Abstract: A Finite Element (FE) based scheme is presented
for quantifying guided wave interaction with Localised Nonlinear
Structural Damage (LNSD) within structures of arbitrary layering
and geometric complexity. The through-thickness mode-shape of the
structure is obtained through a wave and finite element method. This
is applied in a time domain FE simulation in order to generate
time harmonic excitation for a specific wave mode. Interaction of
the wave with LNSD within the system is computed through an
element activation and deactivation iteration. The scheme is validated
against experimental measurements and a WFE-FE methodology for
calculating wave interaction with damage. Case studies for guided
wave interaction with crack and delamination are presented to verify
the robustness of the proposed method in classifying and identifying
damage.
Abstract: Polyoxymethylene dimethyl ethers (PODEn) as clean diesel additive can improve the combustion efficiency and quality of diesel fuel and alleviate the problem of atmospheric pollution. Considering synthetic routes, PODE production from methanol and formaldehyde is regarded as the most economical and promising synthetic route. However, methanol used for synthesizing PODE can produce water, which causes the loss of active center of catalyst and hydrolysis of PODEn in the production process. Macroporous strong acidic cation exchange resin catalyst was prepared, which has comparative advantages over other common solid acid catalysts in terms of stability and catalytic efficiency for synthesizing PODE. Catalytic reactions were carried out under 353 K, 1 MPa and 3mL·gcat-1·h-1 in a fixed bed reactor. Methanol conversion and PODE3-6 selectivity reached 49.91% and 23.43%, respectively. Catalyst lifetime evaluation showed that resin catalyst retained its catalytic activity for 20 days without significant changes and catalytic activity of completely deactivated resin catalyst can basically return to previous level by simple acid regeneration. The acid exchange capacities of original and deactivated catalyst were 2.5191 and 0.0979 mmol·g-1, respectively, while regenerated catalyst reached 2.0430 mmol·g-1, indicating that the main reason for resin catalyst deactivation is that Brønsted acid sites of original resin catalyst were temporarily replaced by non-hydrogen ion cations. A separation process consisting of extraction and distillation for PODE3-6 product was designed for separation of water and unreacted formaldehyde from reactive mixture and purification of PODE3-6, respectively. The concentration of PODE3-6 in final product can reach up to 97%. These results indicate that the scale-up production of PODE3-6 from methanol and formaldehyde solution is feasible.
Abstract: Catalysts play an important role in producing valuable fuel products in petroleum refining; but, due to feedstock’s impurities catalyst gets deactivated with carbon and metal deposition. The disposal of spent catalyst falls under the category of hazardous industrial waste that requires strict agreement with environmental regulations. The spent hydroprocessing catalyst contains Mo, V and Ni at high concentrations that have been found to be economically significant for recovery. Metal recovery process includes deoiling, decoking, grinding, dissolving and treatment with complexing leaching agent such as ethylene diamine tetra acetic acid (EDTA). The process conditions have been optimized as a function of time, temperature and EDTA concentration in presence of ultrasonic agitation. The results indicated that optimum condition established through this approach could recover 97%, 94% and 95% of the extracted Mo, V and Ni, respectively, while 95% EDTA was recovered after acid treatment.
Abstract: This work studied the isomerization of 1-butene over
hydrotalcite catalyst. The experiments were conducted at various gas
hourly space velocity (GHSV), reaction temperature and feed
concentration. No catalyst deactivation was observed over the
reaction time of 16 hours. Two major reaction products were trans-2-
butene and cis-2-butene. The reaction temperature played an
important role on the reaction selectivity. At high operating
temperatures, the selectivity of trans-2-butene was higher than the
selectivity of cis-2-butene while it was opposite at lower reaction
temperature. In the range of operating condition, the maximum
conversion of 1-butene was found at 74% when T = 673 K and GHSV
= 4 m3/h/kg-cat with trans- and cis-2-butene selectivities of 54% and
46%, respectively. Finally, the kinetic parameters of the reaction
were determined.
