Abstract: Using the first-principles full-potential linearized
augmented plane wave plus local orbital (FP-LAPW+lo) method
based on density functional theory (DFT), we have investigated the
electronic structure and magnetism of full Heusler alloys Co2ZrGe
and Co2NbB. These compounds are predicted to be half-metallic
ferromagnets (HMFs) with a total magnetic moment of 2.000 B per
formula unit, well consistent with the Slater-Pauling rule.
Calculations show that both the alloys have an indirect band gaps, in
the minority-spin channel of density of states (DOS), with values of
0.58 eV and 0.47 eV for Co2ZrGe and Co2NbB, respectively.
Analysis of the DOS and magnetic moments indicates that their
magnetism is mainly related to the d-d hybridization between the Co
and Zr (or Nb) atoms. The half-metallicity is found to be relatively
robust against volume changes. In addition, an atom inside molecule
AIM formalism and an electron localization function ELF were also
adopted to study the bonding properties of these compounds, building
a bridge between their electronic and bonding behavior.
As they have a good crystallographic compatibility with the lattice of
semiconductors used industrially and negative calculated cohesive
energies with considerable absolute values these two alloys could be
promising magnetic materials in the spintronic field.
Abstract: In the past few decades, the field of chemistry
education has grown tremendously and researches indicated that after
traditional chemistry instruction students often lacked deep
conceptual understanding and failed to integrate their ideas into
coherent conceptual framework. For several concepts in chemistry,
students at all levels have demonstrated difficulty in changing their
initial perceptions. Their perceptions are most often wrong and don't
agree with correct scientific concepts. This study explored the
effectiveness of intervention discussion sections for a college general
chemistry course designed to apply research on students
preconceptions, knowledge integration and student explanation.
Three interventions discussions lasting three hours on bond energy
and spontaneity were done tested and intervention (treatment)
students’ performances were compared with that of control group
which did not use the experimental pedagogy. Results indicated that
this instruction which was capable of identifying students'
misconceptions, initial conceptions and integrating those ideas into
class discussion led to enhanced conceptual understanding and better
achievement for the experimental group.
Abstract: The use OF adhesive anchors for wooden constructions is an efficient technology to connect and design timber members in new timber structures and to rehabilitate the damaged structural members of historical buildings. Due to the lack of standard regulation in this specific area of structural design, designers’ choices are still supported by test analysis that enables knowledge, and the prediction, of the structural behaviour of glued in rod joints. The paper outlines an experimental research activity aimed at identifying the tensile resistance capacity of several new adhesive joint prototypes made of epoxy resin, steel bar and timber, Oak and Douglas Fir species. The development of new adhesive connectors has been carried out by using epoxy to glue stainless steel bars into pre-drilled holes, characterised by smooth and rough internal surfaces, in timber samples. The realization of a threaded contact surface using a specific drill bit has led to an improved bond between wood and epoxy. The applied changes have also reduced the cost of the joints’ production. The paper presents the results of this parametric analysis and a Finite Element analysis that enables identification and study of the internal stress distribution in the proposed adhesive anchors.
Abstract: Sandwich structure composites produced by epoxy
core and aluminium skin were developed as potential building
materials. Interface bonding between core and skin was controlled by
varying kenaf content. Five different weight percentage of kenaf
loading ranging from 10 wt% to 50 wt% were employed in the core
manufacturing in order to study the mechanical properties of the
sandwich composite. Properties of skin aluminium with epoxy were
found to be affected by drying time of the adhesive. Mechanical
behavior of manufactured sandwich composites in relation with
properties of constituent materials was studied. It was found that 30
wt% of kenaf loading contributed to increase the flexural strength and
flexural modulus up to 102 MPa and 32 GPa, respectively. Analysis
were done on the flatwise and edgewise compression test. For
flatwise test, it was found that 30 wt% of fiber loading could
withstand maximum force until 250 kN, with compressive strength
results at 96.94 MPa. However, at edgewise compression test, the
sandwich composite with same fiber loading only can withstand 31
kN of the maximum load with 62 MPa of compressive strength
results.
Abstract: The industrial process adds to engineering wood
products features absent in solid wood, with homogeneous structure
and reduced defects, improved physical and mechanical properties,
bio-deterioration, resistance and better dimensional stability,
improving quality and increasing the reliability of structures wood.
