Abstract: Low oxygen content vanadium powder was
prepared by hydrogenation dehydrogenization (HDH). The
effect of purification treatment on hydrogen absorption kinetics
of dendritic vanadium was tested, and the effects of milling
technique on powder yield and grain size were studied. The
crystal phase, oxygen and nitrgen content, and grain size of
prepared powder were characterized and analyzed by X-ray
diffraction (XRD), oxygen and nitrogen analyzer and grain size
analyzer. The results show that the alkaline cleaning can
improve the hydrogen absorption of vanadium. The yield of
vanadium hydride powder can reach as high as 90% by 4h
ball-milling, The resultant product also have an oxygen content
less than 600μg/g, and the grain size is smaller than 37μm.
Meanwhile, the XRD results show that the phase of hydride
vanadium powder is mainly VH0.81. After a hydrogen
desorption treatment in vacuum at 700Ôäâ, the phase of the
powder converts into V and a little of V2H.
Abstract: High purity hydrogen and the valuable by-product of carbon nanotubes (CNTs) can be produced by the methane catalytic decomposition. The methane conversion and the performance of CNTs were determined by the choices of catalysts and the condition of decomposition reaction. In this paper, Ni/MgO and Ni/O-D (oxidized diamond) catalysts were prepared by wetness impregnation method. The effects of reaction temperature and space velocity of methane on the methane conversion were investigated in a fixed-bed. The surface area, structure and micrography were characterized with BET, XPS, SEM, EDS technology. The results showed that the conversion of methane was above 8% within 150 min (T=500) for 33Ni/O-D catalyst and higher than 25% within 120 min (T=650) for 41Ni/MgO catalyst. The initial conversion increased with the increasing temperature of the decomposition reaction, but their catalytic activities decreased rapidly while at too higher temperature. To decrease the space velocity of methane was propitious to promote the methane conversion, but not favor of the hydrogen yields. The appearance of carbon resulted from the methane decomposition lied on the support type and the condition of catalytic reaction. It presented as fiber shape on the surface of Ni/O-D at the relatively lower temperature such as 500 and 550, but as grain shape stacked on and overlayed on the surface of the metal nickel while at 650. The carbon fiber can form on the Ni/MgO surface at 650 and the diameter of the carbon fiber increased with the decreasing space velocity.
Abstract: A measurement system was successfully fabricated to
detect ion concentrations (hydrogen and chlorine) in this study.
PIC18F4520, the microcontroller was used as the control unit in the
measurement system. The measurement system was practically used
to sense the H+ and Cl- in different examples, and the pH and pCl
values were exhibited on real-time LCD display promptly. In the study,
the measurement method is used to judge whether the response voltage
is stable. The change quantity is smaller than 0.01%, that the present
response voltage compares with next response voltage for H+
measurement, and the above condition is established only 6 sec.
Besides, the change quantity is smaller than 0.01%, that the present
response voltage compares with next response voltage for Clmeasurement,
and the above condition is established only 5 sec.
Furthermore, the average error quantities would also be considered,
and they are 0.05 and 0.07 for measurements of pH and pCl values,
respectively.
Abstract: The investigation results of high-density hydrogen
heating by high-current electric arc are presented at initial pressure
from 5 MPa to 160 MPa with current amplitude up to 1.6 MA and
current rate of rise 109-1011 A/s. When changing the initial pressure
and current rate of rise, channel temperature varies from several
electronvolts to hundreds electronvolts. Arc channel radius is several
millimeters. But the radius of the discharge chamber greater than the
radius of the arc channel on approximately order of magnitude. High
efficiency of gas heating is caused by radiation absorption of
hydrogen surrounding the arc. Current channel consist from vapor of
the initiating wire. At current rate of rise of 109 A/s and relatively
small current amplitude gas heating occurs due to radiation
absorption in the band transparency of hydrogen by the wire vapours
with photon energies less than 13.6 eV. At current rate of rise of
1011 A/s gas heating is due to hydrogen absorption of soft X-rays
from discharge channel.
