Abstract: Experimental data are presented to show the influence of different types of chemical demulsifier on the stability and demulsification of emulsions. Three groups of demulsifier with different functional groups were used in this work namely amines, alcohol and polyhydric alcohol. The results obtained in this study have exposed the capability of chemical breaking agents in destabilization of water in crude oil emulsions. From the present study, found that molecular weight of the demulsifier were influent the capability of the emulsion to separate.
Abstract: A new chelating resin is prepared by coupling Amberlite XAD-4 with 1-amino-2-naphthole through an azo spacer. The resulting sorbent has been characterized by FT-IR, elemental analysis and thermogravimetric analysis (TGA) and studied for preconcentrating of Fe (II) using flame atomic absorption spectrometry (FAAS) for metal monitoring. The optimum pH value for sorption of the iron ions was 6.5. The resin was subjected to evaluation through batch binding of mentioned metal ion. Quantitative desorption occurs instantaneously with 0.5 M HNO3. The sorption capacity was found 4.1 mmol.g-1 of resin for Fe (II) in the aqueous solution. The chelating resin can be reused for 10 cycles of sorption-desorption without any significant change in sorption capacity. A recovery of 97% was obtained the metal ions with 0.5 M HNO3 as eluting agent. The method was applied for metal ions determination from industrial waste water sample.
Abstract: The effects of down slope steepness on soil splash distribution under a water drop impact have been investigated in this study. The equipment used are the burette to simulate a water drop, a splash cup filled with sandy soil which forms the source area and a splash board to collect the ejected particles. The results found in this study have shown that the apparent mass increased with increasing downslope angle following a linear regression equation with high coefficient of determination. In the same way, the radial soil splash distribution over the distance has been analyzed statistically, and an exponential function was the best fit of the relationship for the different slope angles. The curves and the regressions equations validate the well known FSDF and extend the theory of Van Dijk.
Abstract: Environmental factors affect agriculture production
productivity and efficiency resulted in changing of profit efficiency.
This paper attempts to estimate the impacts of environmental factors
to profitability of rice farmers in the Red River Delta of Vietnam. The
dataset was extracted from 349 rice farmers using personal
interviews. Both OLS and MLE trans-log profit functions were used
in this study. Five production inputs and four environmental factors
were included in these functions. The estimation of the stochastic
profit frontier with a two-stage approach was used to measure
profitability. The results showed that the profit efficiency was about
75% on the average and environmental factors change profit
efficiency significantly beside farm specific characteristics. Plant
disease, soil fertility, irrigation apply and water pollution were the
four environmental factors cause profit loss in rice production. The
result indicated that farmers should reduce household size, farm
plots, apply row seeding technique and improve environmental
factors to obtain high profit efficiency with special consideration is
given for irrigation water quality improvement.
Abstract: Today we tend to go back to the past to our root
relation to nature. Therefore in search of friendly spaces there are
elements of natural environment introduced as elements of spatial
composition. Though reinvented through the use of the new
substance such as greenery, water etc. made possible by state of the
art technologies, still, in principal, they remain the same. As a result,
sustainable design, based upon the recognized means of composition
in addition to the relation of architecture and urbanism vs. nature
introduces a new aesthetical values into architectural and urban
space.
Abstract: In this research, an aerobic composting method is
studied to reuse organic waste from rubber factory waste as soil fertilizer and to study the effect of cellulolytic microbial activator
(CMA) as the activator in the rubber factory waste composting. The
performance of the composting process was monitored as a function
of carbon and organic matter decomposition rate, temperature and
moisture content. The results indicate that the rubber factory waste is best composted with water hyacinth and sludge than composted
alone. In addition, the CMA is more affective when mixed with the rubber factory waste, water hyacinth and sludge since a good fertilizer is achieved. When adding CMA into the rubber factory
waste composted alone, the finished product does not achieve a
standard of fertilizer, especially the C/N ratio.
Finally, the finished products of composting rubber factory waste and water hyacinth and sludge (both CMA and without CMA), can be an environmental friendly alternative to solve the disposal problems of rubber factory waste. Since the C/N ratio, pH, moisture
content, temperature, and nutrients of the finished products are acceptable for agriculture use.
