Abstract: We measured the major and trace element contents
and Rb-Sr isotopic compositions of 12 tektites from the Maoming
area, Guandong province (south China). All the samples studied are
splash-form tektites which show pitted or grooved surfaces with
schlieren structures on some surfaces. The trace element ratios Ba/Rb
(avg. 4.33), Th/Sm (avg. 2.31), Sm/Sc (avg. 0.44), Th/Sc (avg. 1.01) ,
La/Sc (avg. 2.86), Th/U (avg. 7.47), Zr/Hf (avg. 46.01) and the rare
earth elements (REE) contents of tektites of this study are similar to the
average upper continental crust. From the chemical composition, it is
suggested that tektites in this study are derived from similar parental
terrestrial sedimentary deposit which may be related to post-Archean
upper crustal rocks. The tektites from the Maoming area have high
positive εSr(0) values-ranging from 176.9~190.5 which indicate that
the parental material for these tektites have similar Sr isotopic
compositions to old terrestrial sedimentary rocks and they were not
dominantly derived from recent young sediments (such as soil or
loess). The Sr isotopic data obtained by the present study support the
conclusion proposed by Blum et al. (1992)[1] that the depositional age
of sedimentary target materials is close to 170Ma (Jurassic). Mixing
calculations based on the model proposed by Ho and Chen (1996)[2]
for various amounts and combinations of target rocks indicate that the
best fit for tektites from the Maoming area is a mixture of 40% shale,
30% greywacke, 30% quartzite.
Abstract: Sugarcane Shoots is an abundantly available
residual resources consisting of lignocelluloses which take it into
the benefit. The present study was focused on utilizing of
sugarcane shoot for reducing sugar production as a substrate in
ethanol production. Physical and chemical pretreatments of
sugarcane shoot were investigated. Results showed that the size of
sugarcane shoot influenced the cellulose content. The maximum
cellulose yield (60 %) can be obtained from alkaline pretreated
sugarcane shoot with 1.0 M NaOH at 30 oC for 90 min. The
cellulose yield reached up to 93.9% (w/w). Enzymatically
hydrolyzed of cellulosic residual in 0.04 citrate buffer (pH 5) with
celluclast 1.5L (0.7 FPU/ml) resulted in the highest amount of
reducing sugar at a rate of 32.1 g/l after 4 h incubation at 50°C,
and 100 oC for 5 min . Cellulose conversion was 55.5%.
Abstract: Hypersonic flows around spatial vehicles during their
reentry phase in planetary atmospheres are characterized by intense
aerothermal phenomena. The aim of this work is to analyze high
temperature flows around an axisymmetric blunt body taking into
account chemical and vibrational non-equilibrium for air mixture
species. For this purpose, a finite volume methodology is employed
to determine the supersonic flow parameters around the axisymmetric
blunt body, especially at the stagnation point and along the wall of
spacecraft for several altitudes. This allows the capture shock wave
before a blunt body placed in supersonic free stream. The numerical
technique uses the Flux Vector Splitting method of Van Leer. Here,
adequate time stepping parameter, along with CFL coefficient and
mesh size level are selected to ensure numerical convergence, sought
with an order of 10-8
Abstract: Solid waste can be considered as an urban burden or
as a valuable resource depending on how it is managed. To meet the
rising demand for energy and to address environmental concerns, a
conversion from conventional energy systems to renewable resources
is essential. For the sustainability of human civilization, an
environmentally sound and techno-economically feasible waste
treatment method is very important to treat recyclable waste. Several
technologies are available for realizing the potential of solid waste as
an energy source, ranging from very simple systems for disposing of
dry waste to more complex technologies capable of dealing with
large amounts of industrial waste. There are three main pathways for
conversion of waste material to energy: thermo chemical,
biochemical and physicochemical. This paper investigates the thermo
chemical conversion of solid waste for energy recovery. The
processes, advantages and dis-advantages of various thermo chemical
conversion processes are discussed and compared. Special attention
is given to Gasification process as it provides better solutions
regarding public acceptance, feedstock flexibility, near-zero
emissions, efficiency and security. Finally this paper presents
comparative statements of thermo chemical processes and introduces
an integrated waste management system.
