Abstract: In this paper we study a system composed by carbon
nanotube (CNT) and bundle of carbon nanotube (BuCNT) interacting
with a specific fatty acid as molecular probe. Full system is
represented by open nanotube (or nanotubes) and the linoleic acid
(LA) relaxing due the interaction with CNT and BuCNT. The LA has
in his form an asymmetric shape with COOH termination provoking
a close BuCNT interaction mainly by van der Waals force field. The
simulations were performed by classical molecular dynamics with
standard parameterizations.
Our results show that these BuCNT and CNT are dynamically
stable and it shows a preferential interaction position with LA
resulting in three features: (i) when the LA is interacting with CNT
and BuCNT (including both termination, CH2 or COOH), the LA is
repelled; (ii) when the LA terminated with CH2 is closer to open
extremity of BuCNT, the LA is also repelled by the interaction
between them; and (iii) when the LA terminated with COOH is
closer to open extremity of BuCNT, the LA is encapsulated by the
BuCNT. These simulations are part of a more extensive work on
searching efficient selective molecular devices and could be useful to
reach this goal.
Abstract: Fabrication and efficiency enhancement of non-mercury, high efficiency and green field emission lamps using carbon nano-materials such as carbon nanotubes as cathode field emitters was studied. Phosphor was coated on the ITO glass or metal substrates as the anode. The luminescence efficiency enhancement was carried out by upgrading the uniform of the emitters, improving electron and thermal conductivity of the phosphor and the optimization of the design of different cathode/anode configurations. After evaluation of the aforementioned parameters, the luminescence efficiency of the field emission lamps was raised.
Abstract: Highly ordered TiO2 nanotube (TNT) arrays were
fabricated onto a pre-treated titanium foil by anodic oxidation with a
voltage of 20V in phosphoric acid/sodium fluoride electrolyte. A pretreatment
of titanium foil involved washing with acetone,
isopropanol, ethanol and deionized water. Carbon doped TiO2
nanotubes (C-TNT) was fabricated 'in-situ' with the same method in
the presence of polyvinyl alcohol and urea as carbon sources. The
affects of polyvinyl alcohol concentration and oxidation time on the
composition, morphology and structure of the C-TN were studied by
FE-SEM, EDX and XRD techniques. FESEM images of the
nanotubes showed uniform arrays of C-TNTs. The density and
microstructures of the nanotubes were greatly affected by the content
of PVA. The introduction of the polyvinyl alcohol into the electrolyte
increases the amount of C content inside TiO2 nanotube arrays
uniformly. The influence of carbon content on the photo-current of
C-TNT was investigated and the I-V profiles of the nanotubes were
established. The preliminary results indicated that the 'in-situ'
doping technique produced a superior quality nanotubes compared to
post doping techniques.
Abstract: Studies of vocal communication in Sooty-headed
Bulbul were carried out from January to December 2011. Vocal
recordings and behavioral observations were made in their natural
habitats at some localities of Lampang, Thailand. After editing, cuts
of high quality recordings were analyzed with the help of Avisoft-
SASLab Pro (version 4.40) software. More than one thousand
element repertoires in five groups were found within two vocal
structures. The two structures were short sounds with single element
and phrases composed of elements, the frequency ranged from 1-10
kHz. Most phrases were composed of 2 to 5 elements that were often
dissimilar in structure, however, these phrases were not as complex
as song phrases. The elements and phrases were combined to form
many patterns. The species used ten types of calls; i.e. alert, alarm,
aggressive, begging, contact, courtship, distress, exciting, flying and
invitation. Alert and contact calls were used more frequently than
other calls. Aggressive, alarm and distress calls could be used for
interspecific communication among some other bird species in the
same habitats.
Abstract: In Algeria, some fruit trees produce fruits in free nature. Such trees are Celtis australis, Crataegus azarolus, Crataegus monogyna and Zizyphus lotus. In spite of their appreciable consumption, their nutritional value remains unknown. The objective of this study is the determination of sugars in the pulpe and almond of the above fruits. The biochemical analysis shows that these fruits present interesting contents of soluble sugars which confers significant caloric intakes to them. As well as significant fibres which give them therapeutic and industrial benefits? The analysis of the almonds shows that it contains considerable contents of sugars which enable them to be an energetic food.
Abstract: A composite made of plasma functionalized multiwall
carbon nanotubes (MWNTs) coated with SnO2 was synthesized by
sonochemical precipitation method. Thick layer of this
nanocomposite material was used as ethanol sensor at low
temperatures. The composite sensitivity for ethanol has increased by
a factor of 2 at room temperature and by a factor of 13 at 250°C in
comparison to that of pure SnO2. SEM image of nanocomposite
material showed MWNTs were embedded in SnO2 matrix and also a
higher surface area was observed in the presence of functionalized
MWNTs. Greatly improved sensitivity of the composite material to
ethanol can be attributed to new gas accessing passes through
MWNTs and higher specific surface area.
