
Abstract: This work considered the thermodynamic feasibility
of scrubbing volatile organic compounds into biodiesel in view of
designing a gas treatment process with this absorbent. A detailed
vapour – liquid equilibrium investigation was performed using the
original UNIFAC group contribution method. The four biodiesels
studied in this work are methyl oleate, methyl palmitate, methyl
linolenate and ethyl stearate. The original UNIFAC procedure was
used to estimate the infinite dilution activity coefficients of 13
selected volatile organic compounds in the biodiesels. The
calculations were done at the VOC mole fraction of 9.213x10-8. Ethyl
stearate gave the most favourable phase equilibrium. A close
agreement was found between the infinite dilution activity coefficient
of toluene found in this work and those reported in literature.
Thermodynamic models can efficiently be used to calculate vast
amount of phase equilibrium behaviour using limited number of
experimental data.
Abstract: In Korea, the technology of a load fo nuclear power plant has been being developed.
automatic controller which is able to control temperature and axial power distribution was developed. identification algorithm and a model predictive contact former transforms the nuclear reactor status into
numerically. And the latter uses them and ge
manipulated values such as two kinds of control ro
this automatic controller, the performance of a coperation was evaluated. As a result, the automatic generated model parameters of a nuclear react to nuclear reactor average temperature and axial power the desired targets during a daily load follow.
Abstract: The effect of extraction solvent upon properties
of carrageenan from Eucheuma cottonii was studied. The
distilled water and KOH solution (concentration 0.1- 0.5N) were
used as the solvent. Extraction process was carried out in water
bath equipped by stirrer with constant speed of 275 rpm with a
constant ratio of seaweed weight to solvent volume ( 1:50 g/mL)
at 86oC for 45 minutes. The extract was then precipitated in 3
volume of 90% ethanol, oven dried at 60oC. Based on
experimental data, alkali significantly influenced yield and
properties of extracted carrageenan. The extracted carrageenan
was found to have essentially identical FTIR spectra to the
reference samples of kappa-carrageenan. Increasing the KOH
concentration led to carrageenan containing less sulfate content
and intrinsic viscosity. The gel strength increased along with the
increasing of KOH concentration. The decreasing of intrinsic
viscosity value indicates that a polymer degradation occurs
during alkali extraction.
Abstract: The paper presents a computational tool developed for
the evaluation of technical and economic advantages of an innovative
cleaning and conditioning technology of fluidized bed steam/oxygen
gasifiers outlet product gas. This technology integrates into a single
unit the steam gasification of biomass and the hot gas cleaning and
conditioning system. Both components of the computational tool,
process flowsheet and economic evaluator, have been developed
under IPSEpro software. The economic model provides information
that can help potential users, especially small and medium size
enterprises acting in the regenerable energy field, to decide the
optimal scale of a plant and to better understand both potentiality and
limits of the system when applied to a wide range of conditions.
Abstract: carbonylation of methanol in homogenous phase is
one of the major routesfor production of acetic acid. Amongst group
VIII metal catalysts used in this process iridium has displayed the
best capabilities. To investigate effect of operating parameters like:
temperature, pressure, methyl iodide, methyl acetate, iridium,
ruthenium, and water concentrations on the reaction rate,
experimental design for this system based upon central composite
design (CCD) was utilized. Statistical rate equation developed by this
method contained individual, interactions and curvature effects of
parameters on the reaction rate. The model with p-value less than
0.0001 and R2 values greater than 0.9; confirmeda satisfactory fitness
of the experimental and theoretical studies. In other words, the
developed model and experimental data obtained passed all
diagnostic tests establishing this model as a statistically significant.
