Abstract: This paper reports on the enhanced photoluminescence
(PL) of nanocomposites through the layered structuring of phosphor
and quantum dot (QD). Green phosphor of Sr2SiO4:Eu, red QDs of
CdSe/CdS/CdZnS/ZnS core-multishell, and thermo-curable resin
were used for this study. Two kinds of composite (layered and mixed)
were prepared, and the schemes for optical energy transfer between
QD and phosphor were suggested and investigated based on PL decay
characteristics. It was found that the layered structure is more effective
than the mixed one in the respects of PL intensity, PL decay and
thermal loss. When this layered nanocomposite (QDs on phosphor) is
used to make white light emitting diode (LED), the brightness is
increased by 37 %, and the color rendering index (CRI) value is raised
to 88.4 compared to the mixed case of 80.4.
Abstract: This research aimed to modify pineapple leaf paper
(PALP) for using as wet media in the evaporation cooling system by
improving wet mechanical property (tensile strength) without
compromising water absorption property. Polyamideamineepichorohydrin
resin (PAE) and carboxymethylcellulose (CMC)
were used to strengthen the paper, and the PAE and CMC ratio of
80:20 showed the optimum wet and dry tensile index values, which
were higher than those of the commercial cooling pad (CCP).
Compared with CCP, PALP itself and all the PAE/CMC modified
PALP possessed better water absorption. The PAE/CMC modified
PALP had potential to become a new type of wet media.
Abstract: In this paper, a thermal model of cast- resin dry type
transformer is proposed. The proposed thermal model is solved by
finite element technique to get the temperature at any location of the
transformer. The basic modes of heat transfer such as conduction;
convection and radiation are used to get the steady state temperature
distribution of the transformer. The predicted temperatures are
compared with experimental results reported in this paper and it is
found a good agreement between them. The effects of various
parameters such as width of air duct, ambient temperature and
emissivity of the outer surface were also studied.
Abstract: Two Amphiphilic catalysts, iron (III) dodecylbenzene
sulfonate and nickel (II) dodecylbenzene sulfonate, were synthesized
and used in the catalytic aquathermolysis of heavy crude oil to reduce
its viscosity. The prepared catalysts exhibited good performance in
the aquathermolysis and the viscosity is reduced by ~ 78.9 % for
Egyptian heavy crude oil. The chemical and physical properties of
heavy oil both before and after reaction were investigated by FT-IR,
dynamic viscosity, molecular weight and SARA analysis. The results
indicated that the content of resin, asphaltene, average molecular
weight and sulfur content of heavy oil is reduced after the catalytic
aquathermolysis.
Abstract: This study evaluates the performance of horizontal
subsurface flow constructed wetland (HSSF-CW) for the removal of
chlorinated resin and fatty acids (RFAs) from pulp and paper mill
wastewater. The dimensions of the treatment system were 3.5 m x 1.5
m x 0.28 m with surface area of 5.25 m2, filled with fine sand and
gravel. The cell was planted with an ornamental plant species Canna
indica. The removal efficiency of chlorinated RFAs was in the range
of 92-96% at the hydraulic retention time (HRT) of 5.9 days. Plant
biomass and soil (sand and gravel) were analyzed for chlorinated
RFAs content. No chlorinated RFAs were detected in plant biomass
but detected in soil samples. Mass balance studies of chlorinated
RFAs in HSSF-CW were also carried out.
Abstract: In this paper, an automated system is presented for
identification and separation of plastic resins based on near infrared
(NIR) reflectance spectroscopy. For identification and separation
among resins, a "Two-Filter" identification method is proposed that
is capable to distinguish among polyethylene terephthalate (PET),
high density polyethylene (HDPE), polyvinyl chloride (PVC),
polypropylene (PP) and polystyrene (PS). Through surveying effects
of parameters such as surface contamination, sample thickness, label
and cap existence, it was obvious that the "Two-Filter" method has a
high efficiency in identification of resins. It is shown that accurate
identification and separation of five major resins can be obtained
through calculating the relative reflectance at two wavelengths in the
NIR region.