Abstract: An aqueous methanol sensor for use in direct
methanol fuel cells (DMFCs) applications is demonstrated; the
methanol sensor is built using dispersed single-walled carbon
nanotubes (SWCNTs) with Nafion117 solution to detect the methanol
concentration in water. The study is aimed at the potential use of the
carbon nanotubes array as a methanol sensor for direct methanol fuel
cells (DMFCs). The concentration of methanol in the fuel circulation
loop of a DMFC system is an important operating parameter, because
it determines the electrical performance and efficiency of the fuel cell
system. The sensor is also operative even at ambient temperatures
and responds quickly to changes in the concentration levels of the
methanol. Such a sensor can be easily incorporated into the methanol
fuel solution flow loop in the DMFC system.
Abstract: Mixed Model Production is the practice of assembling
several distinct and different models of a product on the same
assembly line without changeovers and then sequencing those models
in a way that smoothes the demand for upstream components. In this
paper, we consider an objective function which minimizes total
stoppage time and total idle time and it is presented sequence
dependent set up time. Many studies have been done on the mixed
model assembly lines. But in this paper we specifically focused on
reducing the idle times. This is possible through various help policies.
For improving the solutions, some cases developed and about 40 tests
problem was considered. We use scatter search for optimization and
for showing the efficiency of our algorithm, experimental results
shows behavior of method. Scatter search and help policies can
produce high quality answers, so it has been used in this paper.
Abstract: A computational study at the level density functional theory (DFT) was carried out to investigate the influences of Si and C-doping on the 14N and 27Al quadrupole coupling constant in the (10, 0) zigzag single ? walled Aluminum-Nitride nanotube (AlNNT). To this aim, a 1.16nm, length of AlNNT consisting of 40 Al atoms and 40 N atoms were selected where the end atoms are capped by hydrogen atom. To follow the purpose, three Si atoms and three C atoms were doped instead of three Al atoms and three N atoms as a central ring in the surface of the Si and C-doped AlNNT. At first both of systems optimized at the level of BLYP method and 6-31G (d) basis set and after that, the NQR parameters were calculated at the level BLYP method and 6-311+G** basis set in two optimized forms. The calculate CQ values for both optimized AlNNT systems, raw and Si and C-doped, reveal different electronic environments in the mentioned systems. It was also demonstrated that the end nuclei have the largest CQ values in both considered AlNNT systems. All the calculations were carried out using Gaussian 98 package of program.
Abstract: We fabricated multi-walled carbon nanotube (MCNT)
emitters by an electroporetic deposition (EPD) method using a
MCNT-sodium dodecyl sulfate (SDS) suspension. MCNT films were
prepared on graphite tip using EPD. We observe field emission
properties of MCNT film after heat treatment. Consequently, The
MCNT film on graphite tip exhibit good electron emission current.
Abstract: The aim of this study was to synthesize the single
walled carbon nanotubes (SWCNTs) and determine their hydrogen
storage capacities. SWCNTs were firstly synthesized by chemical
vapor deposition (CVD) of acetylene (C2H2) on a magnesium oxide
(MgO) powder impregnated with an iron nitrate (Fe(NO3)3·9H2O)
solution. The synthesis parameters were selected as: the synthesis
temperature of 800°C, the iron content in the precursor of 5% and the
synthesis time of 30 min. Purification process of SWCNTs was
fulfilled by microwave digestion at three different temperatures (120,
150 and 200 °C), three different acid concentrations (0.5, 1 and 1.5
M) and for three different time intervals (15, 30 and 60 min). Nitric
acid (HNO3) was used in the removal of the metal catalysts. The
hydrogen storage capacities of the purified materials were measured
using volumetric method at the liquid nitrogen temperature and gas
pressure up to 100 bar. The effects of the purification conditions such
as temperature, time and acid concentration on hydrogen adsorption
were investigated.
Abstract: Sol-gel method has been used to fabricate
nanocomposite films on glass substrates composed halloysite clay
mineral and nanocrystalline TiO2. The methodology for the synthesis
involves a simple chemistry method utilized nonionic surfactant
molecule as pore directing agent along with the acetic acid-based solgel
route with the absence of water molecules. The thermal treatment
of composite films at 450oC ensures elimination of organic material
and lead to the formation of TiO2 nanoparticles onto the surface of
the halloysite nanotubes. Microscopy techniques and porosimetry
methods used in order to delineate the structural characteristics of the
materials. The nanocomposite films produced have no cracks and
active anatase crystal phase with small crystallite size were deposited
on halloysite nanotubes. The photocatalytic properties for the new
materials were examined for the decomposition of the Basic Blue 41
azo dye in solution. These, nanotechnology based composite films
show high efficiency for dye’s discoloration in spite of different
halloysite quantities and small amount of halloysite/TiO2 catalyst
immobilized onto glass substrates. Moreover, we examined the
modification of the halloysite/TiO2 films with silver particles in order
to improve the photocatalytic properties of the films. Indeed, the
presence of silver nanoparticles enhances the discoloration rate of the
Basic Blue 41 compared to the efficiencies obtained for unmodified
films.
Abstract: In this study we investigate the insertion of
pioglitazone, a Thiazolidinedione, into the two different sizes of
Carbon nanotub. It was shown that the insertion of pioglitazone into
the carbon nanotube in a water solute environment could be related
to the diameter of the nanotube and in the flow of the waters via
hydrophilic interactions. This encapsulated drug-carbon nanotube
molecule can be further applicable in other investigations in target
therapy with these agents regarding to reduce their potential toxic
effects.