Abstract: Snow cover is an important phenomenon in
hydrology, hence modeling the snow accumulation and melting is an
important issue in places where snowmelt significantly contributes to
runoff and has significant effect on water balance. The physics-based
models are invariably distributed, with the basin disaggregated into
zones or grid cells. Satellites images provide valuable data to verify
the accuracy of spatially distributed model outputs. In this study a
spatially distributed physically based model (WetSpa) was applied to
predict snow cover and melting in the Latyan dam watershed in Iran.
Snowmelt is simulated based on an energy balance approach. The
model is applied and calibrated with one year of observed daily
precipitation, air temperature, windspeed, and daily potential
evaporation. The predicted snow-covered area is compared with
remotely sensed images (MODIS). The results show that simulated
snow cover area SCA has a good agreement with satellite image
snow cover area SCA from MODIS images. The model performance
is also tested by statistical and graphical comparison of simulated and
measured discharges entering the Latyan dam reservoir.
Abstract: We developed a method based on quasi-molecular
modelling to simulate the fall of water drops on horizontally smooth
and rough surfaces. Each quasi-molecule was a group of particles
that interacted in a fashion entirely analogous to classical Newtonian
molecular interactions. When a falling water droplet was simulated at
low impact velocity on both smooth and rough surfaces, the droplets
moved periodically (i.e. the droplets moved up and down for a
certain period, finally they stopped moving and reached a steady
state), spreading and recoiling without splash or break-up. Spreading
rates of falling water droplets increased rapidly as time increased
until the spreading rate reached its steady state at time t ~ 0.25 s for
rough surface and t ~ 0.40 s for smooth surface. The droplet height
above both surfaces decreased as time increased, remained constant
after the droplet diameter attained a maximum value and reached its
steady state at time t ~ 0.4 s. However, rough surface had higher
spreading rates of falling water droplets and lower height on the
surface than smooth one.
Abstract: The rate of production of main products of the Fischer-Tropsch reactions over Fe/HZSM5 bifunctional catalyst in a fixed bed reactor is investigated at a broad range of temperature, pressure, space velocity, H2/CO feed molar ratio and CO2, CH4 and water flow rates. Model discrimination and parameter estimation were performed according to the integral method of kinetic analysis. Due to lack of mechanism development for Fisher – Tropsch Synthesis on bifunctional catalysts, 26 different models were tested and the best model is selected. Comprehensive one and two dimensional heterogeneous reactor models are developed to simulate the performance of fixed-bed Fischer – Tropsch reactors. To reduce computational time for optimization purposes, an Artificial Feed Forward Neural Network (AFFNN) has been used to describe intra particle mass and heat transfer diffusion in the catalyst pellet. It is seen that products' reaction rates have direct relation with H2 partial pressure and reverse relation with CO partial pressure. The results show that the hybrid model has good agreement with rigorous mechanistic model, favoring that the hybrid model is about 25-30 times faster.
Abstract: The implementations of green roof have been widely
used in the developed countries such as Germany, United Kingdom,
United States and Canada. Green roof have many benefits such as
aesthetic and economic value, ecological gain which are optimization
of storm water management, urban heat island mitigation and energy
conservation. In term of pollution, green roof can control the air and
noise pollution in urban cities. The application of green roof in
Malaysian building has been studied with the previous work of green
roof either in Malaysia or other Asian region as like Indonesia,
Singapore, Thailand, Taiwan and several other countries that have
similar climate and environment as in Malaysia. These technologies
of adapting green roof have been compared to the Green Building
Index (GBI) of Malaysian buildings. The study has concentrated on
the technical aspect of green roof system having focused on i) waste
& recyclable materials ii) types of plants and method of planting and
iii) green roof as tool to reduce storm water runoff. The finding of
these areas will be compared to the suitability in achieving good
practice of the GBI in Malaysia. Results show that most of the
method are based on the countries own climate and environment.
This suggests that the method of using green roof must adhere to the
tropical climate of Malaysia. Suggestion of this research will be
viewed in term of the sustainability of the green roof. Further
research can be developed to implement the best method and
application in Malaysian climate especially in urban cities and
township.
