Preservation of Carbon Dioxide Clathrate Hydrate Coexisting with Sucrose at Temperatures below the Water Freezing Point under Atmospheric Pressure
This paper reports the influence of sucrose on the
preservation of CO2 hydrate crystal samples. The particle diameter of
hydrate samples were 1.0 and 5.6-8.0 mm. Mass fraction of sucrose in
the sample was 0.16. The samples were stored at the aerated condition
under atmospheric pressure and at the temperature of 253 or 258 K.
The results indicated that the mass fractions of CO2 hydrate in the
samples with sucrose were 0.10 ± 0.03 at the end of 3-week
preservation, regardless of temperature and particle diameter. Mass
fraction of CO2 hydrate in the samples with sucrose was higher than
that of pure CO2 hydrate for 1.0 mm particle diameter, while was
lower than that of pure CO2 hydrate for 5.6-8.0 mm particle diameter.
Discussion is made on the influence of sucrose on the dissociation of
CO2 hydrate and the resulting formation of ice.
[1] L. W. Diamond, N. N. Akinfiev, "Solubility of CO2 in water from -1.5 to
100 ┬░C and from 0.1 to 100 MPa: evaluation of literature data and
thermodynamic modeling," Fluid. Phase Equilibri, 2003, vol. 208, pp.
265-290.
[2] R. Rohde, P. Price, "Diffusion-controlled metabolism for long-term
survival of single isolated microorganism trapped within ice crystals,"
Proc Natl. Sci. U.S.A. 2007, vol. 104, pp. 16592-16597.
[3] X. M. Peng, Y. F. Hu, L. Y. Yang, C. W. Jin, "Decomposition Kinetics
for Formation of CO2 Hydrate in Natural Silica Sands," Chin. J. Chem.
Eng. 2010, vol. 18 (1), pp. 61-65.
[4] S. Takeya, T. Uchida, J. Nagao, R. Ohmura, W. Shimada, Y. Kamata, T.
Ebinuma, H. Narita, "Particle Size Effect of CH4 Hydrate for
Self-Preservation," Chem. Eng. Sci. 2005, vol. 60, pp. 1383-1387.
[5] Y. H. Mori, "Recent Advances in Hydrate-based Technologies for
Natural Gas StorageÔÇöA Review," J. Chem. Ind. Eng. (China) 2003, vol.
54, pp. 1´╝ì17 (Suppl),
[6] S. Watanabe, S. Takahashi, H. Mizubayashi, S. Murata, H. A. Murakami,
"Demonstration Project of NGH Land Transportation System," 6th
International Conference on Gas Hydrates, Vancouver, Canada, 2008.
[7] P. Englezos, J. D. Lee, "Gas hydrates: A cleaner source of energy and
opportunity for innovative technologies," Korean J. Chem. Eng. 2005,
vol. 22, pp. 671-681.
[8] A. Falenty, W. F. Kuhs, "Self-Preservation of CO2 Gas Hydrate´╝ìSurface
Microstructure and Ice Perfection," J. Phys. Chem. B 2009, vol. 113, pp.
15975-15988.
[9] D. W. Davidson, S. K. Garg, S. R. Gough, Y. P. Handa, C. I. Ratecliffe, J.
A. Ripmeester, J. S. Tse, W. F. Lawson, "Laboratory Analysis of a
Naturally-Occurring Gas Hydrate From Sediment of the Gulf of Mexico,"
Geochim. Cosmochim. Acta 1986, vol. 50 (4), pp. 619-623.
[10] V. S. Yakushev, V. A. Istomin, "Gas-Hydrate Self-Preservation Effect,"
In Physics and Chemistry of Ice, N. Maeno, T. Hondoh, Eds.; Hokkaido
University Press: Sapporo, Japan 1992, pp. 136´╝ì139.
[11] L. A. Stern, S. Circone, S. H. Kirby, Durham,W. B. Anomalous
preservation of pure methane hydrate at 1 atm. J. Phys. Chem. B 2001,
vol. 105 (9), pp. 1756-1762.
[12] S. Takeya, W. Shimada, Y. Kamata, T. Ebinuma, T. Uchida, J. Nagao, H.
Narita, "In Situ X-ray Diffraction Measurement of the Self - Preservation
effect of CH4 Hydrate," J. Phys. Chem. A 2001, vol. 105 (42), pp.
9756-9759.
[13] S. Circone, L. A. Stern, S. H. Kirby, W. B. Durham, B. C. Chakoumakos,
C. J. Rawn, A. J. Rondinone, Y. Ishii, "CO2 Hydrate: Synthesis,
Composition, Structure, Dissociation Behavior, and a Comparison to
Structure I CH4 Hydrate," J. Phys. Chem. B 2003, vol. 107 (23), pp.
