Abstract: The irradiation of polymeric materials has received
much attention because it can produce diverse changes in chemical
structure and physical properties. Thus, studying the chemical and
structural changes of polymers is important in practice to achieve
optimal conditions for the modification of polymers. The effect of
gamma irradiation on the crystalline structure of poly(vinylidene
fluoride) (PVDF) has been investigated using differential scanning
calorimetry (DSC) and X-ray diffraction techniques (XRD). Gamma
irradiation was carried out in atmosphere air with doses between 100
kGy at 3,000 kGy with a Co-60 source. In the melting thermogram of
the samples irradiated can be seen a bimodal melting endotherm is
detected with two melting temperature. The lower melting
temperature is attributed to melting of crystals originally present and
the higher melting peak due to melting of crystals reorganized upon
heat treatment. These results are consistent with those obtained by
XRD technique showing increasing crystallinity with increasing
irradiation dose, although the melting latent heat is decreasing.
Abstract: The combination of multi–walled carbon nanotubes
(MWCNTs) with polymers offers an attractive route to reinforce the
macromolecular compounds as well as the introduction of new
properties based on morphological modifications or electronic
interactions between the two constituents. As they are only a few
nanometers in dimension, it offers ultra-large interfacial area per
volume between the nano-element and polymer matrix. Nevertheless,
the use of MWCNTs as a rough material in different applications has
been largely limited by their poor processability, insolubility, and
infusibility. Studies concerning the nanofiller reinforced polymer
composites are justified in an attempt to overcome these limitations.
This work presents one preliminary study of MWCNTs dispersion
into the PVDF homopolymer. For preparation, the composite
components were diluted in n,n-dimethylacetamide (DMAc) with
mechanical agitation assistance. After complete dilution, followed by
slow evaporation of the solvent at 60°C, the samples were dried.
Films of about 80 μm were obtained. FTIR and UV-Vis
spectroscopic techniques were used to characterize the
nanocomposites. The appearance of absorption bands in the FTIR
spectra of nanofilled samples, when compared to the spectrum of
pristine PVDF samples, are discussed and compared with the UV-Vis
measurements.
Abstract: The adjoint method has been used as a successful tool to
obtain sensitivity gradients in aerodynamic design and optimisation
for many years. This work presents an alternative approach to the
continuous adjoint formulation that enables one to compute gradients
of a given measure of merit with respect to control parameters other
than those pertaining to geometry. The procedure is then applied to
the steady 2–D compressible Euler and incompressible Navier–Stokes
flow equations. Finally, the results are compared with sensitivities
obtained by finite differences and theoretical values for validation.
Abstract: This paper analyzes the institutionalization of social
protest in Spain. In the current crisis Podemos party seems to
represent the political positions of the most affected citizens by the
economic situation. It studies using quantitative techniques (statistical
bivariate analysis), focusing on the exploitation of several bases of
statistics data from the Center for Sociological and Research of
Spanish Government, 15M movement characterization to its
institutionalization in the Podemos party. Making a comparison
between the participant's profile by the 15M and the social bases of
Podemos votes. Data on the transformation of the socio-demographic
profile of the fans, connoisseurs and 15M participants and voters are
given.
Abstract: Large scale Indian manufacturers started
implementing Six Sigma to their supply core to fulfill the endless
need of high quality products. As well, they initiated encouraging
their suppliers to apply the well-ascertain SS management practice
and kept no resource for supplier enterprises, generally small midsized
enterprises to think for the admittance of Six Sigma as a quality
promotion drive. There are many issues to study for requisite changes
before the introduction of Six Sigma in auto SMEs. This paper
converges on impeding factors while implementing SS drive and also
pinpoints the gains achieved through successful implementation. The
result of this study suggest some operational guidelines for effective
implementation of Six Sigma from evidences acquired through
research questionnaire and interviews with industrial professionals,
apportioned to assort auto sector mid-sized enterprises (MSEs) in
India.