Abstract: fibers of pure cellulose can be made from some bacteria such as acetobacter xylinum. Bacterial cellulose fibers are very pure, tens of nm across and about 0.5 micron long. The fibers are very stiff and, although nobody seems to have measured the strength of individual fibers. Their stiffness up to 70 GPa. Fundamental strengths should be at least greater than those of the best commercial polymers, but best bulk strength seems to about the same as that of steel. They can potentially be produced in industrial quantities at greatly lowered cost and water content, and with triple the yield, by a new process. This article presents a critical review of the available information on the bacterial cellulose as a biological nonwoven fabric with special emphasis on its fermentative production and applications. Characteristics of bacterial cellulose biofabric with respect to its structure and physicochemical properties are discussed. Current and potential applications of bacterial cellulose in textile, nonwoven cloth, paper, films synthetic fiber coating, food, pharmaceutical and other industries are also presented.
Abstract: The paper presents an analytical solution for dispersion
of a solute in the peristaltic motion of a micropolar fluid in the
presence of magnetic field and both homogeneous and heterogeneous
chemical reactions. The average effective dispersion coefficient has
been found using Taylor-s limiting condition under long wavelength
approximation. The effects of various relevant parameters on the average
coefficient of dispersion have been studied. The average effective
dispersion coefficient increases with amplitude ratio, cross viscosity
coefficient and heterogeneous chemical reaction rate parameter. But it
decreases with magnetic field parameter and homogeneous chemical
reaction rate parameter. It can be noted that the presence of peristalsis
enhances dispersion of a solute.
Abstract: Formaldehyde is the illegal chemical substance used
for food preservation in fish and vegetable. It can promote
carcinogenesis. Superoxide dismutases are the important
antioxidative enzymes that catalyze the dismutation of superoxide
anion into oxygen and hydrogen peroxide. The resultant level of
oxidative stress in formaldehyde-treated lymphocytes was
investigated. The formaldehyde concentrations of 0, 20, 40, 60, 80
and 120μmol/L were treated in human lymphocytes for 12 hours.
After 12 treated hours, the superoxide dismutase activity change was
measured in formaldehyde-treated lymphocytes. The results showed
that the formaldehyde concentrations of 60, 80 and 120μmol/L
significantly decreased superoxide dismutase activities in
lymphocytes (P < 0.05). The change of superoxide dismutase
activity in formaldehyde-treated lymphocytes may be the biomarker
for detect cellular injury, such as damage to DNA, due to
formaldehyde exposure.
Abstract: Six parameters, the effective diffusivity (De),
activation energy of De, pre-exponential factor of De, amount
(ASOW) of self-organized water species, and amplitude (α) of the
forced oscillation of the molecular mobility (1/tC) derived from the
forced cyclic temperature change operation, were characterized by
using six typical foods, squid, sardines, scallops, salmon, beef, and
pork, as a function of the correlation time (tC) of the water molecule-s
proton retained in the foods. Each of the six parameters was clearly
divided into the water species A1 and A2 at a specified value of tC
=10-8s (=CtC), indicating an anomalous change in the physicochemical
nature of the water species at the CtC. The forced oscillation of 1/tC
clearly demonstrated a characteristic mode depending on the food
shown as a three dimensional map associated with 1/tC, the amount of
self-organized water, and tC.
Abstract: Graph has become increasingly important in modeling
complicated structures and schemaless data such as proteins, chemical
compounds, and XML documents. Given a graph query, it is desirable
to retrieve graphs quickly from a large database via graph-based
indices. Different from the existing methods, our approach, called
VFM (Vertex to Frequent Feature Mapping), makes use of vertices
and decision features as the basic indexing feature. VFM constructs
two mappings between vertices and frequent features to answer graph
queries. The VFM approach not only provides an elegant solution to
the graph indexing problem, but also demonstrates how database
indexing and query processing can benefit from data mining,
especially frequent pattern mining. The results show that the proposed
method not only avoids the enumeration method of getting subgraphs
of query graph, but also effectively reduces the subgraph isomorphism
tests between the query graph and graphs in candidate answer set in
verification stage.
Abstract: The present study was conducted to investigate the
response of plants exposed to lignite-based thermal power plant
emission. For this purpose, five plant species were collected from 1.0
km distance (polluted site) and control plants were collected from
20.0 km distance (control site) to thermal power plant. The common
tree species Cassia siamea Lamk., Polyalthia longifolia. Sonn,
Acacia longifolia (Andrews) Wild., Azadirachta indica A.Juss, Ficus
religiosa L. were selected as test plants. Photosynthetic pigments
changes (chlorophyll a, chlorophyll b and carotenoids) and rubisco
enzyme modifications were studied. Reduction was observed in the
photosynthetic pigments of plants growing in polluted site and also
large sub unit of the rubisco enzyme was degraded in Azadirachta
indica A. Juss collected from polluted site.