Abstract: Sol-gel method has been used to fabricate
nanocomposite films on glass substrates composed halloysite clay
mineral and nanocrystalline TiO2. The methodology for the synthesis
involves a simple chemistry method utilized nonionic surfactant
molecule as pore directing agent along with the acetic acid-based solgel
route with the absence of water molecules. The thermal treatment
of composite films at 450oC ensures elimination of organic material
and lead to the formation of TiO2 nanoparticles onto the surface of
the halloysite nanotubes. Microscopy techniques and porosimetry
methods used in order to delineate the structural characteristics of the
materials. The nanocomposite films produced have no cracks and
active anatase crystal phase with small crystallite size were deposited
on halloysite nanotubes. The photocatalytic properties for the new
materials were examined for the decomposition of the Basic Blue 41
azo dye in solution. These, nanotechnology based composite films
show high efficiency for dye’s discoloration in spite of different
halloysite quantities and small amount of halloysite/TiO2 catalyst
immobilized onto glass substrates. Moreover, we examined the
modification of the halloysite/TiO2 films with silver particles in order
to improve the photocatalytic properties of the films. Indeed, the
presence of silver nanoparticles enhances the discoloration rate of the
Basic Blue 41 compared to the efficiencies obtained for unmodified
films.
Abstract: The aim of this article is to narrate the utility of novel simulation approach i.e. convolution method to predict blood concentration of drug utilizing dissolution data of salbutamol sulphate microparticulate formulations with different release patterns (1:1, 1:2 and 1:3, drug:polymer). Dissolution apparatus II USP 2007 and 900 ml double distilled water stirrd at 50 rpm was employed for dissolution analysis. From dissolution data, blood drug concentration was determined, and in return predicted blood drug concentration data was used to calculate the pharmacokinetic parameters i.e. Cmax, Tmax, and AUC. Convolution is a good biwaiver technique; however its better utility needs it application in the conditions where biorelevant dissolution media are used.
Abstract: This paper compares planning results of the electricity and water generation inventory up to year 2030 in the State of
Kuwait. Currently, the generation inventory consists of oil and gas fired technologies only. The planning study considers two main cases. The first case, Reference case, examines a generation inventory based on oil and gas fired generation technologies only.
The second case examines the inclusion of renewables as part of the generation inventory under two scenarios. In the first scenario, Ref-RE, renewable build-out is based on optimum economic performance
of overall generation system. Result shows that the optimum installed
renewable capacity with electric energy generation of 11% . In the second scenario, Ref-RE20, the renewable capacity build-out is
forced to provide 20% of electric energy by 2030. The respective energy systems costs of Reference, Ref-RE and Ref-RE20 case
scenarios reach US dollar 24, 10 and 14 billion annually in 2030.
Abstract: A study was conducted to determine the effect of
feeding glycerol on dairy cows performance. Twenty four Holstein
Friesian crossbred (>87.5% Holstein Friesian) lactating dairy cows in
early lactation; averaging 13+2.4 kg of milk, 64+45 days in milk,
55+16 months old and 325+26 kg live weight, were stratified for
milk yield, days in milk, age, stage of lactation and body weight, and
then randomly allocated to three treatment groups. All cows were fed
approximate 8 kg of concentrate together with ad libitum corn silage
and freely access to clean water. Nil or 150 and 300g of glycerol
were supplemented to the cows according to treatment groups. All
cows consumed similar concentrate, corn silage and total DM and
NELP. There were no significant differences in DM intake, CP intake,
NELP intake, milk and milk composition yields. All cows had similar
fat, protein, lactose, solid not fat and total solid percentage. All cows
gain similar live weight. The present study indicated that,
supplementation of glycerol did not enhance milk yield, milk
composition and live weight change.
Abstract: Cyprus- offshore aquaculture industry has promising
prospects taking into account that Cyprus is an island. Its production
trend is increasing overtaking bigger countries such Greece and Italy.
However, current mooring systems seem to be under-performing
acting as obstacles for its future development. Furthermore, shallow
coastal waters scarcity due to competing industries dictates future
development to come by moving further from shore exposing fish
farms and subsequently mooring systems to harsher environmental
loadings. It is, therefore, of paramount importance to design mooring
systems based on engineering and scientific principles and leave
behind the present “trial and error" methods. This paper presents the
current state of Cyprus- offshore aquaculture industry and focuses of
its mooring designs by proposing a new methodology for designing
more reliable systems, hence ensuring its future.