5529-5539.
[14] S. Muromachi, R. Ohmura, S. Takeya, Y. H. Mori, "Clathrate Hydrate for
Ozone Preservation," J. Phys. Chem. B 2010, vol. 114, pp. 11430-11435.
[15] L. A. Stern, S. Circone, S. H. Kirby, W. B. Durham, "Temperature,
Pressure, an Compositional Effects on Anomalous or "Self" Preservation
of Gas Hydrate," Can. J. Phys. 2003, vol. 81, pp. 271-283.
[16] S. Takeya, J. A. Ripmeester, "Dissociation Behavior of Clatherate
Hydrate to Ice and Dependence on Guest Molecules," Angew. Chem., Int.
Ed. 2008, vol. 47, pp. 1276-1279.
[17] C. Giavirini,; F. Maccioni,; M. Politi,; A. L. Santarelli, "O2 Hydrate:
Formation and Dissociation Compared to Methane Hydrate," Energy
Fuels 2007, vol. 21, pp. 3284-3291.
[18] T. Makiya, T. Murakami, S. Takeya, A. K. Sum, S. Alavi, R. Ohmura,
"Synthesis and Characterization of Clathrate Hydrates Containing Carbon
Dioxide and Ethanol," Phys. Chem. Chem. Phys. 2010, vol. 12, pp.
9927-9932.
[19] T. B. Peters, J. L. Smith, J. G. Brisson, "Production of CO2 Clathrate
hydrate frozen desserts by flash freezing," J. Food Eng. 2010, pp.
669-677.
[20] K. A. Udachin, C. I. Ratcliffe, J. A. Ripmeester, "Structure, Composition,
and Thermal Expansion of CO2 Hydrate from Single Crystal X-ray
Diffraction Measurements," J. Phys. Chem. B 2001, vol. 105, pp.
4200-4204.
[21] D. Sun, Y. Shimono, S. Takeya, R. Ohmura, "Preservation of Carbon
Dioxide Clathrate Hydrate at Temperatures below the Water Freezing
Point under Atmospheric Pressure.," Ind. Eng. Chem. Res. 2011, vol. 50,
pp. 13854-13858.
[1] L. W. Diamond, N. N. Akinfiev, "Solubility of CO2 in water from -1.5 to
100 ┬░C and from 0.1 to 100 MPa: evaluation of literature data and
thermodynamic modeling," Fluid. Phase Equilibri, 2003, vol. 208, pp.
265-290.
[2] R. Rohde, P. Price, "Diffusion-controlled metabolism for long-term
survival of single isolated microorganism trapped within ice crystals,"
Proc Natl. Sci. U.S.A. 2007, vol. 104, pp. 16592-16597.
[3] X. M. Peng, Y. F. Hu, L. Y. Yang, C. W. Jin, "Decomposition Kinetics
for Formation of CO2 Hydrate in Natural Silica Sands," Chin. J. Chem.
Eng. 2010, vol. 18 (1), pp. 61-65.
[4] S. Takeya, T. Uchida, J. Nagao, R. Ohmura, W. Shimada, Y. Kamata, T.
Ebinuma, H. Narita, "Particle Size Effect of CH4 Hydrate for
Self-Preservation," Chem. Eng. Sci. 2005, vol. 60, pp. 1383-1387.
[5] Y. H. Mori, "Recent Advances in Hydrate-based Technologies for
Natural Gas StorageÔÇöA Review," J. Chem. Ind. Eng. (China) 2003, vol.
54, pp. 1´╝ì17 (Suppl),
[6] S. Watanabe, S. Takahashi, H. Mizubayashi, S. Murata, H. A. Murakami,
"Demonstration Project of NGH Land Transportation System," 6th
International Conference on Gas Hydrates, Vancouver, Canada, 2008.
[7] P. Englezos, J. D. Lee, "Gas hydrates: A cleaner source of energy and
opportunity for innovative technologies," Korean J. Chem. Eng. 2005,
vol. 22, pp. 671-681.
[8] A. Falenty, W. F. Kuhs, "Self-Preservation of CO2 Gas Hydrate´╝ìSurface
Microstructure and Ice Perfection," J. Phys. Chem. B 2009, vol. 113, pp.
15975-15988.
[9] D. W. Davidson, S. K. Garg, S. R. Gough, Y. P. Handa, C. I. Ratecliffe, J.
A. Ripmeester, J. S. Tse, W. F. Lawson, "Laboratory Analysis of a
Naturally-Occurring Gas Hydrate From Sediment of the Gulf of Mexico,"
Geochim. Cosmochim. Acta 1986, vol. 50 (4), pp. 619-623.