Abstract: Boron minerals are very useful for various industrial
activities, such as glass industry and detergent industry, due to its
mechanical and chemical properties. During the production of boron
compounds, many of these are introduced into the environment in the
form of waste. Boron is also an important micro nutrient for the
plants to vegetate but if it exists in high concentrations, it could have
toxic effects. The maximum boron level in drinking water for human
health is given as 0.3 mg/L in World Health Organization (WHO)
standards. The toxic effects of boron should be noted especially for
dry regions, thus, in recent years, increasing attention has been paid
to remove the boron from waste waters. In this study, boron removal
is implemented by ion exchange process using Amberlite IRA-743
resin. Amberlite IRA-743 resin is a boron specific resin and it
belongs to the polymerizate sorbent group within the aminopolyol
functional group. Batch studies were performed to investigate the
effects of various experimental parameters, such as adsorbent dose,
initial concentration and pH, on the removal of boron. It is found
that, when the adsorbent dose increases removal of boron from the
liquid phase increases. However, an increase in the initial
concentration decreases the removal of boron. The effective pH
values for removal of boron are determined between 8.5 and 9.
Equilibrium isotherms were also analyzed by Langmuir and
Freundlich isotherm models. The Langmuir isotherm is obeyed better
than the Freundlich isotherm.
Abstract: In the present work, an attempt has been made to
understand the feasibility of using UHF technique for identification
of any corona discharges/ arcing in insulating material due to water
droplets. The sensors of broadband type are useful for identification
of such discharges. It is realised that arcing initiated by liquid droplet
radiates UHF signals in the entire bandwidth up to 2 GHz. The
frequency content of the UHF signal generated due to corona/arcing
is not much varied in epoxy nanocomposites with different weight
percentage of clay content. The exfoliated/intercalated properties
were analysed through TEM studies. It is realized that corona
initiated discharges are of intermittent process. The hydrophobicity
of the material characterized through contact angle measurement. It
is realized that low Wt % of nanoclay content in epoxy resin reduces
the surface carbonization due to arcing/corona discharges. The results
of the study with gamma irradiated specimen indicates that contact
angle, discharge inception time and evaporation time of the liquid are
much lower than the virgin epoxy nanocomposite material.
Abstract: The leaching rate of 137Cs from spent mix bead (anion and cation) exchange resins in a cement-bentonite matrix has been studied. Transport phenomena involved in the leaching of a radioactive material from a cement-bentonite matrix are investigated using three methods based on theoretical equations. These are: the diffusion equation for a plane source an equation for diffusion coupled to a firstorder equation and an empirical method employing a polynomial equation. The results presented in this paper are from a 25-year mortar and concrete testing project that will influence the design choices for radioactive waste packaging for a future Serbian radioactive waste disposal center.
Abstract: In this paper, the construction of a detailed spine
model is presented using the LifeMOD Biomechanics Modeler. The
detailed spine model is obtained by refining spine segments in
cervical, thoracic and lumbar regions into individual vertebra
segments, using bushing elements representing the intervertebral
discs, and building various ligamentous soft tissues between
vertebrae. In the sagittal plane of the spine, constant force will be
applied from the posterior to anterior during simulation to determine
dynamic characteristics of the spine. The force magnitude is
gradually increased in subsequent simulations. Based on these
recorded dynamic properties, graphs of displacement-force
relationships will be established in terms of polynomial functions by
using the least-squares method and imported into a haptic integrated
graphic environment. A thoracolumbar spine model with complex
geometry of vertebrae, which is digitized from a resin spine
prototype, will be utilized in this environment. By using the haptic
technique, surgeons can touch as well as apply forces to the spine
model through haptic devices to observe the locomotion of the spine
which is computed from the displacement-force relationship graphs.
This current study provides a preliminary picture of our ongoing
work towards building and simulating bio-fidelity scoliotic spine
models in a haptic integrated graphic environment whose dynamic
properties are obtained from LifeMOD. These models can be helpful
for surgeons to examine kinematic behaviors of scoliotic spines and
to propose possible surgical plans before spine correction operations.
