Abstract: In this article, biomechanical aspects of hen-s eggshell as a natural ceramic structure are studied. The images, taken by a scanning electron microscope (SEM), are used to investigate the microscopic aspects of the egg. It is observed that eggshell has a three-layered microstructure with different morphological and structural characteristics. Studies on the eggshell membrane (ESM) as a prosperous tissue suggest that it is placed to prevent the penetration of microorganisms into the egg. Finally, numerical models of the egg are presented to study the stress distribution and its deformation under different loading conditions. The effects of two different types of loading (hydrostatic and point loadings) on two different shell models (with constant and variable thicknesses) are investigated in detail.
Abstract: Ceramics comprise the largest proportion of Korea-s cultural heritage currently preserved (Cited from “The Beauty of Old Ceramics of Korea" written by Yoon Yong-iee). Thus, this researcher conducted this investigation in an attempt to gain insight into Korea-s past culture and the lost period of the colonial period and the Korean War by looking into the ceramics. Korea, China and Japan are part of the similar cultural bloc within the East Asian region. Their porcelains manifest distinctive characteristics by each nation along with similarities. Thus, this research seeks to find the distinctive characteristics of the Korean porcelain by conducting comparative analysis of the similarities and distinctive characteristics. These distinctive characteristics are manifested effectively in the colors of the porcelains following the materials that can be obtained in Korea, China and Japan and production method. Likewise, this research seeks to identify the characteristics of the Korean porcelains- colors based on the comparative analysis of the porcelain colors. The reasons that porcelains were selected were because they are the most well preserved cultural remains in Korea and since they have both similarities and distinctive characteristics due to the cultural interchanges among Korea, China and Japan, which facilitates comparative study. The research targets include Korea, China and Japan-s porcelains. By comparing the colors of the porcelains from Korea, China and Japan that have their distinctive characteristics, this research seeks to identify Korea-specific porcelain colors. These colors derive from the materials that can be obtained only in Korea, and they are affected by the ideologies that governed at the time. This research is meaningful in the sense that this identifies the colors that embraces the Korean culture and provides important data by leveraging the study of the characteristics of the Korea-specific porcelains.
Abstract: Waste problem is becoming a future problem all over the world. Magnesium wastes which can be used in recycling processes are produced by many industrial activities. Magnesium borates which have useful properties such as; high heat resistance, corrosion resistance, supermechanical strength, superinsulation, light weight, high coefficient of elasticity and so on. Addition, magnesium borates have great potential in the development of ceramic and detergents industry, whisker-reinforced composites, antiwear, and reducing friction additives.
In this study, using the starting materials of waste magnesium and H3BO3 the hydrothermal method was applied at a moderate temperature of 70oC with different reaction times. Several reaction times of waste magnesium to H3BO3 were selected as; 30, 60, 120, 240 minutes. After the synthesis, X-Ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FT-IR) techniques were applied to products. As a result, the forms of Admontite [MgO(B2O3)3.7(H2O)] and Mcallisterite [Mg2(B6O7(OH)6)2.9(H2O)] were synthesized.
Abstract: Restoration of endodontically treated teeth is a
common problem in dentistry, related to the fractures occurring in
such teeth and to concentration of forces little information regarding
variation of basic preparation guidelines in stress distribution has
been available. To date, there is still no agreement in the literature
about which material or technique can optimally restore
endodontically treated teeth. The aim of the present study was to
evaluate the influence of the core height and restoration materials on
corono-radicular restored upper first premolar. The first step of the
study was to achieve 3D models in order to analyze teeth, dowel and
core restorations and overlying full ceramic crowns. The FEM model
was obtained by importing the solid model into ANSYS finite
element analysis software. An occlusal load of 100 N was conducted,
and stresses occurring in the restorations, and teeth structures were
calculated. Numerical simulations provide a biomechanical
explanation for stress distribution in prosthetic restored teeth. Within
the limitations of the present study, it was found that the core height
has no important influence on the stress generated in coronoradicular
restored premolars. It can be drawn that the cervical regions
of the teeth and restorations were subjected to the highest stress
concentrations.
