Abstract: This paper presents the effects of mixing procedures
on mechanical properties of flyash-based geopolymer matrices
containing nanosilica (NS) at 0.5%, 1.0%, 2.0%, and 3.0% by weight.
Comparison is made with conventional mechanical dry-mixing of NS
with flyash and wet-mixing of NS in alkaline solutions. Physical and
mechanical properties are investigated using X-Ray Diffraction
(XRD) and Scanning Electron Microscope (SEM). Results show that
generally the addition of NS particles enhanced the microstructure
and improved flexural and compressive strengths of geopolymer
nanocomposites. However, samples, prepared using dry-mixing
approach, demonstrate better physical and mechanical properties
comparing to wet-mixing samples.
Abstract: Lightweight and efficient structures have the aim to
enhance the efficiency of the components in various industries.
Toward this end, composites are one of the most widely used
materials because of durability, high strength and modulus, and low
weight. One type of the advanced composites is grid-stiffened
composite (GSC) structures, which have been extensively considered
in aerospace, automotive, and aircraft industries. They are one of the
top candidates for replacing some of the traditional components,
which are used here. Although there are a good number of published
surveys on the design aspects and fabrication of GSC structures, little
systematic work has been reported on their material modification to
improve their properties, to our knowledge. Matrix modification
using nanoparticles is an effective method to enhance the flexural
properties of the fibrous composites. In the present study, a silanecoupling
agent (3-glycidoxypropyltrimethoxysilane/3-GPTS) was
introduced onto the silica (SiO2) nanoparticle surface and its effects
on the three-point flexural response of isogrid E-glass/epoxy
composites were assessed. Based on the Fourier Transform Infrared
Spectrometer (FTIR) spectra, it was inferred that the 3-GPTS
coupling agent was successfully grafted onto the surface of SiO2
nanoparticles after modification. Flexural test revealed an
improvement of 16%, 14%, and 36% in stiffness, maximum load and
energy absorption of the isogrid specimen filled with 3 wt.% 3-
GPTS/SiO2 compared to the neat one. It would be worth mentioning
that in these structures, considerable energy absorption was observed
after the primary failure related to the load peak. In addition, 3-
GPTMS functionalization had a positive effect on the flexural
behavior of the multiscale isogrid composites. In conclusion, this
study suggests that the addition of modified silica nanoparticles is a
promising method to improve the flexural properties of the gridstiffened
fibrous composite structures.
Abstract: Mineral product, waste concrete (fine aggregates),
waste in the optical field, industry, and construction employ separators
to separate solids and classify them according to their size. Various
sorting machines are used in the industrial field such as those operating
under electrical properties, centrifugal force, wind power, vibration,
and magnetic force. Study on separators has been carried out to
contribute to the environmental industry. In this study, we perform
CFD analysis for understanding the basic mechanism of the separation
of waste concrete (fine aggregate) particles from air with a machine
built with a rotor with blades. In CFD, we first performed
two-dimensional particle tracking for various particle sizes for the
model with 1 degree, 1.5 degree, and 2 degree angle between each
blade to verify the boundary conditions and the method of rotating
domain method to be used in 3D. Then we developed 3D numerical
model with ANSYS CFX to calculate the air flow and track the
particles. We judged the capability of particle separation for given size
by counting the number of particles escaping from the domain toward
the exit among 10 particles issued at the inlet. We confirm that
particles experience stagnant behavior near the exit of the rotating
blades where the centrifugal force acting on the particles is in balance
with the air drag force. It was also found that the minimum particle
size that can be separated by the machine with the rotor is determined
by its capability to stay at the outlet of the rotor channels.
Abstract: This experimental study consists of a characterization
of epoxy grout where an amount of 2% of graphene nanoplatelets
particles were added to commercial epoxy resin to evaluate their
behavior regarding neat epoxy resin. Compressive tests, tensile tests
and flexural tests were conducted to study the effect of graphene
nanoplatelets on neat epoxy resin. By comparing graphene-based and
neat epoxy grout, there is no significant increase of strength due to
weak interface in the graphene nanoplatelets/epoxy composites.
From this experiment, the tension and flexural strength of graphenebased
epoxy grouts is slightly lower than ones of neat epoxy grout.
