Abstract: This paper presents results of compressive strength,
capillary water absorption, and density tests conducted on concrete
containing recycled aggregate (RCA) which is obtained from
structural waste generated by the construction industry in Turkey. In
the experiments, 0%, 15%, 30%, 45% and 60% of the normal
(natural) coarse aggregate was replaced by the recycled aggregate.
Maximum aggregate particle sizes were selected as 16 mm, 22,4 mm
and 31,5 mm; and 0,06%, 0,13% and 0,20% of air-entraining agent
(AEA) were used in mixtures. Fly ash and superplasticizer were used
as a mineral and chemical admixture, respectively. The same type
(CEM I 42.5) and constant dosage of cement were used in the study.
Water/cement ratio was kept constant as 0.53 for all mixture. It was
concluded that capillary water absorption, compressive strength, and
density of concrete decreased with increasing RCA ratio. Increasing
in maximum aggregate particle size and amount of AEA also affect
the properties of concrete significantly.
Abstract: Fibre cement plates, often used in construction,
generally are made using quartz as an inert material, cement as a
binder and cellulose as a fibre. This paper, first of all, investigates the
mechanical properties and durability of fibre cement plates when
quartz is both partly and fully replaced with diatomite. Diatomite
does not only have lower density compared to quartz but also has
high pozzolanic activity. The main objective of this paper is the
investigation of the effects of supplementary cementing materials
(SCMs) on the short and long term mechanical properties and
durability characteristics of fibre cement plates prepared using
diatomite. Supplementary cementing materials such as ground
granulated blast furnace slug (GGBS) and fly ash (FA) are used in
this study. Volume proportions of 10, 20, 30 and 40% of GGBS and
FA are used as partial replacement materials to cement. Short and
long term mechanical properties such as compressive and flexural
strengths as well as sorptivity characteristics and mass were
investigated. Consistency and setting time at each replacement levels
of SCMs were also recorded. The effects of using supplementary
cementing materials on the carbonation and sulphate resistance of
fibre cement plates were then experimented. The results, first of all,
show that the use of diatomite as a full or partial replacement to
quartz resulted in a systematic decrease in total mass of the fibre
cement plates. The reduction of mass was largely due to the lower
density and finer particle size of diatomite compared to quartz. The
use of diatomite did not only reduce the mass of these plates but also
increased the compressive strength significantly as a result of its high
pozzolanic activity. The replacement levels of both GGBS and FA
resulted in a systematic decrease in short term compressive strength
with increasing replacement levels. This was essentially expected as
the total rate of hydration is much lower in GGBS and FA than that
of cement. Long term results however, indicated that the compressive
strength of fibre cement plates prepared using both GGBS and FA
increases with time and hence the compressive strength of plates
prepared using SCMs is either equivalent or more than the
compressive strength of plates prepared using cement alone.
Durability characteristics of fibre cement plates prepared using SCMs
were enhanced significantly. Measurements of sopritivty
characteristics were also indicated that the plates prepared using
SCMs has much lower water absorption capacities compared to
plates prepared cement alone. Much higher resistance to carbonation
and sulphate attach were observed with plates prepared using SCMs.
The results presented in this paper show that the use of SCMs does
not only support the production of more sustainable construction
materials but also enhances the mechanical properties and durability
characteristics of fibre cement plates.
Abstract: In recent years a new method of combination
treatment for cancer has been developed and studied that has led to
significant advancements in the field of cancer therapy. Hyperthermia
is a traditional therapy that, along with a creation of a medically
approved level of heat with the help of an alternating magnetic AC
current, results in the destruction of cancer cells by heat. This paper
gives details regarding the production of the spherical nanocomposite
PVA/γ-Fe2O3 in order to be used for medical purposes such as tumor
treatment by hyperthermia. To reach a suitable and evenly distributed
temperature, the nanocomposite with core-shell morphology and
spherical form within a 100 to 200 nanometer size was created using
phase separation emulsion, in which the magnetic nano-particles γ-
Fe2O3 with an average particle size of 20 nano-meters and with
different percentages of 0.2, 0.4, 0.5 and 0.6 were covered by
polyvinyl alcohol. The main concern in hyperthermia and heat
treatment is achieving desirable specific absorption rate (SAR) and
one of the most critical factors in SAR is particle size. In this project
all attempts has been done to reach minimal size and consequently
maximum SAR. The morphological analysis of the spherical
structure of the nanocomposite PVA/γ-Fe2O3 was achieved by SEM
analyses and the study of the chemical bonds created was made
possible by FTIR analysis. To investigate the manner of magnetic
nanocomposite particle size distribution a DLS experiment was
conducted. Moreover, to determine the magnetic behavior of the γ-
Fe2O3 particle and the nanocomposite PVA/γ-Fe2O3 in different
concentrations a VSM test was conducted. To sum up, creating
magnetic nanocomposites with a spherical morphology that would be
employed for drug loading opens doors to new approaches in
developing nanocomposites that provide efficient heat and a
controlled release of drug simultaneously inside the magnetic field,
which are among their positive characteristics that could significantly
improve the recovery process in patients.
