Abstract: Cements, which are intrinsically brittle materials, can
exhibit a degree of pseudo-ductility when reinforced with a sufficient
volume fraction of a fibrous phase. This class of materials, called
Engineered Cement Composites (ECC) has the potential to be used in
future tunneling applications where a level of pseudo-ductility is
required to avoid brittle failures. However uncertainties remain
regarding mechanical performance. Previous work has focused on
comparatively thin specimens; however for future civil engineering
applications, it is imperative that the behavior in tension of thicker
specimens is understood. In the present work, specimens containing
cement powder and admixtures have been manufactured following
two different processes and tested in tension. Multiple matrix
cracking has been observed during tensile testing, leading to a
“strain-hardening" behavior, confirming the possible suitability of
ECC material when used as thick sections (greater than 50mm) in
tunneling applications.
Abstract: Protective coatings that resist oxide scale growth and
decrease chromium evaporation are necessary to make stainless steel
interconnect materials for long-term durable operation of solid oxide
fuel cells (SOFCs). In this study a layer of cobalt was electroplated
on the surface of AISI 441 ferritic stainless steel which is used in
solid oxide fuel cells for interconnect applications. The oxidation
behavior of coated substrates was studied as a function of time at
operating conditions of SOFCs. Cyclic oxidation has been also tested
at 800ºC for 100 cycles. Cobalt coating during isothermal oxidation
caused to the oxide growth resistance by limiting the outward
diffusion of Cr cation and the inward diffusion of oxygen anion.
Results of cyclic oxidation exhibited that coated substrates
demonstrate an excellent resistance against the spallation and
cracking.
Abstract: This work presents the experimental results obtained
at a pilot plant which works with a slow, wet and catalytic pyrolysis
process of dry fowl manure. This kind of process mainly consists in
the cracking of the organic matrix and in the following reaction of
carbon with water, which is either already contained in the organic
feed or added, to produce carbon monoxide and hydrogen. Reactions
are conducted in a rotating reactor maintained at a temperature of
500°C; the required amount of water is about 30% of the dry organic
feed. This operation yields a gas containing about 59% (on a volume
basis) of hydrogen, 17% of carbon monoxide and other products such
as light hydrocarbons (methane, ethane, propane) and carbon
monoxide in lesser amounts. The gas coming from the reactor can be
used to produce not only electricity, through internal combustion
engines, but also heat, through direct combustion in industrial
boilers. Furthermore, as the produced gas is devoid of both solid
particles and pollutant species (such as dioxins and furans), the
process (in this case applied to fowl manure) can be considered as an
optimal way for the disposal and the contemporary energetic
valorization of organic materials, in such a way that is not damaging
to the environment.
Abstract: Reinforced concrete has good durability and excellent structural performance. But there are cases of early deterioration due to a number of factors, one prominent factor being corrosion of steel reinforcement. The process of corrosion sets in due to ingress of moisture, oxygen and other ingredients into the body of concrete, which is unsound, permeable and absorbent. Cracks due to structural and other causes such as creep, shrinkage, etc also allow ingress of moisture and other harmful ingredients and thus accelerate the rate of corrosion. There are several interactive factors both external and internal, which lead to corrosion of reinforcement and ultimately failure of structures. Suitable addition of mineral admixture like silica fume (SF) in concrete improves the strength and durability of concrete due to considerable improvement in the microstructure of concrete composites, especially at the transition zone. Secondary reinforcement in the form of fibre is added to concrete, which provides three dimensional random reinforcement in the entire mass of concrete. Reinforced concrete beams of size 0.1 m X 0.15 m and length 1m have been cast using M 35 grade of concrete. The beams after curing process were subjected to corrosion process by impressing an external Direct Current (Galvanostatic Method) for a period of 15 days under stressed and unstressed conditions. The corroded beams were tested by applying two point loads to determine the ultimate load carrying capacity and cracking pattern and the results of specimens were compared with that of the companion specimens. Gravimetric method is used to quantify corrosion that has occurred.
Abstract: The nearly 21-year-old Jiujiang Bridge, which is suffering from uneven line shape, constant great downwarping of the main beam and cracking of the box girder, needs reinforcement and cable adjustment. It has undergone cable adjustment for twice with incomplete data. Therefore, the initial internal force state of the Jiujiang Bridge is identified as the key for the cable adjustment project. Based on parameter identification by means of static force test data, this paper suggests determining the initial internal force state of the cable-stayed bridge according to the cable force-displacement relationship parameter identification method. That is, upon measuring the displacement and the change in cable forces for twice, one can identify the parameters concerned by means of optimization. This method is applied to the cable adjustment, replacement and reinforcement project for the Jiujiang Bridge as a guidance for the cable adjustment and reinforcement project of the bridge.
