Abstract: This work studied the isomerization of 1-butene over
hydrotalcite catalyst. The experiments were conducted at various gas
hourly space velocity (GHSV), reaction temperature and feed
concentration. No catalyst deactivation was observed over the
reaction time of 16 hours. Two major reaction products were trans-2-
butene and cis-2-butene. The reaction temperature played an
important role on the reaction selectivity. At high operating
temperatures, the selectivity of trans-2-butene was higher than the
selectivity of cis-2-butene while it was opposite at lower reaction
temperature. In the range of operating condition, the maximum
conversion of 1-butene was found at 74% when T = 673 K and GHSV
= 4 m3/h/kg-cat with trans- and cis-2-butene selectivities of 54% and
46%, respectively. Finally, the kinetic parameters of the reaction
were determined.
Abstract: In the present research, the titanium-catalyzed
ethylene dimerization and more specifically, the concomitant byproducts
and polymer formation have been studied in the presence of 2,5-dimethoxytetrahydrofuran as an electron donor compound in the
combination with triethylaluminium (TEA) as activator. Then, we
added ethylene chlorobromide as a new efficient promoter to the
relevant catalyst system. Finally, the behavior of novel homogeneous
[Titanium tetrabutoxide (Ti(OC4H9)4)/2,5-dimethoxytetrahydrofuran/
TEA/ethylene chlorobromide] was investigated in the various
operating conditions for the optimum production of 1-butene. In the
optimum conditions, a very high ethylene conversion (almost 90.77
%), a relative high selectivity to 1-butene (79.00 %), yield of reaction equal to 71.70 % and a significant productivity (turnover frequency
equal to 1370 h-1) were achieved.