Abstract: This paper represents the results of experimental work to investigate the suitability of a waste material (WM) for soft soil stabilisation. In addition, the effect of particle size distribution (PSD) of the waste material on its performance as a soil stabiliser was investigated. The WM used in this study is produced from the incineration processes in domestic energy power plant and it is available in two different grades of fineness (coarse waste material (CWM) and fine waste material (FWM)). An intermediate plasticity silty clayey soil with medium organic matter content has been used in this study. The suitability of the CWM and FWM to improve the physical and engineering properties of the selected soil was evaluated dependant on the results obtained from the consistency limits, compaction characteristics (optimum moisture content (OMC) and maximum dry density (MDD)); along with the unconfined compressive strength test (UCS). Different percentages of CWM were added to the soft soil (3, 6, 9, 12 and 15%) to produce various admixtures. Then the UCS test was carried out on specimens under different curing periods (zero, 7, 14, and 28 days) to find the optimum percentage of CWM. The optimum and other two percentages (either side of the optimum content) were used for FWM to evaluate the effect of the fineness of the WM on UCS of the stabilised soil. Results indicated that both types of the WM used in this study improved the physical properties of the soft soil where the index of plasticity (IP) was decreased significantly. IP was decreased from 21 to 13.64 and 13.10 with 12% of CWM and 15% of FWM respectively. The results of the unconfined compressive strength test indicated that 12% of CWM was the optimum and this percentage developed the UCS value from 202kPa to 500kPa for 28 days cured samples, which is equal, approximately 2.5 times the UCS value for untreated soil. Moreover, this percentage provided 1.4 times the value of UCS for stabilized soil-CWA by using FWM which recorded just under 700kPa after 28 days curing.
Abstract: The aim of this investigation is to elaborate nearinfrared
methods for testing and recognition of chemical components
and quality in “Pannon wheat” allied (i.e. true to variety or variety
identified) milling fractions as well as to develop spectroscopic
methods following the milling processes and evaluate the stability of
the milling technology by different types of milling products and
according to sampling times, respectively. These wheat categories
produced under industrial conditions where samples were collected
versus sampling time and maximum or minimum yields. The changes
of the main chemical components (such as starch, protein, lipid) and
physical properties of fractions (particle size) were analysed by
dispersive spectrophotometers using visible (VIS) and near-infrared
(NIR) regions of the electromagnetic radiation. Close correlation
were obtained between the data of spectroscopic measurement
techniques processed by various chemometric methods (e.g. principal
component analysis [PCA], cluster analysis [CA]) and operation
condition of milling technology. It is obvious that NIR methods are
able to detect the deviation of the yield parameters and differences of
the sampling times by a wide variety of fractions, respectively. NIR
technology can be used in the sensitive monitoring of milling
technology.
Abstract: One of the main challenges in using the Discrete
Element Method (DEM) is to specify the correct input parameter
values. In general, the models are sensitive to the input parameter
values and accurate results can only be achieved if the correct values
are specified. For the linear contact model, micro-parameters such as
the particle density, stiffness, coefficient of friction, as well as the
particle size and shape distributions are required. There is a need for
a procedure to accurately calibrate these parameters before any
attempt can be made to accurately model a complete bulk materials
handling system. Since DEM is often used to model applications in
the mining and quarrying industries, a calibration procedure was
developed for materials that consist of relatively large (up to 40 mm
in size) particles. A coarse crushed aggregate was used as the test
material. Using a specially designed large shear box with a diameter
of 590 mm, the confined Young’s modulus (bulk stiffness) and
internal friction angle of the material were measured by means of the
confined compression test and the direct shear test respectively. DEM
models of the experimental setup were developed and the input
parameter values were varied iteratively until a close correlation
between the experimental and numerical results was achieved. The
calibration process was validated by modelling the pull-out of an
anchor from a bed of material. The model results compared well with
experimental measurement.
