Abstract: Li1.5Al0.5Ti1.5 (PO4)3(LATP) has received much
attention as a solid electrolyte for lithium batteries. In this study, the
LATP solid electrolyte is prepared by the co-precipitation method
using Li3PO4 as a Li source. The LATP is successfully prepared and
the Li ion conductivities of bulk (inner crystal) and total (inner crystal
and grain boundary) are 1.1 × 10-3 and 1.1 × 10-4 S cm-1, respectively.
These values are comparable to the reported values, in which Li2C2O4
is used as the Li source. It is conclude that the LATP solid electrolyte
can be prepared by the co-precipitation method using Li3PO4 as the Li
source and this procedure has an advantage in mass production over
previous procedure using Li2C2O4 because Li3PO4 is lower price
reagent compared with Li2C2O4.
Abstract: When designing satellites, one of the major issues aside for designing its primary subsystems is to devise its thermal. The thermal management of satellites requires solving different sets of issues with regards to modelling. If the satellite is well conditioned all other parts of the satellite will have higher temperature no matter what. The main issue of thermal modelling for satellite design is really making sure that all the other points of the satellite will be within the temperature limits they are designed. The insertion of power electronics in aerospace technologies is becoming widespread and the modern electronic systems used in space must be reliable and efficient with thermal management unaffected by outer space constraints. Many advanced thermal management techniques have been developed in recent years that have application in high power electronic systems. This paper presents a Three-Dimensional Modal Transmission Line Matrix (3D-TLM) implementation of transient heat flow in space power electronics. In such kind of components heat dissipation and good thermal management are essential. Simulation provides the cheapest tool to investigate all aspects of power handling. The 3DTLM has been successful in modeling heat diffusion problems and has proven to be efficient in terms of stability and complex geometry. The results show a three-dimensional visualisation of self-heating phenomena in the device affected by outer space constraints, and will presents possible approaches for increasing the heat dissipation capability of the power modules.
Abstract: Simulation of occlusal function during laboratory
material-s testing becomes essential in predicting long-term
performance before clinical usage. The aim of the study was to assess
the influence of chamfer preparation depth on failure risk of heat
pressed ceramic crowns with and without zirconia framework by
means of finite element analysis. 3D models of maxillary central
incisor, prepared for full ceramic crowns with different depths of the
chamfer margin (between 0.8 and 1.2 mm) and 6-degree tapered
walls together with the overlying crowns were generated using
literature data (Fig. 1, 2). The crowns were designed with and
without a zirconia framework with a thickness of 0.4 mm. For all
preparations and crowns, stresses in the pressed ceramic crown,
zirconia framework, pressed ceramic veneer, and dentin were
evaluated separately. The highest stresses were registered in the
dentin. The depth of the preparations had no significant influence on
the stress values of the teeth and pressed ceramics for the studied
cases, only for the zirconia framework. The zirconia framework
decreases the stress values in the veneer.
Abstract: Fatigue behaviors of Lead Zirconate Titanate (PZT)
ceramics under different amplitude of bipolar electrical loads have
been investigated. Fatigue behavior is represented by the change of
hysteresis loops and remnant polarization. Three levels of electrical
load amplitudes (1.00, 1.25 and 1.50 kV /mm) were applied in this
experimental. It was found that the remnant polarization decreased
significantly with the number of loading cycles. The degree of fatigue
degradation depends on the amplitude of electric field. The higher
amplitude exhibits the greater fatigue degradation.
Abstract: The Institute of Product Development is dealing
with the development, design and dimensioning of micro components
and systems as a member of the Collaborative Research
Centre 499 “Design, Production and Quality Assurance of
Molded micro components made of Metallic and Ceramic Materials".