Nevertheless, the addition of graphene has produced more consistent
results according to a smaller standard deviation of strength.
Furthermore, the graphene has also improved the ductility of the
grout, hence reducing its brittle behaviour. This shows that the
performance of graphene-based grout is reliably predictable and able
to minimise sudden rupture. This is important since repair design of
damaged pipeline is of deterministic nature.
Abstract: This article developed an ion thruster optic system
sputter erosion depth numerical 3D model by IFE-PIC (Immersed
Finite Element-Particle-in-Cell) and Mont Carlo method, and
calculated the downstream surface sputter erosion rate of accelerator
grid; compared with LIPS-200 life test data. The results of the
numerical model are in reasonable agreement with the measured data.
Finally, we predicted the lifetime of the 20cm diameter ion thruster via
the erosion data obtained with the model. The ultimate result
demonstrated that under normal operating condition, the erosion rate
of the grooves wears on the downstream surface of the accelerator grid
is 34.6μm⁄1000h, which means the conservative lifetime until
structural failure occurring on the accelerator grid is 11500 hours.
Abstract: Cadmium oxide (CdO) nanoparticles have been
prepared by chemical coprecipitation method. The synthesized
nanoparticles were characterized by X-ray diffraction analysis
(XRD), scanning electron microscopy (SEM), transmission electron
microscopy (TEM), UV analysis, and dielectric studies. The
crystalline nature and particle size of the CdO nanoparticles were
characterized by Powder X-ray diffraction analysis (XRD). The
morphology of prepared CdO nanoparticles was studied by scanning
electron microscopy. The particle size was studied using the
transmission electron microscopy (TEM).The optical properties were
obtained from UV-Vis absorption spectrum. The dielectric properties
of CdO nanoparticles were studied in the frequency range of 50 Hz–5
MHz at different temperatures. The frequency dependence of the
dielectric constant and dielectric loss is found to decrease with an
increase in the frequency at different temperatures. The ac
conductivity of CdO nanoparticle has been studied.
Abstract: Highly stable and homogeneously dispersed amino
acid coated silver nanoparticles (ANP) of ≈ 10 nm diameter, ranging
from 420 to 430 nm are prepared on AgNO3 solution addition to gum
of Azadirachta indica solution at 373.15 K. The amino acids were
selected based on their polarity. The synthesized nanoparticles were
characterized by UV-Vis, FTIR spectroscopy, HR-TEM, XRD, SEM
and 1H-NMR. The coated nanoparticles were used as catalyst for the
reduction of methylene blue dye in presence of Sn(II) in aqueous,
anionic and cationic micellar media. The rate of reduction of dye was
determined by measuring the absorbance at 660 nm,
spectrophotometrically and followed the order: Kcationic > Kanionic >
Kwater. After 12 min and in absence of the ANP, only 2%, 3% and 6%
of the dye reduction was completed in aqueous, anionic and cationic
micellar media respectively while, in presence of ANP coated by
polar neutral amino acid with non-polar -R group, the reduction
completed to 84%, 95% and 98% respectively. The ANP coated with
polar neutral amino acid having non-polar -R group, increased the
rate of reduction of the dye by 94, 3205 and 6370 folds in aqueous,
anionic and cationic micellar media respectively. Also, the rate of
reduction of the dye increased by three folds when the micellar media
was changed from anionic to cationic when the ANP is coated by a
polar neutral amino acid having a non-polar -R group.
Abstract: Hydrogen produced by means of polymer electrolyte
membrane electrolyzer (PEME) is one of the most promising
methods due to clean and renewable energy source. In the process,
some energy loss due to mass transfer through a PEM is caused by
diffusion, electro-osmotic drag, and the pressure difference between
the cathode channel and anode channel. In PEME, water molecules
and ionic particles transferred between the electrodes from anode to
cathode, Extensive mixing of the hydrogen and oxygen at anode
channel due to gases cross-over must be avoided. In recent times the
consciousness of safety issue in high pressure PEME where the
oxygen mix with hydrogen at anode channel could create, explosive
conditions have generated a lot of concern. In this paper, the steady
state and simulation analysis of gases crossover in PEME on the
temperature and pressure effect are presented. The simulations have
been analysis in MATLAB based on the well-known Fick’s Law of
molecular diffusion. The simulation results indicated that as
temperature increases, there is a significant decrease in operating
voltage.
