Abstract: Hydrogen fuel is a zero-emission fuel which uses electrochemical cells or combustion in internal engines, to power vehicles and electric devices. Methods of hydrogen storage for subsequent use span many approaches, including high pressures, cryogenics and chemical compounds that reversibly release H2 upon heating. Most research into hydrogen storage is focused on storing hydrogen as a lightweight, compact energy carrier for mobile applications. With the accelerating demand for cleaner and more efficient energy sources, hydrogen research has attracted more attention in the scientific community. Until now, full implementation of a hydrogen-based energy system has been hindered in part by the challenge of storing hydrogen gas, especially onboard an automobile. New techniques being researched may soon make hydrogen storage more compact, safe and efficient. In this overview, few hydrogen storage methods and mechanism of hydrogen uptake in carbon nanotubes are summarized.
Abstract: Essential hypertension (HTN) usually clusters with other cardiovascular risk factors such as age, overweight, diabetes, insulin resistance and dyslipidemia. The target organ damage (TOD) such as left ventricular hypertrophy, microalbuminuria (MA), acute coronary syndrome (ACS), stroke and cognitive dysfunction takes place early in course of hypertension. Though the prevalence of hypertension is high in India, the relationship between microalbuminuria and target organ damage in hypertension is not well studied. This study aim at detecting MA in essential hypertension and its relation to severity of HTN, duration of HTN, body mass index (BMI), age and TOD such as HTN retinopathy and acute coronary syndrome The present study was done in 100 patients of essential hypertension non diabetics admitted to B.L.D.E.University-s Sri B.M.Patil Medical College, Bijapur, from October 2008 to April 2011. The patients underwent detailed history and clinical examination. Early morning 5 ml of urine sample was collected & MA was estimated by immunoturbidometry method. The relationship of MA with the duration & severity of HTN, BMI, age, sex and TOD's like hypertensive retinopathy, ACS was assessed by univariate analysis. The prevalence of MA in this study was found to be 63 %. In that 42% were male & 21% were female. In this study a significant association between MA and the duration of hypertension (p = 0.036) & (OR =0.438). Longer the duration of hypertension, more possibility of microalbumin in urine. Also there was a significant association between severity of hypertension and MA (p=0.045) and (OR=0.093). MA was positive in 50 (79.4%) patients out of 63, whose blood pressure was >160/100 mm Hg. In this study a significant association between MA and the grades of hypertensive retinopathy (p =0.011) and acute coronary syndrome (p = 0.041) (OR =2.805). Gender and BMI did not pose high risk for MA in this study.The prevalence of MA in essential hypertension is high in this part of the community and MA will increase the risk of developing target organ damage.Early screening of patients with essential hypertension for MA and aggressive management of positive cases might reduce the burden of chronic kidney diseases and cardiovascular diseases in the community.
Abstract: In this paper, we summarize recent work of the authors on nanocomputing memory devices. We investigate two memory devices, each comprising a charged metallofullerene and carbon nanotubes. The first device involves two open nanotubes of the same radius that are joined by a centrally located nanotube of a smaller radius. A metallofullerene is then enclosed inside the structure. The second device also involves a etallofullerene that is located inside a closed carbon nanotube. Assuming the Lennard-Jones interaction energy and the continuum approximation, for both devices, the metallofullerene has two symmetrically placed equal minimum energy positions. On one side the metallofullerene represents the zero information state and by applying an external electrical field, it can overcome the energy barrier, and pass from one end of the tube to the other, where the metallofullerene then represents the one information state.
Abstract: This paper aims to scale up Dye-sensitized Solar Cell
(DSSC) production using a commonly available industrial material –
stainless steel - and industrial plasma equipment. A working DSSC
electrode formed by (1) coating titania nanotube (TiO2 NT) film on
304 stainless steel substrate using a plasma spray technique; then, (2)
filling the nano-pores of the TiO2 NT film using a TiF4 sol-gel method.
A DSSC device consists of an anode absorbed photosensitive dye
(N3), a transparent conductive cathode with platinum (Pt)
nano-catalytic particles adhered to its surface, and an electrolytic
solution sealed between the anode and the transparent conductive
cathode. The photo-current conversion efficiency of the DSSC sample
was tested under an AM 1.5 Solar Simulator. The sample has a short
current (Isc) of 0.83 mA cm-2, open voltage (Voc) of 0.81V, filling
factor (FF) of 0.52, and conversion efficiency (η) of 2.18% on a 0.16
cm2 DSSC work-piece.