Abstract: The Želazny Most tailing pond is one of the largest
facilities worldwide for waste disposal from the copper mines located
in South-West Poland. A potential failure of the dam would allow
more than 10 million cubic meters of contaminated slurry to flow to
the valley, causing immense environmental problems to the
surrounding area. Thus, the determination of the strength properties
of the dam's soils and their variability is of utmost importance.
An extensive site investigation consisting of more than 480 cone
penetration tests (CPTs) with or without pore water pressure
measurements were conducted within a period of 13 years to study
the mechanical properties of the tailings body. The present work
investigates the point variability of the soil strength parameters
(effective friction angle
Abstract: We present an implementation of an Online Exhibition System (OES) web service(s) that reflects our experiences with using web service development packages and software process models. The system provides major functionality that exists in similar packages. While developing such a complex web service, we gained insightful experience (i) in the traditional software development processes: waterfall model and evolutionary development and their fitness to web services development, (ii) in the fitness and effectiveness of a major web services development kit.
Abstract: Analytical investigation of the sedimentation
processes in the river engineering and hydraulic structures is of vital
importance as this can affect water supply for the cultivating lands in
the command area. The reason being that gradual sediment formation
behind the reservoir can reduce the nominal capacity of these dams.
The aim of the present paper is to analytically investigate
sedimentation process along the river course and behind the storage
reservoirs in general and the Eastern Intake of the Dez Diversion weir
in particular using the SHARC software. Results of the model
indicated the water level at 115.97m whereas the real time
measurement from the river cross section was 115.98 m which
suggests a significantly close relation between them. The average
transported sediment load in the river was measured at 0.25mm ,
from which it can be concluded that nearly 100% of the suspended
loads in river are moving which suggests no sediment settling but
indicates that almost all sediment loads enters into the intake. It was
further showed the average sediment diameter entering the intake to
be 0.293 mm which in turn suggests that about 85% of suspended
sediments in the river entre the intake. Comparison of the results
from the SHARC model with those obtained form the SSIIM
software suggests quite similar outputs but distinguishing the
SHARC model as more appropriate for the analysis of simpler
problems than other model.
Abstract: In this study, single nozzle method used for
electrospinning technique which composite polymer solution with
cellulose nanowiskers (CNW) was treated by ultrasonic sonificator
have been compared with coaxial (double) nozzle method, in terms of
mechanical, thermal and morphological properties of composite
nanofiber. The effect of water content in composite polymer solution
on properties of nanofiber has also been examined. It has been seen
that single nozzle method which polymer solution does not contain
water has better results than that of coaxial method, in terms of
mechanical, thermal and morphological properties of nanofiber.
However, it is necessary to make an optimization study on setting
condition of ultrasonic treatment to get better dispersion of CNW in
composite nanofiber and to get better mechanical and thermal
properties
Abstract: The paper presents the results of a series of
experiments conducted on physical models of Quarter-circle
breakwater (QBW) in a two dimensional monochromatic wave
flume. The purpose of the experiments was to evaluate the reflection
coefficient Kr of QBW models of different radii (R) for different
submergence ratios (d/hc), where d is the depth of water and hc is the
height of the breakwater crest from the sea bed. The radii of the
breakwater models studied were 20cm, 22.5cm, 25cm, 27.5cm and
submergence ratios used varied from 1.067 to 1.667. The wave
climate off the Mangalore coast was used for arriving at the various
model wave parameters. The incident wave heights (Hi) used in the
flume varied from 3 to 18cm, and wave periods (T) ranged from 1.2 s
to 2.2 s. The water depths (d) of 40cm, 45cm and 50cm were used in
the experiments. The data collected was analyzed to compute
variation of reflection coefficient Kr=Hr/Hi (where Hr=reflected wave
height) with the wave steepness Hi/gT2 for various R/Hi
(R=breakwater radius) values. It was found that the reflection
coefficient increased as incident wave steepness increased. Also as
wave height decreases reflection coefficient decreases and as
structure radius R increased Kr decreased slightly.
Abstract: The effects of global warming on India vary from the
submergence of low-lying islands and coastal lands to the melting of
glaciers in the Indian Himalayas, threatening the volumetric flow rate
of many of the most important rivers of India and South Asia. In
India, such effects are projected to impact millions of lives. As a
result of ongoing climate change, the climate of India has become
increasingly volatile over the past several decades; this trend is
expected to continue.