Abstract: In hypersonic environments, the aerothermal effect
makes it difficult for the optical side windows of optical guided
missiles to withstand high heat. This produces cracking or breaking,
resulting in an inability to function. This study used computational
fluid mechanics to investigate the external cooling jet conditions of
optical side windows. The turbulent models k-ε and k-ω were
simulated. To be in better accord with actual aerothermal
environments, a thermal radiation model was added to examine
suitable amounts of external coolants and the optical window
problems of aero-thermodynamics. The simulation results indicate that
when there are no external cooling jets, because airflow on the optical
window and the tail groove produce vortices, the temperatures in these
two locations reach a peak of approximately 1600 K. When the
external cooling jets worked at 0.15 kg/s, the surface temperature of
the optical windows dropped to approximately 280 K. When adding
thermal radiation conditions, because heat flux dissipation was faster,
the surface temperature of the optical windows fell from 280 K to
approximately 260 K. The difference in influence of the different
turbulence models k-ε and k-ω on optical window surface temperature
was not significant.
Abstract: Post cracking behavior and load –bearing capacity of
the steel fiber reinforced high-strength concrete (SFRHSC) are
dependent on the number of fibers are crossing the weakest crack
(bridged the crack) and their orientation to the crack surface. Filling
the mould by SFRHSC, fibers are moving and rotating with the
concrete matrix flow till the motion stops in each internal point of the
concrete body. Filling the same mould from the different ends
SFRHSC samples with the different internal structures (and different
strength) can be obtained. Numerical flow simulations (using Newton
and Bingham flow models) were realized, as well as single fiber
planar motion and rotation numerical and experimental investigation
(in viscous flow) was performed. X-ray pictures for prismatic
samples were obtained and internal fiber positions and orientations
were analyzed. Similarly fiber positions and orientations in cracked
cross-section were recognized and were compared with numerically
simulated. Structural SFRHSC fracture model was created based on
single fiber pull-out laws, which were determined experimentally.
Model predictions were validated by 15x15x60cm prisms 4 point
bending tests.
Abstract: As the resources for naturally occurring aggregates
diminished at an ever increasing rate, researchers are keen to utilize
recycled materials in road construction in harmony with sustainable
development. Steel slag, a waste product from the steel making
industry, is one of the recycled materials reported to exhibit great
potential to replace naturally occurring aggregates in asphalt
mixtures. This paper presents the resilient modulus properties of
steel slag asphalt mixtures subjected to short term oven ageing
(STOA). The resilient modulus test was carried out to evaluate the
stiffness of asphalt mixtures at 10ºC, 25ºC and 40ºC. Previous
studies showed that stiffness changes in asphalt mixture played an
important role in inflicting pavement distress particularly cracking
and rutting that are common at low and high temperatures
respectively. Temperature was found to significantly influence the
resilient modulus of asphalt mixes. The resilient modulus of the
asphalt specimens tested decreased by more than 90% when the test
temperature increased from 10°C to 40°C.
Abstract: Sandwich panels are widely used in the construction
industry for their ease of assembly, light weight and efficient thermal
performance. They are composed of two RC thin outer layers
separated by an insulating inner layer. In this research the inner
insulating layer is made of lightweight Autoclaved Aerated Concrete
(AAC) blocks which has good thermal insulation properties and yet
possess reasonable mechanical strength. The shear strength of the
AAC infill is relied upon to replace the traditionally used insulating
foam and to provide the shear capacity of the panel. A
comprehensive experimental program was conducted on full scale
sandwich panels subjected to bending. In this paper, detailed
numerical modeling of the tested sandwich panels is reported. Nonlinear
3-D finite element modeling of the composite action of the
sandwich panel is developed using ANSYS. Solid elements with
different crashing and cracking capabilities and different constitutive
laws were selected for the concrete and the AAC. Contact interface
elements are used in this research to adequately model the shear
transfer at the interface between the different layers. The numerical
results showed good correlation with the experimental ones
indicating the adequacy of the model in estimating the loading
capacity of panels.