Abstract: Ulexite (Na2O.2CaO.5B2O3.16H2O) is boron mineral
that is found in large quantities in the Turkey and world. In this
study, the dissolution of this mineral in the disodium hydrogen
phosphate solutions has been studied. Temperature, concentration,
stirring speed, solid liquid ratio and particle size were selected as
parameters. The experimental results were successfully correlated by
linear regression using Statistica program. Dissolution curves were
evaluated shrinking core models for solid-fluid systems. It was
observed that increase in the reaction temperature and decrease in the
solid/liquid ratio causes an increase the dissolution rate of ulexite.
The activation energy was found to be 63.4 kJ/mol. The leaching of
ulexite was controlled by chemical reaction.
Abstract: This paper deals with the theoretical and numerical
investigation of magneto hydrodynamic boundary layer flow of a
nanofluid past a wedge shaped wick in heat pipe used for the cooling
of electronic components and different type of machines. To
incorporate the effect of nanoparticle diameter, concentration of
nanoparticles in the pure fluid, nanothermal layer formed around the
nanoparticle and Brownian motion of nanoparticles etc., appropriate
models are used for the effective thermal and physical properties of
nanofluids. To model the rotation of nanoparticles inside the base
fluid, microfluidics theory is used. In this investigation ethylene
glycol (EG) based nanofluids, are taken into account. The non-linear
equations governing the flow and heat transfer are solved by using a
very effective particle swarm optimization technique along with
Runge-Kutta method. The values of heat transfer coefficient are
found for different parameters involved in the formulation viz.
nanoparticle concentration, nanoparticle size, magnetic field and
wedge angle etc. It is found that, the wedge angle, presence of
magnetic field, nanoparticle size and nanoparticle concentration etc.
have prominent effects on fluid flow and heat transfer characteristics
for the considered configuration.
Abstract: Properties of Portland cement mixtures with various
fractions of metakaolin were studied. 10% of Portland cement CEM I
42.5 R was replaced by different fractions of high reactivity
metakaolin with defined chemical and mineralogical properties.
Various fractions of metakaolin were prepared by jet mill classifying
system. There is a clear trend between fineness of metakaolin and
hydration heat development. Due to metakaolin presence in mixtures
the compressive strength development of mortars is rather slower for
coarser fractions but 28-day flexural strengths are improved for all
fractions of metakaoline used in mixtures compared to reference
sample of pure Portland cement. Yield point, plastic viscosity and
adhesion of fresh pastes are considerably influenced by fineness of
metakaolin used in cement pastes.
Abstract: Over the past four decades, the fatigue behavior of
nickel-based alloys has been widely studied. However, in recent
years, significant advances in the fabrication process leading to grain
size reduction have been made in order to improve fatigue properties
of aircraft turbine discs. Indeed, a change in particle size affects the
initiation mode of fatigue cracks as well as the fatigue life of the
material. The present study aims to investigate the fatigue behavior of
a newly developed nickel-based superalloy under biaxial-planar
loading. Low Cycle Fatigue (LCF) tests are performed at different
stress ratios so as to study the influence of the multiaxial stress state
on the fatigue life of the material. Full-field displacement and strain
measurements as well as crack initiation detection are obtained using
Digital Image Correlation (DIC) techniques. The aim of this
presentation is first to provide an in-depth description of both the
experimental set-up and protocol: the multiaxial testing machine, the
specific design of the cruciform specimen and performances of the
DIC code are introduced. Second, results for sixteen specimens
related to different load ratios are presented. Crack detection, strain
amplitude and number of cycles to crack initiation vs. triaxial stress
ratio for each loading case are given. Third, from fractographic
investigations by scanning electron microscopy it is found that the
mechanism of fatigue crack initiation does not depend on the triaxial
stress ratio and that most fatigue cracks initiate from subsurface
carbides.
Abstract: This study was developed to compare the behavior
and the ability of polymer foam composites towards sound absorption
test of Shorea leprosula wood (SL) of acid hydrolysis treatment with
particle size
Abstract: Collection of storm water runoff and forcing it into the
groundwater is the need of the hour to sustain the ground water table.
However, the runoff entraps various types of sediments and other
floating objects whose removal are essential to avoid pollution of
ground water and blocking of pores of aquifer. However, it requires
regular cleaning and maintenance due to problem of clogging. To
evaluate the performance of filter system consisting of coarse sand
(CS), gravel (G) and pebble (P) layers, a laboratory experiment was
conducted in a rectangular column. The effect of variable thickness
of CS, G and P layers of the filtration unit of the recharge shaft on the
recharge rate and the sediment concentration of effluent water were
evaluated.