Because of technological restrictions in the miniaturization
of conventional manufacturing techniques, shape and
material deviations cannot be scaled down in the same proportion
as the micro parts, rendering components with relatively
wide tolerance fields. Systems that include such components
should be designed with this particularity in mind, often requiring
large clearance. On the end, the output of such systems
results variable and prone to dynamical instability. To save
production time and resources, every study of these effects
should happen early in the product development process and
base on computer simulation to avoid costly prototypes. A
suitable method is proposed here and exemplary applied to a
micro technology demonstrator developed by the CRC499. It
consists of a one stage planetary gear train in a sun-planet-ring
configuration, with input through the sun gear and output
through the carrier. The simulation procedure relies on ordinary
Multi Body Simulation methods and subsequently adds
other techniques to further investigate details of the system-s
behavior and to predict its response. The selection of the relevant
parameters and output functions followed the engineering
standards for regular sized gear trains. The first step is to
quantify the variability and to reveal the most critical points of
the system, performed through a whole-mechanism Sensitivity
Analysis. Due to the lack of previous knowledge about the system-s
behavior, different DOE methods involving small and
large amount of experiments were selected to perform the SA.
In this particular case the parameter space can be divided into
two well defined groups, one of them containing the gear-s profile
information and the other the components- spatial location.
This has been exploited to explore the different DOE techniques
more promptly. A reduced set of parameters is derived for
further investigation and to feed the final optimization process,
whether as optimization parameters or as external perturbation
collective. The 10 most relevant perturbation factors and 4 to 6
prospective variable parameters are considered in a new, simplified
model. All of the parameters are affected by the mentioned
production variability. The objective functions of interest
are based on scalar output-s variability measures, so the
problem becomes an optimization under robustness and reliability constrains. The study shows an initial step on the development
path of a method to design and optimize complex micro
mechanisms composed of wide tolerated elements accounting
for the robustness and reliability of the systems- output.
Abstract: Optical 3D measurement of objects is meaningful in
numerous industrial applications. In various cases shape acquisition
of weak textured objects is essential. Examples are repetition parts
made of plastic or ceramic such as housing parts or ceramic bottles as
well as agricultural products like tubers. These parts are often
conveyed in a wobbling way during the automated optical inspection.
Thus, conventional 3D shape acquisition methods like laser scanning
might fail. In this paper, a novel approach for acquiring 3D shape of
weak textured and moving objects is presented. To facilitate such
measurements an active stereo vision system with structured light is
proposed. The system consists of multiple camera pairs and auxiliary
laser pattern generators. It performs the shape acquisition within one
shot and is beneficial for rapid inspection tasks. An experimental
setup including hardware and software has been developed and
implemented.
Abstract: This study investigated a strategy of blending lead-laden sludge and Al-rich precursors to reduce the release of metals from the stabilized products. Using PbO as the simulated lead-laden sludge to sinter with γ-Al2O3 by Pb:Al molar ratios of 1:2 and 1:12, PbAl2O4 and PbAl12O19 were formed as final products during the sintering process, respectively. By firing the PbO + γ-Al2O3 mixtures with different Pb/Al molar ratios at 600 to 1000 °C, the lead transformation was determined through X-ray diffraction (XRD) data. In Pb/Al molar ratio of 1/2 system, the formation of PbAl2O4 is initiated at 700 °C, but an effective formation was observed above 750 °C. An intermediate phase, Pb9Al8O21, was detected in the temperature range of 800-900 °C. However, different incorporation behavior for sintering PbO with Al-rich precursors at a Pb/Al molar ratio of 1/12 was observed during the formation of PbAl12O19 in this system. In the sintering process, both temperature and time effect on the formation of PbAl2O4 and PbAl12O19 phases were estimated. Finally, a prolonged leaching test modified from the U.S. Environmental Protection Agency-s toxicity characteristic leaching procedure (TCLP) was used to evaluate the durability of PbO, Pb9Al8O21, PbAl2O4 and PbAl12O19 phases. Comparison for the leaching results of the four phases demonstrated the higher intrinsic resistance of PbAl12O19 against acid attack.