Abstract: The incidence of mechanical fracture of an
automobile piston rings prompted development of fracture analysis
method on this case. The three rings (two compression rings and one
oil ring) were smashed into several parts during the power-test (after
manufacturing the engine) causing piston and liner to be damaged.
The radial and oblique cracking happened on the failed piston rings.
The aim of the fracture mechanics simulations presented in this paper
was the calculation of particular effective fracture mechanics
parameters, such as J-integrals and stress intensity factors. Crack
propagation angles were calculated as well. Two-dimensional
fracture analysis of the first compression ring has been developed in
this paper using ABAQUS CAE6.5-1 software. Moreover, SEM
fractography was developed on fracture surfaces and is discussed in
this paper. Results of numerical calculations constitute the basis for
further research on real object.
Abstract: The steam cracking reactions are always accompanied with the formation of coke which deposits on the walls of the tubular reactors. The investigation has attempted to control catalytic coking by the applying aluminum, zinc and ceramic coating like aluminum-magnesium by thermal spray and pack cementation method. Rate of coke formation during steam cracking of naphtha has been investigated both for uncoated stainless steel (with different alloys) and metal coating constructed with thermal Spray and pack cementation method with metal powders of Aluminum, Aluminum-Magnesium, zinc, silicon, nickel and chromium. The results of the study show that passivating the surface of SS321 with a coating of Aluminum and Aluminum-Magnesium can significantly reduce the rate of coke deposition during naphtha pyrolysis. SEM and EDAX techniques (Philips XL Series) were used to examine the coke deposits formed by the metal-hydrocarbon reactions. Our objective was to separate the different stages by identifying the characteristic morphologies.
Abstract: This work aims to test the application of computational fluid dynamics (CFD) modeling to fixed bed catalytic cracking reactors. Studies of CFD with a fixed bed design commonly use a regular packing with N=2 to define bed geometry. CFD allows us to obtain a more accurate view of the fluid flow and heat transfer mechanisms present in fixed bed equipment. Naphtha was used as feedstock and the reactor length was 80cm. It is divided in three sections that catalyst bed packed in the middle section of the reactor. The reaction scheme was involved one primary reaction and 24 secondary reactions. Because of high CPU times in these simulations, parallel processing have been used. In this study the coke formation process in fixed bed and empty tube reactor was simulated and coke in these reactors are compared. In addition, the effect of steam ratio and feed flow rate on coke formation was investigated.
Abstract: The production of ethyl tert-butyl ether (ETBE) was
simulated through Aspen Plus. The objective of this work was to use
the simulation results to be an alternative platform for ETBE
production from naphtha cracking wastes for the industry to develop.
ETBE is produced from isobutylene which is one of the wastes in
naphtha cracking process. The content of isobutylene in the waste is
less than 30% weight. The main part of this work was to propose a
process to save the environment and to increase the product value by
converting a great majority of the wastes into ETBE. Various
processes were considered to determine the optimal production of
ETBE. The proposed process increased ETBE production yield by
100% from conventional process with the purity of 96% weight. The
results showed a great promise for developing this proposed process
in an industrial scale.
Abstract: In this paper are illustrated the principal aspects
connected with the numerical evaluation of thermal stress induced by high gradient temperature in the concrete beam. The reinforced concrete beam has many advantages over steel
beam, such as high resistance to high temperature, high resistance to thermal shock, Better resistance to fatigue and buckling, strong
resistance against, fire, explosion, etc.
The main drawback of the reinforced concrete beam is its poor resistance to tensile stresses. In order to investigate the thermal
induced tensile stresses, a numerical model of a transient thermal
analysis is presented for the evaluation of thermo-mechanical
response of concrete beam to the high temperature, taking into account the temperature dependence of the thermo physical properties of the concrete like thermal conductivity and specific heat.
Abstract: In the present research, steam cracking of two types of
feedstocks i.e., naphtha and ethane is simulated for Pyrocrack1-1 and
2/2 coil configurations considering two key parameters of coil outlet
temperature (COT) and coil capacity using a radical based kinetic
model. The computer model is confirmed using the industrial data
obtained from Amirkabir Petrochemical Complex. The results are in
good agreement with performance data for naphtha cracking in a
wide range of severity (0.4-0.7), and for ethane cracking on various
conversions (50-70). It was found that Pyrocrack2-2 coil type is an
appropriate choice for steam cracking of ethane at reasonable
ethylene yield while resulting in much lower tube wall temperature
while Pyrocrack1-1 coil type is a proper selection for liquid
feedstocks i.e. naphtha. It can be used for cracking of liquid
feedstocks at optimal ethylene yield whereas not exceeding the
allowable maximum tube temperature.