Abstract: This research was to evaluate a technical feasibility of
making single-layer experimental particleboard panels from bamboo
waste (Dendrocalamus asper Backer) by converting bamboo into
strips, which are used to make laminated bamboo furniture. Variable
factors were density (600, 700 and 800 kg/m3) and temperature of
condition (25, 40 and 55 °C). The experimental panels were tested for
their physical and mechanical properties including modulus of
elasticity (MOE), modulus of rupture (MOR), internal bonding
strength (IB), screw holding strength (SH) and thickness swelling
values according to the procedures defined by Japanese Industrial
Standard (JIS). The test result of mechanical properties showed that
the MOR, MOE and IB values were not in the set criteria, except the
MOR values at the density of 700 kg/m3 at 25 °C and at the density
of 800 kg/m3 at 25 and 40 °C, the IB values at the density of 600
kg/m3, at 40 °C, and at the density of 800 kg/m3 at 55 °C. The SH
values had the test result according to the set standard, except with
the density of 600 kg/m3, at 40 and 55 °C. Conclusively, a valuable
renewable biomass, bamboo waste could be used to manufacture
boards.
Abstract: The urban centers within northeastern Brazil are
mainly influenced by the intense rainfalls, which can occur after long
periods of drought, when flood events can be observed during such
events. Thus, this paper aims to study the rainfall frequencies in such
region through the wavelet transform. An application of wavelet
analysis is done with long time series of the total monthly rainfall
amount at the capital cities of northeastern Brazil. The main
frequency components in the time series are studied by the global
wavelet spectrum and the modulation in separated periodicity bands
were done in order to extract additional information, e.g., the 8 and
16 months band was examined by an average of all scales, giving a
measure of the average annual variance versus time, where the
periods with low or high variance could be identified. The important
increases were identified in the average variance for some periods,
e.g. 1947 to 1952 at Teresina city, which can be considered as high
wet periods. Although, the precipitation in those sites showed similar
global wavelet spectra, the wavelet spectra revealed particular
features. This study can be considered an important tool for time
series analysis, which can help the studies concerning flood control,
mainly when they are applied together with rainfall-runoff
simulations.
Abstract: In this paper, the effect of modified clay on the
mechanical efficiency of epoxy resin is examined. Studies by X ray
diffraction and microscopic transient electron method show that
modified clay distribution in polymer area is intercalated kind.
Examination the results of mechanical tests shows that existence of
modified clay in epoxy area increases pressure yield strength, tension
module and nano composite fracture toughness in relate of pure
epoxy. By microscopic examinations it is recognized too that the
action of toughness growth of this kind of nano composite is due to
crack deflection, formation of new surfaces and fracture of clay piles.
Abstract: Resins are used in nuclear power plants for water
ultrapurification. Two approaches are considered in this work:
column experiments and simulations. A software called OPTIPUR
was developed, tested and used. The approach simulates the onedimensional
reactive transport in porous medium with convectivedispersive
transport between particles and diffusive transport within
the boundary layer around the particles. The transfer limitation in the
boundary layer is characterized by the mass transfer coefficient
(MTC). The influences on MTC were measured experimentally. The
variation of the inlet concentration does not influence the MTC; on
the contrary of the Darcy velocity which influences. This is consistent
with results obtained using the correlation of Dwivedi&Upadhyay.
With the MTC, knowing the number of exchange site and the relative
affinity, OPTIPUR can simulate the column outlet concentration
versus time. Then, the duration of use of resins can be predicted in
conditions of a binary exchange.
Abstract: Fire disaster is the major factor to endanger the public
and environmental safety. People lost their life during fire disaster
mainly be attributed to the dense smoke and toxic gas under
combustion, which hinder the escape of people and the rescue of
firefighters under fire disaster. The smoke suppression effect of
several transitional metals oxide on the epoxy resin treated with
intumescent flame retardant and titanate couple agent
(EP/IFR/Titanate) system have been investigated. The results showed
manganese dioxide has great effect on reducing the smoke density rate
(SDR) of EP/IFR/Titanate system; however it has little effect to reduce
the maximum smoke density (MSD) of EP/IFR/Titanate system.
Copper oxide can decrease the maximum smoke density (MSD) and
smoke density rate of EP/IFR/Titanate system substantially. The MSD
and SDR of EP/IFR/Titanate system can reduce 20.3% and 39.1%
respectively when 2% of copper oxide is introduced.
