Abstract: The abundance and availability of rice husk, an agricultural waste, make them as a good source for precursor of activated carbon. In this work, rice husk-based activated carbons were prepared via base treated chemical activation process prior the carbonization process. The effect of carbonization temperatures (400, 600 and 800oC) on their pore structure was evaluated through morphology analysis using scanning electron microscope (SEM). Sample carbonized at 800oC showed better evolution and development of pores as compared to those carbonized at 400 and 600oC. The potential of rice husk-based activated carbon as an alternative adsorbent was investigated for the removal of Ni(II), Zn(II) and Pb(II) from single metal aqueous solution. The adsorption studies using rice husk-based activated carbon as an adsorbent were carried out as a function of contact time at room temperature and the metal ions were analyzed using atomic absorption spectrophotometer (AAS). The ability to remove metal ion from single metal aqueous solution was found to be improved with the increasing of carbonization temperature. Among the three metal ions tested, Pb(II) ion gave the highest adsorption on rice husk-based activated carbon. The results obtained indicate the potential to utilize rice husk as a promising precursor for the preparation of activated carbon for removal of heavy metals.
Abstract: 16-Mercaptohexadecanoic acid (MHDA) and tripeptide glutathione conjugated with gold nanoparticles (Au-NPs) are characterized by Fourier Transform InfaRared (FTIR) spectroscopy combined with Surface-enhanced Raman scattering (SERS) spectroscopy. Surface Plasmon Resonance (SPR) technique based on FTIR spectroscopy has become an important tool in biophysics, which is perspective for the study of organic compounds. FTIR-spectra of MHDA shows the line at 2500 cm-1 attributed to thiol group which is modified by presence of Au-NPs, suggesting the formation of bond between thiol group and gold. We also can observe the peaks originate from characteristic chemical group. A Raman spectrum of the same sample is also promising. Our preliminary experiments confirm that SERS-effect takes place for MHDA connected with Au-NPs and enable us to detected small number (less than 106 cm-2) of MHDA molecules. Combination of spectroscopy methods: FTIR and SERS – enable to study optical properties of Au- NPs and immobilized bio-molecules in context of a bio-nano-sensors.
Abstract: Ground-level tropospheric ozone is one of the air
pollutants of most concern. It is mainly produced by photochemical
processes involving nitrogen oxides and volatile organic compounds
in the lower parts of the atmosphere. Ozone levels become
particularly high in regions close to high ozone precursor emissions
and during summer, when stagnant meteorological conditions with
high insolation and high temperatures are common.
In this work, some results of a study about urban ozone
distribution patterns in the city of Badajoz, which is the largest and
most industrialized city in Extremadura region (southwest Spain) are
shown. Fourteen sampling campaigns, at least one per month, were
carried out to measure ambient air ozone concentrations, during
periods that were selected according to favourable conditions to
ozone production, using an automatic portable analyzer.
Later, to evaluate the ozone distribution at the city, the measured
ozone data were analyzed using geostatistical techniques. Thus, first,
during the exploratory analysis of data, it was revealed that they were
distributed normally, which is a desirable property for the subsequent
stages of the geostatistical study. Secondly, during the structural
analysis of data, theoretical spherical models provided the best fit for
all monthly experimental variograms. The parameters of these
variograms (sill, range and nugget) revealed that the maximum
distance of spatial dependence is between 302-790 m and the
variable, air ozone concentration, is not evenly distributed in reduced
distances. Finally, predictive ozone maps were derived for all points
of the experimental study area, by use of geostatistical algorithms
(kriging). High prediction accuracy was obtained in all cases as
cross-validation showed. Useful information for hazard assessment
was also provided when probability maps, based on kriging
interpolation and kriging standard deviation, were produced.
Abstract: Bacterial magnetic nanoparticles have great useful potential in biotechnological and biomedical applications. In this study, a liquid growth medium was modified for cultivation a fastidious magnetotactic bacterium that has been isolated from Anzali
lagoon, Iran in our previous research. These modifications include
change in vitamin, mineral, carbon sources and etcetera. In our
experience, the serum bottles and designed air-tight laboratory bottles
were used to create microaerobic conditions in order to development
of a method for scale-up experiment. This information may serve as a
guide to green chemistry based biological protocols for the synthesis
of magnetic nanoparticles with control over the chemical
composition, morphology and size.
Abstract: The quantum mechanics simulation was applied for
calculating the interaction force between 2 molecules based on atomic level. For the simple extractive distillation system, it is ternary
components consisting of 2 closed boiling point components (A,lower boiling point and B, higher boiling point) and solvent (S). The
quantum mechanics simulation was used to calculate the intermolecular force (interaction force) between the closed boiling
point components and solvents consisting of intermolecular between
A-S and B-S.