Abstract: This paper deals with the thermo-mechanical deformation behavior of shear deformable functionally graded ceramicmetal (FGM) plates. Theoretical formulations are based on higher order shear deformation theory with a considerable amendment in the transverse displacement using finite element method (FEM). The mechanical properties of the plate are assumed to be temperaturedependent and graded in the thickness direction according to a powerlaw distribution in terms of the volume fractions of the constituents. The temperature field is supposed to be a uniform distribution over the plate surface (XY plane) and varied in the thickness direction only. The fundamental equations for the FGM plates are obtained using variational approach by considering traction free boundary conditions on the top and bottom faces of the plate. A C0 continuous isoparametric Lagrangian finite element with thirteen degrees of freedom per node have been employed to accomplish the results. Convergence and comparison studies have been performed to demonstrate the efficiency of the present model. The numerical results are obtained for different thickness ratios, aspect ratios, volume fraction index and temperature rise with different loading and boundary conditions. Numerical results for the FGM plates are provided in dimensionless tabular and graphical forms. The results proclaim that the temperature field and the gradient in the material properties have significant role on the thermo-mechanical deformation behavior of the FGM plates.
Abstract: Ranong province has the best kaolin, and it is the most
useful of all the clay types used in ceramic making. Until recently,
there has been only one community business making ceramics in
Ranong province. And this business could not build the mix of body
and glaze from their raw material without assistance. Considering
these problems, this research is aimed to test the composition of
ceramic body and glaze which suit. Kaolin from Ranong is the raw
material which these search focuses on. All other raw materials use in
the investigation will come from southern Thailand, kaolin and
limestone from Ranong province, ball clay from Surat Thani
province, white sand from Songkhla province, and feldspar from
Nakhon Si Thammarat province. Results can be used to develop the
efficiency of industrial production which in return will enhance the
business process.
Abstract: The mineral having chemical compositional formula MgAl2O4 is called “spinel". The ferrites crystallize in spinel structure are known as spinel-ferrites or ferro-spinels. The spinel structure has a fcc cage of oxygen ions and the metallic cations are distributed among tetrahedral (A) and octahedral (B) interstitial voids (sites). The X-ray diffraction (XRD) intensity of each Bragg plane is sensitive to the distribution of cations in the interstitial voids of the spinel lattice. This leads to the method of determination of distribution of cations in the spinel oxides through XRD intensity analysis. The computer program for XRD intensity analysis has been developed in C language and also tested for the real experimental situation by synthesizing the spinel ferrite materials Mg0.6Zn0.4AlxFe2- xO4 and characterized them by X-ray diffractometry. The compositions of Mg0.6Zn0.4AlxFe2-xO4(x = 0.0 to 0.6) ferrites have been prepared by ceramic method and powder X-ray diffraction patterns were recorded. Thus, the authenticity of the program is checked by comparing the theoretically calculated data using computer simulation with the experimental ones. Further, the deduced cation distributions were used to fit the magnetization data using Localized canting of spins approach to explain the “recovery" of collinear spin structure due to Al3+ - substitution in Mg-Zn ferrites which is the case if A-site magnetic dilution and non-collinear spin structure. Since the distribution of cations in the spinel ferrites plays a very important role with regard to their electrical and magnetic properties, it is essential to determine the cation distribution in spinel lattice.
Abstract: There are many kinds of metal borates found not only
in nature but also synthesized in the laboratory such as magnesium
borates. Due to its excellent properties, as remarkable ceramic
materials, they have also application areas in anti-wear and friction
reducing additives as well as electro-conductive treating agents. The
synthesis of magnesium borate powders can be fulfilled simply with
two different methods, hydrothermal and thermal synthesis.
Microwave assisted method, also another way of producing
magnesium borate, can be classified into thermal synthesis because of
using the principles of solid state synthesis. It also contributes
producing particles with small size and high purity in nano-size
material synthesize. In this study the production of magnesium
borates, are aimed using MgCl2.6H2O and H3BO3. The identification
of both starting materials and products were made by the equipments
of, X-Ray Diffraction (XRD) and Fourier Transform Infrared
Spectroscopy (FT-IR). After several synthesis steps magnesium
borates were synthesized and characterized by XRD and FT-IR, as
well.