Abstract: The coalescer process is one of the methods for oily water treatment by increasing the oil droplet size in order to enhance the separating velocity and thus effective separation. However, the presence of surfactants in an oily emulsion can limit the obtained mechanisms due to the small oil size related with stabilized emulsion. In this regard, the purpose of this research is to improve the efficiency of the coalescer process for treating the stabilized emulsion. The effects of bed types, bed height, liquid flow rate and stage coalescer (step-bed) on the treatment efficiencies in term of COD values were studied. Note that the treatment efficiency obtained experimentally was estimated by using the COD values and oil droplet size distribution. The study has shown that the plastic media has more effective to attach with oil particles than the stainless one due to their hydrophobic properties. Furthermore, the suitable bed height (3.5 cm) and step bed (3.5 cm with 2 steps) were necessary in order to well obtain the coalescer performance. The application of step bed coalescer process in reactor has provided the higher treatment efficiencies in term of COD removal than those obtained with classical process. The proposed model for predicting the area under curve and thus treatment efficiency, based on the single collector efficiency (ηT) and the attachment efficiency (α), provides relatively a good coincidence between the experimental and predicted values of treatment efficiencies in this study.
Abstract: In this study we investigate the insertion of
pioglitazone, a Thiazolidinedione, into the two different sizes of
Carbon nanotub. It was shown that the insertion of pioglitazone into
the carbon nanotube in a water solute environment could be related
to the diameter of the nanotube and in the flow of the waters via
hydrophilic interactions. This encapsulated drug-carbon nanotube
molecule can be further applicable in other investigations in target
therapy with these agents regarding to reduce their potential toxic
effects.
Abstract: Decentralized eco-sanitation system is a promising and sustainable mode comparing to the century-old centralized conventional sanitation system. The decentralized concept relies on an environmentally and economically sound management of water, nutrient and energy fluxes. Source-separation systems for urban waste management collect different solid waste and wastewater streams separately to facilitate the recovery of valuable resources from wastewater (energy, nutrients). A resource recovery centre constituted for 20,000 people will act as the functional unit for the treatment of urban waste of a high-density population community, like Singapore. The decentralized system includes urine treatment, faeces and food waste co-digestion, and horticultural waste and organic fraction of municipal solid waste treatment in composting plants. A design model is developed to estimate the input and output in terms of materials and energy. The inputs of urine (yellow water, YW) and faeces (brown water, BW) are calculated by considering the daily mean production of urine and faeces by humans and the water consumption of no-mix vacuum toilet (0.2 and 1 L flushing water for urine and faeces, respectively). The food waste (FW) production is estimated to be 150 g wet weight/person/day. The YW is collected and discharged by gravity into tank. It was found that two days are required for urine hydrolysis and struvite precipitation. The maximum nitrogen (N) and phosphorus (P) recovery are 150-266 kg/day and 20-70 kg/day, respectively. In contrast, BW and FW are mixed for co-digestion in a thermophilic acidification tank and later a decentralized/centralized methanogenic reactor is used for biogas production. It is determined that 6.16-15.67 m3/h methane is produced which is equivalent to 0.07-0.19 kWh/ca/day. The digestion residues are treated with horticultural waste and organic fraction of municipal waste in co-composting plants.
Abstract: Fecal sterol has been proposed as a chemical indicator
of human fecal pollution even when fecal coliform populations have
diminished due to water chlorination or toxic effects of industrial
effluents. This paper describes an improved derivatization procedure
for simultaneous determination of four fecal sterols including
coprostanol, epicholestanol, cholesterol and cholestanol using gas
chromatography-mass spectrometry (GC-MS), via optimization study
on silylation procedures using N-O-bis
(trimethylsilyl)-trifluoroacetamide (BSTFA), and
N-(tert-butyldimethylsilyl)-N-methyltrifluoroacetamide
(MTBSTFA), which lead to the formation of trimethylsilyl (TMS) and
tert-butyldimethylsilyl (TBS) derivatives, respectively. Two
derivatization processes of injection-port derivatization and water bath
derivatization (60 oC, 1h) were inspected and compared. Furthermore,
the methylation procedure at 25 oC for 2h with
trimethylsilydiazomethane (TMSD) for fecal sterols analysis was also
studied. It was found that most of TMS derivatives demonstrated the
highest sensitivities, followed by methylated derivatives. For BSTFA
or MTBSTFA derivatization processes, the simple injection-port
derivatization process could achieve the same efficiency as that in the
tedious water bath derivatization procedure.
Abstract: In this study, we experiment on precise control outlet
temperature of water from the water cooler with hot-gas bypass
method based on PI control logic for machine tool. Recently, technical
trend for machine tools is focused on enhancement of speed and
accuracy. High speedy processing causes thermal and structural
deformation of objects from the machine tools. Water cooler has to be
applied to machine tools to reduce the thermal negative influence with
accurate temperature controlling system. The goal of this study is to
minimize temperature error in steady state. In addition, control period
of an electronic expansion valve were considered to increment of
lifetime of the machine tools and quality of product with a water
cooler.