The requirement of the promising solvent for extractive distillation
is that solvent (S) has to form stronger intermolecular force with only
one component than the other component (A or B). In this study, the
systems of aromatic-aromatic, aromatic-cycloparaffin, and paraffindiolefin
systems were selected as the demonstration for solvent
selection. This study defined new term using for screening the solvents called relative interaction force which is calculated from the
quantum mechanics simulation. The results showed that relative
interaction force gave the good agreement with the literature data
(relative volatilities from the experiment). The reasons are discussed. Finally, this study suggests that quantum mechanics results can improve the relative volatility estimation for screening the solvents leading to reduce time and money consuming
Abstract: A game animals – elk (Alces alces), deer (Cervus
elaphus), roe deer (Capreolus capreolus) or wild boar (Sus scrofa
scrofa) - every autumn and winter period provide an excellent
investment, diversification of many consumer meals. In last years
consumption and assortiment of game meat products significantly
increase. Investigations about biochemical composition of game meat
are not very much. The meat of wild animals is more favourable for
human health because it has lower saturated fatty acids content, but
higher content of protein. Therefore the aim of investigations was to
compare biochemical composition of ungulates obtained in
Latvia.Investigations were carried out in wild animals different
regions of Latvia. In the studied samples protein, intramuscular fat,
fatty acids and cholesterol were determined. The biochemical
analysis of 54 samples were done. Results of analysis showed that
protein content 22.36 – 22.92% of all types of meat samples is not
different statistically, significantly lower fat content 1.33 ± 0.88%
had elk meat samples and 1.59 ± 0.59% roe deer samples. Content of
cholesterol was various 64.41 – 95.07% in the ruminant meat
samples of different species. From the dietetic point of view the best
composition of fatty acids has meat samples of roe deer.
Abstract: The purpose of this work was to study the effect of the
irrigation using waste water with various electric conductivities (T(0,92ds/m), EC3 (3ds/m) and EC6 (6ds/m) on three varieties of
quinoa cultivated in a field south of Morocco. The follow up of the evolution of the chemical and agronomic parameters throughout the
culture made it possible to determine the responses to the saline stress in arid conditions. Results showed that the salinity caused the
depression of plant-s height, and reduced the fresh and dry weight in
the different parts of the three varieties plants. The increase of the irrigation water EC didn-t affect the yield for the varieties. Thus,
quinoa resisted to salinity and proved a behavior of a facultative halophyte crop. In fact, the cultivation of this using treated wastewater is feasible especially in arid areas for a sustainable use of
water resources.
Abstract: Non-uniform current distribution in polymer
electrolyte membrane fuel cells results in local over-heating,
accelerated ageing, and lower power output than expected. This
issue is very critical when fuel cell experiences water flooding. In
this work, the performance of a PEM fuel cell is investigated under
cathode flooding conditions. Two-dimensional partially flooded
GDL models based on the conservation laws and electrochemical
relations are proposed to study local current density distributions
along flow fields over a wide range of cell operating conditions.
The model results show a direct association between cathode inlet
humidity increases and that of average current density but the
system becomes more sensitive to flooding. The anode inlet
relative humidity shows a similar effect. Operating the cell at
higher temperatures would lead to higher average current densities
and the chance of system being flooded is reduced. In addition,
higher cathode stoichiometries prevent system flooding but the
average current density remains almost constant. The higher anode
stoichiometry leads to higher average current density and higher
sensitivity to cathode flooding.
Abstract: Bacterial cellulose, a biopolysaccharide, is produced by the bacterium, Gluconacetobacter xylinus. Static batch fermentation for bacterial cellulose production was studied in sucrose and date syrup solutions (Bx. 10%) at 28 °C using G. xylinus (PTCC, 1734). Results showed that the maximum yields of bacterial cellulose (BC) were 4.35 and 1.69 g/l00 ml for date syrup and sucrose medium after 336 hours fermentation period, respectively. Comparison of FTIR spectrum of cellulose with BC indicated appropriate coincidence which proved that the component produced by G. xylinus was cellulose. Determination of the area under X-ray diffractometry patterns demonstrated that the crystallinity amount of cellulose (83.61%) was more than that for the BC (60.73%). The scanning electron microscopy imaging of BC and cellulose were carried out in two magnifications of 1 and 6K. Results showed that the diameter ratio of BC to cellulose was approximately 1/30 which indicated more delicacy of BC fibers relative to cellulose.