Abstract: In this work, ionic liquids (ILs) for CO2 capturing in typical absorption/stripper process are considered. The use of ionic liquids is considered to be cost-effective because it requires less energy for solvent recovery compared to other conventional processes. A mathematical model is developed for the process based on Peng-Robinson (PR) equation of state (EoS) which is validated with experimental data for various solutions involving CO2. The model is utilized to study the sorbent and energy demand for three types of ILs at specific CO2 capturing rates. The energy demand is manifested by the vapor-liquid equilibrium temperature necessary to remove the captured CO2 from the used solvent in the regeneration step. It is found that higher recovery temperature is required for solvents with higher solubility coefficient. For all ILs, the temperature requirement is less than that required by the typical monoethanolamine (MEA) solvent. The effect of the CO2 loading in the sorbent stream on the process performance is also examined.
Abstract: The main focus of the work was concerned with hydrodynamic and thermal analysis of the plate heat exchanger channel with corrugation patterns suggested to be triangular, sinusoidal, and square corrugation. This study was to numerically model and validate the triangular corrugated channel with dimensions/parameters taken from open literature, and then model/analyze both sinusoidal, and square corrugated channel referred to the triangular model. Initially, 2D modeling with local extensive analysis for triangular corrugated channel was carried out. By that, all local pressure drop, wall shear stress, friction factor, static temperature, heat flux, Nusselt number, and surface heat coefficient, were analyzed to interpret the hydrodynamic and thermal phenomena occurred in the flow. Furthermore, in order to facilitate confidence in this model, a comparison between the values predicted, and experimental results taken from literature for almost the same case, was done. Moreover, a holistic numerical study for sinusoidal and square channels together with global comparisons with triangular corrugation under the same condition, were handled. Later, a comparison between electric, and fluid cooling through varying the boundary condition was achieved. The constant wall temperature and constant wall heat flux boundary conditions were employed, and the different resulted Nusselt numbers as a consequence were justified. The results obtained can be used to come up with an optimal design, a 'compromise' between heat transfer and pressure drop.
Abstract: Measurement of the COD of a spent caustic solution involves firstly digestion of a test sample with dichromate solution and secondly measurement of dichromate remained by titration by ferrous ammonium sulfate [FAS] to an end point. In this paper we study by a potentiometric end point with Ag/AgCl reference electrode and gold rode electrode. The potentiometric end point is sharp and easily identified especially for the samples with high turbidity and color that other methods such as colorimetric in this type of sample do not result in high precision. Because interim of titration responds quickly to potential changes within the [Cr+6/Cr+3& Fe+2/Fe+3] solution producing stable readings that is lead to accurate COD measurement. Finally results are compared with data determined using colorimetric method for standard samples. It is shown that the potentiometric end point titration with gold rode electrode can be used with equal or better facility
Abstract: Fischer-Tropsch synthesis is one of the most
important catalytic reactions that convert the synthetic gas to light
and heavy hydrocarbons. One of the main issues is selecting the type
of reactor. The slurry bubble reactor is suitable choice for Fischer-
Tropsch synthesis because of its good qualification to transfer heat
and mass, high durability of catalyst, low cost maintenance and
repair. The more common catalysts for Fischer-Tropsch synthesis are
Iron-based and Cobalt-based catalysts, the advantage of these
catalysts on each other depends on which type of hydrocarbons we
desire to produce. In this study, Fischer-Tropsch synthesis is modeled
with Iron and Cobalt catalysts in a slurry bubble reactor considering
mass and momentum balance and the hydrodynamic relations effect
on the reactor behavior. Profiles of reactant conversion and reactant
concentration in gas and liquid phases were determined as the
functions of residence time in the reactor. The effects of temperature,
pressure, liquid velocity, reactor diameter, catalyst diameter, gasliquid
and liquid-solid mass transfer coefficients and kinetic
coefficients on the reactant conversion have been studied. With 5%
increase of liquid velocity (with Iron catalyst), H2 conversions
increase about 6% and CO conversion increase about 4%, With 8%
increase of liquid velocity (with Cobalt catalyst), H2 conversions
increase about 26% and CO conversion increase about 4%. With
20% increase of gas-liquid mass transfer coefficient (with Iron
catalyst), H2 conversions increase about 12% and CO conversion
increase about 10% and with Cobalt catalyst H2 conversions increase
about 10% and CO conversion increase about 6%. Results show that
the process is sensitive to gas-liquid mass transfer coefficient and
optimum condition operation occurs in maximum possible liquid
velocity. This velocity must be more than minimum fluidization
velocity and less than terminal velocity in such a way that avoid
catalysts particles from leaving the fluidized bed.