Abstract: The characterization of κ-carrageenan could provide a
better understanding of its functions in biological, medical and
industrial applications. Chemical and physical analyses of
carrageenan from seaweeds, Euchema cottonii L., were done to offer
information on its properties and the effects of Co-60 γ-irradiation on
its thermochemical characteristics. The structural and morphological
characteristics of κ-carrageenan were determined using scanning
electron microscopy (SEM) while the composition, molecular weight
and thermal properties were determined using attenuated total
reflectance Fourier transform infrared spectroscopy (ATR-FTIR), gel
permeation chromatography (GPC), thermal gravimetric analysis
(TGA) and differential scanning calorimetry (DSC). Further chemical
analysis was done using hydrogen-1 nuclear magnetic resonance (1H
NMR) and functional characteristics in terms of biocompatibility
were evaluated using cytotoxicity test.
Abstract: Tomato powder has good potential as substitute of tomato paste and other tomato products. In order to protect physicochemical properties and nutritional quality of tomato during dehydration process, investigation was carried out using different drying methods and pretreatments. Solar drier and continuous conveyor (tunnel) drier were used for dehydration where as calcium chloride (CaCl2), potassium metabisulphite (KMS), calcium chloride and potassium metabisulphite (CaCl2 +KMS), and sodium chloride (NaCl) selected for treatment.. lycopene content, dehydration ratio, rehydration ratio and non-enzymatic browning in addition to moisture, sugar and titrable acidity were studied. Results show that pre-treatment with CaCl2 and NaCl increased water removal and moisture mobility in tomato slices during drying of tomatoes. Where CaCl2 used along with KMS the NEB was recorded the least compared to other treatments and the best results were obtained while using the two chemicals in combination form. Storage studies in LDPE polymeric and metalized polyesters films showed less changes in the products packed in metallized polyester pouches and even after 6 months lycopene content did not decrease more than 20% as compared to the control sample and provide extension of shelf life in acceptable condition for 6 months. In most of the quality characteristics tunnel drier samples presented better values in comparison to solar drier.
Abstract: This is a study on numerical simulation of the convection-diffusion transport of a chemical species in steady flow through a small-diameter tube, which is lined with a very thin layer made up of retentive and absorptive materials. The species may be subject to a first-order kinetic reversible phase exchange with the wall material and irreversible absorption into the tube wall. Owing to the velocity shear across the tube section, the chemical species may spread out axially along the tube at a rate much larger than that given by the molecular diffusion; this process is known as dispersion. While the long-time dispersion behavior, well described by the Taylor model, has been extensively studied in the literature, the early development of the dispersion process is by contrast much less investigated. By early development, that means a span of time, after the release of the chemical into the flow, that is shorter than or comparable to the diffusion time scale across the tube section. To understand the early development of the dispersion, the governing equations along with the reactive boundary conditions are solved numerically using the Flux Corrected Transport Algorithm (FCTA). The computation has enabled us to investigate the combined effects on the early development of the dispersion coefficient due to the reversible and irreversible wall reactions. One of the results is shown that the dispersion coefficient may approach its steady-state limit in a short time under the following conditions: (i) a high value of Damkohler number (say Da ≥ 10); (ii) a small but non-zero value of absorption rate (say Γ* ≤ 0.5).
Abstract: Raisin Concentrate (RC) are the most important
products obtained in the raisin processing industries. These RC
products are now used to make the syrups, drinks and confectionery
productions and introduced as natural substitute for sugar in food
applications. Iran is a one of the biggest raisin exporter in the world
but unfortunately despite a good raw material, no serious effort to
extract the RC has been taken in Iran. Therefore, in this paper, we
determined and analyzed affected parameters on extracting RC
process and then optimizing these parameters for design the
extracting RC process in two types of raisin (round and long)
produced in Khorasan region. Two levels of solvent (1:1 and 2:1),
three levels of extraction temperature (60°C, 70°C and 80°C), and
three levels of concentration temperature (50°C, 60°C and 70°C)
were the treatments. Finally physicochemical characteristics of the
obtained concentrate such as color, viscosity, percentage of reduction
sugar, acidity and the microbial tests (mould and yeast) were
counted. The analysis was performed on the basis of factorial in the
form of completely randomized design (CRD) and Duncan's multiple
range test (DMRT) was used for the comparison of the means.
Statistical analysis of results showed that optimal conditions for
production of concentrate is round raisins when the solvent ratio was
2:1 with extraction temperature of 60°C and then concentration
temperature of 50°C. Round raisin is cheaper than the long one, and
it is more economical to concentrate production. Furthermore, round
raisin has more aromas and the less color degree with increasing the
temperature of concentration and extraction. Finally, according to
mentioned factors the concentrate of round raisin is recommended.