Abstract: Density functional theory (DFT) calculations were performed to calculate aluminum-27, boron-11, and nitrogen-14 quadrupole coupling constant (CQ) in the representative considered model of (6, 0) boron nitride-aluminum nitride nanotube junction (BN-AlNNT) for the first time. To this aim, 1.3 nm length of BNAlN consisting of 18 Al, 18 B, and 36 N atoms was selected where the end atoms capped by hydrogen atoms. The calculated CQ values for optimized BN-AlNNT system reveal different electrostatic environment in the mentioned system. The calculations were performed using the Gaussian 98 package of program.
Abstract: In this work, biohydrogen production via dark
fermentation from alcohol wastewater using upflow anaerobic sludge
blanket reactors (UASB) with a working volume of 4 L was
investigated to find the optimum conditions for a maximum hydrogen
yield. The system was operated at different COD loading rates (23,
31, 46 and 62 kg/m3d) at mesophilic temperature (37 ºC) and pH 5.5.
The seed sludge was pretreated before being fed to the UASB system
by boiling at 95 ºC for 15 min. When the system was operated under
the optimum COD loading rate of 46 kg/m3d, it provided the
hydrogen content of 27%, hydrogen yield of 125.1 ml H2/g COD
removed and 95.1 ml H2/g COD applied, hydrogen production rate of
18 l/d, specific hydrogen production rate of 1080 ml H2/g MLVSS d
and 1430 ml H2/ L d, and COD removal of 24%.
Abstract: There are a many of needs for the development of
SiC-based hydrogen sensor for harsh environment applications. We
fabricated and investigated Pd/Ta2O5/SiC-based hydrogen sensors
with MOS capacitor structure for high temperature process monitoring
and leak detection applications in such automotive, chemical and
petroleum industries as well as direct monitoring of combustion
processes. In this work, we used silicon carbide (SiC) as a substrate to
replace silicon which operating temperatures are limited to below
200°C. Tantalum oxide was investigated as dielectric layer which has
high permeability for hydrogen gas and high dielectric permittivity,
compared with silicon dioxide or silicon nitride. Then, electrical
response properties, such as I-V curve and dependence of capacitance
on hydrogen concentrations were analyzed in the temperature ranges
of room temperature to 500°C for performance evaluation of the
sensor.
Abstract: IFP Group Technology “Sulfrex process" was used in
Iran-s South Pars Gas Complex Refineries for removing sulfur
compounds such as mercaptans, carbonyl sulfide and hydrogen
sulfide, which uses sulfonated cobalt phthalocyanine dispersed in
alkaline solution as catalyst. In this technology, catalyst and alkaline
solution were used circularly. However the stability of catalyst due to
effect of some parameters would reduce with the running of the unit
and therefore sweetening efficiency would be decreased. Hence, the
aim of this research is study the factors effecting on the stability of
catalyst.
Abstract: The kinetic properties of enzymes are often reported
using the apparent KM and Vmax appropriate to the standard
Michaelis-Menten enzyme. However, this model is inappropriate to
enzymes that have more than one substrate or where the rate
expression does not apply for other reasons. Consequently, it is
desirable to have a means of estimating the appropriate kinetic
parameters from the apparent values of KM and Vmax reported for each
substrate. We provide a means of estimating the range within which
the parameters should lie and apply the method to data for glutamate
dehydrogenase from the nematode parasite of sheep Teladorsagia
circumcincta.
