Abstract: Hair is a non homogenous complex material which
can be associated with a polymer. It is made up 95% of Keratin.
Hair has a great social significance for human beings. In the High
Middle Ages, for example, long hairs have been reserved for kings
and nobles.
Most common interest in hair is focused on hair growth, hair types
and hair care, but hair is also an important biomaterial which can
vary depending on ethnic origin or on age, hair colour for example
can be a sign of ethnic ancestry or age (dark hair for Asiatic, blond
hair for Caucasian and white hair for old people in general).
In this context, different approaches have been conducted to
determine the differences in mechanical properties and characterize
the fracture topography at the surface of hair depending on its type
and its age.
A tensile testing machine was especially designed to achieve
tensile tests on hair. This device is composed of a microdisplacement
system and a force sensor whose peak load is limited to
3N. The curves and the values extracted from each experiment, allow
us to compare the evolution of the mechanical properties from one
hair to another.
Observations with a Scanning Electron Microscope (SEM) and
with an interferometer were made on different hairs. Thus, it is
possible to access the cuticle state and the fracture topography for
each category.
Abstract: In our recent study, we have used ZnO nanoparticles assisted with UV light irradiation to investigate the photocatalytic degradation of Phenol Red (PR). The ZnO photocatalyst was characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), specific surface area analysis (BET) and UVvisible spectroscopy. X-ray diffractometry result for the ZnO nanoparticles exhibit normal crystalline phase features. All observed peaks can be indexed to the pure hexagonal wurtzite crystal structures, with the space group of P63mc. There are no other impurities in the diffraction peak. In addition, TEM measurement shows that most of the nanoparticles are rod-like and spherical in shape and fairly monodispersed. A significant degradation of the PR was observed when the catalyst was added into the solution even without the UV light exposure. In addition, the photodegradation increases with the photocatalyst loading. The surface area of the ZnO nanomaterials from the BET measurement was 11.9 m2/g. Besides the photocatalyst loading, the effect of some parameters on the photodegradation efficiency such as initial PR concentration and pH were also studied.
Abstract: Wet chemistry methods are used to prepare the
SiO2/Au nanoshells. The purpose of this research was to synthesize
gold coated SiO2 nanoshells for biomedical applications. Tunable
nanoshells were prepared by using different colloidal concentrations.
The nanoshells are characterized by FTIR, XRD, UV-Vis
spectroscopy and atomic force microscopy (AFM). The FTIR results
confirmed the functionalization of the surfaces of silica nanoparticles
with NH2 terminal groups. A tunable absorption was observed
between 470-600 nm with a maximum range of 530-560 nm. Based
on the XRD results three main peaks of Au (111), (200) and (220)
were identified. Also AFM results showed that the silica core
diameter was about 100 nm and the thickness of gold shell about 10
nm.
Abstract: Requirements that should be met when determining the regimes of circuits with variable elements are formulated. The interpretation of the variations in the regimes, based on projective geometry, enables adequate expressions for determining and comparing the regimes to be derived. It is proposed to use as the parameters of a generalized equivalent generator of an active two-pole with changeable resistor such load current and voltage which provide the current through this resistor equal to zero.
Abstract: A measurement system for pH array sensors is
introduced to increase accuracy, and decrease non-ideal effects
successfully. An array readout circuit reads eight potentiometric
signals at the same time, and obtains an average value. The deviation
value or the extreme value is counteracted and the output voltage is a
relatively stable value. The errors of measuring pH buffer solutions are
decreased obviously with this measurement system, and the non-ideal
effects, drift and hysteresis, are lowered to 1.638mV/hr and 1.118mV,
respectively. The efficiency and stability are better than single sensor.
The whole sensing characteristics are improved.
Abstract: In this paper, the construction of a detailed spine
model is presented using the LifeMOD Biomechanics Modeler. The
detailed spine model is obtained by refining spine segments in
cervical, thoracic and lumbar regions into individual vertebra
segments, using bushing elements representing the intervertebral
discs, and building various ligamentous soft tissues between
vertebrae. In the sagittal plane of the spine, constant force will be
applied from the posterior to anterior during simulation to determine
dynamic characteristics of the spine. The force magnitude is
gradually increased in subsequent simulations. Based on these
recorded dynamic properties, graphs of displacement-force
relationships will be established in terms of polynomial functions by
using the least-squares method and imported into a haptic integrated
graphic environment. A thoracolumbar spine model with complex
geometry of vertebrae, which is digitized from a resin spine
prototype, will be utilized in this environment. By using the haptic
technique, surgeons can touch as well as apply forces to the spine
model through haptic devices to observe the locomotion of the spine
which is computed from the displacement-force relationship graphs.
This current study provides a preliminary picture of our ongoing
work towards building and simulating bio-fidelity scoliotic spine
models in a haptic integrated graphic environment whose dynamic
properties are obtained from LifeMOD. These models can be helpful
for surgeons to examine kinematic behaviors of scoliotic spines and
to propose possible surgical plans before spine correction operations.