Abstract: Ni-based catalysts with different amounts of Na as
promoter from 2 to 6 wt % were prepared by solution combustion
method. The catalytic activity was investigated in syngas methanation
reaction. Carbon oxides conversion and methane selectivity are greatly
influenced by sodium loading. Adding 2 wt% Na remarkably improves
catalytic activity and long-term stability, attributed to its smaller mean
NiO particle size, better distribution, and milder metal-support
interaction. However, excess addition of Na results in deactivation
distinctly due to the blockage of active sites.
Abstract: In industrial scale of Gas to Liquid (GTL) process in
Fischer-Tropsch (FT) synthesis, a part of reactor outlet gases such as
CO2 and CH4 as side reaction products, is usually recycled. In this
study, the influence of CO2 and CH4 on the performance and
selectivity of Co-Ru/Al2O3 catalyst is investigated by injection of
these gases (0-20 vol. % of feed) to the feed stream. The effect of
temperature and feed flow rate, are also inspected. The results show
that low amounts of CO2 in the feed stream, doesn`t change the
catalyst activity significantly but increasing the amount of CO2 (more
than 10 vol. %) cause the CO conversion to decrease and the
selectivity of heavy components to increase. Methane acts as an inert
gas and doesn`t affect the catalyst performance. Increasing feed flow
rate has negative effect on both CO conversion and heavy component
selectivity. By raising the temperature, CO conversion will increase
but there are more volatile components in the product. The effect of
CO2 on the catalyst deactivation is also investigated carefully and a
mechanism is suggested to explain the negative influence of CO2 on
catalyst deactivation.
Abstract: The Ni/α-Al2O3 catalysts with different amounts of La
as promoter from 0 to 4 wt % were prepared, characterized and their
catalytic activity was investigated in syngas methanation reaction.
Effects of reaction temperature and lanthanum loading on carbon
oxides conversion and methane selectivity were also studied. Adding
certain amount of lanthanum to 10Ni /α-Al2O3 catalysts can decrease
the average NiO crystallite diameter which leads to higher activity and
stability while excessive addition would cause deactivation quickly.
Stability on stream towards deactivation was observed up to 800 min
at 500 °C, 0.1MPa and 600000 mL·g-1·h-1.
Abstract: The catalytic dehydroxylation of glycerol to propylene
glycol was investigated over Cu-ZnO/Al2O3 prepared by incipient
wetness impregnation (IWI) method with different purity feedstocks -
refined glycerol and technical grade glycerol. The main purpose is to
investigate the effects of feed impurities that cause the catalyst
deactivation. The prepared catalyst were tested for its catalytic
activity and selectivity in a continuous flow fixed bed reactor at 523
K, 500 psig, H2/feed molar ratio of 4 and WHSV of 3 h-1. The results
showed that conversion of refined glycerol and technical grade
glycerol at time on stream 6 hour are 99% and 71% and selectivity to
propylene glycol are 87% and 56% respectively. The ICP-EOS and
TPO results indicated that the cause of catalyst deactivation was the
amount of impurities in the feedstock. The higher amount of
impurities (especially Na and K) the lower catalytic activity.
Abstract: A four element prototype phased array surface probe
has been designed and constructed to improve clinical human
prostate spectroscopic data. The probe consists of two pairs of
adjacent rectangular coils with an optimum overlap to reduce the
mutual inductance. The two pairs are positioned on the anterior and
the posterior pelvic region and two couples of varactors at the input
of each coil undertake the procedures of tuning and matching. The
probe switches off and on automatically during the consecutive
phases of the MR experiment with the use of an analog switch that is
triggered by a microcontroller. Experimental tests that were carried
out resulted in high levels of tuning accuracy. Also, the switching
mechanism functions properly for various applied loads and pulse
sequence characteristics, producing only 10 μs of latency.
Abstract: The paper relates to a catalyst, comprising copperchromium
spinel, coated on carrier γ-Al2O3. The effect of preparation
conditions on the active component composition and activity
behavior of the catalysts is discussed. It was found that the activity of
carbon monoxide, DME, formaldehyde and methanol oxidation
reaches a maximum at an active component content of 20 – 30 wt. %.
Temperature calcination at 500oC seems to be optimal for the γ–
alumina supported CuO-Cr2O3 catalysts for CO, DME, formaldehyde
and methanol oxidation. A three months industrial experiment was
carried out to elucidate the changes in the catalyst composition
during industrial exploitation of the catalyst and the main reasons for
catalyst deactivation.