Abstract: Group contribution based models are widely used in
industrial applications for its convenience and flexibility. Although a
number of group contribution models have been proposed, there were
certain limitations inherent to those models. Models based on group
contribution excess Gibbs free energy are limited to low pressures and
models based on equation of state (EOS) cannot properly describe
highly nonideal mixtures including acids without introducing
additional modification such as chemical theory. In the present study
new a new approach derived from quantum chemistry have been used
to calculate necessary EOS group interaction parameters. The
COSMO-RS method, based on quantum mechanics, provides a
reliable tool for fluid phase thermodynamics. Benefits of the group
contribution EOS are the consistent extension to hydrogen-bonded
mixtures and the capability to predict polymer-solvent equilibria up to
high pressures. The authors are confident that with a sufficient
parameter matrix the performance of the lattice EOS can be improved
significantly.
Abstract: A renewable energy system discussed in this paper is
a stand-alone wind-hydrogen system for a remote island in Australia.
The analysis of an existing wind-diesel power system was performed.
Simulation technique was used to model the power system currently
employed on the island, and simulated different configurations of
additional hydrogen energy system. This study aims to determine the
suitable hydrogen integrated configuration to setting up the prototype
system for the island, which helps to reduce the diesel consumption
on the island. A set of configurations for the hydrogen system and
associated parameters that consists of wind turbines, electrolysers,
hydrogen internal combustion engines, and storage tanks has been
purposed. The simulation analyses various configurations that
perfectly balances the system to meet the demand on the island.
Abstract: Two-interconnected fluidized bed systems are widely used in various processes such as Fisher-Tropsch, hot gas desulfurization, CO2 capture-regeneration with dry sorbent, chemical-looping combustion, sorption enhanced steam methane reforming, chemical-looping hydrogen generation system, and so on. However, most of two-interconnected fluidized beds systems require riser and/or pneumatic transport line for solid conveying and loopseals or seal-pots for gas sealing, recirculation of solids to the riser, and maintaining of pressure balance. The riser (transport bed) is operated at the high velocity fluidization condition and residence times of gas and solid in the riser are very short. If the reaction rate of catalyst or sorbent is slow, the riser can not ensure sufficient contact time between gas and solid and we have to use two bubbling beds for each reaction to ensure sufficient contact time. In this case, additional riser must be installed for solid circulation. Consequently, conventional two-interconnected fluidized bed systems are very complex, large, and difficult to operate. To solve these problems, a novel two-interconnected fluidized bed system has been developed. This system has two bubbling beds, solid injection nozzles, solid conveying lines, and downcomers. In this study, effects of operating variables on solid circulation rate, gas leakage between two beds have been investigated in a cold mode two-interconnected fluidized bed system. Moreover, long-term operation of continuous solid circulation up to 60 hours has been performed to check feasibility of stable operation.
Abstract: This work presents the experimental results obtained
at a pilot plant which works with a slow, wet and catalytic pyrolysis
process of dry fowl manure. This kind of process mainly consists in
the cracking of the organic matrix and in the following reaction of
carbon with water, which is either already contained in the organic
feed or added, to produce carbon monoxide and hydrogen. Reactions
are conducted in a rotating reactor maintained at a temperature of
500°C; the required amount of water is about 30% of the dry organic
feed. This operation yields a gas containing about 59% (on a volume
basis) of hydrogen, 17% of carbon monoxide and other products such
as light hydrocarbons (methane, ethane, propane) and carbon
monoxide in lesser amounts. The gas coming from the reactor can be
used to produce not only electricity, through internal combustion
engines, but also heat, through direct combustion in industrial
boilers. Furthermore, as the produced gas is devoid of both solid
particles and pollutant species (such as dioxins and furans), the
process (in this case applied to fowl manure) can be considered as an
optimal way for the disposal and the contemporary energetic
valorization of organic materials, in such a way that is not damaging
to the environment.