Abstract: Interaction between mixing and crystallization is often
ignored despite the fact that it affects almost every aspect of the
operation including nucleation, growth, and maintenance of the
crystal slurry. This is especially pronounced in multiple impeller
systems where flow complexity is increased. By choosing proper
mixing parameters, what closely depends on the knowledge of the
hydrodynamics in a mixing vessel, the process of batch cooling
crystallization may considerably be improved. The values that render
useful information when making this choice are mixing time and
power consumption. The predominant motivation for this work was
to investigate the extent to which radial dual impeller configuration
influences mixing time, power consumption and consequently the
values of metastable zone width and nucleation rate. In this research,
crystallization of borax was conducted in a 15 dm3 baffled batch
cooling crystallizer with an aspect ratio (H/T) of 1.3. Mixing was
performed using two straight blade turbines (4-SBT) mounted on the
same shaft that generated radial fluid flow. Experiments were
conducted at different values of N/NJS ratio (impeller speed/
minimum impeller speed for complete suspension), D/T ratio
(impeller diameter/crystallizer diameter), c/D ratio (lower impeller
off-bottom clearance/impeller diameter), and s/D ratio (spacing
between impellers/impeller diameter). Mother liquor was saturated at
30°C and was cooled at the rate of 6°C/h. Its concentration was
monitored in line by Na-ion selective electrode. From the values of
supersaturation that was monitored continuously over process time, it
was possible to determine the metastable zone width and
subsequently the nucleation rate using the Mersmann’s nucleation
criterion. For all applied dual impeller configurations, the mixing
time was determined by potentiometric method using a pulse
technique, while the power consumption was determined using a
torque meter produced by Himmelstein & Co. Results obtained in
this investigation show that dual impeller configuration significantly
influences the values of mixing time, power consumption as well as
the metastable zone width and nucleation rate. A special attention
should be addressed to the impeller spacing considering the flow
interaction that could be more or less pronounced depending on the
spacing value.
Abstract: Nowadays, food safety is a great public concern;
therefore, robust and effective techniques are required for detecting
the safety situation of goods. Hyperspectral Imaging (HSI) is an
attractive material for researchers to inspect food quality and safety
estimation such as meat quality assessment, automated poultry
carcass inspection, quality evaluation of fish, bruise detection of
apples, quality analysis and grading of citrus fruits, bruise detection
of strawberry, visualization of sugar distribution of melons,
measuring ripening of tomatoes, defect detection of pickling
cucumber, and classification of wheat kernels. HSI can be used to
concurrently collect large amounts of spatial and spectral data on the
objects being observed. This technique yields with exceptional
detection skills, which otherwise cannot be achieved with either
imaging or spectroscopy alone. This paper presents a nonlinear
technique based on kernel Fukunaga-Koontz transform (KFKT) for
detection of fat content in ground meat using HSI. The KFKT which
is the nonlinear version of FKT is one of the most effective
techniques for solving problems involving two-pattern nature. The
conventional FKT method has been improved with kernel machines
for increasing the nonlinear discrimination ability and capturing
higher order of statistics of data. The proposed approach in this paper
aims to segment the fat content of the ground meat by regarding the
fat as target class which is tried to be separated from the remaining
classes (as clutter). We have applied the KFKT on visible and nearinfrared
(VNIR) hyperspectral images of ground meat to determine
fat percentage. The experimental studies indicate that the proposed
technique produces high detection performance for fat ratio in ground
meat.
Abstract: Debts reconstruction under some of moratorium
projects is one of important method that highly benefits to both the
Banks and farmers. The method can reduce probabilities for nonprofits
loan. This paper discuss about debts reconstruction and career
development training for farmers in Thailand between 2011 and
2013. The research designed is mix-method between quantitative
survey and qualitative survey. Sample size for quantitative method is
1003 cases. Data gathering procedure is between October and
December 2013. Main results affirmed that debts reconstruction is
needed. And there are numerous benefits from farmers’ career
development training. Many of farmers who attend field school
activities able to bring knowledge learned to apply for the farms’
work. They can reduce production costs. Framers’ quality of life and
their household well-being also improve. This program should apply
in any countries where farmers have highly debts and highly risks for
not return the debts.
