Abstract: Proof of controlling crack width is a basic condition
for securing suitable performance in serviceability limit state. The
cracking in concrete can occur at any time from the casting of time to
the years after the concrete has been set in place. Most codes struggle
with offering procedure for crack width calculation. There is lack in
availability of design charts for designers to compute crack width
with ease. The focus of the study is to utilize design charts and
parametric equations in calculating crack width with minimum error.
The paper contains a simplified procedure to calculate crack width
for reinforced concrete (RC) sections subjected to bending with axial
tensile force following the guidelines of Euro code [DS EN-1992-1-1
& DS EN-1992-1-2]. Numerical examples demonstrate the
application of the suggested procedure. Comparison with parallel
analytical tools supports the validity of result and show the
percentage deviation of crack width in both the procedures. The
technique is simple, user friendly and ready to evolve for a greater
spectrum of section sizes and materials.
Abstract: South Africa has some regions which are susceptible
to moderate seismic activity. A peak ground acceleration of between
0.1g and 0.15g can be expected in the southern parts of the Western
Cape. Unreinforced Masonry (URM) is commonly used as a
construction material for 2 to 5 storey buildings in underprivileged
areas in and around Cape Town. URM is typically regarded as the
material most vulnerable to damage when subjected to earthquake
excitation. In this study, a three-storey URM building was analysed
by applying seven earthquake time-histories, which can be expected
to occur in South Africa using a finite element approach.
Experimental data was used to calibrate the in- and out-of-plane
stiffness of the URM. The results indicated that tensile cracking of
the in-plane piers was the dominant failure mode. It is concluded that
URM buildings of this type are at risk of failure especially if
sufficient ductility is not provided. The results also showed that
connection failure must be investigated further.
Abstract: Stress Corrosion Crack (SCC) in pipeline is a type of
environmentally assisted cracking (EAC), since its discovery in 1965
as a possible cause of failure in pipeline, SCC has caused, on
average, one of two failures per year in the U.S, According to the
NACE SCC DA a pipe line segment is considered susceptible to SCC
if all of the following factors are met: The operating stress exceeds
60% of specified minimum yield strength (SMYS), the operating
temperature exceeds 38°C, the segment is less than 32 km
downstream from a compressor station, the age of the pipeline is
greater than 10 years and the coating type is other than Fusion
Bonded Epoxy(FBE). In this paper as a practical experience in
NISOC, Direct Assessment (DA) Method is used for identification
SCC defect in unpiggable pipeline located downstream of
compressor station.
Abstract: Concerns on corrosion and effective coating
protection of double hull tankers and bulk carriers in service have
been raised especially in water ballast tanks (WBTs). Test
protocols/methodologies specifically that which is incorporated in the
International Maritime Organisation (IMO), Performance Standard
for Protective Coatings for Dedicated Sea Water ballast tanks (PSPC)
are being used to assess and evaluate the performance of the coatings
for type approval prior to their application in WBTs. However, some
of the type approved coatings may be applied as very thick films to
less than ideally prepared steel substrates in the WBT. As such films
experience hygrothermal cycling from operating and environmental
conditions, they become embrittled which may ultimately result in
cracking. This embrittlement of the coatings is identified as an
undesirable feature in the PSPC but is not mentioned in the test
protocols within it. There is therefore renewed industrial research
aimed at understanding this issue in order to eliminate cracking and
achieve the intended coating lifespan of 15 years in good condition.
This paper will critically review test protocols currently used for
assessing and evaluating coating performance, particularly the IMO
PSPC.
Abstract: Outrigger-braced wall systems are commonly used to provide high rise buildings with the required lateral stiffness for wind and earthquake resistance. The existence of outriggers adds to the stiffness and strength of walls as reported by several studies. The effects of different parameters on the elasto-plastic dynamic behavior of outrigger-braced wall systems to earthquakes are investigated in this study. Parameters investigated include outrigger stiffness, concrete strength, and reinforcement arrangement as the main design parameters in wall design. In addition to being significantly affect the wall behavior, such parameters may lead to the change of failure mode and the delay of crack propagation and consequently failure as the wall is excited by earthquakes. Bi-linear stress-strain relation for concrete with limited tensile strength and truss members with bi-linear stress-strain relation for reinforcement were used in the finite element analysis of the problem. The famous earthquake record, El-Centro, 1940 is used in the study. Emphasize was given to the lateral drift, normal stresses and crack pattern as behavior controlling determinants. Results indicated significant effect of the studied parameters such that stiffer outrigger, higher grade concrete and concentrating the reinforcement at wall edges enhance the behavior of the system. Concrete stresses and cracking behavior are too much enhanced while less drift improvements are observed.