These features combined with using fast-growing trees, make them
environmentally ecological products, ensuring a strong consumer
market. The wood I-joists are manufactured by the industrial profiles
bonding flange and web, an important aspect of the production of
wooden I-beams is the adhesive joint that bonds the web to the
flange. Adhesives can effectively transfer and distribute stresses,
thereby increasing the strength and stiffness of the composite. The
objective of this study is to evaluate different resins in a shear strain
specimens with the aim of analyzing the most efficient resin and
possibility of using national products, reducing the manufacturing
cost. First was conducted a literature review, where established the
geometry and materials generally used, then established and analyzed
8 national resins and produced six specimens for each.
Abstract: Complexation of anthocyanins to mimic natural
copigmentation process was investigated. Cyanidin-rich extracts from
Zea mays L. ceritina Kulesh. and delphinidin-rich extracts from
Clitoria ternatea L. were used to form 4 anthocyanin complexes,
AC1, AC2, AC3 and AC4, in the presence of several polyphenols and
a trace metal. Characterizations of the ACs were conducted by UV,
FTIR, DSC/TGA and morphological observations. Bathochromic
shifts of the UV spectra of 4 formulas of ACs were observed at peak
wavelengths of about 510-620 nm by 10 nm suggesting complex
formation. FTIR spectra of the ACs indicate shifts of peaks from
1,733 cm-1 to 1,696 cm-1 indicating interactions and a decrease in the
peak areas within the wavenumber of 3,400-3,500 cm-1 indicating
changes in hydrogen bonding. Thermal analysis of all of the ACs
suggests increases in melting temperature after complexation. AC
with the highest melting temperature was morphologically observed
by SEM and TEM to be crystal-like particles within a range of 50 to
200 nm. Particle size analysis of the AC by laser diffraction gave a
range of 50-600 nm, indicating aggregation. This AC was shown to
have no cytotoxic effect on cultured HGEPp0.5 and HGF (all p>
0.05) by MTT. Therefore, complexation of anthocyanins was simple
and self-assembly process, potentially resulting in nanosized particles
of anthocyanin complex.
Abstract: Carbon fiber reinforced polymersarewidely used to strengthen steel structural elements. These structural elements are normally subjected to static, dynamic and fatigue loadings during their life-time. CFRP laminate is commonly used to strengthen these structures under the subjected loads. A number of studies have focused on the characteristics of CFRP sheets bonded to steel members under static, dynamic and fatigue loadings. However, there is a gap in understanding the bonding behavior between CFRP laminates and steel members under impact loading. This paper shows the effect of high load rates on this bond. CFRP laminate CFK 150/2000 was used to strengthen steel joints using Araldite 420 epoxy. The results show that applying a high load rate significantly affects the bond strength but has little influence on the effective bond length.
Abstract: To develop AZ91D magnesium alloys with improved
properties, we have applied TiN and VN/TiN multilayer coatings
using DC magnetron sputter technique. Coating structure, surface
morphology, chemical bonding and corrosion resistance of coatings
were analyzed by x-ray diffraction (XRD), scanning electron
microscope (SEM), x-ray photoelectron spectroscopy (XPS), and
tafel extrapolation method, respectively. XPS analysis reveal that VN
overlayer reacts with oxygen at the VN/TiN interface and forms more
stable TiN layer. Morphological investigations and the corrosion
results show that VN/TiN multilayer thin film coatings are quite
effective to optimize the corrosion resistance of Mg alloys.
Abstract: PVC foam-fly ash composites (PVC-FA) are
characterized for their structural, morphological, mechanical and
thermal properties. The tensile strength of the composites increased
modestly with higher fly ash loading, while there was a significant
increase in the elastic modulus for the same composites. On the other
hand, a decrease in elongation at UTS was observed upon increasing
fly ash content due to increased rigidity of the composites. Similarly,
the flexural modulus increased as the fly ash loading increased,
where the composites containing 25 phr fly ash showed the highest
flexural strength. Thermal properties of PVC-fly ash composites were
determined by Thermo Gravimetric Analysis (TGA). The
microstructural properties were studied by Scanning Electron
Microscopy (SEM). SEM results confirm that fly ash particles were
mechanically interlocked in PVC matrix with good interfacial
interaction with the matrix. Particle agglomeration and debonding
was observed in samples containing higher amounts of fly ash.
Abstract: Effect of 2wt% Cu addition on tensile properties and
fracture behavior of Al-6Si-0.5Mg-2Ni alloy at various strain rates
were studied. The solution treated Al-6Si-0.5Mg-2Ni (-2Cu) alloys,
were aged isochronally for 1 hour at temperatures up to 300oC. The
uniaxial tension test was carried out at strain rate ranging from 10-4s-1
to 10-2s-1 in order to investigate the strain rate dependence of tensile
properties. Tensile strengths were found to increase with ageing
temperature and the maximum being attained ageing for 1 hr at
225oC (peak aged condition). Addition of 2wt% Cu resulted in an
increase in tensile properties at all strain rates. Evaluation of tensile
properties at three different strain rates (10-4, 10-3 and 10-2 s-1)
showed that strain rates affected the tensile properties significantly.
