Investigation of Silane Modified Ceramic Surface of Porous Mullite Ceramics

The present research focus on the processing of mullite-based ceramics from oil refinery industrial wastes and byproducts of agricultural industry and on the investigating of silane modified surface of ceramics. Two waste products were used as initial material – waste aluminum oxide and waste rice husk. The burning - out additives used were waste rise husk. It is known that  the oxide ceramics surface is hydrophilic due to the presence of – OH groups in it. The nature of ceramic surface regarding permeation of water and hydrocarbons can be changed by further treatment with silanes. The samples were studied mainly by X-ray analysis, FT-IR absorbance measurements and microscopic analysis. The X-ray analyses showed the phase composition depends on the firing temperature and on the purity of the starting alumina. Two kind of silanes were used for the transformation of surface from hydrophilic to hydrophobic – trimethoxymethylsilane (TMMS) and trimethylclorsilane (TMCS).





References:
<p>[1] Food and Agricultural Organizasion (FAO), Production yearbook: Basic
data unit statistics division, Organization of the United Nation, Rome,
Italy, 1996.
[2] M. Patel, A., Karera, A., F. Prasanna, J. Mater. Sci., Effect of Thermal
and chemical treatment on carbon an d silica contents in rice husk, 22,
pp. 2457 – 2464, 1987.
[3] M. G. M. U. Ismail, Zenjiro Nakai, Shigeyuki Sōmiya, Microstructure
and Mechanical Properties of Mullite Prepared by the Sol-Gel Method,
J. Am. Ceram. Soc., 70, 1, pp. C-7–C-8, 1987.
[4] Qi Hui Jia, Jia Chen Liu, Ji Ping Guo, Xiong Wei Du, Zhong Jie, Wen
Jun Wang Preparation of Porous Mullite Ceramics by Fly Ash/Al
Compositions, Kay Eng. Mater., 434 – 435, pp. 81-84, 2010.
[5] K. S. Mazdiyasni, L. M. Brown, Synthesis and Mechanical Properties of
Stoichiometric Aluminum Silicate (Mullite), J. Am. Ceram. Soc., 55,
11, pp. 548–552, 1972.
[6] M. D. Sacks, Nazim Bozkurt, G. W. Scheiffele, Fabrication of Mullite
and Mullite-Matrix Composites by TransientViscous Sintering of
Composite Powders, J. Am. Ceram. Soc., 74, 10, pp. 2428–2437, 1991.
[7] T.Suzuki, A dense cell culture system for microorganisms using a stirred
ceramic membrane reactor incorporating asymmetric porous ceramic
filters, J. Ferment. Bioeng. 82, 3, pp. 264-271, 1996.
[8] I. Markovska, D. Georgiev, B. Bogdanov, Y. Hristov, Synthesis and
treatment of ceramic fractal composition, 12th Conference of the Europ.
Ceram Soc., 19–23 June, 2011, Stockholm, Sweden, pp. 1-4.
[9] S.Bachvarov, B. Samuneva, E. Stavrakeva, Manual of Exercise of
silicates, Technique, Sofia, 1978.
[10] P. V. Della, I. Kuhn, D.Hortza, Mater. Sci. Forum, 416, 2003, pp. 531.
[11] N. Yalcin, V. Servic, Studies on silica obtained from rice husk, Ceram.
Intern. 27, 2, 2001, pp. 219.
[12] J. James, M.S. Rao, Thermochim. Acta, Silica from rice husk through
thermal decomposition. Thermochimica acta, 97, 1986, pp. 329 -336.
[13] T. H. Liou, Preparation and characterization of nano- structured silica
from rice husk, Mater. Sci. Eng. A, 364, 2004, pp. 313 -323.
[14] Encyclopedia Britannica Online, S. V. "Aluminosilicate: phase diagram
of the alumina- silica system", accessed October 27, 2011.
[15] L. Mahnicka, Influence of Raw Materials Ratio and Sintering
Temperature n the Properties of the Refractory Mullite-Corundum
Ceramics, WASET, 63, pp. 404 – 409, 2012.</p>