Abstract: This paper reports the influence of sucrose on the
preservation of CO2 hydrate crystal samples. The particle diameter of
hydrate samples were 1.0 and 5.6-8.0 mm. Mass fraction of sucrose in
the sample was 0.16. The samples were stored at the aerated condition
under atmospheric pressure and at the temperature of 253 or 258 K.
The results indicated that the mass fractions of CO2 hydrate in the
samples with sucrose were 0.10 ± 0.03 at the end of 3-week
preservation, regardless of temperature and particle diameter. Mass
fraction of CO2 hydrate in the samples with sucrose was higher than
that of pure CO2 hydrate for 1.0 mm particle diameter, while was
lower than that of pure CO2 hydrate for 5.6-8.0 mm particle diameter.
Discussion is made on the influence of sucrose on the dissociation of
CO2 hydrate and the resulting formation of ice.