Climate change is one of the most important global environmental
challenges, with implications for food production, water supply,
health, energy, etc. Addressing climate change requires a good
scientific understanding as well as coordinated action at national and
global level. The climate change issue is part of the larger challenge
of sustainable development. As a result, climate policies can be more
effective when consistently embedded within broader strategies
designed to make national and regional development paths more
sustainable. The impact of climate variability and change, climate
policy responses, and associated socio-economic development will
affect the ability of countries to achieve sustainable development
goals.
A very well calibrated Soil and Water Assessment Tool (R2 =
0.9968, NSE = 0.91) was exercised over the Khatra sub basin of the
Kangsabati River watershed in Bankura district of West Bengal,
India, in order to evaluate projected parameters for agricultural
activities. Evapotranspiration, Transmission Losses, Potential
Evapotranspiration and Lateral Flow to reach are evaluated from the
years 2041-2050 in order to generate a picture for sustainable
development of the river basin and its inhabitants.
India has a significant stake in scientific advancement as well as
an international understanding to promote mitigation and adaptation.
This requires improved scientific understanding, capacity building,
networking and broad consultation processes. This paper is a
commitment towards the planning, management and development of
the water resources of the Kangsabati River by presenting detailed
future scenarios of the Kangsabati river basin, Khatra sub basin, over
the mentioned time period.
India-s economy and societal infrastructures are finely tuned to the
remarkable stability of the Indian monsoon, with the consequence
that vulnerability to small changes in monsoon rainfall is very high.
In 2002 the monsoon rains failed during July, causing profound loss
of agricultural production with a drop of over 3% in India-s GDP.
Neither the prolonged break in the monsoon nor the seasonal rainfall
deficit was predicted. While the general features of monsoon
variability and change are fairly well-documented, the causal
mechanisms and the role of regional ecosystems in modulating the
changes are still not clear. Current climate models are very poor at
modelling the Asian monsoon: this is a challenging and critical
region where the ocean, atmosphere, land surface and mountains all
interact. The impact of climate change on regional ecosystems is
likewise unknown. The potential for the monsoon to become more
volatile has major implications for India itself and for economies
worldwide. Knowledge of future variability of the monsoon system,
particularly in the context of global climate change, is of great
concern for regional water and food security.
The major findings of this paper were that of all the chosen
projected parameters, transmission losses, soil water content,
potential evapotranspiration, evapotranspiration and lateral flow to
reach, display an increasing trend over the time period of years 2041-
2050.
Abstract: In recent years, the underground water sources in
southern Taiwan have become salinized because of saltwater
intrusions. This study explores the adsorption characteristics of
activated carbon on salinizing inorganic salts using isothermal
adsorption experiments and provides a model analysis. The
temperature range for the isothermal adsorption experiments ranged
between 5 to 45 ℃, and the amount adsorbed varied between 28.21 to
33.87 mg/g. All experimental data of adsorption can be fitted to both
the Langmuir and the Freundlich models. The thermodynamic
parameters for per chlorate onto granular activated carbon were
calculated as -0.99 to -1.11 kcal/mol for DG°, -0.6 kcal/mol for DH°,
and 1.21 to 1.84 kcal/mol for DS°. This shows that the adsorption
process of granular activated carbon is spontaneously exothermic. The
observation of adsorption behaviors under low ionic strength, low pH
values, and low temperatures is beneficial to the adsorption removal of
perchlorate with granular activated carbon.