Abstract: Sarkhoon gas plant, located in south of Iran, has been installed to removal H2S contained in a high pressure natural gas stream. The solvent used for the H2S removal from gaseous stream is 34% by weight (wt%) Di-ethanol amine (DEA) solutions. Due to increasing concentration of heat stable salt (HSS) in solvent, corrosivity of amine solution had been increased. Reports indicated that there was corrosion on the shell of regeneration column. Because source formation of HSS was unknown, we decided to control the amount of HSS at the limit less than 3% wt amine solvent. Therefore, two small columns were filled by strong anionic base and carbon active, and then polluted amine was passed through beds. Finally a temporary amine recovery package on industrial scale was made based on laboratory’s results. From economical point of view we could save $700000 beside corrosion occurrence of the stripping column has been vigorously decreased.
Abstract: The aluminum bronze matrix alumina composites using hot press and resin infiltration were investigated to study their porosities, hardness, bending strengths, and microstructures. The experiment results show that the hardness of the sintered composites with the decrease of porosity increases. The composites without and with resin infiltration have about HRF 42-61 of about 34-40% of porosity and about HRF 62-83 of about 30-36% of porosity, respectively. Besides, the alumina composites contain a more amount of iron and nickel powders would cause a lower bending strength due to forming some weaker bonding among the iron, nickel, copper, aluminum under this hot pressing of shorter time.
Abstract: A new chelating resin is prepared by coupling
Amberlite XAD-4 with 1-amino-2-naphthole through an azo spacer.
The resulting sorbent has been characterized by FT-IR, elemental
analysis and thermogravimetric analysis (TGA) and studied for
preconcentrating of Cu (II) using flame atomic absorption
spectrometry (FAAS) for metal monitoring. The optimum pH value
for sorption of the copper ions was 6.5. The resin was subjected to
evaluation through batch binding of mentioned metal ion.
Quantitative desorption occurs instantaneously with 0.5 M HNO3.
The sorption capacity was found 4.8 mmol.g-1 of resin for Cu (II) in
the aqueous solution. The chelating resin can be reused for 10 cycles
of sorption-desorption without any significant change in sorption
capacity. A recovery of 99% was obtained the metal ions with 0.5 M
HNO3 as eluting agent. The method was applied for metal ions
determination from industrial waste water sample.
Abstract: The objectives of this research are to produce
prototype coconut oil based solvent offset printing inks and to
analyze a basic quality of printing work derived from coconut oil
based solvent offset printing inks, by mean of bringing coconut oil
for producing varnish and bringing such varnish to produce black
offset printing inks. Then, analysis of qualities i.e. CIELAB value,
density value, and dot gain value of printing work from coconut oil
based solvent offset printing inks which printed on gloss-coated
woodfree paper weighs 130 grams were done. The research result of
coconut oil based solvent offset printing inks indicated that the
suitable varnish formulation is using 51% of coconut oil, 36% of
phenolic resin, and 14% of solvent oil 14%, while the result of
producing black offset ink displayed that the suitable formula of
printing ink is using varnish mixed with 20% of coconut oil, and the
analyzing printing work of coconut oil based solvent offset printing
inks which printed on paper, the results were as follows: CIELAB
value of black offset printing ink is at L* = 31.90, a* = 0.27, and b* =
1.86, density value is at 1.27 and dot gain value was high at mid tone
area of image area.
Abstract: The purpose of this study is to present a non invasive
method for the marginal adaptation evaluation in class V composite
restorations. Standardized class V cavities, prepared in human
extracted teeth, were filled with Premise (Kerr) composite. The
specimens were thermo cycled. The interfaces were examined by
Optical Coherence Tomography method (OCT) combined with the
confocal microscopy and fluorescence. The optical configuration
uses two single mode directional couplers with a superluminiscent
diode as the source at 1300 nm. The scanning procedure is similar to
that used in any confocal microscope, where the fast scanning is enface
(line rate) and the depth scanning is much slower (at the frame
rate). Gaps at the interfaces as well as inside the composite resin
materials were identified. OCT has numerous advantages which
justify its use in vivo as well as in vitro in comparison with
conventional techniques.