Abstract: A composite material with carbon fiber and polymer
matrix has been used as adherent for manufacturing adhesive joints.
In order to evaluate different fiber orientations on joint performance,
the adherents with the 0°, ±15°, ±30°, ±45° fiber orientations were
used in the single lap joint configuration. The joints with an overlap
length of 25 mm were prepared according to the ASTM 1002
specifications and subjected to tensile loadings. The structural
adhesive used was a two-part epoxy to be cured at 70°C for an hour.
First, mechanical behaviors of the adherents were measured using
three point bending test. In the test, considerations were given to
stress to failure and elastic modulus. The results were compared with
theoretical ones using rule of mixture. Then, the joints were
manufactured in a specially prepared jig, after a proper surface
preparation. Experimental results showed that the fiber orientations
of the adherents affected the joint performance considerably; the
joints with ±45° adherents experienced the worst shear strength, half
of those with 0° adherents, and in general, there was a great
relationship between the fiber orientations and failure mechanisms.
Delamination problems were observed for many joints, which were
thought to be due to peel effects at the ends of the overlap. It was
proved that the surface preparation applied to the adherent surface
was adequate. For further explanation of the results, a numerical
work should be carried out using a possible non-linear analysis.
Abstract: The purpose of this study is analyzing the relationship
between trust and social capital of people with using Social Network
Analysis. In this study, two aspects of social capital will be focused:
Bonding, homophilous social capital (BoSC), and Bridging,
heterophilous social capital (BrSC). These two aspects diverge each
other regarding to the social theories. The other concept of the study
is Trust (Tr), namely interpersonal trust, willing to ascribe good
intentions to and have confidence in the words and actions of other
people. In this study, the sample group, 61 people, was selected from
a private firm from the defense industry. The relation between
BoSC/BrSC and Tr is shown by using Social Network Analysis
(SNA) and statistical analysis with Likert type-questionnaire. The
results of the analysis show the Cronbach’s alpha value is 0.756 and
social capital values (BoSC/BrSC) is not correlated with Tr values of
the people.
Abstract: Companies face increasing challenges in research due
to higher costs and risks. The intensifying technology complexity and
interdisciplinarity require unique know-how. Therefore, companies
need to decide whether research shall be conducted internally or
externally with partners. On the other hand, research institutes meet
increasing efforts to achieve good financing and to maintain high
research reputation. Therefore, relevant research topics need to be
identified and specialization of competency is necessary. However,
additional competences for solving interdisciplinary research projects
are also often required. Secured financing can be achieved by
bonding industry partners as well as public fundings. The realization
of faster and better research drives companies and research institutes
to cooperate in organized research networks, which are managed by
an administrative organization. For an effective and efficient
cooperation, necessary processes, roles, tools and a set of rules need
to be determined. Goal of this paper is to show the state-of-art
research and to propose a governance framework for organized
research networks.
Abstract: The 1:1 cocrystal of 2-amino-4-chloro-6-
methylpyrimidine (2A4C6MP) with 4-methylbenzoic acid (4MBA)
(I) has been prepared by slow evaporation method in methanol,
which was crystallized in monoclinic C2/c space group, Z = 8, and a
= 28.431 (2) Å, b = 7.3098 (5) Å, c = 14.2622 (10) Å and β =
109.618 (3)°. The presence of unionized –COOH functional group in
cocrystal I was identified both by spectral methods (1H and 13C
NMR, FTIR) and X-ray diffraction structural analysis. The
2A4C6MP molecule interact with the carboxylic group of the
respective 4MBA molecule through N—H⋯O and O—H⋯N
hydrogen bonds, forming a cyclic hydrogen–bonded motif R2
2(8).
The crystal structure was stabilized by Npyrimidine—H⋯O=C and
C=O—H⋯Npyrimidine types hydrogen bonding interactions.
Theoretical investigations have been computed by HF and density
function (B3LYP) method with 6–311+G (d,p)basis set. The
vibrational frequencies together with 1H and 13C NMR chemical
shifts have been calculated on the fully optimized geometry of
cocrystal I. Theoretical calculations are in good agreement with the
experimental results. Solvent–free formation of this cocrystal I is
confirmed by powder X-ray diffraction analysis.