At higher strain rates the strength was better but ductility was poor.
Microstructures of broken specimens showed that both the void
coalescence and the interface debonding affect the fracture behavior
of the alloys
Abstract: The aesthetic qualities and the versatility of reinforced
concrete have made it a popular choice for many architects and
structural engineers. Therefore, the exploration of natural materials
such as gravels and sands as well as lime-stone for cement production
is increasing to produce a concrete material. The exploration must
affect to the environment. Therefore, the using of the concrete
materials should be as efficient as possible. According to its natural
behavior of the concrete material, it is strong in compression and weak
in tension. Therefore the contribution of the tensile stresses of the
concrete to the flexural capacity of the beams is neglected. However,
removing of concrete on tension zone affects to the decreasing of
flexural capacity. Introduce the strut action of truss structures may an
alternative to solve the decreasing of flexural capacity. A series of
specimens were prepared to clarify the effect of the truss structures in
the concrete beams without concrete on the tension zone. Results
indicated that the truss system is necessary for the external reinforced
concrete beams. The truss system of concrete beam without concrete
on tension zone (BR) could develop almost same capacity to the
normal beam (BN). It can be observed also that specimens BR has
lower number of cracks than specimen BN. This may be caused by the
fact that there was no bonding effect on the tensile reinforcement on
specimen BR to distribute the cracks.
Abstract: Concrete-filled-steel-tube (CFST) columns are becoming increasingly popular owing to the superior behavior contributed by the composite action. However, this composite action cannot be fully developed because of different dilation properties between steel tube and concrete. During initial compression, there will be de-bonding between the constitutive materials. As a result, the strength, initial stiffness and ductility of CFST columns reduce significantly. To resolve this problem, external confinement in the form of spirals is proposed to improve the interface bonding. In this paper, a total of 14CFST columns with high-strength as well as ultra-high-strength concrete in-filled were fabricated and tested under uni-axial compression. From the experimental results, it can be concluded that the proposed spirals can improve the strength, initial stiffness, ductility and the interface bonding condition of CFST columns by restraining the lateral expansion of steel tube and core concrete. Moreover, the failure modes of confined core concrete change due to the strong confinement provided by spirals.
Abstract: The aim of this paper is to summarize the literature on micromorphology and composition of the enamel of the cat and present an original experiment by SEM on how it responds to the etching with ortophosphoric acid for the time recommended in the veterinary literature (30", 45", 60"), derived from research and experience on human enamel; 21 teeth of cat were randomly divided into three groups of 7 (A, B, C): Group A was subjected to etching for 30 seconds by means of orthophosphoric acid to 40% on a circular area with diameter of about 2mm of the enamel coronal; the Groups B and C had the same treatment but, respectively, for 45 and 60 seconds. The samples obtained were observed by SEM to constant magnification of 1000x framing, in particular, the border area between enamel exposed and not exposed to etching to highlight differences. The images were subjected to the analysis of three blinded experienced operators in electron microscopy. In the enamel of the cat the etching for the times considered is not optimally effective for the purpose adhesives and the presence of a thick prismless layer could explain this situation. To improve this condition may clinically in the likeness of what is proposed for the enamel of human deciduous teeth: a bevel or a chamfer of 1 mm on the contour of the cavity to discover the prismatic enamel and increase the bonding surface.
Abstract: 12.7-mm thick plates of 6061-T6511 aluminum alloy and high hardness steel (528 HV) were successfully joined by a friction stir bonding process using a tungsten-rhenium stir tool. Process parameter variation experiments, which included tool design geometry, plunge and traverse rates, tool offset, spindle tilt, and rotation speed, were conducted to develop a parameter set which yielded a defect free joint. Laboratory tensile tests exhibited yield stresses which exceed the strengths of comparable AA6061-to-AA6061 fusion and friction stir weld joints. Scanning electron microscopy and energy dispersive X-ray spectroscopy analysis also show atomic diffusion at the material interface region.
Abstract: Sandwich construction is widely accepted as a method of construction especially in the aircraft industry. It is a type of stressed skin construction formed by bonding two thin faces to a thick core, the faces resist all of the applied edge loads and provide all or nearly all of the required rigidities, the core spaces the faces to increase cross section moment of inertia about common neutral axis and transmit shear between them provides a perfect bond between core and faces is made.