Abstract: The aim of this paper is to experimentally discover the workability coefficient of the Inconel 718 material by using a slide turning machining. Two different types of cutting inserts, one made of carbide and the other one made of ceramic, are being used. The purpose is to compare measured results and recommend the appropriate materials and cutting parameters for a machining of the Inconel 718. Furthermore, the durability of inserts with the chosen wear criterion is being compared for different cutting speeds. Machinability of these materials is a crucial characteristic as it allows us to shorten the technological cycle time and increase the machining productivity. And this is of great importance from an economic point of view.
Abstract: The alumosilicate ceramics with mullite crystalline phase are used in various branches of science and technique. The mullite refractory ceramics with high porosity serve as a heat insulator and as a constructional materials [1], [2]. The purpose of the work was to sinter high porosity ceramic and to increase the quantity of mullite phase in this mullite, mullite-corundum ceramics. Two types of compositions were prepared at during the experiment. The first type is compositions with commercial alumina and silica oxides. The second type is from mixing these oxides with 10, 20 and 30 wt.%. of kaolin. In all samples the Al2O3 and SiO2 were in 2.57:1 ratio, because that was conformed to mullite stechiometric compositions (3Al2O3.2SiO2). The types of alumina oxides were α-Al2O3 (d50=4µm) and γ-Al2O3 (d50=80µm). Ratios of α-: γ-Al2O3 were (1:1) or (1:3). The porous materials were prepared by slip casting of suspension of raw materials. The aluminium paste (0.18 wt.%) was used as a pore former. Water content in the suspensions was 26-47 wt.%. Pore formation occurred as a result of hydrogen formation in chemical reaction between aluminium paste and water [2]. The samples were sintered at the temperature of 1650°C and 1750°C for one hour. The increasing amount of kaolin, α-: γ-Al2O3 at the ratio (1:3) and sintering at the highest temperature raised the quantity of mullite phase. The mullite phase began to dominate over the corundum phase.
Abstract: The present research focus on the processing of mullite-based ceramics from oil refinery industrial wastes and byproducts of agricultural industry and on the investigating of silane modified surface of ceramics. Two waste products were used as initial material – waste aluminum oxide and waste rice husk. The burning - out additives used were waste rise husk. It is known that the oxide ceramics surface is hydrophilic due to the presence of – OH groups in it. The nature of ceramic surface regarding permeation of water and hydrocarbons can be changed by further treatment with silanes. The samples were studied mainly by X-ray analysis, FT-IR absorbance measurements and microscopic analysis. The X-ray analyses showed the phase composition depends on the firing temperature and on the purity of the starting alumina. Two kind of silanes were used for the transformation of surface from hydrophilic to hydrophobic – trimethoxymethylsilane (TMMS) and trimethylclorsilane (TMCS).
Abstract: Lightweight ceramic materials in the form of bricks
and blocks are widely used in modern construction. They may be
obtained by adding of rice husk, rye straw, etc, as porous forming
materials. Rice husk is a major by-product of the rice milling
industry. Its utilization as a valuable product has always been a
problem. Various technologies for utilization of rice husk through
biological and thermochemical conversion are being developed.
The purpose of this work is to develop lightweight ceramic
materials with clay matrix and filler of rice husk and examine their
main physicomechanical properties. The results obtained allow to
suppose that the materials synthesized on the basis of waste materials
can be used as lightweight materials for construction purpose.
Abstract: (Bi0.5Na0.5)TiO3 doped with 8 mol % BaTiO3 powder
(BNT-BT0.08), prepared by sol-gel method was compacted and
sintered by Spark Plasma Sintering (SPS) process. The influence of
SPS temperature on the densification of BNT-BT0.08 ceramic was
investigated. Starting from sol-gel nanopowder of BNT-BT
containing 8 mol % BaTiO3 with an average particles size of about
30 nm, were obtained ceramics with density around 98 % of the
theoretical density value when the SPS temperature used was about
850 °C. The average grain size of the resulting ceramics was 80 nm.
The BNT-BT0.08 ceramic sample obtained by SPS method has shown
good electric properties at various frequencies.