Abstract: The study conducted a simulation of the effect of sea
water to the bonding capacity of GFRP sheet on the concrete beams
using a simulation tank. Fiber reinforced polymer (FRP) has been
developed and applied in many fields civil engineering structures on
the new structures and also for strengthening of the deteriorated
structures. The FRP has advantages such as its corrosion resistance as
well as high tensile strength to weight ratio. Compared to the other
FRP materials, Glass composed FRP (GFRP) is relatively cheaper.
GFRP sheet is applied externally by bonding it on the concrete surface.
The studies regarding the application of GFRP sheet have been
conducted such as strengthening system, bonding behavior of GFRP
sheet including the application as reinforcement in new structures. For
application to the structures with direct contact to sea environment, a
study regarding the effect of sea water to the bonding capacity of
GFRP sheet is important to be clarified. To achieve the objective of the
study, a series of concrete beams strengthened with GFRP sheet on
extreme tension surface were prepared. The beams then were stored on
the sea water tank for six months. Results indicated the bonding
capacity decreased after six month exposed to the sea water.
Abstract: Carbon nanotubes (CNTs) are known for having high elastic properties with high surface area that promote them as good candidates for reinforcing polymeric matrices. In composite materials, CNTs lack chemical bonding with the surrounding matrix which decreases the possibility of better stress transfer between the components. In this work, a chemical treatment for activating the surface of the multi-wall carbon nanotubes (MWCNT) was applied and the effect of this functionalization on the elastic properties of the epoxy nanocomposites was studied. Functional amino-groups were added to the surface of the CNTs and it was evaluated to be about 34% of the total weight of the CNTs. Elastic modulus was found to increase by about 40% of the neat epoxy resin at CNTs’ weight fraction of 0.5%. The elastic modulus was found to decrease after reaching a certain concentration of CNTs which was found to be 1% wt. The scanning electron microscopic pictures showed the effect of the CNTs on the crack propagation through the sample by forming stress concentrated spots at the nanocomposite samples.
Abstract: The purpose of this research was to investigate the
creep behaviour of the heterogeneous Timber-UHPFRC beams. New
developments have been done to further improve the structural
performance, such as strengthening of the timber (glulam) beam by
bonding composite material combine with an ultra-high performance
fibre reinforced concrete (UHPFRC) internally reinforced with or
without carbon fibre reinforced polymer (CFRP) bars. However, in
the design of wooden structures, in addition to the criteria of
strengthening and stiffness, deformability due to the creep of wood,
especially in horizontal elements, is also a design criterion. Glulam,
UHPFRC and CFRP may be an interesting composite mix to respond
to the issue of creep behaviour of composite structures made of
different materials with different rheological properties. In this paper,
we describe an experimental and analytical investigation of the creep
performance of the glulam-UHPFRC-CFRP beams assembled by
bonding. The experimental investigations creep behaviour was
conducted for different environments: in- and outside under constant
loading for approximately a year. The measured results are compared
with numerical ones obtained by an analytical model. This model was
developed to predict the creep response of the glulam-UHPFRCCFRP
beams based on the creep characteristics of the individual
components. The results show that heterogeneous glulam-UHPFRC
beams provide an improvement in both the strengthening and
stiffness, and can also effectively reduce the creep deflection of
wooden beams.
Abstract: Concrete is strong in compression however weak in
tension. The tensile strength as well as ductile property of concrete
could be improved by addition of short dispersed fibers. Polyethylene
terephthalate (PET) fiber obtained from hand cutting or mechanical
slitting of plastic sheets generally used as discrete reinforcement in
substitution of steel fiber. PET fiber obtained from the former process
is in the form of straight slit sheet pattern that impart weaker
mechanical bonding behavior in the concrete matrix. To improve the
limitation of straight slit sheet fiber the present study considered two
additional geometry of fiber namely (a) flattened end slit sheet and
(b) deformed slit sheet. The mix for plain concrete was design for a
compressive strength of 25 MPa at 28 days curing time with a watercement
ratio of 0.5. Cylindrical and beam specimens with 0.5% fibers
volume fraction and without fibers were cast to investigate the
influence of geometry on the mechanical properties of concrete. The
performance parameters mainly studied include flexural strength,
splitting tensile strength, compressive strength and ultrasonic pulse
velocity (UPV). Test results show that geometry of fiber has a
marginal effect on the workability of concrete. However, it plays a
significant role in achieving a good compressive and tensile strength
of concrete. Further, significant improvement in term of flexural and
energy dissipation capacity were observed from other fibers as
compared to the straight slit sheet pattern. Also, the inclusion of PET
fiber improved the ability in absorbing energy in the post-cracking
state of the specimen as well as no significant porous structures.