[10] V. S. Yakushev, V. A. Istomin, "Gas-Hydrate Self-Preservation Effect,"
In Physics and Chemistry of Ice, N. Maeno, T. Hondoh, Eds.; Hokkaido
University Press: Sapporo, Japan 1992, pp. 136´╝ì139.
[11] L. A. Stern, S. Circone, S. H. Kirby, Durham,W. B. Anomalous
preservation of pure methane hydrate at 1 atm. J. Phys. Chem. B 2001,
vol. 105 (9), pp. 1756-1762.
[12] S. Takeya, W. Shimada, Y. Kamata, T. Ebinuma, T. Uchida, J. Nagao, H.
Narita, "In Situ X-ray Diffraction Measurement of the Self - Preservation
effect of CH4 Hydrate," J. Phys. Chem. A 2001, vol. 105 (42), pp.
9756-9759.
[13] S. Circone, L. A. Stern, S. H. Kirby, W. B. Durham, B. C. Chakoumakos,
C. J. Rawn, A. J. Rondinone, Y. Ishii, "CO2 Hydrate: Synthesis,
Composition, Structure, Dissociation Behavior, and a Comparison to
Structure I CH4 Hydrate," J. Phys. Chem. B 2003, vol. 107 (23), pp.
5529-5539.
[14] S. Muromachi, R. Ohmura, S. Takeya, Y. H. Mori, "Clathrate Hydrate for
Ozone Preservation," J. Phys. Chem. B 2010, vol. 114, pp. 11430-11435.
[15] L. A. Stern, S. Circone, S. H. Kirby, W. B. Durham, "Temperature,
Pressure, an Compositional Effects on Anomalous or "Self" Preservation
of Gas Hydrate," Can. J. Phys. 2003, vol. 81, pp. 271-283.
[16] S. Takeya, J. A. Ripmeester, "Dissociation Behavior of Clatherate
Hydrate to Ice and Dependence on Guest Molecules," Angew. Chem., Int.
Ed. 2008, vol. 47, pp. 1276-1279.
[17] C. Giavirini,; F. Maccioni,; M. Politi,; A. L. Santarelli, "O2 Hydrate:
Formation and Dissociation Compared to Methane Hydrate," Energy
Fuels 2007, vol. 21, pp. 3284-3291.
[18] T. Makiya, T. Murakami, S. Takeya, A. K. Sum, S. Alavi, R. Ohmura,
"Synthesis and Characterization of Clathrate Hydrates Containing Carbon
Dioxide and Ethanol," Phys. Chem. Chem. Phys. 2010, vol. 12, pp.
9927-9932.
[19] T. B. Peters, J. L. Smith, J. G. Brisson, "Production of CO2 Clathrate
hydrate frozen desserts by flash freezing," J. Food Eng. 2010, pp.
669-677.
[20] K. A. Udachin, C. I. Ratcliffe, J. A. Ripmeester, "Structure, Composition,
and Thermal Expansion of CO2 Hydrate from Single Crystal X-ray
Diffraction Measurements," J. Phys. Chem. B 2001, vol. 105, pp.
4200-4204.
[21] D. Sun, Y. Shimono, S. Takeya, R. Ohmura, "Preservation of Carbon
Dioxide Clathrate Hydrate at Temperatures below the Water Freezing
Point under Atmospheric Pressure.," Ind. Eng. Chem. Res. 2011, vol. 50,
pp. 13854-13858.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:57463", author = "Tadaaki Sato and Ryo Ohmura", title = "Preservation of Carbon Dioxide Clathrate Hydrate Coexisting with Sucrose at Temperatures below the Water Freezing Point under Atmospheric Pressure", abstract = "This paper reports the influence of sucrose on the
preservation of CO2 hydrate crystal samples. The particle diameter of
hydrate samples were 1.0 and 5.6-8.0 mm. Mass fraction of sucrose in
the sample was 0.16. The samples were stored at the aerated condition
under atmospheric pressure and at the temperature of 253 or 258 K.
The results indicated that the mass fractions of CO2 hydrate in the
samples with sucrose were 0.10 ± 0.03 at the end of 3-week
preservation, regardless of temperature and particle diameter. Mass
fraction of CO2 hydrate in the samples with sucrose was higher than
that of pure CO2 hydrate for 1.0 mm particle diameter, while was
lower than that of pure CO2 hydrate for 5.6-8.0 mm particle diameter.
Discussion is made on the influence of sucrose on the dissociation of
CO2 hydrate and the resulting formation of ice.", keywords = "Clathrate hydrates, Carbon dioxide", volume = "7", number = "2", pages = "121-4", }