Abstract: Wireless Sensor Networks (WSNs) have attracted the attention of many researchers. This has resulted in their rapid integration in very different areas such as precision agriculture,environmental monitoring, object and event detection and military surveillance. Due to the current WSN characteristics this technology is specifically useful in industrial areas where security, reliability and autonomy are basic, such as nuclear power plants, chemical plants, and others. In this paper we present a system based on WSNs to monitor environmental conditions around and inside a nuclear power plant, specifically, radiation levels. Sensor nodes, equipped with radiation sensors, are deployed in fixed positions throughout the plant. In addition, plant staff are also equipped with mobile devices with higher capabilities than sensors such as for example PDAs able to monitor radiation levels and other conditions around them. The system enables communication between PDAs, which form a Mobile Ad-hoc Wireless Network (MANET), and allows workers to monitor remote conditions in the plant. It is particularly useful during stoppage periods for inspection or in the event of an accident to prevent risk situations.
Abstract: The purpose of this study is to investigate the chemical
degradation of the organophosphorus pesticide of parathion and
carbamate insecticide of methomyl in the aqueous phase through
Fenton process. With the employment of batch Fenton process, the
degradation of the two selected pesticides at different pH, initial
concentration, humic acid concentration, and Fenton reagent dosages
was explored. The Fenton process was found effective to degrade
parathion and methomyl. The optimal dosage of Fenton reagents (i.e.,
molar concentration ratio of H2O2 to Fe2+) at pH 7 for parathion
degradation was equal to 3, which resulted in 50% removal of
parathion. Similarly, the optimal dosage for methomyl degradation
was 1, resulting in 80% removal of methomyl. This study also found
that the presence of humic substances has enhanced pesticide
degradation by Fenton process significantly. The mass spectroscopy
results showed that the hydroxyl free radical may attack the single
bonds with least energy of investigated pesticides to form smaller
molecules which is more easily to degrade either through
physio-chemical or bilolgical processes.
Abstract: Dill contains range of phytochemicals, such as vitamin C and polyphenols, which significantly contribute to their total antioxidant activity. The aim of the current research was to determine the best blanching method for processing of dill prior to microwave vacuum drying based on the content of phenolic compounds, vitamin C and free radical scavenging activity. Two blanching mediums were used – water and steam, and for part of the samples microwave pretreatment was additionally used. Evaluation of vitamin C, phenolic contents and scavenging of DPPH˙ radical in dried dill was performed. Blanching had an effect on all tested parameters and the blanching conditions are very important. After evaluation of the results, as the best method for dill pretreatment was established blanching at 90 °C for 30 seconds.
Abstract: The purpose of this work is to establish the theoretical
foundations for calculating and designing the sublimationcondensation
processes in chemical apparatuses which are intended
for production of ultrafine powders of crystalline and amorphous
materials with controlled fractional composition. Theoretic analysis
of the primary processes of nucleation and growth kinetics of the
clusters according to the degree of super-saturation and the
homogeneous or heterogeneous nature of nucleation has been carried
out. The engineering design procedures of desublimation processes
have been offered and tested for modification of the Claus process.
Abstract: The present study addresses problems and solutions
related to new functional food production. Wheat (Triticum aestivum
L) bran obtained from industrial mill company “Dobeles
dzirnavieks”, was used to investigate them as raw material like
nutrients for Bifidobacterium lactis Bb-12. Enzymatic hydrolysis of
wheat bran starch was carried out by α-amylase from Bacillus
amyloliquefaciens (Sigma Aldrich). The Viscozyme L purchased
from (Sigma Aldrich) were used for reducing released sugar.
Bifidibacterium lactis Bb-12 purchased from (Probio-Tec® CHR
Hansen) was cultivated in enzymatically hydrolysed wheat bran
mash. All procedures ensured the number of active Bifidobacterium
lactis Bb-12 in the final product reached 105 CFUg-1. After enzymatic
and bacterial fermentations sample were freeze dried for analysis of
chemical compounds. All experiments were performed at Faculty of
Food Technology of Latvia University of Agriculture in January-
March 2013. The obtained results show that both types of wheat bran
(enzymatically treated and non-treated) influenced the fermentative
activity and number of Bifidibacterium lactis Bb-12 viable in wheat
bran mash. Amount of acidity strongly increase during the wheat
bran mash fermentation. The main objective of this work was to
create low-energy functional enzymatically and bacterially treated
food from wheat bran using enzymatic hydrolysis of carbohydrates
and following cultivation of Bifidobacterium lactis Bb-12.
