Abstract: TiO2 nanoparticles were synthesized by hydrothermal
method at 180°C from TiOSO4 aqueous solution with1m/l
concentration. The obtained products were coated with silica by
means of a seeded polymerization technique for a coating time of
1440 minutes to obtain well defined TiO2@SiO2 core-shell structure.
The uncoated and coated nanoparticles were characterized by using
X-Ray diffraction technique (XRD), Fourier Transform Infrared
Spectroscopy (FT-IR) to study their physico-chemical properties.
Evidence from XRD and FTIR results show that SiO2 is
homogenously coated on the surface of titania particles. FTIR spectra
show that there exists an interaction between TiO2 and SiO2 and
results in the formation of Ti-O-Si chemical bonds at the interface of
TiO2 particles and SiO2 coating layer. The non linear optical limiting
properties of TiO2 and TiO2@SiO2 nanoparticles dispersed in
ethylene glycol were studied at 532nm using 5ns Nd:YAG laser
pulses. Three-photon absorption is responsible for optical limiting
characteristics in these nanoparticles and it is seen that the optical
nonlinearity is enhanced in core-shell structures when compared with
single counterparts. This effective three-photon type absorption at
this wavelength, is of potential application in fabricating optical
limiting devices.