Study of the Oxidation Resistance of Coated AISI 441 Ferritic Stainless Steel for SOFCs

Protective coatings that resist oxide scale growth and
decrease chromium evaporation are necessary to make stainless steel
interconnect materials for long-term durable operation of solid oxide
fuel cells (SOFCs). In this study a layer of cobalt was electroplated
on the surface of AISI 441 ferritic stainless steel which is used in
solid oxide fuel cells for interconnect applications. The oxidation
behavior of coated substrates was studied as a function of time at
operating conditions of SOFCs. Cyclic oxidation has been also tested
at 800ºC for 100 cycles. Cobalt coating during isothermal oxidation
caused to the oxide growth resistance by limiting the outward
diffusion of Cr cation and the inward diffusion of oxygen anion.
Results of cyclic oxidation exhibited that coated substrates
demonstrate an excellent resistance against the spallation and
cracking.





References:
<p>[1] W. Z. Zhu and S. C. Deevi, 2003, Materials Science and Engineering A,
348, pp. 227.
[2] W. J. Quadakkers, J. P. Abellan, V. Shemet and L. Singheiser., 2003,
Materials at High Temperatures, 20, pp. 115.
[3] X. Chen, P. Y. Hou, C. P. Jacobson, S.J. Visko and L.C. De Jonghe.,
2005, Solid State Ionics., 176, pp. 425.
[4] H. Kurokawa, C. P. Jacobson, L. C. DeJonghe and S. J. Visco, 2007,
Solid State Ionics, 178, pp. 287.
[5] X. Chen, P. Y. Hou, C. P. Jacobson, S. J. Visko and L. C. De Jonghe.,
2005, Solid State Ionics. 176, pp. 425.
[6] Z. Yang, G. Xia, S. P. Simner and J.W. Stevenson., 2005, Journal of the
Electrochemical Society, 152, pp. 1896.
[7] Z. Yang, G. Xia, X. Li and J.W. Stevenson., 2007, International Journal
of Hydrogen Energy, 32, pp. 3648.
[8] Z. Yang, G. Xia and J. W. Stevenson., 2005, Electrochemical and Solid-
State Letters., 8, pp. A168.
[9] W. Wei, W. Chen and D.G. Ivey., 2007, Chemistry of Materials, 19, pp.
2816.
[10] M.R. Bateni, P. Wei, X. Deng and A. Petric., 2007, Surface &amp; Coating
Technology., 201, pp. 4677.
[11] P. Wei, X. Deng, M.R. Bateni and A. Petric., 2007, Corrosion 63, pp.
529.
[12] X. Deng, P. Wei, M.R. Bateni and A. Petric., 2006, Journal of Power
Sources 160, pp. 1225.
[13] Y.S. Chou, J.W. Stevenson and P. Singh., 2008, Journal of Power
Sources, 185, pp. 1001.
[14] W.J Quadakkers, J. Piron-Abellan, V. Shemet and L. Singheiser, 2003,
Materials at High Temperatures, 20, pp. 115.
[15] N. Shaigan, D.G. Ivey and W. Chen., 2008, J. power sources, 185, pp.
331.
[16] L. Cooper, S. Benhaddad, A. Wood and D.G. Ivey., 2008, J. power
sources, 184, pp. 220.
[17] M.G.C. Cox, B. Mcenaney and V.D. Scott, 1972, Phil Mag., 26, pp.
839.
[18] H. Kurokawa, K. Kawamura and T. Maruyama, 2004, Solid State
Ionics, 168, pp. 13.
[19] Z.G. Yang, 2008, International Materials Reviews, 53, pp. 39.
[20] E. N&rsquo;Dah, S. Tsipas, M.P. Hierro and F.J. P&eacute;rez, 2007, Corrosion
Science, 49, pp. 3850.
[21] S. Molin, B. Kusz, M. Gazda and P. Jasinski, 2008, J. power sources,
181, pp. 31.
[22] A. Petric and H. Ling, 2007, J. Am. Ceram. Soc. 90, pp. 1515.</p>