Abstract: Catalytic cracking of butene to propylene was carried out in a continuous-flow fixed-bed reactor over HZSM-5 catalysts modified by nickel and phosphorus. The structure and acidity of catalysts were measured by N2 adsorption, NH3-TPD and XPS. The results revealed that surface area and strong acid sites both decreased with increasing phosphorus loadings. The increment of phosphorus loadings reduced the butene conversion but enhanced the propylene selectivity and catalyst stability.
Abstract: This work details the generation of thin films of
structured zeolite catalysts (ZSM–5 and Y) onto the surface of a
metal substrate (FeCrAlloy) using in-situ hydrothermal synthesis. In
addition, the zeolite Y is post-synthetically modified by acidified
ammonium ion exchange to generate US-Y. Finally the catalytic
activity of the structured ZSM-5 catalyst films (Si/Al = 11, thickness
146 0m) and structured US–Y catalyst film (Si/Al = 8, thickness
230m) were compared with the pelleted powder form of ZSM–5 and
USY catalysts of similar Si/Al ratios.
The structured catalyst films have been characterised using a range
of techniques, including X-ray diffraction (XRD), Electron
microscopy (SEM), Energy Dispersive X–ray analysis (EDX) and
Thermogravimetric Analysis (TGA). The transition from oxide-onalloy
wires to hydrothermally synthesised uniformly zeolite coated
surfaces was followed using SEM and XRD. In addition, the
robustness of the prepared coating was confirmed by subjecting these
to thermal cycling (ambient to 550oC).
The cracking of n–heptane over the pellets and structured catalysts
for both ZSM–5 and Y zeolite showed very similar product
selectivities for similar amounts of catalyst with an apparent
activation energy of around 60 kJ mol-1. This paper demonstrates that
structured catalysts can be manufactured with excellent zeolite
adherence and when suitably activated/modified give comparable
cracking results to the pelleted powder forms. These structured
catalysts will improve temperature distribution in highly exothermic
and endothermic catalysed processes.
Abstract: This paper present a mechanical characteristics on fatigue crack propagation in Aluminium Plate based on strain and stress distribution using the abaqus software. The changes in shear strain and stress distribution during the fatigue cycle with crack growth is identified. In progressive crack in the strain distribution and the stress is increase in the critical zone. Numerical Modal analysis of the model developed, prove that the Eigen frequencies of aluminium plate were decreased after cracking, and this reduce is nonlinear. These results can provide a reference for analysts and designers of aluminium alloys in aeronautical systems.
Therefore, the modal analysis is an important factor for monitoring the aeronautic structures.
Abstract: The work involves develops attended by a numerical
execution of the eXtend Finite Element Method premises a
measurement by the fracture process cracked so many cracked plates
an application will be processed for the calculation of the stress
intensity factor SIF. In the first we give in statically part the
distribution of stress, displacement field and strain of composite plate
in two cases uncrack/edge crack, also in dynamical part the first six
modes shape. Secondly, we calculate Stress Intensity Factor SIF for
different orientation angle θ of central crack with length (2a=0.4mm)
in plan strain condition, KI and KII are obtained for mode I and mode
II respectively using X-FEM method. Finally from crack inclined
involving mixed modes results, the comparison we chose dangerous
inclination and the best crack angle when K is minimal.
Abstract: A large part of Russia is located in permafrost areas. These areas are widely used because there are concentrated valuable natural resources. Therefore to explore of cryosols it is important due to the significant increase of anthropogenic stress as well as the problem of global climate change. In the north of Western Siberia permafrost phenomena is widespread. Permafrost as a factor of soil formation and cryogenesis as a process have a great impact on the soil formation of these areas. Based on the research results of permafrost-affected soils tundra landscapes formed in the central part of the Tazovskiy Peninsula in cryogenic conditions, data were obtained which characterize the morphological features of soils. The specificity of soil cover distribution and manifestation of soil-forming processes within the study area are noted. Permafrost features such as frost cracking, cryoturbation, thixotropy, movement of humus are formed. The formation of these features is increased with the development of the territory. As a consequence, there is a change in the components of the environment and the destruction of the soil cover.