Abstract: Oxidative stress is considered to be the cause for onset
and the progression of type 2 diabetes mellitus (T2DM) and
complications including neuropathy. It is a deleterious process that
can be an important mediator of damage to cell structures: protein,
lipids and DNA. Data suggest that in patients with diabetes and
diabetic neuropathy DNA repair is impaired, which prevents effective
removal of lesions. Objective: The aim of our study was to evaluate
the association of the hOGG1 (326 Ser/Cys) and XRCC1 (194
Arg/Trp, 399 Arg/Gln) gene polymorphisms whose protein is
involved in the BER pathway with DNA repair efficiency in patients
with diabetes type 2 and diabetic neuropathy compared to the healthy
subjects. Genotypes were determined by PCR-RFLP analysis in 385
subjects, including 117 with type 2 diabetes, 56 with diabetic
neuropathy and 212 with normal glucose metabolism. The
polymorphisms studied include codon 326 of hOGG1 and 194, 399
of XRCC1 in the base excision repair (BER) genes. Comet assay was
carried out using peripheral blood lymphocytes from the patients and
controls. This test enabled the evaluation of DNA damage in cells
exposed to hydrogen peroxide alone and in the combination with the
endonuclease III (Nth). The results of the analysis of polymorphism
were statistically examination by calculating the odds ratio (OR) and
their 95% confidence intervals (95% CI) using the ¤ç2-tests. Our data
indicate that patients with diabetes mellitus type 2 (including those
with neuropathy) had higher frequencies of the XRCC1 399Arg/Gln
polymorphism in homozygote (GG) (OR: 1.85 [95% CI: 1.07-3.22],
P=0.3) and also increased frequency of 399Gln (G) allele (OR: 1.38
[95% CI: 1.03-1.83], P=0.3). No relation to other polymorphisms
with increased risk of diabetes or diabetic neuropathy. In T2DM
patients complicated by neuropathy, there was less efficient repair of
oxidative DNA damage induced by hydrogen peroxide in both the
presence and absence of the Nth enzyme. The results of our study
suggest that the XRCC1 399 Arg/Gln polymorphism is a significant
risk factor of T2DM in Polish population. Obtained data suggest a
decreased efficiency of DNA repair in cells from patients with
diabetes and neuropathy may be associated with oxidative stress.
Additionally, patients with neuropathy are characterized by even
greater sensitivity to oxidative damage than patients with diabetes,
which suggests participation of free radicals in the pathogenesis of
neuropathy.
Abstract: The objective from this paper is to design a solar
thermal engine for space vehicles orbital control and electricity
generation. A computational model is developed for the prediction of
the solar thermal engine performance for different design parameters and conditions in order to enhance the engine efficiency. The engine is divided into two main subsystems. First, the concentrator dish
which receives solar energy from the sun and reflects them to the
cavity receiver. The second one is the cavity receiver which receives
the heat flux reflected from the concentrator and transfers heat to the
fluid passing over. Other subsystems depend on the application required from the engine. For thrust application, a nozzle is
introduced to the system for the fluid to expand and produce thrust.
Hydrogen is preferred as a working fluid in the thruster application.
Results model developed is used to determine the thrust for a
concentrator dish 4 meters in diameter (provides 10 kW of energy),
focusing solar energy to a 10 cm aperture diameter cavity receiver.
The cavity receiver outer length is 50 cm and the internal cavity is 47
cm in length. The suggested design material of the internal cavity is
tungsten to withstand high temperature. The thermal model and
analysis shows that the hydrogen temperature at the plenum reaches
2000oK after about 250 seconds for hot start operation for a flow rate
of 0.1 g/sec.Using solar thermal engine as an electricity generation
device on earth is also discussed. In this case a compressor and
turbine are used to convert the heat gained by the working fluid (air)
into mechanical power. This mechanical power can be converted into
electrical power by using a generator.
Abstract: New lead-free ferroelectric relaxor ceramics were
prepared by conventional solid-state synthesis in the BaTiO3-Bi2O3-
Y2O3 systems. Some of these ceramics present a ferroelectric relaxor
with transition temperature close to room temperature. These new
materials are very interesting for applications and can replace leadbased
ceramic to prevent the toxic pollutions during the preparation
state. In the other hand, the energy band diagram shows the
potentiality of these compounds for the solar energy conversion.