Abstract: Conventional materials like glass, wood or metals
replacement with polymer materials is still continuing. More simple
thus cheaper production is the main reason. However due to high
energy and petrochemical prices are polymer prices increasing too.
That´s why various kinds of fillers are used to make polymers
cheaper. Of course target is to maintain or improve properties of
these compounds. In this paper are solved rheology issues of
polymers compounded with vegetal origin fibers.
Abstract: Yogurts are prepared by fermenting milk with bacterial cultures consisting of a mixture of Streptococcus ssp. thermophilus and Lactobacillus delbrueckii ssp. bulgaricus. The main aim of this investigation was to develop a majority goat yogurt, with the addition of sheep milk in order to have a final product with good physicochemical quality properties and sensorial attributes. Four types of yogurts were prepared presenting the following proportion of goat and sheep milk respectively: C100 – 100%; C80 – 80%/20%; C60 – 60%/40%; C50 – 50%/50%. The goat milk was from the Serrana Jarmelista breed and the sheep milk from the Serra da Estrela breed. The inclusion of sheep milk improved attractiveness to consumers, and it also improved the nutritional value of the product, mainly the fatty acid and mineral contents. The C50 yogurt was preferred by 28% of the panellists, followed by the C100 with 16% and the commercial cow yogurt was 40% of preferences.
Abstract: For many chemical and biological processes, the understanding of the mixing phenomenon and flow behavior in a stirred tank is of major importance. A three-dimensional numerical study was performed using the software Fluent, to study the flow field in a stirred tank with a Rushton turbine. In this work, we first studied the flow generated in the tank with a Rushton turbine. Then, we studied the effect of the variation of turbine’s submergence on the thermodynamic quantities defining the flow field. For that, four submergences were considered, while maintaining the same rotational speed (N =250rpm). This work intends to optimize the aeration performances of a Rushton turbine in a stirred tank.
Abstract: The mathematical modeling of different biological
processes is usually used to predict or assess behavior of systems in
which these processes take place. This study deals with mathematical
and computer modeling of bi-substrate enzymatic reactions with
ping-pong mechanism, which play an important role in different
biochemical pathways. Besides that, three models of competitive
inhibition were designed using different software packages. The main
objective of this study is to represent the results from in silico
investigation of bi-substrate enzymatic reactions with ordered pingpong
mechanism in the presence of competitive inhibitors, as well as
to describe in details the inhibition effects. The simulation of the
models with certain kinetic parameters allowed investigating the
behavior of reactions as well as determined some interesting aspects
concerning influence of different cases of competitive inhibition.
Simultaneous presence of two inhibitors, competitive to the S1 and S2
substrates have been studied. Moreover, we have found the pattern of
simultaneous influence of both inhibitors.
Abstract: Atrazine, a herbicide widely used in sugarcane and corn production, is a frequently detected groundwater contaminant. An atrazine-degrading bacterium, strain KB02, was obtained from long-term atrazine-treated sugarcane field soils in Kanchanaburi province of Thailand. Strain KB02 had a rod-to-coccus morphological cycle during growth. Sequence analysis of the PCR product indicated that the 16S rRNA gene in strain KB02 was ranging from 97-98% identical to the same region in Klebsiella sp. Based on biochemical, physiological analysis and 16S rDNA sequence analysis of one representative isolate, strain KB02, the isolates belong to the genus Klebsiella in the family Enterobacteriaceae. Interestingly that the various primers for atzA, B and C failed to amplify genomic DNA of strain KB02. Whereas the expected PCR product of atzA, B and C were obtained from the reference strain, Arthrobacter sp. strain KU001.
Abstract: Gluconic acid is one of interesting chemical products
in industries such as detergents, leather, photographic, textile, and
especially in food and pharmaceutical industries. Fermentation is an
advantageous process to produce gluconic acid. Mathematical
modeling is important in the design and operation of fermentation
process. In fact, kinetic data must be available for modeling. The
kinetic parameters of gluconic acid production by Aspergillus niger
in batch culture was studied in this research at initial substrate
concentration of 150, 200 and 250 g/l. The kinetic models used were
logistic equation for growth, Luedeking-Piret equation for gluconic
acid formation, and Luedeking-Piret-like equation for glucose
consumption. The Kinetic parameters in the model were obtained by
minimizing non linear least squares curve fitting.