Abstract: Catalytic wet air oxidation (CWAO) is normally carried out at elevated temperature and pressure. This work investigates the potential of NiO-CeO2 nano-catalyst in CWAO of paper industry wastewater under milder operating conditions of 90 °C and 1 atm. The NiO-CeO2 nano-catalysts were synthesized by a simple co-precipitation method and characterized by X-ray diffraction (XRD), before and after use, in order to study any crystallographic change during experiment. The extent of metal-leaching from the catalyst was determined using the inductively coupled plasma optical emission spectrometry (ICP-OES). The catalytic activity of nano-catalysts was studied in terms of total organic carbon (TOC), adsorbable organic halides (AOX) and chlorophenolics (CHPs) removal. Interestingly, mixed oxide catalysts exhibited higher activity than the corresponding single-metal oxides. The maximum removal efficiency was achieved with Ce40Ni60 catalyst. The results indicate that the CWAO process is efficient in removing the priority organic pollutants from wastewater, as it exhibited up to 59% TOC, 55% AOX, and 54 % CHPs removal.
Abstract: Modeling and simulation of fixed bed three-phase
catalytic reactors are considered for wet air catalytic oxidation of
phenol to perform a comparative numerical analysis between tricklebed
and packed-bubble column reactors. The modeling involves
material balances both for the catalyst particle as well as for different
fluid phases. Catalyst deactivation is also considered in a transient
reactor model to investigate the effects of various parameters
including reactor temperature on catalyst deactivation. The
simulation results indicated that packed-bubble columns were
slightly superior in performance than trickle beds. It was also found
that reaction temperature was the most effective parameter in catalyst
deactivation.