Abstract: Carbon disulfide is widely used for the production of
viscose rayon, rubber, and other organic materials and it is a
feedstock for the synthesis of sulfuric acid. The objective of this
paper is to analyze possibilities for efficient production of CS2 from
sour natural gas reformation (H2SMR) (2H2S+CH4 =CS2 +4H2) .
Also, the effect of H2S to CH4 feed ratio and reaction temperature on
carbon disulfide production is investigated numerically in a
reforming reactor. The chemical reaction model is based on an
assumed Probability Density Function (PDF) parameterized by the
mean and variance of mixture fraction and β-PDF shape. The results
show that the major factors influencing CS2 production are reactor
temperature. The yield of carbon disulfide increases with increasing
H2S to CH4 feed gas ratio (H2S/CH4≤4). Also the yield of C(s)
increases with increasing temperature until the temperature reaches
to 1000°K, and then due to increase of CS2 production and
consumption of C(s), yield of C(s) drops with further increase in the
temperature. The predicted CH4 and H2S conversion and yield of
carbon disulfide are in good agreement with result of Huang and TRaissi.
Abstract: Batch adsorption of recalcitrant melanoidin using the abundantly available coal fly ash was carried out. It had low specific surface area (SBET) of 1.7287 m2/g and pore volume of 0.002245 cm3/g while qualitative evaluation of the predominant phases in it was done by XRD analysis. Colour removal efficiency was found to be dependent on various factors studied. Maximum colour removal was achieved around pH 6, whereas increasing sorbent mass from 10g/L to 200 g/L enhanced colour reduction from 25% to 86% at 298 K. Spontaneity of the process was suggested by negative Gibbs free energy while positive values for enthalpy change showed endothermic nature of the process. Non-linear optimization of error functions resulted in Freundlich and Redlich-Peterson isotherms describing sorption equilibrium data best. The coal fly ash had maximum sorption capacity of 53 mg/g and could thus be used as a low cost adsorbent in melanoidin removal.
Abstract: The utilization of cheese whey as a fermentation
substrate to produce bio-ethanol is an effort to supply bio-ethanol
demand as a renewable energy. Like other process systems, modeling
is also required for fermentation process design, optimization and
plant operation. This research aims to study the fermentation process
of cheese whey by applying mathematics and fundamental concept in
chemical engineering, and to investigate the characteristic of the
cheese whey fermentation process. Steady state simulation results for
inlet substrate concentration of 50, 100 and 150 g/l, and various
values of hydraulic retention time, showed that the ethanol
productivity maximum values were 0.1091, 0.3163 and 0.5639 g/l.h
respectively. Those values were achieved at hydraulic retention time
of 20 hours, which was the minimum value used in this modeling.
This showed that operating reactor at low hydraulic retention time
was favorable. Model of bio-ethanol production from cheese whey
will enhance the understanding of what really happen in the
fermentation process.
Abstract: Cross sections of As radionuclides in the interaction of natGe with 14-30 MeV protons have been deduced by off-line y-ray spectroscopy to find optimal reaction channels leading to radiotracers for positron emission tomography. The experimental results were compared with the previous results and those estimated by the compound nucleus reaction model.