Abstract: A continuum model is presented to study vdW
interaction on buckling analysis of multi-walled walled carbon
nanotube. In previous studies, only the vdW interaction between
adjacent two layers was considered and the vdW interaction between
the other two layers was neglected. The results show that the vdW
interaction cofficients are dependent on the change of interlayer
spacing and the radii of tubes. With increase of radii the vdW
coefficients approach a constant value. The numerical results show
that the effect of vdW interaction on the critical strain for a doublewalled
CNT is negligible when the radius is large enough for the
both the cases of before and after buckling.
Abstract: It is important to remove manganese from water
because of its effects on human and the environment. Human
activities are one of the biggest contributors for excessive manganese
concentration in the environment. The proposed method to remove
manganese in aqueous solution by using adsorption as in carbon
nanotubes (CNT) at different parameters: The parameters are CNT
dosage, pH, agitation speed and contact time. Different pHs are pH
6.0, pH 6.5, pH 7.0, pH 7.5 and pH 8.0, CNT dosages are 5mg,
6.25mg, 7.5mg, 8.75mg or 10mg, contact time are 10 min, 32.5 min,
55 min, 87.5 min and 120 min while the agitation speeds are 100rpm,
150rpm, 200rpm, 250rpm and 300rpm. The parameters chosen for
experiments are based on experimental design done by using Central
Composite Design, Design Expert 6.0 with 4 parameters, 5 levels and
2 replications. Based on the results, condition set at pH 7.0, agitation
speed of 300 rpm, 7.5mg and contact time 55 minutes gives the
highest removal with 75.5%. From ANOVA analysis in Design
Expert 6.0, the residual concentration will be very much affected by
pH and CNT dosage. Initial manganese concentration is 1.2mg/L
while the lowest residual concentration achieved is 0.294mg/L,
which almost satisfy DOE Malaysia Standard B requirement.
Therefore, further experiments must be done to remove manganese
from model water to the required standard (0.2 mg/L) with the initial
concentration set to 0.294 mg/L.
Abstract: The in vitro culture procedure of purple nutsedge
(Cyperus rotundus L.) for multiple shoot induction and tuber
formation was established. Multiple shoots were significantly
induced from a single shoot of about 0.5 – 0.8 cm long, on Murashige
and Skoog (MS) medium supplemented with 4.44 μM 6-
benzyladinine (BA) alone or in combination with 2.85 μM 1-
indoleacetic acid (IAA), providing 17.6 and 15.3 shoots per explant
with 31.2 and 27.5 leaves per explant, respectively, within 6 weeks of
culturing. Moreover, MS medium supplemented with 4.44 μM BA
and 2.85 μM IAA was suitable for tuber induction, obtaining 5.9
tubers with 3.4 rhizomes per explant. In combination with ancymidol
and higher concentration of sucrose, 11.1 μM BA and 60 g/L sucrose
or 11.1 μM BA, 7.8 μM ancymidol and 60 g/L sucrose induced 3.5
tubers with 1.6 rhizomes or 3.5 tubers without rhizome, respectively.
However, MS medium containing 3.9 or 7.8 μM ancymidol in
combination with either 60 or 80 g/L sucrose enchanced significant
root formation at 20.9 – 23.6 roots per explant.
Abstract: The presence of chemical bonding between functionalized carbon nanotubes and matrix in carbon nanotube reinforced composites is modeled by elastic beam elements representing covalent bonding characteristics. Neglecting other reinforcing mechanisms in the composite such as relatively weak interatomic Van der Waals forces, this model shows close results to the Rule of Mixtures model-s prediction for effective Young-s modulus of a Representative Volume Element of composite for small volume fractions (~1%) and high aspect ratios (L/D>200) of CNTs.
Abstract: The nutrient composition and sensory properties of
poultry-based patties (PBPs) incorporated with various levels of grey
oyster mushroom (Pleurotus sajor-caju, PSC) were studied. The
PBPs were formulated with either 0%, 25% or 50% of fresh ground
PSC. Results show poultry patty formulated with 25% PSC had
protein content of 17.46% lower than the control patty which had
18.13% but it was not significant. Meanwhile, both cooked poultry
patties containing 25% and 50% PSC significantly recorded lower
concentration of fat at 10.67% and 7.15%, respectively. On the other
hand, poultry patty added with 50% ground PSC shows the highest
concentration of total dietary fibre (TDF) of 4.90 g/100g compared to
poultry patty containing 25% of mushroom (3.40 g/100g) and to the
control (1.90g/100g). In addition, patty incorporated with 25% PSC
had moisture content of 57.91% which is significantly lower than
patty formulated with 50% which had moisture of 61.80%. In the
sensory evaluation, there were no differences recorded in all sensory
attributes of PSC-based patties judged by untrained panelists. In
conclusion, the addition of PSC to replace poultry meat can be
recommended for the purpose of lowering production cost, enhancing
nutritional composition and maintaining the acceptability of poultry
patties.
