Abstract: Toxic and bloom-forming cyanobacterium Microcystis
aeruginosa was exposed to antialgal allelochemical gramine (0, 0.5, 1,
2, 4, 8 mg·L-1), The effects of gramine on photosynthetic pigments
(lipid soluble: chlorophyll a and β-carotene; water soluble:
phycocyanin, allophycocyanin, phycoerythrin, and total phycobilins)
and absorption spectra were studied in order to identify the most
sensitive pigment probe implicating the crucial suppression site on
photosynthetic apparatus. The results obtained indicated that all
pigment parameters were decreased with gramine concentration
increasing and exposure time extending. The above serious bleaching
of pigments was also reflected on the scanning results of absorption
spectra. Phycoerytherin exhibited the highest sensitivity to gramine
added, following by the largest relative decrease. It was concluded that
gramine seriously influenced algal photosynthetic activity by
destroying photosynthetic pigments and phycoerythrin most sensitive
to gramine might be contributed to its placing the outside of
phycobilins.
Abstract: The effect of variable chemical reaction on heat and mass transfer characteristics over unsteady stretching surface embedded in a porus medium is studied. The governing time dependent boundary layer equations are transformed into ordinary differential equations containing chemical reaction parameter, unsteadiness parameter, Prandtl number and Schmidt number. These equations have been transformed into a system of first order differential equations. MATHEMATICA has been used to solve this system after obtaining the missed initial conditions. The velocity gradient, temperature, and concentration profiles are computed and discussed in details for various values of the different parameters.
Abstract: The aim of this paper is to compare the effectiveness and electrochemical behavior of typical oilfield corrosion inhibitors with previous oilfield corrosion inhibitors under the same electrochemical techniques to control preferential weld corrosion of X65 pipeline steel in artificial seawater saturated with carbon dioxide at a pressure of one bar. A secondary aim is to investigate the conditions under which current reversal takes place. A flow channel apparatus was used in the laboratory to simulate the actual condition that occurs in marine pipelines. Different samples from the parent metal, the weld metal and the heat affected zone in the pipeline steel were galvanically coupled. The galvanic currents flowing between the weld regions were recorded using zero-resistance ammeters and tested under static and flowing conditions in both inhibited and uninhibited media. The results show that a current reversal took place when 30ppm of both green oilfield inhibitors were present, resulting in accelerated weld corrosion.
Abstract: The understanding of the system level of biological behavior and phenomenon variously needs some elements such as gene sequence, protein structure, gene functions and metabolic pathways. Challenging problems are representing, learning and reasoning about these biochemical reactions, gene and protein structure, genotype and relation between the phenotype, and expression system on those interactions. The goal of our work is to understand the behaviors of the interactions networks and to model their evolution in time and in space. We propose in this study an ontological meta-model for the knowledge representation of the genetic regulatory networks. Ontology in artificial intelligence means the fundamental categories and relations that provide a framework for knowledge models. Domain ontology's are now commonly used to enable heterogeneous information resources, such as knowledge-based systems, to communicate with each other. The interest of our model is to represent the spatial, temporal and spatio-temporal knowledge. We validated our propositions in the genetic regulatory network of the Aarbidosis thaliana flower
Abstract: Boron minerals are very useful for various industrial
activities, such as glass industry and detergent industry, due to its
mechanical and chemical properties. During the production of boron
compounds, many of these are introduced into the environment in the
form of waste. Boron is also an important micro nutrient for the
plants to vegetate but if it exists in high concentrations, it could have
toxic effects. The maximum boron level in drinking water for human
health is given as 0.3 mg/L in World Health Organization (WHO)
standards. The toxic effects of boron should be noted especially for
dry regions, thus, in recent years, increasing attention has been paid
to remove the boron from waste waters. In this study, boron removal
is implemented by ion exchange process using Amberlite IRA-743
resin. Amberlite IRA-743 resin is a boron specific resin and it
belongs to the polymerizate sorbent group within the aminopolyol
functional group. Batch studies were performed to investigate the
effects of various experimental parameters, such as adsorbent dose,
initial concentration and pH, on the removal of boron. It is found
that, when the adsorbent dose increases removal of boron from the
liquid phase increases. However, an increase in the initial
concentration decreases the removal of boron. The effective pH
values for removal of boron are determined between 8.5 and 9.
Equilibrium isotherms were also analyzed by Langmuir and
Freundlich isotherm models. The Langmuir isotherm is obeyed better
than the Freundlich isotherm.
Abstract: In the process of polyethylene extrusion polymer
material similar to powder or granule is under compression, melting
and transmission operation and on base of special form, extrudate has
been produced. Twin-screw extruders are applicable in industries
because of their high capacity. The powder mixing with chemical
additives and melting with thermal and mechanical energy in three
zones (feed, compression and metering zone) and because of gear
pump and screw's pressure, converting to final product in latest plate.