Medium sand (MS) of three particle sizes, viz. 0.150–0.300 mm
(T1), 0.300–0.425 mm (T2) and 0.425–0.600 mm of thickness 25 cm,
30 cm and 35 cm respectively in the top layer of the filter system and
having seven influent sediment concentrations of 250–3,000 mg/l
were used for experimental study. The performance was evaluated in
terms of recharge rates and clogging time. The results indicated that
100 % suspended solids were entrapped in the upper 10 cm layer of
MS, the recharge rates declined sharply for influent concentrations of
more than 1,000 mg/l. All treatments with higher thickness of MS
media indicated recharge rate slightly more than that of all treatment
with lower thickness of MS media respectively. The performance of
storm water infiltration systems was highly dependent on the
formation of a clogging layer at the filter. An empirical relationship
has been derived between recharge rates, inflow sediment load, size
of MS and thickness of MS with using MLR.
Abstract: For the treatment of acute and chronic lung diseases it is preferred to deliver medicaments by inhalation. The drug is delivered directly to tracheobronchial tree. This way allows the given medicament to get directly into the place of action and it makes rapid onset of action and maximum efficiency. The transport of aerosol particles in the particular part of the lung is influenced by their size, anatomy of the lungs, breathing pattern and airway resistance. This article deals with calculation of airway resistance in the lung model of Horsfield. It solves the problem of determination of the pressure losses in bifurcation and thus defines the pressure drop at a given location in the bronchial tree. The obtained data will be used as boundary conditions for transport of aerosol particles in a central part of bronchial tree realized by Computational Fluid Dynamics (CFD) approach. The results obtained from CFD simulation will allow us to provide information on the required particle size and optimal inhalation technique for particle transport into particular part of the lung.
Abstract: Risperidone (RISP) is an antipsychotic agent and has
low water solubility and nontargeted delivery results in numerous
side effects. Hence, an attempt was made to develop SLNs hydrogel
for intranasal delivery of RISP to achieve maximum bioavailability
and reduction of side effects. RISP loaded SLNs composed of 1.65%
(w/v) lipid mass were produced by high shear homogenization (HSH)
coupled ultrasound (US) method using glycerylmonostearate (GMS)
or Imwitor 900K (solid lipid). The particles were loaded with 0.2%
(w/v) of the RISP & surface-tailored with a 2.02% (w/v) non-ionic
surfactant Tween® 80. Optimization was done using 32 factorial
design using Design Expert® software. The prepared SLNs
dispersion incorporated into Polycarbophil AA1 hydrogel (0.5%
w/v). The final gel formulation was evaluated for entrapment
efficiency, particle size, rheological properties, X ray diffraction, in
vitro diffusion, ex vivo permeation using sheep nasal mucosa and
histopathological studies for nasocilliary toxicity. The entrapment
efficiency of optimized SLNs was found to be 76 ± 2%,
polydispersity index
Abstract: Complexation of anthocyanins to mimic natural
copigmentation process was investigated. Cyanidin-rich extracts from
Zea mays L. ceritina Kulesh. and delphinidin-rich extracts from
Clitoria ternatea L. were used to form 4 anthocyanin complexes,
AC1, AC2, AC3 and AC4, in the presence of several polyphenols and
a trace metal. Characterizations of the ACs were conducted by UV,
FTIR, DSC/TGA and morphological observations. Bathochromic
shifts of the UV spectra of 4 formulas of ACs were observed at peak
wavelengths of about 510-620 nm by 10 nm suggesting complex
formation. FTIR spectra of the ACs indicate shifts of peaks from
1,733 cm-1 to 1,696 cm-1 indicating interactions and a decrease in the
peak areas within the wavenumber of 3,400-3,500 cm-1 indicating
changes in hydrogen bonding. Thermal analysis of all of the ACs
suggests increases in melting temperature after complexation. AC
with the highest melting temperature was morphologically observed
by SEM and TEM to be crystal-like particles within a range of 50 to
200 nm. Particle size analysis of the AC by laser diffraction gave a
range of 50-600 nm, indicating aggregation. This AC was shown to
have no cytotoxic effect on cultured HGEPp0.5 and HGF (all p>
0.05) by MTT. Therefore, complexation of anthocyanins was simple
and self-assembly process, potentially resulting in nanosized particles
of anthocyanin complex.
Abstract: In recent years, the compression of date (Phoenix
dactylifera L.) fruit powders (DP) to obtain date tablets (DT) has
been suggested as a promising form of valorization of non
commercial valuable date fruit (DF) varieties. To further improve
and characterize DT, the present study aims to investigate the
influence of the DP particle size and compression force on some
physical properties of DT. The results show that independently of
particle size, the hardness (y) of tablets increases with the increase of
the compression force (x) following a logarithmic law (y = a ln (bx)
where a and b are the constants of model). Further, a full factorial
design (FFD) at two levels, applied to investigate the erosion %,
reveals that the effects of time and particle size are the same in
absolute value and they are beyond the effect of the compression.