Abstract: This study makes an integrated investigation on how
life satisfaction is associated with the Korean game users'
psychological variables (self-esteem, game and life self- efficacy),
social variables (bonding and bridging social capital), and
demographic variables (age, gender). The data used for the empirical
analysis came from a representative sample survey conducted in South
Korea. Results show that self-esteem and game efficacy were an
important antecedent to the degree of users’ life satisfaction. Both
bonding social capital and bridging social capital enhance the level of
the users’ life satisfaction. The importance of perspectives as well as
their implications for the game users and further associated research is
explored.
Abstract: In this study, nuclear magnetic resonance
spectroscopy and nuclear quadrupole resonance spectroscopy
parameters of 14N (Nitrogen in imidazole ring) in N–H…O hydrogen
bonding for Histidine hydrochloride monohydrate were calculated via
density functional theory. We considered a five-molecule model
system of Histidine hydrochloride monohydrate. Also we examined
the trends of environmental effect on hydrogen bonds as well as
cooperativity. The functional used in this research is M06-2X which
is a good functional and the obtained results has shown good
agreement with experimental data. This functional was applied to
calculate the NMR and NQR parameters. Some correlations among
NBO parameters, NMR and NQR parameters have been studied
which have shown the existence of strong correlations among them.
Furthermore, the geometry optimization has been performed using
M062X/6-31++G(d,p) method. In addition, in order to study
cooperativity and changes in structural parameters, along with
increase in cluster size, natural bond orbitals have been employed.
Abstract: The elastic properties and fracture of two-dimensional
graphene were calculated purely from the atomic bonding (stretching
and bending) based on molecular mechanics method. Considering the
representative unit cell of graphene under various loading conditions,
the deformations of carbon bonds and the variations of the interlayer
distance could be realized numerically under the geometry constraints
and minimum energy assumption. In elastic region, it was found that
graphene was in-plane isotropic. Meanwhile, the in-plane deformation
of the representative unit cell is not uniform along armchair direction
due to the discrete and non-uniform distributions of the atoms. The
fracture of graphene could be predicted using fracture criteria based on
the critical bond length, over which the bond would break. It was
noticed that the fracture behavior were directional dependent, which
was consistent with molecular dynamics simulation results.
Abstract: It is an established fact that polymers have several
physical limitations such as low stiffness and low resistance to
impact on loading. Hence, polymers do not usually have requisite
mechanical strength for application in various fields. The
reinforcement by high strength fibers provides the polymer
substantially enhanced mechanical properties and makes them more
suitable for a large number of diverse applications. This research
evaluates the effects of particulate Cow bone and Groundnut shell
additions on the mechanical properties and microstructure of cow
bone and groundnut shell reinforced epoxy composite in order to
assess the possibility of using it as a material for engineering
applications. Cow bone and groundnut shell particles reinforced with
epoxy (CBRPC and GSRPC) was prepared by varying the cow bone
and groundnut shell particles from 0-25 wt% with 5 wt% intervals. A
Hybrid of the Cow bone and Groundnut shell (HGSCB) reinforce
with epoxy was also prepared. The mechanical properties of the
developed composites were investigated. Optical microscopy was
used to examine the microstructure of the composites. The results
revealed that mechanical properties did not increase uniformly with
additions in filler but exhibited maximum properties at specific
percentages of filler additions. From the Microscopic evaluation, it
was discovered that homogeneity decreases with increase in % filler,
this could be due to poor interfacial bonding.