Material for face sheets can be of metal or reinforced plastics laminates, core material can be metallic cores of thin sheets forming corrugation or honeycomb, or non metallic core of Balsa wood, plastic foams, or honeycomb made of reinforced plastics.
For in plane axial loading web core and web-foam core Sandwich panels can fail by local buckling of plates forming the cross section with buckling wave length of the order of length of spacing between webs.
In this study local buckling of web core and web-foam core Sandwich panels is carried out for given materials of facing and core, and given panel overall dimension for different combinations of cross section geometries.
The Finite Strip Method is used for the analysis, and Fortran based computer program is developed and used.
Abstract: This investigation presents preparation of sample and
analysis of results of ballistic impact test as per EN 1063 on the size,
thickness, number, position, and type of the bonding interlayer
Polyvinyl Butyral, Poly Carbonate and Poly Urethane on bullet proof
glass. It was observed that impact energy absorbed by bullet proof
glass increases with the increase of the total thickness from 33mm to
42mm to 51mm for all the three samples respectively. Absorption
impact energy is greater for samples with more number of bonding
interlayers than with the number of glass layers for uniform increase
in total sample thickness. There is no effect on the absorption impact
energy with the change in position of the bonding interlayer.
Abstract: Al/Cu clad sheet has been fabricated by using differential speed rolling (DSR) process, which caused severe shear deformation between Al and Cu plate to easily bond to each other. Rolling was carried out at 100 and 150oC with speed ratios from 1.4 to 2.2, in which the total thickness reduction was in the range between 14 and 46%. Interfacial microstructure and mechanical properties of Al/Cu clad were investigated by scanning electron microscope equipped with energy dispersive X-ray detector, and tension tests. The DSR process was very effective to provide a good interface for atoms diffusion during subsequent annealing. The strength of bonding was higher with the increasing speed ratio. Post heat treatment enhanced the mechanical properties of clad sheet by forming intermetallic compounds in the interface area.
Abstract: This paper presents the retrofitting of beam-column joint using CFRP (Carbon Fiber Reinforced Polymer) and steel plate. This specimen was tested until failure up to 1.0% drift. This joint suffered severe damages and diagonal cracks at upper crack at upper column before retrofitted. CFRP were wrapped at corbel, bottom and top of the column. Steel plates with bonding were attached to the two beams and the jointing system. This retrofitted specimen is tested again under lateral cyclic loading up 1.75% drift. Visual observations show that the cracks started at joint when 0.5% drift applied at top of column. Damage of retrofitted beam-column joint occurred inside the CFRP and it cannot be seen from outside. Analysis of elastic stiffness, lateral strength, ductility, hysteresis loops and equivalent viscous damping shows that these values are higher than before retrofitting. Therefore, it is recommended to use this type of retrofitting method for beam-column joint with corbel which suffers severe damage after the earthquake.
Abstract: CFRP (Carbon Fiber Reinforced Polymer) is mainly used as reinforcing material for degraded structures owing to its advantages including its non-corrodibility, high strength and lightweight properties. Recently, dedicated studies focused not only on its simple bonding but also on its tensioning. The tension necessary for prestressing requires the anchoring of multi-CFRP tendons with high capacity and the surface treatment of the CFRP tendons may also constitute an important issue according to the type of anchor. The wedge type, swage type or bonded type anchor can be used to anchor the CFRP tendon. The bonded type anchor presents the disadvantage to lengthen the length of the anchor due to the low bond strength of the CFRP tendon without surface treatment. This study intends to overcome this drawback through the application of a method enlarging the bond area at the end of the CFRP tendon. This method enlarges the bond area by splitting the end of the CFRP tendon along its length and can be applied when CFRP is produced by pultrusion. The application of this method shows that the mono-CFRP tendon and 3-multi CFRP tendon secured the anchor performance corresponding to the tensile performance of the CFRP tendon and that the 7-multi tendon secured anchor performance corresponding to 90% of the tensile strength due to the occurrence of buckling in the steel tube anchorage.
Abstract: The research investigated the use of nylon solution to enhance the California bearing ratio (CBR) of soil. Used nylon sachet of potable water were dissolved in four separate solvents namely acetone, toluene, ethyl glycol and dual purpose kerosene (DPK). It was discovered that DPK has the highest nylon solubility of 29g/ml at 91oC. The nylon solution was used to stabilize poorly graded sandy soil. The result showed that at less or equal to 4% stabilization, the CBR value decreased from 25.3% to 15.85% and later appreciated to 67.78% at 16% stabilization. The initial decrease in CBR value of soil sample observed was as a result of inadequate nylon solution to coat soil particles for proper bonding.