Abstract: Commercial nanocomposite food packaging type nano-silver containers were characterised using scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX). The presence of nanoparticles consistent with the incorporation of 1% nano-silver (Ag) and 0.1% titanium dioxide (TiO2) nanoparticle into polymeric materials formed into food containers was confirmed. Both nanomaterials used in this type of packaging appear to be embedded in a layered configuration within the bulk polymer. The dimensions of the incorporated nanoparticles were investigated using X-ray diffraction (XRD) and determined by calculation using the Scherrer Formula; these were consistent with Ag and TiO2 nanoparticles in the size range 20-70nm both were spherical shape nanoparticles. Antimicrobial assessment of the nanocomposite container has also been performed and the results confirm the antimicrobial activity of Ag and TiO2 nanoparticles in food packaging containers. Migration assessments were performed in a wide range of food matrices to determine the migration of nanoparticles from the packages. The analysis was based upon the relevant European safety Directives and involved the application of inductively coupled plasma mass spectrometry (ICP-MS) to identify the range of migration risk. The data pertain to insignificance levels of migration of Ag and TiO2 nanoparticles into the selected food matrices.
Abstract: Palm shell obtained from coastal part of southern
India was studied for the removal for the adsorption of Hg (II) ions.
Batch adsorption experiments were carried out as a function of pH,
concentration of Hg (II) ions, time, temperature and adsorbent dose.
Maximum removal was seen in the range pH 4.0- pH 7.0. The palm
shell powder used as adsorbent was characterized for its surface area,
SEM, PXRD, FTIR, ion exchange capacity, moisture content, and
bulk density, soluble content in water and acid and pH. The
experimental results were analyzed using Langmuir I, II, III, IV and
Freundlich adsorption isotherms. The batch sorption kinetics was
studied for the first order reversible reaction, pseudo first order;
pseudo second order reaction and the intra-particle diffusion reaction.
The biomass was successfully used for removal Hg (II) from
synthetic and industrial effluents and the technique appears
industrially applicable and viable.
Abstract: The hydraulic actuated excavator, being a non-linear
mobile machine, encounters many uncertainties. There are
uncertainties in the hydraulic system in addition to the uncertain
nature of the load. The simulation results obtained in this study show
that there is a need for intelligent control of such machines and in
particular interval type-2 fuzzy controller is most suitable for
minimizing the position error of a typical excavator-s bucket under
load variations. We consider the model parameter uncertainties such
as hydraulic fluid leakage and friction. These are uncertainties which
also depend up on the temperature and alter bulk modulus and
viscosity of the hydraulic fluid. Such uncertainties together with the
load variations cause chattering of the bucket position. The interval
type-2 fuzzy controller effectively eliminates the chattering and
manages to control the end-effecter (bucket) position with positional
error in the order of few millimeters.
Abstract: e-mail has become an important means of electronic
communication but the viability of its usage is marred by Unsolicited
Bulk e-mail (UBE) messages. UBE consists of many types
like pornographic, virus infected and 'cry-for-help' messages as well
as fake and fraudulent offers for jobs, winnings and medicines. UBE
poses technical and socio-economic challenges to usage of e-mails.
To meet this challenge and combat this menace, we need to
understand UBE. Towards this end, the current paper presents a
content-based textual analysis of nearly 3000 winnings-announcing
UBE. Technically, this is an application of Text Parsing and
Tokenization for an un-structured textual document and we approach
it using Bag Of Words (BOW) and Vector Space Document Model
techniques. We have attempted to identify the most frequently
occurring lexis in the winnings-announcing UBE documents. The
analysis of such top 100 lexis is also presented. We exhibit the
relationship between occurrence of a word from the identified lexisset
in the given UBE and the probability that the given UBE will be
the one announcing fake winnings. To the best of our knowledge and
survey of related literature, this is the first formal attempt for
identification of most frequently occurring lexis in winningsannouncing
UBE by its textual analysis. Finally, this is a sincere
attempt to bring about alertness against and mitigate the threat of
such luring but fake UBE.