Abstract: Rapid Prototyping (RP) technologies enable physical
parts to be produced from various materials without depending on the
conventional tooling. Fused Deposition Modeling (FDM) is one of
the famous RP processes used at present. Tensile strength and
compressive strength resistance will be identified for different sample
structures and different layer orientations of ABS rapid prototype
solid models. The samples will be fabricated by a FDM rapid
prototyping machine in different layer orientations with variations in
internal geometrical structure. The 0° orientation where layers were
deposited along the length of the samples displayed superior strength
and impact resistance over all the other orientations. The anisotropic
properties were probably caused by weak interlayer bonding and
interlayer porosity.
Abstract: This study will examine how the therapeutic factors
(therapeutic catharsis-seeking and game-efficacy of the game player)
and self-construal factors (independent and interdependent
self-construal of the game player) as well as social capital factors
(bonding and bridging social capital of the game player) affect
aggression in the game. Results show that both therapeutic
catharsis-seeking and game self-efficacy are particularly important to
the players since they cause the game players’ aggressive tendencies to
be greatly diminished. Independent self-construal reduces the level of
the players’ aggression. Interestingly enough, the bonding social
capital enhances the level of the players’ aggression, while individuals
with bridging social capital did not show any significant effects. The
results and implications will be discussed herein.
Abstract: The arsenic and iron environments in different growth
stages have been studied with EXAFS and XANES using
Brookhaven Synchrotron Light Source. Collard Greens plants were
grown and tissue samples were harvested. The project studied the
EXAFS and XANES of tissue samples using As and Fe K-edges. The
Fe absorption and the Fourier transform bond length information
were used as a control comparison. The Fourier transform of the
XAFS data revealed the coexistence of As (III) and As (V) in the As
bonding environment inside the studied plant tissue samples,
although the soil only had As (III). The data suggests that Collard
Greens has a novel pathway to handle arsenic absorption in soil.
Abstract: The changes of the optical and structural properties of
Bismuth-Boro-Tellurite glasses pre and post gamma irradiation were
studied. Six glass samples, with different composition [(TeO2)0.7
(B2O3)0.3]1-x (Bi2O3)x prepared by melt quenching method were
irradiated with 25kGy gamma radiation at room temperature. The
Fourier Transform Infrared Spectroscopy (FTIR) was used to explore
the structural bonding in the prepared glass samples due to exposure,
while UV-VIS Spectrophotometer was used to evaluate the changes
in the optical properties before and after irradiation. Gamma
irradiation causes profound changes in the peak intensity as shown by
FTIR spectra which is due to the breaking of the network bonding.
Before gamma irradiation, the optical band gap, Eg value decreased
from 2.44 eV to 2.15 eV with the addition of Bismuth content. The
value kept decreasing (from 2.18 eV to 2.00 eV) following exposure
to gamma radiation due to the increase of non-bridging oxygen
(NBO) and the increase of defect in the glass. In conclusion, the glass
with high content of Bi2O3 (0.30Bi) give smallest Eg and show less
changes in FTIR spectra after gamma irradiation which indicate that
this glass is more resistant to gamma radiation compared to other
glasses.
Abstract: The structures obtained with the use of sandwich
technologies combine low weight with high energy absorbing
capacity and load carrying capacity. Hence, there is a growing and
markedly interest in the use of sandwiches with aluminum foam core
because of very good properties such as flexural rigidity and energy
absorption capability. In the current investigation, the static threepoint
bending tests were carried out on the sandwiches with
aluminum foam core and glass fiber reinforced polymer (GFRP)
skins at different values of support span distances aiming the analyses
of their flexural performance. The influence of the core thickness and
the GFRP skin type was reported in terms of peak load and energy
absorption capacity. For this purpose, the skins with two different
types of fabrics which have same thickness value and the aluminum
foam core with two different thicknesses were bonded with a
commercial polyurethane based flexible adhesive in order to combine
the composite sandwich panels. The main results of the bending tests
are: force-displacement curves, peak force values, absorbed energy,
collapse mechanisms and the effect of the support span length and
core thickness. The results of the experimental study showed that the
sandwich with the skins made of S-Glass Woven fabrics and with the
thicker foam core presented higher mechanical values such as load
carrying and energy absorption capacities. The increment of the
support span distance generated the decrease of the mechanical
values for each type of panels, as expected, because of the inverse
proportion between the force and span length. The most common
failure types of the sandwiches are debonding of the lower skin and
the core shear. The obtained results have particular importance for
applications that require lightweight structures with a high capacity
of energy dissipation, such as the transport industry (automotive,
aerospace, shipbuilding and marine industry), where the problems of
collision and crash have increased in the last years.
