Abstract: In the gas refineries of Iran-s South Pars Gas
Complex, Sulfrex demercaptanization process is used to remove
volatile and corrosive mercaptans from liquefied petroleum gases by
caustic solution. This process consists of two steps. Removing low
molecular weight mercaptans and regeneration exhaust caustic. Some
parameters such as LPG feed temperature, caustic concentration and
feed-s mercaptan in extraction step and sodium mercaptide content in
caustic, catalyst concentration, caustic temperature, air injection rate
in regeneration step are effective factors. In this paper was focused on
temperature factor that play key role in mercaptans extraction and
caustic regeneration. The experimental results demonstrated by
optimization of temperature, sodium mercaptide content in caustic
because of good oxidation minimized and sulfur impurities in
product reduced.
Abstract: IFP Group Technology “Sulfrex process" was used in
Iran-s South Pars Gas Complex Refineries for removing sulfur
compounds such as mercaptans, carbonyl sulfide and hydrogen
sulfide, which uses sulfonated cobalt phthalocyanine dispersed in
alkaline solution as catalyst. In this technology, catalyst and alkaline
solution were used circularly. However the stability of catalyst due to
effect of some parameters would reduce with the running of the unit
and therefore sweetening efficiency would be decreased. Hence, the
aim of this research is study the factors effecting on the stability of
catalyst.