Abstract: Prediction of viscosity of natural gas is an important parameter in the energy industries such as natural gas storage and transportation. In this study viscosity of different compositions of natural gas is modeled by using an artificial neural network (ANN) based on back-propagation method. A reliable database including more than 3841 experimental data of viscosity for testing and training of ANN is used. The designed neural network can predict the natural gas viscosity using pseudo-reduced pressure and pseudo-reduced temperature with AARD% of 0.221. The accuracy of designed ANN has been compared to other published empirical models. The comparison indicates that the proposed method can provide accurate results.
Abstract: A microchannel with two inlets and two outlets was tested as a potential reactor to carry out two-phase catalytic phase transfer reaction with phase separation at the exit of the microchannel. The catalytic phase transfer reaction between benzyl chloride and sodium sulfide was chosen as a model reaction. The effect of operational time on the conversion was studied. By utilizing a multiphase parallel flow inside the microchannel reactor with the aid of a guideline structure, the catalytic phase reaction followed by phase separation could be ensured. The organic phase could be separated completely from one exit and part of the aqueous phase was separated purely and could be reused with slightly affecting the catalytic phase transfer reaction.
Abstract: The Pulsed Compression Reactor promises to be a
compact, economical and energy efficient alternative to conventional
chemical reactors.
In this article, the production of synthesis gas using the Pulsed
Compression Reactor is investigated. This is done experimentally as
well as with simulations. The experiments are done by means of a
single shot reactor, which replicates a representative, single
reciprocation of the Pulsed Compression Reactor with great control
over the reactant composition, reactor temperature and pressure and
temperature history. Simulations are done with a relatively simple
method, which uses different models for the chemistry and
thermodynamic properties of the species in the reactor. Simulation
results show very good agreement with the experimental data, and
give great insight into the reaction processes that occur within the
cycle.
Abstract: Vacuum membrane distillation (VMD) process can be
used for water purification or the desalination of salt water. The
process simply consists of a flat sheet hydrophobic micro porous
PTFE membrane and diaphragm vacuum pump without a condenser
for the water recovery or trap. The feed was used aqueous NaCl
solution. The VMD experiments were performed to evaluate the heat
and mass transfer coefficient of the boundary layer in a membrane
module. The only operating parameters are feed inlet temperature,
and feed flow rate were investigated. The permeate flux was strongly
affected by the feed inlet temperature, feed flow rate, and boundary
layer heat transfer coefficient. Since lowering the temperature
polarization coefficient is essential enhance the process performance
considerable and maximizing the heat transfer coefficient for
maximizes the mass flux of distillate water. In this paper, the results
of VMD experiments are used to measure the boundary layer heat
transfer coefficient, and the experimental results are used to reevaluate
the empirical constants in the Dittus- Boelter equation.
Abstract: The present study based on removal of natural dyes of
Roselle petals, then used Roselle petals powder (RPP) as an
adsorbent for the removal of methylene blue dye (as a typical cationic
or basic dye) from aqueous solutions. The present study shows that
used Roselle petals powder exhibit adsorption trend for the dye. The
adsorption processes were carried out at various conditions of
temperatures ranging from 278 to 338 K ± 2 K , concentrations,
processing time and a wide range of pH between 2.5-11. Adsorption
isotherm equations such as Freundlich, and Langmuir were applied to
calculate the values of respective constants. Adsorption study was
found that the currently introduced adsorbent can be used to remove
cationic dyes such as methylene blue from aqueous solutions.
Abstract: Experiments were conducted to characterize fire
properties of wood exposed to the certain external heat flux and
under variety of wood moisture content. Six kinds of Indonesian
wood: keruing, sono, cemara, kamper, pinus, and mahoni were
exposed to radiant heat from a conical heater, result in appearance of
a stable flame on the wood surface caused by spontaneous ignition. A
thermocouple K-type was used to measure the wood surface
temperature. Temperature histories were recorded throughout each
experiment at 1 s intervals using a TC-08. Data of first ignition time
and temperature, end ignition time and temperature, and charring rate
have been successfully collected. It was found that the ignition
temperature and charring rate depend on moisture content of wood.