Abstract: This paper aimed to introduce the solution of concrete
slump recovery using chemical admixture type-F (superplasticizer,
naphthalene base) to the practice in order to solve unusable concrete
problem due to concrete loss its slump, especially for those tropical
countries that have faster slump loss rate. In the other hand, randomly
adding superplasticizer into concrete can cause concrete to segregate.
Therefore, this paper also develops the estimation model used to
calculate amount of second dose of superplasticizer need for concrete
slump recovery. Fresh properties of ordinary Portland cement
concrete with volumetric ratio of paste to void between aggregate
(paste content) of 1.1-1.3 with water-cement ratio zone of 0.30 to
0.67 and initial superplasticizer (naphthalene base) of 0.25%-1.6%
were tested for initial slump and slump loss for every 30 minutes for
one and half hour by slump cone test. Those concretes with slump
loss range from 10% to 90% were re-dosed and successfully
recovered back to its initial slump. Slump after re-dosed was tested
by slump cone test. From the result, it has been concluded that, slump
loss was slower for those mix with high initial dose of
superplasticizer due to addition of superplasticizer will disturb
cement hydration. The required second dose of superplasticizer was
affected by two major parameters, which were water-cement ratio
and paste content, where lower water-cement ratio and paste content
cause an increase in require second dose of superplasticizer. The
amount of second dose of superplasticizer is higher as the solid
content within the system is increase, solid can be either from cement
particles or aggregate. The data was analyzed to form an equation use
to estimate the amount of second dosage requirement of
superplasticizer to recovery slump to its original.
Abstract: The main purpose of this study is to assess the
sediment quality and potential ecological risk in marine sediments in
Gymea Bay located in south Sydney, Australia. A total of 32 surface
sediment samples were collected from the bay. Current track
trajectories and velocities have also been measured in the bay. The
resultant trace elements were compared with the adverse biological
effect values Effect Range Low (ERL) and Effect Range Median
(ERM) classifications. The results indicate that the average values of
chromium, arsenic, copper, zinc, and lead in surface sediments all
reveal low pollution levels and are below ERL and ERM values. The
highest concentrations of trace elements were found close to
discharge points and in the inner bay, and were linked with high
percentages of clay minerals, pyrite and organic matter, which can
play a significant role in trapping and accumulating these elements.
The lowest concentrations of trace elements were found to be on the
shoreline of the bay, which contained high percentages of sand
fractions. It is postulated that the fine particles and trace elements are
disturbed by currents and tides, then transported and deposited in
deeper areas. The current track velocities recorded in Gymea Bay had
the capability to transport fine particles and trace element pollution
within the bay. As a result, hydrodynamic measurements were able to
provide useful information and to help explain the distribution of
sedimentary particles and geochemical properties. This may lead to
knowledge transfer to other bay systems, including those in remote
areas. These activities can be conducted at a low cost, and are
therefore also transferrable to developing countries. The advent of
portable instruments to measure trace elements in the field has also
contributed to the development of these lower cost and easily applied
methodologies available for use in remote locations and low-cost
economies.
Abstract: This study evaluated the acute toxicity and tissue
distribution of intravenously administered gold nanoparticles
(AuNPs) in male rabbits. Rabbits were exposed to single dose of
AuNPs (300 μg/ kg). Toxic effects were assessed via general
behavior, hematological parameters, serum biochemical parameters,
and histopathological examination of various rabbits’ organs.
Inductively coupled plasma–mass spectrometry (ICP-MS) was used
to determine gold concentrations in tissue samples collected at
predetermined time intervals. After one week, AuNPs exerted no
obvious acute toxicity in rabbits. However, inflammatory reactions
were observed in liver, lungs and kidneys accompanied with mild
absolute neutrophilia and significant monocytosis. The highest gold
levels were found in the spleen and liver followed by lungs, and
kidneys. These results indicated that AuNPs could be distributed
extensively to various tissues in the body, but primarily in the spleen
and liver.