Abstract: Asphalt pavement itself is a mixture made up of mainly aggregates, binders, and fillers that acts as a composition used for pavement construction. An experimental program was setup to determine the fatigue performance test of Asphalt with three different grades of conventional binders. Asphalt specimen has achieved the maximum optimum bulk density and air voids with a consistent bulk density of 2.3 t/m3, with an air void of 5% ± 0.5, before loading into the Asphalt Mixture Performance Tested (AMPT) for fatigue test. The number of cycles is defined as the point where phase angle drops, which is caused by the formation of cracks due to the increasing micro cracks when asphalt is undergoing repeated cycles of loading. Thus, the data collected are analyzed using the drop of phase angle as failure criteria. Based in the data analyzed, it is evident that the fatigue life of asphalt lies on the grade of binder. The result obtained shows that all specimens do experience a drop in phase angle due to macro cracks in the asphalt specimen.
Abstract: Green chemistry for plant extraction of active principles is the main interest of many researchers concerned with climate change. While classical organic solvents are detrimental to our environment, greener alternatives to ionic liquids are very promising for sustainable organic chemistry. This study focused on the determination of functional groups observed in the main constituents from the ionic liquid extracts of Coleus aromaticus Benth leaves using FT-IR Spectroscopy. Moreover, this research aimed to determine the best ionic liquid that can separate functionalized plant constituents from the leaves Coleus aromaticus Benth using Fourier Transform Infrared Spectroscopy. Coleus aromaticus Benth leaf extract in different ionic liquids, elucidated pharmacologically important functional groups present in major constituents of the plant, namely, rosmarinic acid, caffeic acid and chlorogenic acid. In connection to distinctive appearance of functional groups in the spectrum and highest % transmittance, potassium chloride-glycerol is the best ionic liquid for green extraction.
Abstract: High double excitation of two-electron atoms has been
investigated using hyperpherical coordinates within a modified
adiabatic expansion technique. This modification creates a novel
fictitious force leading to a spontaneous exchange symmetry breaking
at high double excitation. The Pauli principle must therefore be
regarded as approximation valid only at low excitation energy.
Threshold electron scattering from high Rydberg states shows an
unexpected time reversal symmetry breaking. At threshold for double
escape we discover a broad (few eV) Cooper pair.
Abstract: Reinforced cement concrete is getting extensively used
for construction of different type of structures for the last one century.
During this period, we have constructed many structures like
buildings, bridges, industrial structures, pavement, water tanks etc.
using this construction material. These structures have been created
with huge investment of resources. It is essential to maintain those
structures in functional condition. Since deterioration in RCC
Structures is a common and natural phenomenon it is required to have
a detailed plan, methodology for structural repair and rehabilitation
shall be in place for dealing such issues. It is important to know exact
reason of distress, type of distress and correct method of repair
concrete structures. The different methods of repair are described in
paper according to distress category which can be refereed for repair.
Major finding of the study is that to protect our structure we need to
have maintenance frequency and correct material to be chosen for
repair. Also workmanship during repair needs to be taken utmost care
for quality repair.
Abstract: Ultrasonic metal welding has been the subject of ongoing research and development, most recently concentrating on metal joining in miniature devices, for example to allow solder-free wire bonding. As well as at the small scale, there are also opportunities to research the joining of thicker sheet metals and to widen the range of similar and dissimilar materials that can be successfully joined using this technology. This study presents the design, characterisation and test of a lateral-drive ultrasonic metal spot welding device. The ultrasonic metal spot welding horn is modelled using finite element analysis (FEA) and its vibration behaviour is characterised experimentally to ensure ultrasonic energy is delivered effectively to the weld coupon. The welding stack and fixtures are then designed and mounted on a test machine to allow a series of experiments to be conducted for various welding and ultrasonic parameters. Weld strength is subsequently analysed using tensile-shear tests. The results show how the weld strength is particularly sensitive to the combination of clamping force and ultrasonic vibration amplitude of the welding tip, but there are optimal combinations of these and also limits that must be clearly identified.