Regarding the disintegration time, the obtained results also by means
of a FFD show that the effect of the compression force exceeds 4
times that of the DP particle size. As final stage, the color parameters
in the CIELab system of DT immediately after their obtaining are
differently influenced by the size of the initial powder.
Abstract: The paper involves a chain of activities from
synthesis, establishment of the methodology for characterization and
testing of novel protective materials through the pilot production and
application on model supports.
It summarizes the results regarding the development of the pilot
production protocol for newly developed self-cleaning materials. The
optimization of the production parameters was completed in order to
improve the most important functional properties (mineralogy
characteristics, particle size, self-cleaning properties and
photocatalytic activity) of the newly designed nanocomposite
material.
Abstract: Nanocrystalline powders of the lead-free piezoelectric
material, tantalum-substituted potassium sodium niobate
(K0.5Na0.5)(Nb0.9Ta0.1)O3 (KNNT), were produced using a Retsch
PM100 planetary ball mill by setting the milling time to 15h, 20h,
25h, 30h, 35h and 40h, at a fixed speed of 250rpm. The average
particle size of the milled powders was found to decrease from 12nm
to 3nm as the milling time increases from 15h to 25h, which is in
agreement with the existing theoretical model. An anomalous
increase to 98nm and then a drop to 3nm in the particle size were
observed as the milling time further increases to 30h and 40h
respectively. Various sizes of these starting KNNT powders were
used to investigate the effect of milling time on the microstructure,
dielectric properties, phase transitions and piezoelectric properties of
the resulting KNNT ceramics. The particle size of starting KNNT
was somewhat proportional to the grain size. As the milling time
increases from 15h to 25h, the resulting ceramics exhibit
enhancement in the values of relative density from 94.8% to 95.8%,
room temperature dielectric constant (εRT) from 878 to 1213, and
piezoelectric charge coefficient (d33) from 108pC/N to 128pC/N. For
this range of ceramic samples, grain size refinement suppresses the
maximum dielectric constant (εmax), shifts the Curie temperature (Tc)
to a lower temperature and the orthorhombic-tetragonal phase
transition (Tot) to a higher temperature. Further increase of milling
time from 25h to 40h produces a gradual degradation in the values of
relative density, εRT, and d33 of the resulting ceramics.
Abstract: Yttrium oxide (Y2O3) films have been successfully
deposited with yttrium-ethylenediamine tetraacetic acid (EDTA·Y·H)
complexes prepared by various milling techniques. The effects of the
properties of the EDTA·Y·H complex on the properties of the
deposited Y2O3 films have been analyzed. Seven different types of the
raw EDTA·Y·H complexes were prepared by various commercial
milling techniques such as ball milling, hammer milling, commercial
milling, and mortar milling. The milled EDTA·Y·H complexes
exhibited various particle sizes and distributions, depending on the
milling method. Furthermore, we analyzed the crystal structure,
morphology and elemental distribution profile of the metal oxide films
deposited on stainless steel substrate with the milled EDTA·Y·H
complexes. Depending on the milling technique, the flow properties of
the raw powders differed. The X-ray diffraction pattern of all the
samples revealed the formation of Y2O3 crystalline phase, irrespective
of the milling technique. Of all the different milling techniques, the
hammer milling technique is considered suitable for fabricating dense
Y2O3 films.
Abstract: Powder metallurgy (P/M) is the only economic way to
produce porous parts/products. P/M can produce near net shape parts
hence reduces wastage of raw material and energy, avoids various
machining operations. The most vital use of P/M is in production of
metallic filters and self lubricating bush bearings and siding surfaces.
The porosity of the part can be controlled by varying compaction
pressure, sintering temperature and composition of metal powder
mix. The present work is aimed for experimental analysis of friction
and wear properties of self lubricating copper and tin bush bearing.
Experimental results confirm that wear rate of sintered component
is lesser for components having 10% tin by weight percentage. Wear
rate increases for high tin percentage (experimented for 20% tin and
30% tin) at same sintering temperature. Experimental results also
confirms that wear rate of sintered component is also dependent on
sintering temperature, soaking period, composition of the preform,
compacting pressure, powder particle shape and size.
Interfacial friction between die and punch, between inter powder
particles, between die face and powder particle depends on
compaction pressure, powder particle size and shape, size and shape
of component which decides size & shape of die & punch, material of
die & punch and material of powder particles.