Abstract: The modelling of physical phenomena, such as the
earth’s free oscillations, the vibration of strings, the interaction of
atomic particles, or the steady state flow in a bar give rise to Sturm-
Liouville (SL) eigenvalue problems. The boundary applications of
some systems like the convection-diffusion equation, electromagnetic
and heat transfer problems requires the combination of Dirichlet and
Neumann boundary conditions. Hence, the incorporation of Robin
boundary condition in the analyses of Sturm-Liouville problem. This
paper deals with the computation of the eigenvalues and
eigenfunction of generalized Sturm-Liouville problems with Robin
boundary condition using the finite element method. Numerical
solution of classical Sturm–Liouville problem is presented. The
results show an agreement with the exact solution. High results
precision is achieved with higher number of elements.
Abstract: This research work presents the surface
thermodynamics approach to M-TB/HIV-Human sputum
interactions. This involved the use of the Hamaker coefficient
concept as a surface energetics tool in determining the interaction
processes, with the surface interfacial energies explained using van
der Waals concept of particle interactions. The Lifshitz derivation for
van der Waals forces was applied as an alternative to the contact
angle approach which has been widely used in other biological
systems. The methodology involved taking sputum samples from
twenty infected persons and from twenty uninfected persons for
absorbance measurement using a digital Ultraviolet visible
Spectrophotometer. The variables required for the computations with
the Lifshitz formula were derived from the absorbance data. The
Matlab software tools were used in the mathematical analysis of the
data produced from the experiments (absorbance values). The
Hamaker constants and the combined Hamaker coefficients were
obtained using the values of the dielectric constant together with the
Lifshitz Equation. The absolute combined Hamaker coefficients
A132abs and A131abs on both infected and uninfected sputum samples
gave the values of A132abs = 0.21631x10-21Joule for M-TB infected
sputum and Ã132abs = 0.18825x10-21Joule for M-TB/HIV infected
sputum. The significance of this result is the positive value of the
absolute combined Hamaker coefficient which suggests the existence
of net positive van der waals forces demonstrating an attraction
between the bacteria and the macrophage. This however, implies that
infection can occur. It was also shown that in the presence of HIV,
the interaction energy is reduced by 13% conforming adverse effects
observed in HIV patients suffering from tuberculosis.
Abstract: Rotary entrainment is a phenomenon in which the
interface of two immiscible fluids are subjected to external flux by
means of rotation. Present work reports the experimental study on
rotary motion of a horizontal cylinder between the interface of air and
water to observe the penetration of gas inside the liquid. Experiments
have been performed to establish entrainment of air mass in water
alongside the cylindrical surface. The movement of tracer and seeded
particles has been tracked to calculate the speed and path of the
entrained air inside water. Simplified particle image velocimetry
technique has been used to trace the movement of particles/tracers at
the moment they are injected inside the entrainment zone and
suspended beads have been used to replicate the particle movement
with respect to time in order to determine the flow dynamics of the
fluid along the cylinder. Present paper establishes a thorough experimental analysis of the
rotary entrainment phenomenon between air and water keeping in
interest the extent to which we can intermix the two and also to study
its entrainment trajectories.
Abstract: Unsteady flow and heat transfer from a circular
cylinder in cross-flow is studied numerically. The governing
equations are solved by using finite volume method. Reynolds
number varies in range of 50 to 200; in this range flow is considered
to be laminar and unsteady. Al2O3 nanoparticle with volume fraction
in range of 5% to 20% is added to pure water. Effects of adding
nanoparticle to pure water on lift and drag coefficient and Nusselt
number is presented. Addition of Al2O3 has inconsiderable effect on
the value of drags and lift coefficient. However, it has significant
effect on heat transfer; results show that heat transfer of Al2O3
nanofluid is about 9% to 36% higher than pure water.
Abstract: This paper describes the development of a DNA-based
nanobiosensor to detect the dengue virus in mosquito using
electrically active magnetic (EAM) nanoparticles as concentrator and
electrochemical transducer. The biosensor detection encompasses
two sets of oligonucleotide probes that are specific to the dengue
virus: the detector probe labeled with the EAM nanoparticles and the
biotinylated capture probe. The DNA targets are double hybridized to
the detector and the capture probes and concentrated from
nonspecific DNA fragments by applying a magnetic field.