Abstract: The development of new construction materials using
recycled plastic is important to both the construction and the plastic
recycling industries. Manufacturing of fibers from industrial or
postconsumer plastic waste is an attractive approach with such
benefits as concrete performance enhancement, and reduced needs
for land filling. The main objective of this study is to investigate the
effect of Plastic fibers obtained locally from recycled waste on plastic
shrinkage cracking of ordinary cement based mortar. Parameters
investigated include: fiber length ranging from 20 to 50mm, and fiber
volume fraction ranging from 0% to 1.5% by volume. The test results
showed significant improvement in crack arresting mechanism and
substantial reduction in the surface area of cracks for the mortar
reinforced with recycled plastic fibers compared to plain mortar.
Furthermore, test results indicated that there was a slight decrease in
compressive strength of mortar reinforced with different lengths and
contents of recycled fibers compared to plain mortar. This study
suggests that adding more than 1% of RP fibers to mortar, can be
used effectively for controlling plastic shrinkage cracking of cement
based mortar, and thus results in waste reduction and resources
conservation.
Abstract: The use of a conventional air plasma-sprayed thermal barrier coating (TBC) and a porous, functionally graded TBC as a thermal insulator for Al7075 alloy was explored. A quench test at 1200°C employing fast heating and cooling rates was setup to represent a dynamic thermal condition of an aerospace component. During the test, coated samples were subjected the ambient temperature of 1200°C for a very short time. This was followed by a rapid drop in temperature resulting in cracking of the coatings. For the conventional TBC, it was found that the temperature of the Al7075 substrate decreases with the increase in the ZrO2 topcoat thickness. However, at the topcoat thickness of 1100 µm, large horizontal cracks can be observed in the topcoat and at the topcoat thickness of 1600 µm, the topcoat delaminate during cooling after the quench test. The porous, functionally graded TBC with 600 µm thick topcoat, on the other hand, was found to be as effective at reducing the substrate temperature as the conventional TBC with 1100 µm thick topcoat. The maximum substrate temperature is about 213°C for the former and 208°C for the latter when a heating rate of 38°C/s was used. When the quench tests were conducted with a faster heating rate of 128°C/s, the Al7075 substrate heat up faster with a reduction in the maximum substrate temperatures. The substrate temperatures dropped from 297 to 212°C for the conventional TBC and from 213 to 155°C for the porous TBC, both with 600 µm thick topcoat. Segmentation cracks were observed in both coating after the quench test.
Abstract: This paper presents the study of strengthening R/C
beams with large circular and square opening located at flexure zone
by Carbon Fiber Reinforced Polymer (CFRP) laminates. A total of
five beams were tested to failure under four point loading to
investigate the structural behavior including crack patterns, failure
mode, ultimate load and load deflection behaviour. Test results show
that large opening at flexure reduces the beam capacity and stiffness;
and increases cracking and deflection. A strengthening configuration
was designed for each un-strengthened beams based on their
respective crack patterns. CFRP laminates remarkably restore the
beam capacity of beam with large circular opening at flexure location
while 10% re-gain of beam capacity with square opening. The use of
CFRP laminates with the designed strengthening configuration could
significantly reduce excessive cracking and deflection and increase
the ultimate capacity and stiffness of beam.
Abstract: According to Rostler method (ASTM D 2006), saturates content of bitumen is determined based on its reactivity to sulphuric acid. While Corbett method (ASTM D 4124) based on its polarity level. This paper presents results from the study on the effect of saturates content determined by two different fractionation methods on the rheological and aging characteristics of bitumen. The result indicated that the increment of saturates content tended to reduce all the rheological characteristics concerned. Bitumen became less elastic, less viscous, and less resistant to plastic deformation, but became more resistant to fatigue cracking. After short and long term aging process, the treatment effect coefficients of saturates decreased, saturates became thicker due to aging process. This study concludes that saturates is not really stable or reactive in aging process. Therefore, the reactivity of saturates should be considered in bitumen aging index
Abstract: At present, dictionary attack has been the basic tool for
recovering key passwords. In order to avoid dictionary attack, users
purposely choose another character strings as passwords. According to
statistics, about 14% of users choose keys on a keyboard (Kkey, for
short) as passwords. This paper develops a framework system to attack
the password chosen from Kkeys and analyzes its efficiency. Within
this system, we build up keyboard rules using the adjacent and parallel
relationship among Kkeys and then use these Kkey rules to generate
password databases by depth-first search method. According to the
experiment results, we find the key space of databases derived from
these Kkey rules that could be far smaller than the password databases
generated within brute-force attack, thus effectively narrowing down
the scope of attack research. Taking one general Kkey rule, the
combinations in all printable characters (94 types) with Kkey adjacent
and parallel relationship, as an example, the derived key space is about
240 smaller than those in brute-force attack. In addition, we
demonstrate the method's practicality and value by successfully
cracking the access password to UNIX and PC using the password
databases created
Abstract: Oilsands bitumen is an extremely important source of
energy for North America. However, due to the presence of large
molecules such as asphaltenes, the density and viscosity of the
bitumen recovered from these sands are much higher than those of
conventional crude oil. As a result the extracted bitumen has to be
diluted with expensive solvents, or thermochemically upgraded in
large, capital-intensive conventional upgrading facilities prior to
pipeline transport. This study demonstrates that globally abundant
natural zeolites such as clinoptilolite from Saint Clouds, New Mexico
and Ca-chabazite from Bowie, Arizona can be used as very effective
reagents for cracking and visbreaking of oilsands bitumen. Natural
zeolite cracked oilsands bitumen products are highly recoverable (up
to ~ 83%) using light hydrocarbons such as pentane, which indicates
substantial conversion of heavier fractions to lighter components.