Extruders with twin-screw and short distance between screws are
better than other types because of their high capacity and good
thermal and mechanical stress.
In this paper, process of polyethylene extrusion and various tapes
of extruders are studied. It is necessary to have an exact control on
process to producing high quality products with safe operation and
optimum energy consumption.
The granule size is depending on granulator motor speed. Results
show at constant feed rate a decrease in granule size was found whit
Increase in motor speed. Relationships between HDPE feed rate and
speed of granulator motor, main motor and gear pump are calculated
following as:
x = HDPE feed flow rate, yM = Main motor speed
yM = (-3.6076e-3) x^4+ (0.24597) x^3+ (-5.49003) x^2+ (64.22092)
x+61.66786 (1)
x = HDPE feed flow rate, yG = Gear pump speed
yG = (-2.4996e-3) x^4+ (0.18018) x^3+ (-4.22794) x^2+ (48.45536)
x+18.78880 (2)
x = HDPE feed flow rate, y = Granulator motor speed
10th Degree Polynomial Fit: y = a+bx+cx^2+dx^3... (3)
a = 1.2751, b = 282.4655, c = -165.2098,
d = 48.3106, e = -8.18715, f = 0.84997
g = -0.056094, h = 0.002358, i = -6.11816e-5
j = 8.919726e-7, k = -5.59050e-9
Abstract: Acetaminophen (Paracetamol) tablets are popular OTC products among patients as analgesics and antipyretics. Paracetamol is marketed by a lot of suppliers around the world. The aim of the present investigation was to compare between many types of paracetamol tablets obtained from different suppliers (six brands produced by different pharmaceutical companies in middle east countries, and Panadol® manufactured in Ireland), by different quality control tests according to USP pharmacopeia.Using Non official tests-hardness and friability; official tests- disintegration, dissolution, and drug content. Additionally, evaluate the influence of temperatures 4°C, 25°C and 40°C at 75% relative humidity on the stability of the same brands in their original packaging has been conducted for two months. The results revealed that all paracetamol tablet brands complied with the official USP specifications. In conclusion, paracetamol tablets preferred to be stored at 25°C. All the tested brands being biopharmaceutically and chemically equivalent.
Abstract: Anodizing is an electrochemical process that converts the metal surface into a decorative, durable, corrosion-resistant, anodic oxide finish. Aluminum is ideally suited to anodizing, although other nonferrous metals, such as magnesium and titanium, also can be anodized. The anodic oxide structure originates from the aluminum substrate and is composed entirely of aluminum oxide. This aluminum oxide is not applied to the surface like paint or plating, but is fully integrated with the underlying aluminum substrate, so cannot chip or peel. It has a highly ordered, porous structure that allows for secondary processes such as coloring and sealing. In this experimental paper, we focus on a reliable method for fabricating nanoporous alumina with high regularity. Starting from study of nanostructure materials synthesize methods. After that, porous alumina fabricate in the laboratory by anodization of aluminum oxide. Hard anodization processes are employed to fabricate the nanoporous alumina using 0.3M oxalic acid and 90, 120 and 140 anodized voltages. The nanoporous templates were characterized by SEM and FFT. The nanoporous templates using 140 voltages have high ordered. The pore formation, influence of the experimental conditions on the pore formation, the structural characteristics of the pore and the oxide chemical reactions involved in the pore growth are discuss.
Abstract: The studies concerned an effect of six variants of ion
exchange substrate (nutrient carriers with a different potential impact
on pH of soil solution) on vegetation of orchard grass during two
different periods (42 and 84 days). In the pot experiment plants were
grown on sand (model of degraded soil) and six mixtures of sand and
2% (v/v) additions of particular variants of ion exchange substrate
(with pH ranged from 5.5 to 8.0). The study results showed that the
addition of the substrate at pH=6.5 caused the highest increase in
plant yield after shorter vegetation period whereas the addition of the
substrate at pH=5.5 increased dry stem and root biomass of orchard
grass after longer vegetation period. Thus, the ion exchange substrate
at pH=6.5 can be recommended for restoration of exhausted soils
when shorter vegetation period is planned; the ion exchange substrate
at pH=5.5 can be used for the same purpose when longer periods of
vegetative growth are considered.