Abstract: In this paper we present a novel error model for
packet loss and subsequent error description. The proposed model
simulates the error performance of wireless communication link. The
model is designed as two independent Markov chains, where the first
one is used for packet generation and the second one generates
correctly and incorrectly transmitted bits for received packets from
the first chain. The statistical analyses of real communication on the
wireless link are used for determination of model-s parameters. Using
the obtained parameters and the implementation of the generator, we
collected generated traffic. The obtained results generated by
proposed model are compared with the real data collection.
Abstract: This study aims to determine the level of resistance of Hevea brasiliensis and Paraserianthes falcataria (synonym: Falcataria molucana) against wood rot fungi Pleurotus ostreatus based on Indonesian standard SNI 01.7207-2006 and Japanese standard JIS K 1571-2004. The variables measured were visual appearance and weight loss percentage of wood based on longitudinal and cross section fiber directions of rubber wood and sengon wood. Measurement of oven dry weight loss of wood samples performed after 12 weeks incubation. Replication performed was 10 times at each treatment combination. The results based on SNI 01.7207-2006, weight loss value of H. brasiliensis and P. falcataria wood with fiber direction longitudinal were 23,12 and 22,25% respectively and cross section were 20,77 and 18,76% respectively, and all were classified to resistance class IV (no resistance). The results based on JIS K 1571-2004, weight loss value of both woods with fiber direction cross section were 10,95 and 14,20% respectively.
Abstract: In this paper, free vibration analysis of carbon nanotube (CNT) reinforced laminated composite panels is presented. Three types of panels such as flat, concave and convex are considered for study. Numerical simulation is carried out using commercially available finite element analysis software ANSYS. Numerical homogenization is employed to calculate the effective elastic properties of randomly distributed carbon nanotube reinforced composites. To verify the accuracy of the finite element method, comparisons are made with existing results available in the literature for conventional laminated composite panels and good agreements are obtained. The results of the CNT reinforced composite materials are compared with conventional composite materials under different boundary conditions.
Abstract: The contribution deals with current or potential approaches to the modeling and optimization of tactical activities. This issue takes on importance in recent times, particularly with the increasing trend of digitized battlefield, the development of C4ISR systems and intention to streamline the command and control process at the lowest levels of command. From fundamental and philosophically point of view, this new approaches seek to significantly upgrade and enhance the decision-making process of the tactical commanders.
Abstract: Magnetic carbon nanotubes composites were obtained
by filling carbon nanotubes with paramagnetic iron oxide particles.
Detailed investigation of magnetic behaviour of resulting composites
was done at different temperatures. Measurements indicate that these
functionalized nanotubes are superparamagnetic at room temperature;
however, no superparamagnetism was observed at 125 K and 80 K.
The blocking temperature TB was estimated at 145 K. These magnetic
carbon nanotubes have the potential of being used in a wide range of
applications, in particular, the production of nanofluids, which can be
controlled and steered by appropriate magnetic fields.
Abstract: In this study, structural, mechanical, thermal and
electrical properties of poly (lactic acid) (PLA) nanocomposites with
low-loaded (0-1.5 wt%) untreated, heat and nitric acid treated multiwalled
carbon nanotubes (MWCNTs) were studied. Among the
composites, untreated 0.5 wt % MWCNTs and acid-treated 1.0 wt%
MWCNTs reinforced PLA show the tensile strength and modulus
values higher than the others. These two samples along with pure
PLA exhibit the stable orthorhombic α-form, whilst other samples
reveal the less stable orthorhombic β-form, as demonstrated by X-ray
diffraction study. Differential scanning calorimetry reveals the
evolution of the mentioned different phases by controlled cooling and
discloses an enhancement of PLA crystallization by nanotubes
incorporation. Thermogravimetric analysis shows that the MWCNTs
loaded sample degraded faster than PLA. Surface resistivity of the
nanocomposites is found to be dropped drastically by a factor of 1013
with a low loading of MWCNTs (1.5 wt%).
Abstract: Nowadays due to globalization of economy and
competition environment, innovation and technology plays key role
at creation of wealth and economic growth of countries. In fact
prompt growth of practical and technologic knowledge may results in
social benefits for countries when changes into effective innovation.
