Magnesium Borate Synthesis by Microwave Method Using MgCl2.6H2O and H3BO3
There are many kinds of metal borates found not only
in nature but also synthesized in the laboratory such as magnesium
borates. Due to its excellent properties, as remarkable ceramic
materials, they have also application areas in anti-wear and friction
reducing additives as well as electro-conductive treating agents. The
synthesis of magnesium borate powders can be fulfilled simply with
two different methods, hydrothermal and thermal synthesis.
Microwave assisted method, also another way of producing
magnesium borate, can be classified into thermal synthesis because of
using the principles of solid state synthesis. It also contributes
producing particles with small size and high purity in nano-size
material synthesize. In this study the production of magnesium
borates, are aimed using MgCl2.6H2O and H3BO3. The identification
of both starting materials and products were made by the equipments
of, X-Ray Diffraction (XRD) and Fourier Transform Infrared
Spectroscopy (FT-IR). After several synthesis steps magnesium
borates were synthesized and characterized by XRD and FT-IR, as
well.
[1] http://www.boren.gov.tr/icerik.php?id=30 (retrieved on 15.03.2013)
[2] W. Zhu, X. Zhang, L. Xiang, S. Zhu, "Hydrothermal Formation of the
Head-to-Head Coalesced Szaibelyite MgBO2(OH) Nanowires",
Nanoscale Research Letters, 4:724-731, 2009.
[3] S. Li, D. Xu, H. Shen, J. Zhou, Y. Fan, "Synthesis and Raman Properties
of Magnesium Borate Micro/Nanorods", Materials Research Bulletin
3650-3653, 2012.
[4] A. S. Kipcak, F. T. Senberber, E. Moroydor Derun, S. Piskin,
"Evaluation of the Magnesium Wastes with Boron Oxide in Magnesium
Borate Synthesis", World Academy of Science, Engineering and
Technology, pp. 1074-1078, 2012.
[5] M. Kör├╝k, ─É. Girgin, "Synthesis of Magnesium Borates Using Sodium
Borate and Magnesium Sulfate", Journal of Non-Crystalline Solids 355,
pp. 965-969, 2009.
[6] L. Dou, J. Zhong, H. Wang, "Preparation and Characterization of
Magnesium Borate for Special Glass", Physica Scripta T139 014010,
2010.
[7] E. Moroydor Derun, A. S. Kipcak, E. Gurel, S. Piskin, "Microwave
Assited Solid-State Synthesis of Magnesium Borate Hydrates at 270 W",
World Academy of Science, Engineering and Technology, pp. 1643-
1647, 2012.
[8] A. S. Kipcak, F. T. Senberber, E. Moroydor Derun, S. Piskin,
"Hydrothermal Synthesis of Magnesium Borate Hydrates from MgO and
H3BO3 at 80┬░C", Research Bulletin of the Australian Institute of High
Energetic Materials, vol. 1, pp. 47-55, 2011.
[9] W. Zhu, L. Xiang, Q. Zhang, X. Zhang, L. Hu, S. Zhu, "Morphology
preservation and cristallinity improvement in the thermal conversion of
the hydrothermal synthesized MgBO2(OH) nanowhiskers to Mg2B2O5
nanowhiskers", Journal of Crystal Growth, vol. 310, pp. 4262-4267,
2008
[10] H. Lee, K. Kim, M. Park, W. Kang, "Microwave-assisted Sintering of
Amorphous Powders", Journal of the Korean Ceramic Society, vol. 48,
pp. 14-19, 2011.
[11] A. Baykal, A. Evren, "Hydrothermal and Microwave-Assited Synthesis
of Boroarsenate, BaSO4", Turk J Chem, vol. 30, pp. 723-730 2006.
[12] F. Mawandadi, A. Pilotti, "The impact of microwave-assisted organic
synthesis in drug discovery", DDT, vol. 11, no. 3/4, 2006.
[13] B. L. Hayes, "Recent Advances in Microwave-Assisted Synthesis",
Aldrichimica ACTA, vol. 37, no.2, 2004.
[14] F. Demiral Kurtulus, H. Güler, "Bazı metal içeren boratlı ve borfosfatlı
bilesiklerin kat─▒-hal yöntemleriyle sentezlenmesi", BA├£ Fen Bil. Enst.
Derg., vol 5.1, 2003.
[15] A. Ajavakoma, S. Supsvetsonb, A. Sombootb, M. Sukwattanasinitta,
"Products from microwave and ultrasonic wave assisted acid hydrolysis
of chitin", Carbohydrate Polymer, vol. 90, pp. 73-77, 2012.
[16] E. Ay, "Magnezyum Boratl─▒ Bilesiklerin Kat─▒-Hal Kimyasal
Yöntemlerle Sentezlenmesi ve Karakterizasyon ├çal─▒smalar─▒", Bal─▒kesir
Üniversity,Institute of Science, Balıkesir, 2006.