Abstract: A virtualized and virtual approach is presented on
academically preparing students to successfully engage at a strategic
perspective to understand those concerns and measures that are both
structured and not structured in the area of cyber security and
information assurance. The Master of Science in Cyber Security and
Information Assurance (MSCSIA) is a professional degree for those
who endeavor through technical and managerial measures to ensure
the security, confidentiality, integrity, authenticity, control,
availability and utility of the world-s computing and information
systems infrastructure. The National University Cyber Security and
Information Assurance program is offered as a Master-s degree. The
emphasis of the MSCSIA program uniquely includes hands-on
academic instruction using virtual computers. This past year, 2011,
the NU facility has become fully operational using system
architecture to provide a Virtual Education Laboratory (VEL)
accessible to both onsite and online students. The first student cohort
completed their MSCSIA training this past March 2, 2012 after
fulfilling 12 courses, for a total of 54 units of college credits. The
rapid pace scheduling of one course per month is immensely
challenging, perpetually changing, and virtually multifaceted. This
paper analyses these descriptive terms in consideration of those
globalization penetration breaches as present in today-s world of
cyber security. In addition, we present current NU practices to
mitigate risks.
Abstract: The field of polymeric biomaterials is very important
from the socio-economical viewpoint. Synthetic carbohydrate
polymers are being increasingly investigated as biodegradable,
biocompatible and biorenewable materials. The aim of this study was
to synthesize and characterize some derivatives based on D-mannose.
D-mannose was chemically modified to obtain 1-O-allyl-2,3:5,6-di-
O-isopropylidene-D-mannofuranose and 1-O-(2-,3--epoxy-propyl)-
2,3:5,6-di-O-isopropylidene-D-mannofuranose.
The chemical structure of the resulting compounds was
characterized by FT-IR and NMR spectroscopy, and by HPLC-MS.
Abstract: TiO2 nanoparticles were synthesized by hydrothermal
method at 180°C from TiOSO4 aqueous solution with1m/l
concentration. The obtained products were coated with silica by
means of a seeded polymerization technique for a coating time of
1440 minutes to obtain well defined TiO2@SiO2 core-shell structure.
The uncoated and coated nanoparticles were characterized by using
X-Ray diffraction technique (XRD), Fourier Transform Infrared
Spectroscopy (FT-IR) to study their physico-chemical properties.
Evidence from XRD and FTIR results show that SiO2 is
homogenously coated on the surface of titania particles. FTIR spectra
show that there exists an interaction between TiO2 and SiO2 and
results in the formation of Ti-O-Si chemical bonds at the interface of
TiO2 particles and SiO2 coating layer. The non linear optical limiting
properties of TiO2 and TiO2@SiO2 nanoparticles dispersed in
ethylene glycol were studied at 532nm using 5ns Nd:YAG laser
pulses. Three-photon absorption is responsible for optical limiting
characteristics in these nanoparticles and it is seen that the optical
nonlinearity is enhanced in core-shell structures when compared with
single counterparts. This effective three-photon type absorption at
this wavelength, is of potential application in fabricating optical
limiting devices.
Abstract: The degradation of selected pharmaceuticals in some
water matrices was studied by using several chemical treatments. The
pharmaceuticals selected were the beta-blocker metoprolol, the
nonsteroidal anti-inflammatory naproxen, the antibiotic amoxicillin,
and the analgesic phenacetin; and their degradations were conducted
by using UV radiation alone, ozone, Fenton-s reagent, Fenton-like
system, photo-Fenton system, and combinations of UV radiation and
ozone with H2O2, TiO2, Fe(II), and Fe(III). The water matrices, in
addition to ultra-pure water, were a reservoir water, a groundwater,
and two secondary effluents from two municipal WWTP. The results
reveal that the presence of any second oxidant enhanced the
oxidation rates, with the systems UV/TiO2 and O3/TiO2 providing the
highest degradation rates. It is also observed in most of the
investigated oxidation systems that the degradation rate followed the
sequence: amoxicillin > naproxen > metoprolol > phenacetin. Lower
rates were obtained with the pharmaceuticals dissolved in natural
waters and secondary effluents due to the organic matter present
which consume some amounts of the oxidant agents.
Abstract: Visfatin and apelin are two new adipokines that recently gained a special interest in diabetes research. This study was conducted to study the interplay between these two adipokines and their correlation with other inflammatory and biochemical parameters in type 2 diabetic (T2D) postmenopausal women with CAD. Visfatin and apelin were measured by enzyme-linked immunoassay (ELISA). Visfatin was found to be significantly higher in the following groups: T2D patients without CAD, non-obese and obese T2D patients with CAD when compared to control group. Apelin was found to be significantly lower in non-obese and obese T2D patients with CAD when compared to control group. Visfatin and apelin were found to be significantly associated with each other and with other biochemical parameters. The current study provides evidence for the interplay between visfatin and apelin through the inflammatory milieu characteristic of T2D and their possible role in the pathogenesis of CAD complication of T2D.
