Partial Oxidation of Methane in the Pulsed Compression Reactor: Experiments and Simulation
The Pulsed Compression Reactor promises to be a
compact, economical and energy efficient alternative to conventional
chemical reactors.
In this article, the production of synthesis gas using the Pulsed
Compression Reactor is investigated. This is done experimentally as
well as with simulations. The experiments are done by means of a
single shot reactor, which replicates a representative, single
reciprocation of the Pulsed Compression Reactor with great control
over the reactant composition, reactor temperature and pressure and
temperature history. Simulations are done with a relatively simple
method, which uses different models for the chemistry and
thermodynamic properties of the species in the reactor. Simulation
results show very good agreement with the experimental data, and
give great insight into the reaction processes that occur within the
cycle.
[1] Brutzkus, M., Apparatus for chemical production and research, US
Patent 1586508, 1926
[2] Kolbanovskii, Y. A., et al., Impulsnoe sgatie gasov v chimii i
technologii, Moskva, Nauka, 1982. (Pulsed compression of gases in
chemistry and technology, Moskow, Nauka, 1982.)
[3] Glushenkov M. Y., Russian Pat., No 2097121, 29.01.1997; No
2115467, 02.12.1997; No 2142844, 05.04.1999.
[4] Roestenberg, T., et al. Heat transfer study of the pulsed compression
reactor, Chemical Engineering Science, 2009
[5] Open source code downloaded from: http://code.google.com/p/cantera/
Cantera website is under construction http://www.cantera.org (accessed
Jan 2010)
[6] Smith, Gregory P., et al., http://www.me.berkeley.edu/gri_mech/
[7] Hughes, K. J. et al. Development and testing of a comprehensive
chemical mechanism for the oxidation of methane. International Journal
of Chemical Kinetics, 33:513-538, 2001
[8] Konnov, A. A., Detailed reaction mechanism for small hydrocarbons
combustion. Release 0.5. http://homepages.vub.ac.be/~akonnov/.
(accessed Dec 2009)
[9] Petersen, E. L., et al., Methane/propane oxidation at high presures:
Experimental and detailed chemical kinetic modelling. Proceedings of
the combustion institute, 31:447-454, 2007.
[10] Bourque, G., et al. Ignition and flame speed kinetics of two natural gas
blends with high levels of heavier hydrocarbons. Proceedings of the
ASME Turbo Expo, 3:1051-1066, 2008
[1] Brutzkus, M., Apparatus for chemical production and research, US
Patent 1586508, 1926
[2] Kolbanovskii, Y. A., et al., Impulsnoe sgatie gasov v chimii i
technologii, Moskva, Nauka, 1982. (Pulsed compression of gases in
chemistry and technology, Moskow, Nauka, 1982.)
[3] Glushenkov M. Y., Russian Pat., No 2097121, 29.01.1997; No
2115467, 02.12.1997; No 2142844, 05.04.1999.
[4] Roestenberg, T., et al. Heat transfer study of the pulsed compression
reactor, Chemical Engineering Science, 2009
[5] Open source code downloaded from: http://code.google.com/p/cantera/
Cantera website is under construction http://www.cantera.org (accessed
Jan 2010)
[6] Smith, Gregory P., et al., http://www.me.berkeley.edu/gri_mech/
[7] Hughes, K. J. et al. Development and testing of a comprehensive
chemical mechanism for the oxidation of methane. International Journal
of Chemical Kinetics, 33:513-538, 2001
[8] Konnov, A. A., Detailed reaction mechanism for small hydrocarbons
combustion. Release 0.5. http://homepages.vub.ac.be/~akonnov/.
(accessed Dec 2009)
[9] Petersen, E. L., et al., Methane/propane oxidation at high presures:
Experimental and detailed chemical kinetic modelling. Proceedings of
the combustion institute, 31:447-454, 2007.
[10] Bourque, G., et al. Ignition and flame speed kinetics of two natural gas
blends with high levels of heavier hydrocarbons. Proceedings of the
ASME Turbo Expo, 3:1051-1066, 2008
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:56646", author = "Timo Roestenberg and Maxim Glushenkov and Alexander Kronberg and Anton A. Verbeek and Theo H. vd Meer", title = "Partial Oxidation of Methane in the Pulsed Compression Reactor: Experiments and Simulation", abstract = "The Pulsed Compression Reactor promises to be a
compact, economical and energy efficient alternative to conventional
chemical reactors.
In this article, the production of synthesis gas using the Pulsed
Compression Reactor is investigated. This is done experimentally as
well as with simulations. The experiments are done by means of a
single shot reactor, which replicates a representative, single
reciprocation of the Pulsed Compression Reactor with great control
over the reactant composition, reactor temperature and pressure and
temperature history. Simulations are done with a relatively simple
method, which uses different models for the chemistry and
thermodynamic properties of the species in the reactor. Simulation
results show very good agreement with the experimental data, and
give great insight into the reaction processes that occur within the
cycle.", keywords = "Chemical reactors, Energy, Pulsed compressionreactor, Simulation", volume = "4", number = "7", pages = "442-5", }