Abstract: Over a million tonnes of cigarette butts (CBs) are produced worldwide annually. These CBs accumulate in the environment due to the poor biodegradability of the cellulose acetate filters and pose a serious environmental risk. This paper presents some of the results from a continuing study on recycling CBs into fired clay bricks. Properties including compressive strength, flexural strength, density, water absorption and thermal conductivity of fired clay bricks are reported and discussed. Furthermore, leaching of heavy metals from the manufactured clay bricks was tested. The results show that the density of fired bricks was reduced by about 8 – 30 %, depending on the percentage of CBs incorporated into the raw materials. The compressive strength of bricks tested was 12.57, 5.22 and 3.00 MPa for 2.5, 5.0 and 10 % CB content respectively. Water absorption and initial rate of absorption values increased as density, and hence porosity, of bricks decreased with increasing CB volume. The leaching test results revealed trace amounts of heavy metals.
Abstract: Enhancement of the performance of a reverse osmosis
(RO) unit through periodic control is studied. The periodic control
manipulates the feed pressure and flow rate of the RO unit. To ensure
the periodic behavior of the inputs, the manipulated variables (MV)
are transformed into the form of sinusoidal functions. In this case, the
amplitude and period of the sinusoidal functions become the
surrogate MV and are thus regulated via nonlinear model predictive
control algorithm. The simulation results indicated that the control
system can generate cyclic inputs necessary to enhance the closedloop
performance in the sense of increasing the permeate production
and lowering the salt concentration. The proposed control system can
attain its objective with arbitrary set point for the controlled outputs.
Successful results were also obtained in the presence of modeling
errors.
Abstract: Contour filter strips planted with perennial vegetation
can be used to improve surface and ground water quality by reducing
pollutant, such as NO3-N, and sediment outflow from cropland to a
river or lake. Meanwhile, the filter strips of perennial grass with biofuel
potentials also have economic benefits of producing ethanol. In
this study, The Soil and Water Assessment Tool (SWAT) model was
applied to the Walnut Creek Watershed to examine the effectiveness
of contour strips in reducing NO3-N outflows from crop fields to the
river or lake. Required input data include watershed topography,
slope, soil type, land-use, management practices in the watershed and
climate parameters (precipitation, maximum/minimum air
temperature, solar radiation, wind speed and relative humidity).
Numerical experiments were conducted to identify potential
subbasins in the watershed that have high water quality impact, and
to examine the effects of strip size and location on NO3-N reduction
in the subbasins under various meteorological conditions (dry,
average and wet). Variable sizes of contour strips (10%, 20%, 30%
and 50%, respectively, of a subbasin area) planted with perennial
switchgrass were selected for simulating the effects of strip size and
location on stream water quality. Simulation results showed that a
filter strip having 10%-50% of the subbasin area could lead to 55%-
90% NO3-N reduction in the subbasin during an average rainfall
year. Strips occupying 10-20% of the subbasin area were found to be
more efficient in reducing NO3-N when placed along the contour
than that when placed along the river. The results of this study can
assist in cost-benefit analysis and decision-making in best water
resources management practices for environmental protection.
Abstract: In the first part of the research work, an electrolyzer (10.16 cm dia and 24.13 cm height) to produce hydrogen and oxygen was constructed for single slice O2/H2 fuel cell using cation exchange membrane. The electrolyzer performance was tested with 23% NaOH, 30% NaOH, 30% KOH and 35% KOH electrolyte solution with current input 4 amp and 2.84 V from the rectifier. Rates of volume of hydrogen produced were 0.159 cm3/sec, 0.155 cm3/sec, 0.169 cm3/sec and 0.163 cm3/sec respectively from 23% NaOH, 30% NaOH, 30% KOH and 35% KOH solution. Rates of volume of oxygen produced were 0.212 cm3/sec, 0.201 cm3/sec, 0.227 cm3/sec and 0.219 cm3/sec respectively from 23% NaOH, 30% NaOH, 30% KOH and 35% KOH solution (1.5 L). In spite of being tested the increased concentration of electrolyte solution, the gas rate does not change significantly. Therefore, inexpensive 23% NaOH electrolyte solution was chosen to use as the electrolyte in the electrolyzer. In the second part of the research work, graphite serpentine flow plates, fiberglass end plates, stainless steel screen electrodes, silicone rubbers were made to assemble the single slice O2/H2 polymer electrolyte membrane fuel cell (PEMFC).