Abstract: Magnesium alloy has been widely investigated as
biodegradable cardiovascular stent and bone implant. Its application
for biodegradable esophageal stenting remains unexplored. This
paper reports the biodegradation behaviors of AZ31 magnesium alloy
in artificial saliva and various types of beverage in vitro. Results
show that the magnesium ion release rate of AZ31 in artificial saliva
for a stent (2cm diameter, 10cm length at 50% stent surface
coverage) is 43 times lower than the daily allowance of human body
magnesium intakes. The degradation rates of AZ31 in different
beverages could also be significantly different. These results suggest
that the esophagus in nature is a less aggressive chemical
environment for degradation of magnesium alloys. The significant
difference in degradation rates of AZ31 in different beverages opens
new opportunities for development of degradation controllable
esophageal stent through customizing ingested beverages.
Abstract: One year (November 2009-October 2010) sediment monitoring was used to evaluate pollution status, concentration and distribution of heavy metals (As, Cu, Cd, Cr, Hg, Ni, Pb and Zn) in West Port of Malaysia. Sediment sample were collected from nine stations every four months. Geo-accumulation factor and Pollution Load Index (PLI) were estimated to better understand the pollution level in study area. The heavy metal concentration (Mg/g dry weight) were ranged from 20.2 to 162 for As, 7.4 to 27.6 for Cu, 0.244 to 3.53 for Cd, 11.5 to 61.5 for Cr, 0.11 to 0.409 for Hg, 7.2 to 22.2 for Ni, 22.3 to 80 for Pb and 23 to 98.3 for Zn. In general, concentration some metals (As,Cd, Hg and Pb) was higher than background values that are considered as serious concern for aquatic life and the human health.
Abstract: New graph similarity methods have been proposed in this work with the aim to refining the chemical information extracted from molecules matching. For this purpose, data fusion of the isomorphic and nonisomorphic subgraphs into a new similarity measure, the Approximate Similarity, was carried out by several approaches. The application of the proposed method to the development of quantitative structure-activity relationships (QSAR) has provided reliable tools for predicting several pharmacological parameters: binding of steroids to the globulin-corticosteroid receptor, the activity of benzodiazepine receptor compounds, and the blood brain barrier permeability. Acceptable results were obtained for the models presented here.
Abstract: In order to study the effects of supplemental irrigation, different levels of nitrogen chemical fertilizer and inoculation with rhizobium bacteria on the grain yield of chickpea, an experiment was carried out using split plot arrangement in randomize complete block design with three replication in agricultural researches station of Zanjan, Iran during 2009-2010 cropping season. The factors of experiment consisted of irritation (without irrigation (I1), irrigation at flowering stage (I2), irrigation at flowering and grain filling stages (I3) and full irrigation (I4)) and different levels of nitrogen fertilizer (without using of nitrogen fertilizer (N0), 75 kg.ha-1 (N75), 150 kg.ha-1 (N150) and inoculation with rhizobium bacteria (N4). The results of the analysis of variance showed that the effects of irrigation, nitrogen fertilizer levels and bacterial inoculation, were significant affect on number of pods per plant, number grains per plant, grain weight, grain yield, biological yield and harvest index at 1% probability level. Also Results showed that the grain yield in full irrigation treatment and inoculated with rhizobium bacteria was significantly higher than the other treatments.
Abstract: The aim of current research was to investigate ASLT method suitability for accelerated beer shelf-life determination. The research was accomplished on popular Latvian beer: light filtrated and unfiltered pasteurized beer with alcohol content 5.2%; dark filtrated pasteurized beer with alcohol content 4.2% with shelf-life five months. Bottled in dark glass bottles beer samples were storage during 20 weeks at several temperature regimes: +10±1 °C, +20±1 °C, +30±1 °C, +40±1 °C. Samples quality parameters as physically-chemical and microbiological was tested every two weeks using standard methods. It is possible to determine beer shelf-life rapidly during storage at +30±1 °C for filtered pasteurized light beer by 2.5 times, unfiltered pasteurized light beer by 1.4 times and for filtered pasteurized dark beer by 1.7 times. During preset experiments it was proved, that it is possible to determine beer shelf-life rapidly using ASLT method if beer storage temperature could be increased by +10±1 °C.
Abstract: Amphawa is the most popular weekend destination for
both domestic and international tourists in Thailand. More than 112
homestays and resorts have been developed along the water
resources. This research aims to initiate appropriate environmental
management system for riverside tourist accommodations in
Amphawa by investigating current environmental characteristics.
Eighty-eight riverside tourist accommodations were survey from
specific questionnaire, GPS data were also gathered for spatial
analysis. The results revealed that the accommodations are welled
manage in regards to some environmental aspects. In order to reduce
economic costs, energy efficiency equipment is utilized. A substantial
number of tourist accommodations encouraged waste separation,
followed by transfer to local administration organization. Grease
traps also utilized in order to decrease chemical discharged, grease
and oil from canteen and restaurants on natural environment. The
most notable mitigation is to initiate environmental friendly cleansers
for tourist accommodation along the riverside in tourism destinations.