Considering the importance of innovation for the development of
countries, this study addresses the radical technological innovation
introduced by nanopapers at different stages of producing paper
including stock preparation, using authorized additives, fillers and
pigments, using retention, calender, stages of producing conductive
paper, porous nanopaper and Layer by layer self-assembly. Research
results show that in coming years the jungle related products will lose
considerable portion of their market share, unless embracing radical
innovation. Although incremental innovations can make this industry
still competitive in mid-term, but to have economic growth and
competitive advantage in long term, radical innovations are
necessary. Radical innovations can lead to new products and
materials which their applications in packaging industry can produce
value added. However application of nanotechnology in this industry
can be costly, it can be done in cooperation with other industries to
make the maximum use of nanotechnology possible. Therefore this
technology can be used in all the production process resulting in the
mass production of simple and flexible papers with low cost and
special properties such as facility at shape, form, easy transportation,
light weight, recovery and recycle marketing abilities, and sealing.
Improving the resistance of the packaging materials without reducing
the performance of packaging materials enhances the quality and the
value added of packaging. Improving the cellulose at nano scale can
have considerable electron optical and magnetic effects leading to
improvement in packaging and value added. Comparing to the
specifications of thermoplastic products and ordinary papers,
nanopapers show much better performance in terms of effective
mechanical indexes such as the modulus of elasticity, tensile strength,
and strain-stress. In densities lower than 640 kgm -3, due to the
network structure of nanofibers and the balanced and randomized
distribution of NFC in flat space, these specifications will even
improve more. For nanopapers, strains are 1,4Gpa, 84Mpa and 17%,
13,3 Gpa, 214Mpa and 10% respectively. In layer by layer self
assembly method (LbL) the tensile strength of nanopaper with Tio3
particles and Sio2 and halloysite clay nanotube are 30,4 ±7.6Nm/g
and 13,6 ±0.8Nm/g and 14±0.3,3Nm/g respectively that fall within
acceptable range of similar samples with virgin fiber. The usage of
improved brightness and porosity index in nanopapers can create
more competitive advantages at packaging industry.
Abstract: Modeling of the distributed systems allows us to
represent the whole its functionality. The working system instance
rarely fulfils the whole functionality represented by model; usually
some parts of this functionality should be accessible periodically.
The reporting system based on the Data Warehouse concept seams to
be an intuitive example of the system that some of its functionality is
required only from time to time. Analyzing an enterprise risk
associated with the periodical change of the system functionality, we
should consider not only the inaccessibility of the components
(object) but also their functions (methods), and the impact of such a
situation on the system functionality from the business point of view.
In the paper we suggest that the risk attributes should be estimated
from risk attributes specified at the requirements level (Use Case in
the UML model) on the base of the information about the structure of
the model (presented at other levels of the UML model). We argue
that it is desirable to consider the influence of periodical changes in
requirements on the enterprise risk estimation. Finally, the
proposition of such a solution basing on the UML system model is
presented.
Abstract: novel and simple method is introduced for rapid and
highly efficient water treatment by reverse osmosis (RO) method using
multi-walled carbon nanotubes (MWCNTs) / polyacrylonitrile (PAN)
polymer as a flexible, highly efficient, reusable and semi-permeable
mixed matrix membrane (MMM). For this purpose, MWCNTs were
directly synthesized and on-line purified by chemical vapor deposition
(CVD) process, followed by directing the MWCNT bundles towards an
ultrasonic bath, in which PAN polymer was simultaneously suspended
inside a solid porous silica support in water at temperature to ~70 οC.
Fabrication process of MMM was finally completed by hot isostatic
pressing (HIP) process. In accordance with the analytical figures of
merit, the efficiency of fabricated MMM was ~97%. The rate of water
treatment process was also evaluated to 6.35 L min-1. The results reveal
that, the CNT-based MMM is suitable for rapid treatment of different
forms of industrial, sea, drinking and well water samples.
Abstract: Pleurotus ostreatus is a common edible mushroom with a number of properties that can help to solve the nutritional and economical problems of people in Chiapas, Mexico. The objective of this project was to produce the mushroom under a sustainable management in which only regional products were allowed as a way to promote the cultivation and consumption of Pleurotus ostreatus; 5 different substrates were tested as well as 2 sanitation methods. The obtained results showed that the highest yields were obtained using corn husk and a thermal sanitation method. Pests and diseases were not a problem during the project but they appeared more in the substrates sanitized with calcium hydroxide.
Abstract: Chemical vapor deposition method was used to
produce carbon nanotubes on an iron based catalyst from acetylene.
Gas-phase samples collected from the different positions of the tubular reactor were analyzed by GC/MS. A variety of species ranging from hydrogen to naphthalene were observed and changes in their concentrations were plotted against the reactor position. Briefly benzene, toluene, styrene, indene and naphthalene were the main
higher molecular weight species and vinylacetylene and diacetylene were the important intermediates. Nanotube characterization was performed by scanning electron microscopy and transmission electron microscopy.