Abstract: The kinetics of palm oil catalytic cracking over
aluminum containing mesoporous silica Al-MCM-41 (5% Al) was
investigated in a batch autoclave reactor at the temperatures range of
573 – 673 K. The catalyst was prepared by using sol-gel technique
and has been characterized by nitrogen adsorption and x-ray
diffraction methods. Surface area of 1276 m2/g with average pore
diameter of 2.54 nm and pore volume of 0.811 cm3/g was obtained.
The experimental catalytic cracking runs were conducted using 50 g
of oil and 1 g of catalyst. The reaction pressure was recorded at
different time intervals and the data were analyzed using Levenberg-
Marquardt (LM) algorithm using polymath software. The results
show that the reaction order was found to be -1.5 and activation
energy of 3200 J/gmol.
Abstract: The dominant judgment for earthquake damaged reinforced concrete (RC) structures is to rebuild them with the new ones. Consequently, this paper estimates if there is chance to repair earthquake RC beams and obtain economical contribution to modern day society. Therefore, the totally damaged (damaged in shear under cyclic load) reinforced concrete (RC) beams repaired and strengthened by externally bonded carbon fibre reinforced polymer (CFRP) strips in this study. Four specimens, apart from the reference beam, were separated into two distinct groups. Two experimental beams in the first group primarily tested up to failure then appropriately repaired and strengthened with CFRP strips. Two undamaged specimens from the second group were not repaired but strengthened by the identical strengthening scheme as the first group for comparison. This study studies whether earthquake damaged RC beams that have been repaired and strengthened will validate similar strength and behavior to equally strengthened, undamaged RC beams. Accordingly, a strength correspondence according to strengthened specimens was acquired for the repaired and strengthened specimens. Test results confirmed that repair and strengthening, which were estimated in the experimental program, were effective for the specimens with the cracking patterns considered in the experimental program.
Abstract: Solidification cracking and hydrogen cracking are some defects generated in the fusion welding of ultrahigh carbon steels. However, friction stir welding (FSW) of such steels, being a solid-state technique, has been demonstrated to alleviate such problems encountered in traditional welding. FSW include different process parameters that must be carefully defined prior processing. These parameters included but not restricted to: tool feed, tool RPM, tool geometry, tool tilt angle. These parameters form a key factor behind avoiding warm holes and voids behind the tool and in achieving a defect-free weld. More importantly, these parameters directly affect the microstructure of the weld and hence the final mechanical properties of weld. For that, 3D finite element (FE) thermo-mechanical model was developed using DEFORM 3D to simulate FSW of carbon steel. At points of interest in the joint, tracking is done for history of critical state variables such as temperature, stresses, and strain rates. Typical results found include the ability to simulate different weld zones. Simulations predictions were successfully compared to experimental FSW tests. It is believed that such a numerical model can be used to optimize FSW processing parameters to favor desirable defect free weld with better mechanical properties.
Abstract: The objective of this work is to study the influence of the properties of the substrate on the retrofit (thin repair) of damaged concrete elements, with the SCC. Fluidity, principal characteristic of the SCC, would enable it to cover and adhere to the concrete to be repaired. Two aspects of repair are considered, the bond (Adhesion) and the tensile strength and the cracking. The investigation is experimental; It was conducted over test specimens made up of ordinary concrete prepared and hardened in advance (the material to be repaired) over which a self compacting concrete layer is cast. Three alternatives of SC concrete and one ordinary concrete (comparison) were tested. It appears that the self-compacting concrete constitutes a good material for repairing. It follows perfectly the surfaces- forms to be repaired and allows a perfect bond. Fracture tests made on specimens of self-compacting concrete show a brittle behaviour. However when a small percentage of fibres is added, the resistance to cracking is very much improve.
Abstract: This article presents the analysis of experimental values regarding cracking pattern, specific strains and deformability for reinforced high strength concrete beams. The beams have the concrete class C80/95 and a longitudinal reinforcement ratio of 2.01%, respectively 3.39%. The elements were subjected to flexure under static short-term and long-term loading. The experimental values are compared with calculation values using the design relationships according to Eurocode 2.