It was concluded that the CuO–Cr2O3/γ–alumina supported
catalysts have enhanced activity toward CO, DME, formaldehyde
and methanol oxidation and that these catalysts are suitable for
industrial application. The main reason for catalyst deactivation
seems to be the deposition of iron and molybdenum, coming from the
main reactor, on the active component surface.
Abstract: Passive systems were born with the purpose of the
greatest exploitation of solar energy in cold climates and high
altitudes. They spread themselves until the 80-s all over the world
without any attention to the specific climate and the summer
behavior; this caused the deactivation of the systems due to a series
of problems connected to the summer overheating, the complex
management and the rising of the dust.
Until today the European regulation limits only the winter
consumptions without any attention to the summer behavior but, the
recent European EN 15251 underlines the relevance of the indoor
comfort, and the necessity of the analytic studies validation by
monitoring case studies.
In the porpose paper we demonstrate that the solar wall is an
efficient system both from thermal comfort and energy saving point
of view and it is the most suitable for our temperate climates because
it can be used as a passive cooling sistem too. In particular the paper
present an experimental and numerical analisys carried out on a case
study with nine different solar passive systems in Ancona, Italy.
We carried out a detailed study of the lodging provided by the
solar wall by the monitoring and the evaluation of the indoor
conditions.
Analyzing the monitored data, on the base of recognized models
of comfort (ISO, ASHRAE, Givoni-s BBCC), is emerged that the
solar wall has an optimal behavior in the middle seasons. In winter
phase this passive system gives more advantages in terms of energy
consumptions than the other systems, because it gives greater heat
gain and therefore smaller consumptions. In summer, when outside
air temperature return in the mean seasonal value, the indoor comfort
is optimal thanks to an efficient transversal ventilation activated from
the same wall.
Abstract: Pentachlorophenol (PCP) is a polychlorinated
aromatic compound that is widespread in industrial effluents and is
considered to be a serious pollutant. Among the variety of industrial
effluents encountered, effluents from tanning industry are very
important and have a serious pollution potential. PCP is also formed
unintentionally in effluents of paper and pulp industries. It is highly
persistent in soils and is lethal to a wide variety of beneficial
microorganisms and insects, human beings and animals. The natural
processes that breakdown toxic chemicals in the environment have
become the focus of much attention to develop safe and environmentfriendly
deactivation technologies. Microbes and plants are among
the most important biological agents that remove and degrade waste
materials to enable their recycling in the environment. The present
investigation was carried out with the aim of developing a microbial
system for bioremediation of PCP polluted soils. A number of plant
species were evaluated for their ability to tolerate different
concentrations of pentachlorophenol (PCP) in the soil. The
experiment was conducted for 30 days under pot culture conditions.
The toxic effect of PCP on plants was studied by monitoring seed
germination, plant growth and biomass. As the concentration of PCP
was increased to 50 ppm, the inhibition of seed germination, plant
growth and biomass was also increased. Although PCP had a
negative effect on all plant species tested, maize and groundnut
showed the maximum tolerance to PCP. Other tolerating crops
included wheat, safflower, sunflower, and soybean. From the
rhizosphere soil of the tolerant seedlings, as many as twenty seven
PCP tolerant bacteria were isolated. From soybean, 8; sunflower, 3;
safflower 8; maize 2; groundnut and wheat, 3 each isolates were
made. They were screened for their PCP degradation potentials.
HPLC analyses of PCP degradation revealed that the isolate MAZ-2
degraded PCP completely. The isolate MAZ-1 was the next best
isolate with 90 per cent PCP degradation. These strains hold promise
to be used in the bioremediation of PCP polluted soils.
Abstract: Modeling of a heterogeneous industrial fixed bed
reactor for selective dehydrogenation of heavy paraffin with Pt-Sn-
Al2O3 catalyst has been the subject of current study. By applying
mass balance, momentum balance for appropriate element of reactor
and using pressure drop, rate and deactivation equations, a detailed
model of the reactor has been obtained. Mass balance equations have
been written for five different components. In order to estimate
reactor production by the passage of time, the reactor model which is
a set of partial differential equations, ordinary differential equations
and algebraic equations has been solved numerically.