[17] H. Guler, F. Kurtulus, E. Ay, G. Celik, I. Dogan, "Mg2B2O5 ve
Mg3(BO3)2 Bilesiklerinin Kat─▒-Hal ve Mikrodalga Yöntemle Sentezleri
ve Karakterizasyon Çalısmaları", IV. International Boron Symposium,
Eskisehir, September, 2009.
[18] E. Moroydor Derun, A. S. Kipcak, E. Gurel, S. Piskin, "Microwave
Assited Solid-State Synthesis of Magnesium Borate Hydrates at 270 W",
ICCE 2012: International Conference on Chemical Engineering, Paris,
November 2012.
[19] Q. Huang, G. Lu, J. Wang, J. Yu, "Thermal Decomposition Mechanisms
of MgCl2.6H2O and MgCl2.H2O", Journal of Analytical and Applied
Pyrolysis 91, pp. 159-164, 2011.
[20] Z. Zhang, X. Lu, F. Pan, Y. Wang, S.Yang, "Preparation of Anhydrous
Magnesium Chloride from Magnesium Chloride Hexahydrate", The
Minerals, Metals and Materials Society and ASM International, vol. 44-
B, pp. 354-358, 2013.
[21] H. C. Eoma, H. Park, H. S. Yoon, "Preparation of anhydrous magnesium
chloride from ammonium magnesium chloride hexahydrate", Advanced
Powder Technology, vol. 21, pp. 125-130, 2010.
[22] V. M. van Essen, J. Cot Gores, L. P. J. Bleijendaal, H. A. Zondag, R.
Schuitema, W. G. J. van Helden, "Characterization of salt hydrates for
compact seasonal thermochemical storage".
[23] L. Zhihong, H. Mancheng, "New synthetic method and thermochemistry
of szaibelyite", Thermochimica Acta, vol. 411, pp. 27-29, 2004.
[24] L. Zhihong, H. Mancheng, "Synthesis and thermochemistry of
MgO.3B2O3.3.5H2O", Thermochimica Acta, vol. 403, pp. 181-184,
2003.
[25] J. Yongzhong, G. Shiyang, X. Shuping, L. Jun, " FT-IR spectroscopy of
supersaturated aqueous solutions of magnesium borate", Spectrochimica
Acta Part A, vol. 56, pp. 1291-1297, 2000
[26] L. Zhihong, H. Mancheng, "Synthesis, characterization and
thermochemistry of a new form of 2MgO.3B2O3.17H2O",
Thermochimica Acta, vol. 412, pp. 215-218, 2004.
[1] http://www.boren.gov.tr/icerik.php?id=30 (retrieved on 15.03.2013)
[2] W. Zhu, X. Zhang, L. Xiang, S. Zhu, "Hydrothermal Formation of the
Head-to-Head Coalesced Szaibelyite MgBO2(OH) Nanowires",
Nanoscale Research Letters, 4:724-731, 2009.
[3] S. Li, D. Xu, H. Shen, J. Zhou, Y. Fan, "Synthesis and Raman Properties
of Magnesium Borate Micro/Nanorods", Materials Research Bulletin
3650-3653, 2012.
[4] A. S. Kipcak, F. T. Senberber, E. Moroydor Derun, S. Piskin,
"Evaluation of the Magnesium Wastes with Boron Oxide in Magnesium
Borate Synthesis", World Academy of Science, Engineering and
Technology, pp. 1074-1078, 2012.
[5] M. Kör├╝k, ─É. Girgin, "Synthesis of Magnesium Borates Using Sodium
Borate and Magnesium Sulfate", Journal of Non-Crystalline Solids 355,
pp. 965-969, 2009.
[6] L. Dou, J. Zhong, H. Wang, "Preparation and Characterization of
Magnesium Borate for Special Glass", Physica Scripta T139 014010,
2010.
[7] E. Moroydor Derun, A. S. Kipcak, E. Gurel, S. Piskin, "Microwave
Assited Solid-State Synthesis of Magnesium Borate Hydrates at 270 W",
World Academy of Science, Engineering and Technology, pp. 1643-
1647, 2012.
[8] A. S. Kipcak, F. T. Senberber, E. Moroydor Derun, S. Piskin,
"Hydrothermal Synthesis of Magnesium Borate Hydrates from MgO and
H3BO3 at 80┬░C", Research Bulletin of the Australian Institute of High
Energetic Materials, vol. 1, pp. 47-55, 2011.
[9] W. Zhu, L. Xiang, Q. Zhang, X. Zhang, L. Hu, S. Zhu, "Morphology
preservation and cristallinity improvement in the thermal conversion of
the hydrothermal synthesized MgBO2(OH) nanowhiskers to Mg2B2O5
nanowhiskers", Journal of Crystal Growth, vol. 310, pp. 4262-4267,
2008
[10] H. Lee, K. Kim, M. Park, W. Kang, "Microwave-assisted Sintering of
Amorphous Powders", Journal of the Korean Ceramic Society, vol. 48,
pp. 14-19, 2011.
[11] A. Baykal, A. Evren, "Hydrothermal and Microwave-Assited Synthesis
of Boroarsenate, BaSO4", Turk J Chem, vol. 30, pp. 723-730 2006.