Abstract: The coastal sediments of West Port of Malaysia was monitored from Nov. 2009 to Oct. 2010 to assess spatial distribution of heavy metals As, Cu, Cd, Cr, Hg, Ni, Zn and Pb. Sediment samples were collected from 10 stations in dry and rainy season in West Port. The range concentrations measured (Mg/g dry weight ) were from 23.4 to 98.3 for Zn, 22.3 to 80 for Pb, 7.4 to 27.6 Cu, 0.244 to 3.53 for Cd, 7.2 to 22.2 for Ni, 20.2 to 162 for As, 0.11 to 0.409 for Hg and 11.5 to 61.5 for Cr. The geochemical indexes used in this study were Geoaccumulation (Igeo), Contamination Factor (CF) and Pollution Load Index (PLI); these indexes were used to evaluate the levels of sediment contaminations. The results of these indexes show that, the status of West Port sediment quality are moderately polluted by heavy metals except in arsenic which shows the high level of pollution.
Abstract: The photochemical and photo-Fenton oxidation of 1,3-dichloro-2-propanol was performed in a batch reactor, at room temperature, using UV radiation, H2O2 as oxidant, and Fenton-s reagent. The effect of the oxidative agent-s initial concentration was investigated as well as the effect of the initial concentration of Fe(II) by following the target compound degradation, the total organic carbon removal and the chloride ion production. Also, from the kinetic analysis conducted and proposed reaction scheme it was deduced that the addition of Fe(II) significantly increases the production and the further oxidation of the chlorinated intermediates.
Abstract: In order to increase in chickpea quality and
agroecosystem sustainability, field experiments were carried out in
2007 and 2008 growing seasons. In this research the effects of
different organic, chemical and biological fertilizers were
investigated on grain yield and quality of chickpea. Experimental
units were arranged in split-split plots based on randomized complete
blocks with three replications. The highest amounts of yield and yield
components were obtained in G1×N5 interaction. Significant
increasing of N, P, K, Fe and Mg content in leaves and grains
emphasized on superiority of mentioned treatment because each one
of these nutrients has an approved role in chlorophyll synthesis and
photosynthesis ability of the crop. The combined application of
compost, farmyard manure and chemical phosphorus (N5) had the
best grain quality due to high protein, starch and total sugar contents,
low crude fiber and reduced cooking time.
Abstract: Chemical and physical functionalization of multiwalled
carbon nanotubes (MWCNT) has been commonly practiced to
achieve better dispersion of carbon nanotubes (CNTs) in polymer
matrix. This work describes various functionalization methods (acidtreatment,
non-ionic surfactant treatment with TritonX-100),
fabrication of MWCNT/PP nanocomposites via melt blending and
characterization of mechanical properties. Microscopy analysis
(FESEM, TEM, XPS) showed effective purification of MWCNTs
under acid treatment, and better dispersion under both chemical and
physical functionalization techniques combined, in their respective
order. Tensile tests showed increase in tensile strength for the
nanocomposites that contain MWCNTs up to 2 wt%. A decrease in
tensile strength was seen in samples that contain 4 wt% of MWCNTs
for both raw and Triton X-100 functionalized, signifying MWCNT
degradation/rebundling at composition with higher content of
MWCNTs. For the acid-treated MWCNTs, however, the tensile
results showed slight improvement even at 4wt%, indicating effective
dispersion of MWCNTs.
Abstract: Nowadays, the increase of human population every
year results in increasing of water usage and demand. Saen Saep
canal is important canal in Bangkok. The main objective of this study
is using Artificial Neural Network (ANN) model to estimate the
Chemical Oxygen Demand (COD) on data from 11 sampling sites.
The data is obtained from the Department of Drainage and Sewerage,
Bangkok Metropolitan Administration, during 2007-2011. The
twelve parameters of water quality are used as the input of the
models. These water quality indices affect the COD. The
experimental results indicate that the ANN model provides a high
correlation coefficient (R=0.89).
Abstract: In this paper we propose an NLP-based method for
Ontology Population from texts and apply it to semi automatic
instantiate a Generic Knowledge Base (Generic Domain Ontology) in
the risk management domain. The approach is semi-automatic and
uses a domain expert intervention for validation. The proposed
approach relies on a set of Instances Recognition Rules based on
syntactic structures, and on the predicative power of verbs in the
instantiation process. It is not domain dependent since it heavily
relies on linguistic knowledge.
A description of an experiment performed on a part of the
ontology of the PRIMA1 project (supported by the European
community) is given. A first validation of the method is done by
populating this ontology with Chemical Fact Sheets from
Environmental Protection Agency2. The results of this experiment
complete the paper and support the hypothesis that relying on the
predicative power of verbs in the instantiation process improves the
performance.