Abstract: An Australian manufacturer has fabricated an
innovative GFRP sandwich panel made from E-glass fiber skin and a
modified phenolic core for structural applications. Debonding, which
refers to separation of skin from the core material in composite
sandwiches, is one of the most common types of damage in
composites. The presence of debonding is of great concern because it
not only severely affects the stiffness but also modifies the dynamic
behaviour of the structure. Generally it is seen that the majority of
research carried out has been concerned about the delamination of
laminated structures whereas skin-core debonding has received
relatively minor attention. Furthermore it is observed that research
done on composite slabs having multiple skin-core debonding is very
limited. To address this gap, a comprehensive research investigating
dynamic behaviour of composite panels with single and multiple
debonding is presented. The study uses finite-element modelling and
analyses for investigating the influence of debonding on free
vibration behaviour of single and multilayer composite sandwich
panels. A broad parametric investigation has been carried out by
varying debonding locations, debonding sizes and support conditions
of the panels in view of both single and multiple debonding.
Numerical models were developed with Strand7 finite element
package by innovatively selecting the suitable elements to diligently
represent their actual behavior. Three-dimensional finite element
models were employed to simulate the physically real situation as
close as possible, with the use of an experimentally and numerically
validated finite element model. Comparative results and conclusions
based on the analyses are presented. For similar extents and locations
of debonding, the effect of debonding on natural frequencies appears
greatly dependent on the end conditions of the panel, giving greater
decrease in natural frequency when the panels are more restrained.
Some modes are more sensitive to debonding and this sensitivity
seems to be related to their vibration mode shapes. The fundamental
mode seems generally the least sensitive mode to debonding with
respect to the variation in free vibration characteristics. The results
indicate the effectiveness of the developed three dimensional finite
element models in assessing debonding damage in composite
sandwich panels.
Abstract: Verification of vented wooden façade system with
bonded joints is presented in this paper. The potential of bonded
joints is studied and described in more detail. The paper presents the results of an experimental and theoretical research about the effects of freeze cycling on the bonded joint. For the purpose of tests spruce
timber profiles were chosen for the load bearing substructure. Planks from wooden plastic composite and Siberian larch are representing facade cladding. Two types of industrial polyurethane adhesives intended for structural bonding were selected. The article is focused on the preparation as well as on the subsequent curing and conditioning of test samples. All test samples were subjected to 15 cycles that represents sudden temperature changes, i.e. immersion in a water bath at (293.15 ± 3) K for 6 hours and subsequent freezing to (253.15 ± 2) K for 18 hours. Furthermore, the retention of bond strength between substructure and cladding wastested and strength in shear was determined under tensile stress.Research data indicate that little, if any, damage to the bond results from freezingcycles. Additionally, the suitability of selected group of adhesives in combination with timber substructure was confirmed.
Abstract: This paper presents effects of distilled water, seawater
and sustained bending strains of 30% and 50% ultimate strain at
room temperature, on the durability of unidirectional pultruded
carbon fiber reinforced polymer (CFRP) plates. In this study,
dynamic mechanical analyzer (DMA) was used to investigate the
synergic effects of the immersions and bending strains on the viscoelastic
properties of (CFRP) such as storage modulus, tan delta and
glass transition temperature. The study reveals that the storage
modulus and glass transition temperature increase while tan delta
peak decreases in the initial stage of both immersions due to the
progression of curing. The storage modulus and Tg subsequently
decrease and tan delta increases due to the matrix plasticization. The
blister induced damages in the unstrained seawater samples enhance
water uptake and cause more serious degradation of Tg and storage
modulus than in water immersion. Increasing sustained bending
decreases Tg and storage modulus in a long run for both immersions
due to resin matrix cracking and debonding. The combined effects of
immersions and strains are not clearly reflected due to the statistical
effects of DMA sample sizes and competing processes of molecular
reorientation and postcuring.