Abstract: The use of artificial neural network (ANN) modeling
for prediction and forecasting variables in water resources
engineering are being increasing rapidly. Infrastructural applications
of ANN in terms of selection of inputs, architecture of networks,
training algorithms, and selection of training parameters in different
types of neural networks used in water resources engineering have
been reported. ANN modeling conducted for water resources
engineering variables (river sediment and discharge) published in
high impact journals since 2002 to 2011 have been examined and
presented in this review. ANN is a vigorous technique to develop
immense relationship between the input and output variables, and
able to extract complex behavior between the water resources
variables such as river sediment and discharge. It can produce robust
prediction results for many of the water resources engineering
problems by appropriate learning from a set of examples. It is
important to have a good understanding of the input and output
variables from a statistical analysis of the data before network
modeling, which can facilitate to design an efficient network. An
appropriate training based ANN model is able to adopt the physical
understanding between the variables and may generate more effective
results than conventional prediction techniques.
Abstract: Droughts are complex, natural hazards that, to a
varying degree, affect some parts of the world every year. The range
of drought impacts is related to drought occurring in different stages
of the hydrological cycle and usually different types of droughts,
such as meteorological, agricultural, hydrological, and socioeconomical
are distinguished. Streamflow drought was analyzed by
the method of truncation level (at 70% level) on daily discharges
measured in 54 hydrometric stations in southwestern Iran. Frequency
analysis was carried out for annual maximum series (AMS) of
drought deficit volume and duration series. Some factors including
physiographic, climatic, geologic, and vegetation cover were studied
as influential factors in the regional analysis. According to the results
of factor analysis, six most effective factors were identified as area,
rainfall from December to February, the percent of area with
Normalized Difference Vegetation Index (NDVI)
Abstract: In this article, the phenomenon of nonlinear
consolidation in saturated and homogeneous clay layer is studied.
Considering time-varied drainage model, the excess pore water
pressure in the layer depth is calculated. The Generalized Differential
Quadrature (GDQ) method is used for the modeling and numerical
analysis. For the purpose of analysis, first the domain of independent
variables (i.e., time and clay layer depth) is discretized by the
Chebyshev-Gauss-Lobatto series and then the nonlinear system of
equations obtained from the GDQ method is solved by means of the
Newton-Raphson approach. The obtained results indicate that the
Generalized Differential Quadrature method, in addition to being
simple to apply, enjoys a very high accuracy in the calculation of
excess pore water pressure.
Abstract: The assessment of surface waters in Enugu metropolis
for fecal coliform bacteria was undertaken. Enugu urban was divided
into three areas (A1, A2 and A3), and fecal coliform bacteria
analysed in the surface waters found in these areas for four years
(2005-2008). The plate count method was used for the analyses. Data
generated were subjected to statistical tests involving; Normality test,
Homogeneity of variance test, correlation test, and tolerance limit
test. The influence of seasonality and pollution trends were
investigated using time series plots. Results from the tolerance limit
test at 95% coverage with 95% confidence, and with respect to EU
maximum permissible concentration show that the three areas suffer
from fecal coliform pollution. To this end, remediation procedure
involving the use of saw-dust extracts from three woods namely;
Chlorophora-Excelsa (C-Excelsa),Khayan-Senegalensis,(CSenegalensis)
and Erythrophylum-Ivorensis (E-Ivorensis) in
controlling the coliforms was studied. Results show that mixture of
the acetone extracts of the woods show the most effective
antibacterial inhibitory activities (26.00mm zone of inhibition)
against E-coli. Methanol extract mixture of the three woods gave best
inhibitory activity (26.00mm zone of inhibition) against S-areus, and
25.00mm zones of inhibition against E-Aerogenes. The aqueous
extracts mixture gave acceptable zones of inhibitions against the
three bacteria organisms.
Abstract: Modeling and simulation of fixed bed three-phase
catalytic reactors are considered for wet air catalytic oxidation of
phenol to perform a comparative numerical analysis between tricklebed
and packed-bubble column reactors. The modeling involves
material balances both for the catalyst particle as well as for different
fluid phases. Catalyst deactivation is also considered in a transient
reactor model to investigate the effects of various parameters
including reactor temperature on catalyst deactivation. The
simulation results indicated that packed-bubble columns were
slightly superior in performance than trickle beds. It was also found
that reaction temperature was the most effective parameter in catalyst
deactivation.