Abstract: In the forming of ceramic materials the plasticity
concept is commonly used. This term is related to a particular
mechanical behavior when clay is mixed with water. A plastic
ceramic material shows a permanent strain without rupture
when a compressive load produces a shear stress that exceeds
the material-s yield strength. For a plastic ceramic body it
observes a measurable elastic behavior before the yield
strength and when the applied load is removed. In this work, a
mathematical model was developed from applied concepts of
the plasticity theory by using the stress/strain diagram under
compression.
Abstract: The fixed partial dentures are mainly used in the frontal
part of the dental arch because of their great esthetics. There are
several factors that are associated with the stress state created in
ceramic restorations, including: thickness of ceramic layers,
mechanical properties of the materials, elastic modulus of the
supporting substrate material, direction, magnitude and frequency of
applied load, size and location of occlusal contact areas, residual
stresses induced by processing or pores, restoration-cement
interfacial defects and environmental defects. The purpose of this
study is to evaluate the capability of Polarization Sensitive Optical
Coherence Tomography (PSOCT) in detection and analysis of
possible material defects in metal-ceramic and integral ceramic fixed
partial dentures. As a conclusion, it is important to have a non
invasive method to investigate fixed partial prostheses before their
insertion in the oral cavity in order to satisfy the high stress
requirements and the esthetic function.
Abstract: Ultrasonic machining (USM) is a non-traditional
machining process being widely used for commercial machining of
brittle and fragile materials such as glass, ceramics and
semiconductor materials. However, USM could be a viable
alternative for machining a tough material such as titanium; and this
aspect needs to be explored through experimental research. This
investigation is focused on exploring the use of ultrasonic machining
for commercial machining of pure titanium (ASTM Grade-I) and
evaluation of tool wear rate (TWR) under controlled experimental
conditions. The optimal settings of parameters are determined
through experiments planned, conducted and analyzed using Taguchi
method. In all, the paper focuses on parametric optimization of
ultrasonic machining of pure titanium metal with TWR as response,
and validation of the optimized value of TWR by conducting
confirmatory experiments.
Abstract: Porcelain specimens were fired at 6C/min to 1250C (dwell time 0.5-3h) and cooled at 6C/min to room temperature. Additionally, three different slower firing/cooling cycles were tried. Sintering profile and effects on MOR, crystalline phase content and morphology were investigated using dilatometry, 4-point bending strength, XRD and FEG-SEM respectively. Industrial-sized specimens prepared using the promising cycle were tested basing on the ANSI standards. Increasing dwell time from 1h to 3h at peak temperature of 1250C resulted in neither a significant effect on the quartz and mullite content nor MOR. Reducing the firing/cooling rate to below 6C/min, for peak temperature of 1250C (dwell time of 1h) does not result in improvement of strength of porcelain. The industrial sized specimen exhibited flashover voltages of 20.3kV (dry) and 9.3kV (wet) respectively, transverse strength of 12.5kN and bulk density of 2.27g/cm3, which are satisfactory. There was however dye penetration during porosity test. KeywordsDwell time, Microstructure, Porcelain, Strength.
Abstract: This paper studies the application of a variety of
sawdust materials in the production of lightweight insulating bricks.
First, the mineralogical and chemical composition of clays was determined. Next, ceramic bricks were fabricated with different
quantities of materials (3–6 and 9 wt. % for sawdust, 65 wt. % for grey clay, 24–27 and 30 wt. % for yellow clay and 2 wt% of tuff).
These bricks were fired at 800 and 950 °C. The effect of adding this sawdust on the technological behaviour of the brick was assessed by
drying and firing shrinkage, water absorption, porosity, bulk density
and compressive strength. The results have shown that the optimum
sintering temperature is 950 °C. Below this temperature, at 950 °C,
increased open porosity was observed, which decreased the compressive strength of the bricks. Based on the results obtained, the
optimum amounts of waste were 9 wt. % sawdust of eucalyptus, 24 wt. % shaping moisture and 1.6 particle size diameter. These percentages produced bricks whose mechanical properties were
suitable for use as secondary raw materials in ceramic brick
production.