[12] F. Mawandadi, A. Pilotti, "The impact of microwave-assisted organic
synthesis in drug discovery", DDT, vol. 11, no. 3/4, 2006.
[13] B. L. Hayes, "Recent Advances in Microwave-Assisted Synthesis",
Aldrichimica ACTA, vol. 37, no.2, 2004.
[14] F. Demiral Kurtulus, H. Güler, "Bazı metal içeren boratlı ve borfosfatlı
bilesiklerin kat─▒-hal yöntemleriyle sentezlenmesi", BA├£ Fen Bil. Enst.
Derg., vol 5.1, 2003.
[15] A. Ajavakoma, S. Supsvetsonb, A. Sombootb, M. Sukwattanasinitta,
"Products from microwave and ultrasonic wave assisted acid hydrolysis
of chitin", Carbohydrate Polymer, vol. 90, pp. 73-77, 2012.
[16] E. Ay, "Magnezyum Boratl─▒ Bilesiklerin Kat─▒-Hal Kimyasal
Yöntemlerle Sentezlenmesi ve Karakterizasyon ├çal─▒smalar─▒", Bal─▒kesir
Üniversity,Institute of Science, Balıkesir, 2006.
[17] H. Guler, F. Kurtulus, E. Ay, G. Celik, I. Dogan, "Mg2B2O5 ve
Mg3(BO3)2 Bilesiklerinin Kat─▒-Hal ve Mikrodalga Yöntemle Sentezleri
ve Karakterizasyon Çalısmaları", IV. International Boron Symposium,
Eskisehir, September, 2009.
[18] E. Moroydor Derun, A. S. Kipcak, E. Gurel, S. Piskin, "Microwave
Assited Solid-State Synthesis of Magnesium Borate Hydrates at 270 W",
ICCE 2012: International Conference on Chemical Engineering, Paris,
November 2012.
[19] Q. Huang, G. Lu, J. Wang, J. Yu, "Thermal Decomposition Mechanisms
of MgCl2.6H2O and MgCl2.H2O", Journal of Analytical and Applied
Pyrolysis 91, pp. 159-164, 2011.
[20] Z. Zhang, X. Lu, F. Pan, Y. Wang, S.Yang, "Preparation of Anhydrous
Magnesium Chloride from Magnesium Chloride Hexahydrate", The
Minerals, Metals and Materials Society and ASM International, vol. 44-
B, pp. 354-358, 2013.
[21] H. C. Eoma, H. Park, H. S. Yoon, "Preparation of anhydrous magnesium
chloride from ammonium magnesium chloride hexahydrate", Advanced
Powder Technology, vol. 21, pp. 125-130, 2010.
[22] V. M. van Essen, J. Cot Gores, L. P. J. Bleijendaal, H. A. Zondag, R.
Schuitema, W. G. J. van Helden, "Characterization of salt hydrates for
compact seasonal thermochemical storage".
[23] L. Zhihong, H. Mancheng, "New synthetic method and thermochemistry
of szaibelyite", Thermochimica Acta, vol. 411, pp. 27-29, 2004.
[24] L. Zhihong, H. Mancheng, "Synthesis and thermochemistry of
MgO.3B2O3.3.5H2O", Thermochimica Acta, vol. 403, pp. 181-184,
2003.
[25] J. Yongzhong, G. Shiyang, X. Shuping, L. Jun, " FT-IR spectroscopy of
supersaturated aqueous solutions of magnesium borate", Spectrochimica
Acta Part A, vol. 56, pp. 1291-1297, 2000
[26] L. Zhihong, H. Mancheng, "Synthesis, characterization and
thermochemistry of a new form of 2MgO.3B2O3.17H2O",
Thermochimica Acta, vol. 412, pp. 215-218, 2004.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:56551", author = "A. S. Kipcak and P. Gurses and K. Kunt and E. Moroydor Derun and S. Piskin", title = "Magnesium Borate Synthesis by Microwave Method Using MgCl2.6H2O and H3BO3", abstract = "There are many kinds of metal borates found not only
in nature but also synthesized in the laboratory such as magnesium
borates. Due to its excellent properties, as remarkable ceramic
materials, they have also application areas in anti-wear and friction
reducing additives as well as electro-conductive treating agents. The
synthesis of magnesium borate powders can be fulfilled simply with
two different methods, hydrothermal and thermal synthesis.
Microwave assisted method, also another way of producing
magnesium borate, can be classified into thermal synthesis because of
using the principles of solid state synthesis. It also contributes
producing particles with small size and high purity in nano-size
material synthesize. In this study the production of magnesium
borates, are aimed using MgCl2.6H2O and H3BO3. The identification
of both starting materials and products were made by the equipments
of, X-Ray Diffraction (XRD) and Fourier Transform Infrared
Spectroscopy (FT-IR). After several synthesis steps magnesium
borates were synthesized and characterized by XRD and FT-IR, as
well.", keywords = "FT-IR, magnesium borates, microwave method,XRD.", volume = "7", number = "5", pages = "287-6", }