The resultant liquid products are much less viscous, and have lighter
product distribution compared to those produced from pure thermal
treatment. These natural minerals impart similar effect on industrially
extracted Athabasca bitumen.
Abstract: The production and consumption of natural gas is on
the rise throughout the world as a result of its wide availability, ease
of transportation, use and clean-burning characteristics. The chief use
of ethane is in the chemical industry in the production of Ethene
(ethylene) by steam cracking. In this simulation, obtained ethane
recovery percent based on Gas sub-cooled process (GSP) is 99.9 by
mole that is included 32.1% by using de-methanizer column and
67.8% by de-ethanizer tower. The outstanding feature of this process
is the novel split-vapor concept that employs to generate reflux for
de-methanizer column. Remain amount of ethane in export gas cause
rise in gross heating value up to 36.66 MJ/Nm3 in order to use in
industrial and household consumptions.
Abstract: Pyrolysis of waste tire is one of alternative technique
to produce petrochemicals, such as light olefins, mixed C4, and monoaromatics.
Noble metals supported on acid zeolite catalysts were
reported as potential catalysts to produce the high valuable products
from waste tire pyrolysis. Especially, Pd supported on HBeta gave a
high yield of olefins, mixed C4, and mono-aromatics. Due to the high
prices of noble metals, the objective of this work was to investigate
whether or not a non-noble Ni metal can be used as a substitute of a
noble metal, Pd, supported on HBeta as a catalyst for waste tire pyrolysis.
Ni metal was selected in this work because Ni has high activity
in cracking, isomerization, hydrogenation and the ring opening of
hydrocarbons Moreover, Ni is an element in the same group as Pd
noble metal, which is VIIIB group, aiming to produce high valuable
products similarly obtained from Pd. The amount of Ni was varied as
5, 10, and 20% by weight, for comparison with a fixed 1 wt% Pd,
using incipient wetness impregnation. The results showed that as a
petrochemical-producing catalyst, 10%Ni/HBeta performed better
than 1%Pd/HBeta because it did not only produce the highest yield of
olefins and cooking gases, but the yields were also higher than
1%Pd/HBeta. 5%Ni/HBeta can be used as a substitute of
1%Pd/HBeta for similar crude production because its crude contains
the similar amounts of naphtha and saturated HCs, although it gave
no concentration of light mono-aromatics (C6-C11) in the oil. Additionally,
10%Ni/HBeta that gave high olefins and cooking gases was
found to give a fairly high concentration of the light mono-aromatics
in the oil.
Abstract: The large and small-scale shaking table tests, which
was conducted for investigating damage evolution of piles inside
liquefied soil, are numerically simulated and experimental verified by the3D nonlinear finite element analysis. Damage evolution of
elasto-plastic circular steel piles and reinforced concrete (RC) one with cracking and yield of reinforcement are focused on, and the failure patterns and residual damages are captured by the proposed constitutive models. The superstructure excitation behind quay wall is
reproduced as well.
Abstract: This study investigated the effect of oxygen and
micro-cracking on the flotation of low grade nickel sulphide ore. The
ore treated contained serpentine minerals which have a history of
being difficult to process efficiently. The use of oxygen as a bubbling
gas has been noted to be effective because it increases the pulp
potential. The desired effect of micro cracking the ore is that the
nickel sulphide minerals will become activated and this activation
will render these minerals more susceptible to react with potassium
amyl xanthate collectors, resulting in a higher recovery of nickel and
hinder the recovery of other undesired minerals contained in the ore.
Higher nickel recoveries were obtained when pure oxygen was used
as a bubbling gas rather than the conventional air. Microwave
cracking favored the recovery of nickel.