Subsequently, the DNA sandwiched targets (EAM-detector probe–
DNA target–capture probe-biotin) are captured on streptavidin
modified screen printed carbon electrodes through the biotinylated
capture probes. Detection is achieved electrochemically by measuring
the oxidation–reduction signal of the EAM nanoparticles. Results
indicate that the biosensor is able to detect the redox signal of the
EAM nanoparticles at dengue DNA concentrations as low as 10
ng/μl.
Abstract: Diets high in processed foods have been found to lack
essential micro-nutrients for optimum human development and
overall health. Some micro-nutrients such as copper (Cu) have been
found to enhance the inflammatory response through its oxidative
functions, thereby having a role in cardiovascular disease, metabolic
syndrome, diabetes and related complications. This research study
was designed to determine if food crops could be bio-fortified with
micro-nutrients by growing sprouts on mineral fortified fiber mats. In
the feasibility study described in this contribution, recycled cellulose
fibers and clay, saturated with either micro-nutrient copper ions or
copper nanoparticles, were converted to a novel mineral-cellulose
fiber carrier of essential micro-nutrient and of antimicrobial
properties. Seeds of Medicago sativa (alfalfa), purchased from a
commercial, organic supplier were germinated on engineered
cellulose fiber mats. After the appearance of the first leaves, the
sprouts were dehydrated and analyzed for Cu content. Nutrient
analysis showed ~2 increase in Cu of the sprouts grown on the fiber
mats with copper particles, and ~4 increase on mats with ionic copper
as compared to the control samples. This study illustrates the
potential for the use of engineered mats as a viable way to increase
the micro-nutrient composition of locally-grown food crops and the
need for additional research to determine the uptake, nutritional
implications and risks of micro-nutrient bio-fortification.
Abstract: Recovering resources from water purification sludge
(WPS) have been gradually stipulated in environmental protection
laws and regulations in many nations. Hence, reusing the WPS is
becoming an important topic, and recovering alum from WPS is one of
the many practical alternatives. Most previous research efforts have
been conducted on studying the amphoteric characteristic of aluminum
hydroxide for investigating the optimum pH range to dissolve the
Al(III) species from WPS, but it has been lack of reaction kinetics or
mechanisms related discussion. Therefore, in this investigation, water
purification sludge (WPS) solution was broken by ultrasound to make
particle size of reactants smaller, specific surface area larger.
According to the reaction kinetics, these phenomena let the dissolved
aluminum salt quantity increased and the reaction rate go faster.
Abstract: The laser-ultrasonic method is realized for
quantifying the influence of porosity on the local Young’s
modulus of isotropic composite materials. The method is based on
a laser thermooptical method of ultrasound generation combined
with measurement of the phase velocity of longitudinal and shear
acoustic waves in samples. The main advantage of this method
compared with traditional ultrasonic research methods is the
efficient generation of short and powerful probing acoustic pulses
required for reliable testing of ultrasound absorbing and
scattering heterogeneous materials. Using as an example samples
of a metal matrix composite with reinforcing microparticles of
silicon carbide in various concentrations, it is shown that to
provide an effective increase in Young’s modulus with increasing
concentration of microparticles, the porosity of the final sample
should not exceed 2%.
Abstract: This study presents experimental and optimization of
nanoparticle mass concentration and heat input based on the total
thermal resistance (Rth) of loop heat pipe (LHP), employed for PCCPU
cooling. In this study, silica nanoparticles (SiO2) in water with
particle mass concentration ranged from 0% (pure water) to 1% is
considered as the working fluid within the LHP. The experimental
design and optimization is accomplished by the design of
experimental tool, Response Surface Methodology (RSM). The
results show that the nanoparticle mass concentration and the heat
input have significant effect on the Rth of LHP. For a given heat
input, the Rth is found to decrease with the increase of the
nanoparticle mass concentration up to 0.5% and increased thereafter.
It is also found that the Rth is decreased when the heat input is
increased from 20W to 60W. The results are optimized with the
objective of minimizing the Rth, using Design-Expert software, and
the optimized nanoparticle mass concentration and heat input are
0.48% and 59.97W, respectively, the minimum thermal resistance
being 2.66 (ºC/W).