Abstract: In a nuclear reactor Loss of Coolant accident (LOCA)
considers wide range of postulated damage or rupture of pipe in the
heat transport piping system. In the case of LOCA with/without
failure of emergency core cooling system in a Pressurised Heavy
water Reactor, the Pressure Tube (PT) temperature could rise
significantly due to fuel heat up and gross mismatch of the heat
generation and heat removal in the affected channel. The extent and
nature of deformation is important from reactor safety point of view.
Experimental set-ups have been designed and fabricated to simulate
ballooning (radial deformation) of PT for 220 MWe IPHWRs.
Experiments have been conducted by covering the CT by ceramic
fibers and then by submerging CT in water of voided PTs. In both
the experiments, it is observed that ballooning initiates at a
temperature around 665´┐¢C and complete contact between PT and
Caldaria Tube (CT) occurs at around 700´┐¢C approximately. The
strain rate is found to be 0.116% per second. The structural integrity
of PT is retained (no breach) for all the experiments. The PT heatup
is found to be arrested after the contact between PT and CT, thus
establishing moderator acting as an efficient heat sink for IPHWRs.
Abstract: Abrasive Jet Machining is an Unconventional
machining process in which the metal is removed from brittle and
hard material in the form of micro-chips. With increase in need of
materials like ceramics, composites, in manufacturing of various
Mechanical & Electronic components, AJM has become a useful
technique for micro machining. The present study highlights the
influence of different parameters like Pressure, SOD, Time, Abrasive
grain size, nozzle diameter on the Metal removal of FRP (Fiber
Reinforced Polymer) composite by Abrasive jet machining. The
results of the Experiments conducted were analyzed and optimized
with TAGUCHI method of Optimization and ANOVA for Optimal
Value.
Abstract: This paper present some preliminary work on the
preparation and physicochemical caracterization of nanocomposite
MFI-alumina structures based on alumina hollow fibres. The fibers
are manufactured by a wet spinning process. α-alumina particles were
dispersed in a solution of polysulfone in NMP. The resulting slurry is
pressed through the annular gap of a spinneret into a precipitation
bath. The resulting green fibres are sintered. The mechanical strength
of the alumina hollow fibres is determined by a three-point-bending
test while the pore size is characterized by bubble-point testing. The
bending strength is in the range of 110 MPa while the average pore
size is 450 nm for an internal diameter of 1 mm and external diameter
of 1.7 mm. To characterize the MFI membranes various techniques
were used for physicochemical characterization of MFI–ceramic
hollow fibres membranes: The nitrogen adsorption, X-ray
diffractometry, scanning electron microscopy combined with X
emission microanalysis. Scanning Electron Microscopy (SEM) and
Energy Dispersive Microanalysis by the X-ray were used to observe
the morphology of the hollow fibre membranes (thickness,
infiltration into the carrier, defects, homogeneity). No surface film,
has been obtained, as observed by SEM and EDX analysis and
confirmed by high temperature variation of N2 and CO2 gas
permeances before cation exchange. Local analysis and characterise
(SEM and EDX) and overall (by ICP elemental analysis) were
conducted on two samples exchanged to determine the quantity and
distribution of the cation of cesium on the cross section fibre of the
zeolite between the cavities.
Abstract: The improvement of a filer case utilized to purify the
let-out smoke and smell in the production of Benjarong Ceramic is
studied through Participatory Action Research (PAR). This research
is aimed to protect smell, dirty smoke, and air pollution which are
effects of incomplete combustion in the production of Benjarong
ceramic. This research was conducted at Jongjint Benjarong Ceramic
Factory in Plai Bang, Bang Kruai, Nonthaburi Province,Thailand,
also 12 employees were interviewed for data collection. All collected
data were analyzed to develop and create solution to protect smoke
and smell pollution from Benjarong ceramic production.
The results revealed that the employees who have used the
developed filer cases are moderately satisfied. In addition to the
efficiency of developed smoke-and-smell filer cases, it was found
that Overall, the respondents were satisfied moderately with
efficiency of modified smoke and smell filter cases.