Abstract: This paper applies recursive cointegration analysis to
examine the dynamic changes in Feldstein-Horioka saving-investment
(S-I) coefficients across China and the ASEAN-5 countries over time.
To the extent that the S-I coefficients measure international capital
mobility, the main empirical results are as follows. The recursive trace
statistics show that the investment- savings nexus varies in these six
countries. There is no cointegration between investment and savings in
three countries (China, Malaysia, and Singapore), which means that
the mobility of the capital markets in the three is high and that
domestic investment in them will be financed by the global pool of
capital. As to the other three countries (Indonesia, Thailand, and
Philippines), there is cointegration between investment and savings for
part of the sample period in the three, including before 2002 for
Thailand, before 2001 for Indonesia, and before 2002 for Philippines.
This shows these three countries achieved highly mobile and open
capital markets later.
Abstract: A composite material with carbon fiber and polymer
matrix has been used as adherent for manufacturing adhesive joints.
In order to evaluate different fiber orientations on joint performance,
the adherents with the 0°, ±15°, ±30°, ±45° fiber orientations were
used in the single lap joint configuration. The joints with an overlap
length of 25 mm were prepared according to the ASTM 1002
specifications and subjected to tensile loadings. The structural
adhesive used was a two-part epoxy to be cured at 70°C for an hour.
First, mechanical behaviors of the adherents were measured using
three point bending test. In the test, considerations were given to
stress to failure and elastic modulus. The results were compared with
theoretical ones using rule of mixture. Then, the joints were
manufactured in a specially prepared jig, after a proper surface
preparation. Experimental results showed that the fiber orientations
of the adherents affected the joint performance considerably; the
joints with ±45° adherents experienced the worst shear strength, half
of those with 0° adherents, and in general, there was a great
relationship between the fiber orientations and failure mechanisms.
Delamination problems were observed for many joints, which were
thought to be due to peel effects at the ends of the overlap. It was
proved that the surface preparation applied to the adherent surface
was adequate. For further explanation of the results, a numerical
work should be carried out using a possible non-linear analysis.
Abstract: This paper investigates the application of metallic
coatings on high fiber volume fraction carbon/epoxy polymer matrix
composites. For the grip of the metallic layer, a method of modifying
the surface of the composite by introducing a mixture of copper and
steel powder (filler powders) which can reduce the impact of thermal
spray particles. The powder was introduced to the surface at the time
of the forming. Arc spray was used to project the zinc coating layer.
The substrate was grit blasted to avoid poor adherence. The porosity, microstructure, and morphology of layers are
characterized by optical microscopy, SEM and image analysis. The
samples were studied also in terms of hardness and erosion resistance.
This investigation did not reveal any visible evidence damage to the
substrates. The hardness of zinc layer was about 25.94 MPa and the
porosity was around (∼6.70%). The erosion test showed that the zinc
coating improves the resistance to erosion. Based on the results
obtained, we can conclude that thermal spraying allows the production
of protective coating on PMC. Zinc coating has been identified as a
compatible material with the substrate. The filler powders layer
protects the substrate from the impact of hot particles and allows
avoiding the rupture of brittle carbon fibers.
Abstract: The rising demand for format-flexible packaging
machines is caused by current market changes. Increasing the formatflexibility
is a new goal for the packaging machine manufacturers’
product development process. There are no methodical or designorientated
tools for a comprehensive consideration of this target. This
paper defines the term format-flexibility in the context of packaging
machines and shows the state-of-the-art for improving the
changeover of production machines. The requirements for a new
approach and the concept itself will be introduced, and the method
elements will be explained. Finally, the use of the concept and the
result of the development of a format-flexible packaging machine
will be shown.
Abstract: Smart metering and demand response are gaining
ground in industrial and residential applications. Smart Appliances
have been given concern towards achieving Smart home. The success
of Smart grid development relies on the successful implementation of
Information and Communication Technology (ICT) in power sector.