Abstract: Municipal solid waste (MSW) comprises of a wide
range of heterogeneous materials generated by individual, household
or organization and may include food waste, garden wastes, papers,
textiles, rubbers, plastics, glass, ceramics, metals, wood wastes,
construction wastes but it is not limited to the above mentioned
fractions. The most common Municipal Solid Waste pretreatment
method in use is thermal pretreatment (incineration) and Mechanical
Biological pretreatment. This paper presents an overview of these
two pretreatment methods describing their benefits and laboratory
scale reactors that simulate landfill conditions were constructed in
order to compare emissions in terms of biogas production and
leachate contamination between untreated Municipal Solid Waste and
Mechanical Biological Pretreated waste. The findings of this study
showed that Mechanical Biological pretreatment of waste reduces the
emission level of waste and the benefit over the landfilling of
untreated waste is significant.
Abstract: This paper presents a solution for ceramic cutting tools availability in interrupted machining. Experiments were performed on a special fixture – the interrupted cut simulator. This fixture was constructed at our Department of Machining and Assembly within the scope of a project by the Czech Science Foundation. The goals of the tests were to contribute to the wider usage of these cutting materials in machining, especially in interrupted machining. Through the centuries, producers of ceramic cutting tools have taken big steps forward. Namely, increasing durability in maintaining high levels of strength and hardness lends an advantage. Some producers of these materials advise cutting inserts for interrupted machining at the present time [1, 2].
Abstract: A judicious choice of insert material, tool geometry and
cutting conditions can make hard turning produce better surfaces than
grinding. In the present study, an attempt has been made to
investigate the effect of cutting tool materials on cutting forces (feed
force, thrust force and cutting force) in finish hard turning of AISI
D2 cold work tool steel. In conclusion of the results obtained with a
constant depth of cut and feed rate, it is important to note that cutting
force is directly affected by cutting tool material.
Abstract: This paper presents an exact solution and a finite element method (FEM) for a Piezoceramic Rod under static load. The cylindrical rod is made from polarized ceramics (piezoceramics) with axial poling. The lateral surface of the rod is traction-free and is unelectroded. The two end faces are under a uniform normal traction. Electrically, the two end faces are electroded with a circuit between the electrodes, which can be switched on or off. Two cases of open and shorted electrodes (short circuit and open circuit) will be considered. Finally, a finite element model will be used to compare the results with an exact solution. The study uses ABAQUS (v.6.7) software to derive the finite element model of the ceramic rod.
Abstract: New lead-free ferroelectric relaxor ceramics were
prepared by conventional solid-state synthesis in the BaTiO3-Bi2O3-
Y2O3 systems. Some of these ceramics present a ferroelectric relaxor
with transition temperature close to room temperature. These new
materials are very interesting for applications and can replace leadbased
ceramic to prevent the toxic pollutions during the preparation
state. In the other hand, the energy band diagram shows the
potentiality of these compounds for the solar energy conversion.
Thus, some compositions have been tested successfully for H2
production upon visible light. The best activity occurs in alkaline
media with a rate evolution of about 0.15 mL g-1 mn-1 and a quantum
yield of 1% under polychromatic light.
Abstract: The paper deals with calculation of the parameters of
ceramic material from a set of destruction tests of ceramic heads of
total hip joint endoprosthesis. The standard way of calculation of the
material parameters consists in carrying out a set of 3 or 4 point
bending tests of specimens cut out from parts of the ceramic material
to be analysed. In case of ceramic heads, it is not possible to cut out
specimens of required dimensions because the heads are too small (if
the cut out specimens were smaller than the normalised ones, the
material parameters derived from them would exhibit higher strength
values than those which the given ceramic material really has). On
that score, a special testing jig was made, in which 40 heads were
destructed. From the measured values of circumferential strains of the
head-s external spherical surface under destruction, the state of stress
in the head under destruction was established using the final elements
method (FEM). From the values obtained, the sought for parameters
of the ceramic material were calculated using Weibull-s weakest-link
theory.