Abstract: An experiment was conducted on the comparative
study of drip and furrow irrigation methods at the farmer-s field in
Umar Kot. The total area under experiment about 4000m2 was
divided into two equal portions. One portion about 40m X 50m was
occupied by drip and the other portion about 40m X 50m by furrow
irrigation method. Soil at the experimental site was clay loam in
texture for 0-60cm depth; average dry bulk density and field capacity
was 1.16g/cm3 and 28.5% respectively. The results reveal that the
drip irrigation method saved 56.4% water and gave 22% more yield
as compared to that of furrow irrigation method. Higher water use
efficiency about 4.87 was obtained in drip irrigation method; whereas
lower water used efficiency about 1.66 was obtained in furrow
irrigation method. The present study suggests farming community to
adopt drip irrigation method instead of old traditional flooding
methods.
Abstract: An organic bulk heterojunction (BHJ) was fabricated using a blended film containing Copper (II) tetrakis(4-acumylphenoxy) phthalocyanine (Tc-CuPc) along with [6,6]-Phenyl C61 butyric acid methyl ester (PCBM). Weight ratio between Tc-CuPc and PCBM was 1:1. The electrical properties of Tc-CuPc: PCBM BHJ were examined. Rectifying nature of the BHJ was displayed by current-voltage (I-V) curves, recorded in dark and at various temperatures. At low voltages, conduction was ohmic succeeded by space-charge limiting current (SCLC) conduction at higher voltages in which exponential trap distribution was dominant. Series resistance, shunt resistance, ideality factor, effective barrier height and mobility at room temperature were found to be 526 4, 482 k4, 3.7, 0.17 eV and 2×10-7 cm2V-1s-1 respectively. Temperature effect towards different BHJ parameters was observed under dark condition.
Abstract: Evaluation of contact pressure, surface and
subsurface contact stresses are essential to know the functional
response of surface coatings and the contact behavior mainly depends
on surface roughness, material property, thickness of layer and the
manner of loading. Contact parameter evaluation of real rough
surface contacts mostly relies on statistical single asperity contact
approaches. In this work, a three dimensional layered solid rough
surface in contact with a rigid flat is modeled and analyzed using
finite element method. The rough surface of layered solid is
generated by FFT approach. The generated rough surface is exported
to a finite element method based ANSYS package through which the
bottom up solid modeling is employed to create a deformable solid
model with a layered solid rough surface on top. The discretization
and contact analysis are carried by using the same ANSYS package.
The elastic, elastoplastic and plastic deformations are continuous in
the present finite element method unlike many other contact models.
The Young-s modulus to yield strength ratio of layer is varied in the
present work to observe the contact parameters effect while keeping
the surface roughness and substrate material properties as constant.
The contacting asperities attain elastic, elastoplastic and plastic states
with their continuity and asperity interaction phenomena is inherently
included. The resultant contact parameters show that neighboring
asperity interaction and the Young-s modulus to yield strength ratio
of layer influence the bulk deformation consequently affect the
interface strength.
Abstract: This paper presents a review on published literature
and experimental works on local sands for possible use as proppant,
specifically those from Terengganu coastal area. This includes
examination on characteristics of sand samples and selection of
experiments for proppant testing. Sand samples from identified areas
were tested according to particle size distribution, density, roundness
and sphericity, turbidity and mineralogy. Results from sand samples
were compared against proppant specifications set by API RP 56 and
selected commercial proppants. The present study found that the size
distribution, sphericity, turbidity and bulk density of Terengganu
sands are at par with some of commercial proppants. Nevertheless,
Terengganu sand samples do not completely surpass the required
roundness for use as proppant.
Abstract: This paper presents the influence of preloading on a)
the contact tractions, b) slip levels and c) stresses at the dovetail
blade-disc interface of an aero-engine through a three-dimensional
(3D) finite element (FE) modeling and analysis. The preloading is
applied by an interference fit at the dovetail interface and the bulk
loading is applied through the rotational speed of rotor. Preloading at
the dovetail interface reduces the peak contact pressure developed
due to bulk loading up to 35%, and reduces the peak contact pressure
and stress difference between top and bottom contact edges.