Paraffins, olefins, dienes, aromatics and hydrogen mole percent as
a function of time and reactor radius have been found by numerical
solution of the model. Results of model have been compared with
industrial reactor data at different operation times. The comparison
successfully confirms validity of proposed model.
Abstract: In the present study, a procedure was developed to
determine the optimum reaction rate constants in generalized
Arrhenius form and optimized through the Nelder-Mead method. For
this purpose, a comprehensive mathematical model of a fixed bed
reactor for dehydrogenation of heavy paraffins over Pt–Sn/Al2O3
catalyst was developed. Utilizing appropriate kinetic rate expressions
for the main dehydrogenation reaction as well as side reactions and
catalyst deactivation, a detailed model for the radial flow reactor was
obtained. The reactor model composed of a set of partial differential
equations (PDE), ordinary differential equations (ODE) as well as
algebraic equations all of which were solved numerically to
determine variations in components- concentrations in term of mole
percents as a function of time and reactor radius. It was demonstrated
that most significant variations observed at the entrance of the bed
and the initial olefin production obtained was rather high. The
aforementioned method utilized a direct-search optimization
algorithm along with the numerical solution of the governing
differential equations. The usefulness and validity of the method was
demonstrated by comparing the predicted values of the kinetic
constants using the proposed method with a series of experimental
values reported in the literature for different systems.
Abstract: Social media has led to paradigm shifts in ways
people work and do business, interact and socialize, learn and obtain
knowledge. So much so that social media has established itself as an
important spatial extension of this nation-s historicity and challenges.
Regardless of the enabling reputation and recommendation features
through social networks embedded in the social media system, the
overflow of broadcasted and publicized media contents turns the
table around from engendering trust to doubting the trust system.
When the trust is at doubt, the effects include deactivation of
accounts and creation of multiple profiles, which lead to the overflow
of 'ghost' contents (i.e. “the abundance of abandoned ships"). In
most literature, the study of trust can be related to culture; hence the
difference between Western-s “openness" and Eastern-s “blue-chip"
concepts in networking and relationships. From a survey on issues
and challenges among Malaysian social media users, 'authenticity'
emerges as one of the main factors that causes and is caused by other
factors. The other issue that has surfaced is credibility either in terms
of message/content and source. Another is the quality of the
knowledge that is shared. This paper explores the terrains of this
critical space which in recent years has been dominated increasingly
by, arguably, social networks embedded in the social media system,
the overflow of broadcasted and publicized media content.
Abstract: Palladium-catalyzed hydrodechlorination is a
promising alternative for the treatment of environmentally relevant
water bodies, such as groundwater, contaminated with chlorinated
organic compounds (COCs). In the aqueous phase
hydrodechlorination of COCs, Pd-based catalysts were found to have
a very high catalytic activity. However, the full utilization of the
catalyst-s potential is impeded by the sensitivity of the catalyst to
poisoning and deactivation induced by reduced sulfur compounds
(e.g. sulfides). Several regenerants have been tested before to recover
the performance of sulfide-fouled Pd catalyst. But these only
delivered partial success with respect to re-establishment of the
catalyst activity. In this study, the deactivation behaviour of
Pd/Al2O3 in the presence of sulfide was investigated. Subsequent to
total deactivation the catalyst was regenerated in the aqueous phase
using potassium permanganate. Under neutral pH condition,
oxidative regeneration with permanganate delivered a slow recovery
of catalyst activity. However, changing the pH of the bulk solution to
acidic resulted in the complete recovery of catalyst activity within a
regeneration time of about half an hour. These findings suggest the
superiority of permanganate as regenerant in re-activating Pd/Al2O3
by oxidizing Pd-bound sulfide.
Abstract: Modeling and simulation of fixed bed three-phase
catalytic reactors are considered for wet air catalytic oxidation of
phenol to perform a comparative numerical analysis between tricklebed
and packed-bubble column reactors. The modeling involves
material balances both for the catalyst particle as well as for different
fluid phases. Catalyst deactivation is also considered in a transient
reactor model to investigate the effects of various parameters
including reactor temperature on catalyst deactivation. The
simulation results indicated that packed-bubble columns were
slightly superior in performance than trickle beds. It was also found
that reaction temperature was the most effective parameter in catalyst
deactivation.