Abstract: Nigella sativa L. is an aromatic plant belonging to the
family Ranunculaceae. It has been used traditionally, especially in the
middle East and India, for the treatment of asthma, cough, bronchitis,
headache, rheumatism, fever, influenza and eczema. Several
biological activities have been reported in Nigella sativa seeds,
including antioxidant. In this context we tried to estimate the
antioxidant activity of various extracts prepared from Nigella sativa
seeds, methanolic extract (ME), chloroformic extract (CE), hexanic
extract (HE : fixed oil), ethyl acetate extract (EAE) water extract
(WE). The Folin-Ciocalteu assay showed that CE and EAE contained
high level of phenolic compounds 81.31 and 72.43μg GAE/mg of
extract respectively. Similarly, the CE and EAE exhibited the highest
DPPH radical scavenging activity, with IC50 values of 106.56μg/ml
and 121.62μg/ml respectively. In addition, CE and HE showed the
most scavenging activity against superoxide radical generated in the
PMS-NADH-NBT system with respective IC50 values of 361.86
μg/ml and 371.80 μg/ml, which is comparable to the activity of the
standard antioxidant BHT (344.59 μg/ml). Ferrous ion chelating
capacity assay showed that WE, EAE and ME are the most active
with 40.57, 39.70 and 22.02 mg EDTA-E/g of extract. The inhibition
of linoleic acid/ß-carotene coupled oxidation was estimated by ßcarotene
bleaching assay, this showed a highest relative antioxidant
activity with CE and EAE (69.82% of inhibition). The antioxidant
activities of the methanolic extract and the fixed oil are confirmed by
an in vivo assay in mice, the daily oral administration of methanolic
extract (500 and 800 mg/kg/day) and fixed oil (2 and 4 ml/kg/day)
during 21 days, resulted in a significant enhancement of the blood
total antioxidant capacity (measured by KRL test) and the plasmatic
antioxidant capacity towards DPPH radical.
Abstract: In order to investigate a PROX microreactor
performance, two-dimensional modeling of the reacting flow
between two parallel plates is performed through a finite volume
method using an improved SIMPLE algorithm. A three-step surface
kinetics including hydrogen oxidation, carbon monoxide oxidation
and water-gas shift reaction is applied for a Pt-Fe/γ-Al2O3 catalyst
and operating temperatures of about 100ºC. Flow pattern, pressure
field, temperature distribution, and mole fractions of species are
found in the whole domain for all cases. Also, the required reactive
length for removing carbon monoxide from about 2% to less than 10
ppm is found. Furthermore, effects of hydraulic diameter, wall
temperature, and inlet mole fraction of air and water are investigated
by considering carbon monoxide selectivity and conversion. It is
found that air and water addition may improve the performance of
the microreactor in carbon monoxide removal in such operating
conditions; this is in agreement with the pervious published results.
Abstract: The objective of this study was to evaluate the
distribution patterns of Cd, Zn and Hg in groundwater by geospatial
interpolation. The study was performed at Rayong province in the
eastern part of Thailand, with high agricultural and industrial
activities. Groundwater samples were collected twice a year from 31
tubewells around this area. Inductively Coupled Plasma-Atomic
Emission Spectrometer (ICP-AES) was used to measure the
concentrations of Cd, Zn, and Hg in groundwater samples. The
results demonstrated that concentrations of Cd, Zn and Hg range
from 0.000-0.297 mg/L (x = 0.021±0.033 mg/L), 0.022-33.236 mg/L
(x = 4.214±4.766 mg/L) and 0.000-0.289 mg/L (x = 0.023±0.034
mg/L), respectively. Most of the heavy metals concentrations were
exceeded groundwater quality standards as specified in the Ministry
of Natural Resources and Environment, Thailand. The trend
distribution of heavy metals were high concentrations at the
southeastern part of the area that especially vulnerable to heavy
metals and other contaminants.
Abstract: The effects of upflow liquid velocity (ULV) on
performance of expanded granular sludge bed (EGSB) system were
investigated. The EGSB reactor, made from galvanized steel pipe
0.10 m diameter and 5 m height, had been used to treat piggery
wastewater, after passing through acidification tank. It consisted of
39.3 l working volume in reaction zone and 122 l working volume in
sedimentation zone, at the upper part. The reactor was seeded with
anaerobically digested sludge and operated at the ULVs of 4, 8, 12
and 16 m/h, consecutively, corresponding to organic loading rates of
9.6 – 13.0 kg COD/ (m3.d). The average COD concentrations in the
influent were 9,601 – 13,050 mg/l. The COD removal was not
significantly different, i.e. 93.0% - 94.0%, except at ULV 12 m/h where
SS in the influent was exceptionally high so that VSS washout had
occurred, leading to low COD removal. The FCOD and VFA
concentrations in the effluent of all experiments were not much
different, indicating the same range of treatment performance. The
biogas production decreased at higher ULV and ULV of 4 m/h is
suggested as design criterion for EGSB system.