Increasing the level of preloading reduces the cyclic stress amplitude
at the interface up to certain values of preload and as a consequence,
an improvement in fatigue life could be expected. Fretting damage,
due to vibration and wind milling effect during engine ground
condition, can be minimized by preloading the dovetail interface.
Abstract: Nanomaterials have attracted considerable attention
during the last two decades, due to their unusual electrical, mechanical
and other physical properties as compared with their bulky
counterparts. The mechanical properties of nanostructured materials
show strong size dependency, which has been explained within the
framework of continuum mechanics by including the effects of surface
stress. The size-dependent deformations of two-dimensional
nanosized structures with surface effects are investigated in the paper
by the finite element method. Truss element is used to evaluate the
contribution of surface stress to the total potential energy and the
Gurtin and Murdoch surface stress model is implemented with
ANSYS through its user programmable features. The proposed
approach is used to investigate size-dependent stress concentration
around a nanosized circular hole and the size-dependent effective
moduli of nanoporous materials. Numerical results are compared with
available analytical results to validate the proposed modeling
approach.
Abstract: The rheological properties of light crude oil and its mixture with water were investigated experimentally. These rheological properties include steady flow behavior, yield stress, transient flow behavior, and viscoelastic behavior. A RheoStress RS600 rheometer was employed in all of the rheological examination tests. The light crude oil exhibits a Newtonian and for emulsion exhibits a non-Newtonian shear thinning behavior over the examined shear rate range of 0.1–120 s-1. In first time, a series of samples of crude oil from the Algerian Sahara has been tested and the results expressed in terms of τ=f(γ) have demonstrated their Newtonian character for the temperature included in [20°C, 70°C]. In second time and at T=20°C, the oil-water emulsions (30%, 50% and 70%) by volume of water), thermodynamically stable, have demonstrated a non-Newtonian rheological behavior that is to say, Herschel-Bulkley and Bingham types. For each type of crude oil-water emulsion, the rheological parameters are calculated by numerical treatment of results.
Abstract: The integrity and issues related to electrostatic performance associated with scaling Si MOSFET bulk sub 10nm channel length promotes research in new device architectures such as SOI, double gate and GAA MOSFET. In this paper, we present some novel characteristic of horizontal rectangular gate\gate all around MOSFETs with dual metal of gate we obtained using SILVACO TCAD tools. We will also exhibit some simulation results we obtained relating to the influence of some parameters variation on our structure, that having a direct impact on their threshold voltage and drain current. In addition, our TFET showed reasonable ION/IOFF ratio of (104) and low drain induced barrier lowering (DIBL) of 39 mV/V.
Abstract: Fourier transform infrared (FT-IR) spectroscopic imaging
is an emerging technique that provides both chemically and
spatially resolved information. The rich chemical content of data
may be utilized for computer-aided determinations of structure and
pathologic state (cancer diagnosis) in histological tissue sections for
prostate cancer. FT-IR spectroscopic imaging of prostate tissue has
shown that tissue type (histological) classification can be performed to
a high degree of accuracy [1] and cancer diagnosis can be performed
with an accuracy of about 80% [2] on a microscopic (≈ 6μm)
length scale. In performing these analyses, it has been observed
that there is large variability (more than 60%) between spectra from
different points on tissue that is expected to consist of the same
essential chemical constituents. Spectra at the edges of tissues are
characteristically and consistently different from chemically similar
tissue in the middle of the same sample. Here, we explain these
differences using a rigorous electromagnetic model for light-sample
interaction. Spectra from FT-IR spectroscopic imaging of chemically
heterogeneous samples are different from bulk spectra of individual
chemical constituents of the sample. This is because spectra not
only depend on chemistry, but also on the shape of the sample.
Using coupled wave analysis, we characterize and quantify the nature
of spectral distortions at the edges of tissues. Furthermore, we
present a method of performing histological classification of tissue
samples. Since the mid-infrared spectrum is typically assumed to
be a quantitative measure of chemical composition, classification
results can vary widely due to spectral distortions. However, we
demonstrate that the selection of localized metrics based on chemical
information can make our data robust to the spectral distortions
caused by scattering at the tissue boundary.