Thus, some compositions have been tested successfully for H2
production upon visible light. The best activity occurs in alkaline
media with a rate evolution of about 0.15 mL g-1 mn-1 and a quantum
yield of 1% under polychromatic light.
Abstract: A combination of photosynthetic bacteria along with
anaerobic acidogenic bacteria is an ideal option for efficient
hydrogen production. In the present study, the optimum
concentration of substrates for the growth of Rhodobacter
sphaeroides was found by response surface methodology. The
optimum combination of three individual fatty acids was determined
by Box Behnken design. Increase of volatile fatty acid concentration
decreased the growth. Combination of sodium acetate and sodium
propionate was most significant for the growth of the organism. The
results showed that a maximum biomass concentration of 0.916 g/l
was obtained when the concentrations of acetate, propionate and
butyrate were 0.73g/l,0.99g/l and 0.799g/l, respectively. The growth
was studied under an optimum concentration of volatile fatty acids
and at a light intensity of 3000 lux, initial pH of 7 and a temperature
of 35°C.The maximum biomass concentration of 0.92g/l was
obtained which verified the practicability of this optimization.
Abstract: Formaldehyde is the illegal chemical substance used
for food preservation in fish and vegetable. It can promote
carcinogenesis. Superoxide dismutases are the important
antioxidative enzymes that catalyze the dismutation of superoxide
anion into oxygen and hydrogen peroxide. The resultant level of
oxidative stress in formaldehyde-treated lymphocytes was
investigated. The formaldehyde concentrations of 0, 20, 40, 60, 80
and 120μmol/L were treated in human lymphocytes for 12 hours.
After 12 treated hours, the superoxide dismutase activity change was
measured in formaldehyde-treated lymphocytes. The results showed
that the formaldehyde concentrations of 60, 80 and 120μmol/L
significantly decreased superoxide dismutase activities in
lymphocytes (P < 0.05). The change of superoxide dismutase
activity in formaldehyde-treated lymphocytes may be the biomarker
for detect cellular injury, such as damage to DNA, due to
formaldehyde exposure.
Abstract: This work focuses on the remediation of polycyclic
aromatic hydrocarbons (PAHs)-contaminated soil via Fenton
treatment coupled with novel chelating agent (CA). The feasibility of
chelated modified Fenton (MF) treatment to promote PAH oxidation
in artificially contaminated soils was investigated in laboratory scale
batch experiments at natural pH. The effects of adding inorganic and
organic CA are discussed. Experiments using different iron catalyst
to CA ratios were conducted, resulting in hydrogen peroxide: soil:
iron: CA weight ratios that varied from 0.049: 1: 0.072: 0.008 to
0.049: 1: 0.072: 0.067. The results revealed that (1) inorganic CA
could provide much higher PAH removal efficiency and (2) most of
the proposed CAs were more efficient than commonly utilised CAs
even at mild ratio. This work highlights the potential of novel
chelating agents in maintaining a suitable environment throughout
the Fenton treatment, particularly in soils with high buffer capacity.
Abstract: The characterization of κ-carrageenan could provide a
better understanding of its functions in biological, medical and
industrial applications. Chemical and physical analyses of
carrageenan from seaweeds, Euchema cottonii L., were done to offer
information on its properties and the effects of Co-60 γ-irradiation on
its thermochemical characteristics. The structural and morphological
characteristics of κ-carrageenan were determined using scanning
electron microscopy (SEM) while the composition, molecular weight
and thermal properties were determined using attenuated total
reflectance Fourier transform infrared spectroscopy (ATR-FTIR), gel
permeation chromatography (GPC), thermal gravimetric analysis
(TGA) and differential scanning calorimetry (DSC). Further chemical
analysis was done using hydrogen-1 nuclear magnetic resonance (1H
NMR) and functional characteristics in terms of biocompatibility
were evaluated using cytotoxicity test.