Smart Appliances have been the technology under development and
many new contributions to its realization have been reported in the
last few years. The role of ICT here is to capture data in real time,
thereby allowing bi-directional flow of information/data between
producing and utilization point; that lead a way for the attainment of
Smart appliances where home appliances can communicate between
themselves and provide a self-control (switch on and off) using the
signal (information) obtained from the grid. This paper depicts the
background on ICT for smart appliances paying a particular attention
to the current technology and identifying the future ICT trends for
load monitoring through which smart appliances can be achieved to
facilitate an efficient smart home system which promote demand
response program. This paper grouped and reviewed the recent
contributions, in order to establish the current state of the art and
trends of the technology, so that the reader can be provided with a
comprehensive and insightful review of where ICT for smart
appliances stands and is heading to. The paper also presents a brief
overview of communication types, and then narrowed the discussion
to the load monitoring (Non-intrusive Appliances Load Monitoring
‘NALM’). Finally, some future trends and challenges in the further
development of the ICT framework are discussed to motivate future
contributions that address open problems and explore new
possibilities.
Abstract: The very well-known stacked sets of numbers referred
to as Pascal’s triangle present the coefficients of the binomial
expansion of the form (x+y)n. This paper presents an approach (the
Staircase Horizontal Vertical, SHV-method) to the generalization of
planar Pascal’s triangle for polynomial expansion of the form
(x+y+z+w+r+⋯)n. The presented generalization of Pascal’s triangle
is different from other generalizations of Pascal’s triangles given in
the literature. The coefficients of the generalized Pascal’s triangles,
presented in this work, are generated by inspection, using embedded
Pascal’s triangles. The coefficients of I-variables expansion are
generated by horizontally laying out the Pascal’s elements of (I-1)
variables expansion, in a staircase manner, and multiplying them with
the relevant columns of vertically laid out classical Pascal’s elements,
hence avoiding factorial calculations for generating the coefficients
of the polynomial expansion. Furthermore, the classical Pascal’s
triangle has some pattern built into it regarding its odd and even
numbers. Such pattern is known as the Sierpinski’s triangle. In this
study, a presentation of Sierpinski-like patterns of the generalized
Pascal’s triangles is given. Applications related to those coefficients
of the binomial expansion (Pascal’s triangle), or polynomial
expansion (generalized Pascal’s triangles) can be in areas of
combinatorics, and probabilities.
Abstract: The recent instability in economy was found to be
influencing the situation in Malaysia whether directly or indirectly.
Taking that into consideration, the government needs to find the best
approach to balance its citizen’s socio-economic strata level urgently.
Through education platform is among the efforts planned and acted
upon for the purpose of balancing the effects of the influence,
through the exposure of social entrepreneurial activity towards youth
especially those in higher institution level. Armed with knowledge
and skills that they gained, with the support by entrepreneurial
culture and environment while in campus; indirectly, the students will
lean more on making social entrepreneurship as a career option when
they graduate. Following the issues of marketability and workability
of current graduates that are becoming dire, research involving how
far the willingness of student to create social innovation that
contribute to the society without focusing solely on personal gain is
relevant enough to be conducted. With that, this research is
conducted with the purpose of identifying the level of entrepreneurial
intention and social entrepreneurship among higher institution
students in Malaysia. Stratified random sampling involves 355
undergraduate students from five public universities had been made
as research respondents and data were collected through surveys. The
data was then analyzed descriptively using min score and standard
deviation. The study found that the entrepreneurial intention of higher
education students are on moderate level, however it is the contrary
for social entrepreneurship activities, where it was shown on a high
level. This means that while the students only have moderate level of
willingness to be a social entrepreneur, they are very committed to
created social innovation through the social entrepreneurship
activities conducted. The implication from this study can be
contributed towards the higher institution authorities in prediction the
tendency of student in becoming social entrepreneurs. Thus, the
opportunities and facilities for realizing the courses related to social
entrepreneurship must be created expansively so that the vision of
creating as many social entrepreneurs as possible can be achieved.