Abstract: In a travelling wave thermoacoustic device, the
regenerator sandwiched between a pair of (hot and cold) heat
exchangers constitutes the so-called thermoacoustic core, where the
thermoacoustic energy conversion from heat to acoustic power takes
place. The temperature gradient along the regenerator caused by the
two heat exchangers excites and maintains the acoustic wave in the
resonator. The devices are called travelling wave thermoacoustic
systems because the phase angle difference between the pressure and
velocity oscillation is close to zero in the regenerator. This paper
presents the construction and testing of a thermoacoustic engine
equipped with a ceramic regenerator, made from a ceramic material
that is usually used as catalyst substrate in vehicles- exhaust systems,
with fine square channels (900 cells per square inch). The testing
includes the onset temperature difference (minimum temperature
difference required to start the acoustic oscillation in an engine), the
acoustic power output, thermal efficiency and the temperature profile
along the regenerator.
Abstract: The steam cracking reactions are always accompanied with the formation of coke which deposits on the walls of the tubular reactors. The investigation has attempted to control catalytic coking by the applying aluminum, zinc and ceramic coating like aluminum-magnesium by thermal spray and pack cementation method. Rate of coke formation during steam cracking of naphtha has been investigated both for uncoated stainless steel (with different alloys) and metal coating constructed with thermal Spray and pack cementation method with metal powders of Aluminum, Aluminum-Magnesium, zinc, silicon, nickel and chromium. The results of the study show that passivating the surface of SS321 with a coating of Aluminum and Aluminum-Magnesium can significantly reduce the rate of coke deposition during naphtha pyrolysis. SEM and EDAX techniques (Philips XL Series) were used to examine the coke deposits formed by the metal-hydrocarbon reactions. Our objective was to separate the different stages by identifying the characteristic morphologies.
Abstract: At present, the tendency to implement the conditionbased
maintenance (CBM), which allows the optimization of the
expenses for equipment monitoring, is more and more evident; also,
the transformer substations with remote monitoring are increasingly
used. This paper reviews all the advantages of the on-line monitoring
and presents an equipment for on-line monitoring of bushings, which
is the own contribution of specialists who are the authors of this
paper. The paper presents a study of the temperature field, using the
finite element method. For carrying out this study, the 3D modelling
of the above mentioned bushing was performed. The analysis study is
done taking into account the extreme thermal stresses, focusing at the
level of the first cooling wing section of the ceramic insulator. This
fact enables to justify the tanδ variation in time, depending on the
transformer loading and the environmental conditions. With a view
to reducing the variation of dielectric losses in bushing insulation, the
use of ferrofuids instead of mineral oils is proposed.
Abstract: This study deals with the phenomena of reflection and transmission (refraction) of qSV-waves, for an incident of quasi transverse vertically waves, at a plane interface of two semi-infinite piezoelectric elastic media under the influence of the initial stresses. The relations governing the reflection and transmission coefficients of these reflected waves for various suitable boundary conditions are derived. We have shown analytically that reflection and transmission coefficients of (qP) and (qSV) waves depend upon the angle of incidence, the parameters of electric potential, the material constants of the medium as will as the initial stresses presented in the media. The numerical calculations of the reflection and transmission amplitude ratios for different values of initial stresses have been carried out by computer for different materials as examples and the results are given in the form of graphs. Finally, some of particular cases are considered.
Abstract: Stress analysis of functionally graded composite plates
composed of ceramic, functionally graded material and metal layers is
investigated using 3-D finite element method. In FGM layer, material
properties are assumed to be varied continuously in the thickness
direction according to a simple power law distribution in terms of the
volume fraction of a ceramic and metal. The 3-D finite element model
is adopted by using an 18-node solid element to analyze more
accurately the variation of material properties in the thickness
direction. Numerical results are compared for three types of materials.
In the analysis, the tensile and the compressive stresses are
summarized for various FGM thickness ratios, volume fraction
distributions, geometric parameters and mechanical loads.