Abstract: Absorptive characteristics of polyaniline synthesized
in mixture of water and acetonitrile in 50/50 volume ratio was
studied. Synthesized polyaniline in powder shape is used as an
adsorbent to remove toxic hexavalent chromium from aqueous
solutions. Experiments were conducted in batch mode with different
variables such as agitation time, solution pH and initial concentration
of hexavalent chromium. Removal mechanism is the combination of
surface adsorption and reduction. The equilibrium time for removal
of Cr(T) and Cr(VI) was about 2 and 10 minutes respectively. The
optimum pH for total chromium removal occurred at pH 7 and
maximum hexavalent chromium removal took place under acidic
condition at pH 3. Investigating the isothermal characteristics showed
that the equilibrium adsorption data fitted both Freundlich-s and
Langmuir-s isotherms. The maximum adsorption of chromium was
calculated 36.1 mg/g for polyaniline
Abstract: The agriculture lignocellulosic by-products are receiving increased attention, namely in the search for filter materials that retain contaminants from water. These by-products, specifically almond and hazelnut shells are abundant in Portugal once almond and hazelnuts production is a local important activity. Hazelnut and almond shells have as main constituents lignin, cellulose and hemicelluloses, water soluble extractives and tannins. Along the adsorption of heavy metals from contaminated waters, water soluble compounds can leach from shells and have a negative impact in the environment. Usually, the chemical characterization of treated water by itself may not show environmental impact caused by the discharges when parameters obey to legal quality standards for water. Only biological systems can detect the toxic effects of the water constituents. Therefore, the evaluation of toxicity by biological tests is very important when deciding the suitability for safe water discharge or for irrigation applications.
The main purpose of the present work was to assess the potential impacts of waters after been treated for heavy metal removal by hazelnut and almond shells adsorption systems, with short term acute toxicity tests.
To conduct the study, water at pH 6 with 25 mg.L-1 of lead, was treated with 10 g of shell per litre of wastewater, for 24 hours. This procedure was followed for each bark. Afterwards the water was collected for toxicological assays; namely bacterial resistance, seed germination, Lemna minor L. test and plant grow. The effect in isolated bacteria strains was determined by disc diffusion method and the germination index of seed was evaluated using lettuce, with temperature and humidity germination control for 7 days. For aquatic higher organism, Lemnas were used with 4 days contact time with shell solutions, in controlled light and temperature. For terrestrial higher plants, biomass production was evaluated after 14 days of tomato germination had occurred in soil, with controlled humidity, light and temperature.
Toxicity tests of water treated with shells revealed in some extent effects in the tested organisms, with the test assays showing a close behaviour as the control, leading to the conclusion that its further utilization may not be considered to create a serious risk to the environment.
Abstract: Soft clays are defined as cohesive soil whose water
content is higher than its liquid limits. Thus, soil-cement mixing is
adopted to improve the ground conditions by enhancing the strength
and deformation characteristics of the soft clays. For the above
mentioned reasons, a series of laboratory tests were carried out to
study some fundamental mechanical properties of cement stabilized
soft clay. The test specimens were prepared by varying the portion of
ordinary Portland cement to the soft clay sample retrieved from the
test site of RECESS (Research Centre for Soft Soil). Comparisons
were made for both homogeneous and columnar system specimens
by relating the effects of cement stabilized clay of for 0, 5 and 10 %
cement and curing for 3, 28 and 56 days. The mechanical properties
examined included one-dimensional compressibility and undrained
shear strength. For the mechanical properties, both homogeneous and
columnar system specimens were prepared to examine the effect of
different cement contents and curing periods on the stabilized soil.
The one-dimensional compressibility test was conducted using an
oedometer, while a direct shear box was used for measuring the
undrained shear strength. The higher the value of cement content, the
greater is the enhancement of the yield stress and the decrease of
compression index. The value of cement content in a specimen is a
more active parameter than the curing period.
Abstract: Chitosan is an attractive polysaccharide obtained by
deacetylation of an abundant natural biopolymer called chitin. Chitin
and chitosan are excellent materials. To improve the potential of
chitin and chitosan modification is needed. In the present study,
grafting of maleic acid on to chitosan by cerium ammonium nitrate in
acetic acid solution was investigated with use of a microwave and
reflux system. The grafted chitosan was characterized by using a
Fourier-transform infrared spectrometry. The solubility and swelling
behavior of grafted chitosans were determined in acetate buffer (pH
3.6), citrophosphate buffer (pH 5.6 and pH 7.0), and boric buffer (pH
9.2) solutions. The sample obtained by microwave system with use of
a chitosan/maleic anhydride/ceric ammonium nitrate 0.2/3.922/0.99
gram of raw material within 30 minute showed the maximum
swelling ratio (13.6) in boric buffer solution.
Abstract: COPD is characterized by loss of elastic fibers from
small airways and alveolar walls, with the decrease in elastin
increasing with disease severity. It is unclear why there is a lack of
repair of elastic fibers. We have examined fibroblasts cultured from
lung tissue from normal and COPD subjects to determine if the
secretory profile explains lack of tissue repair. In this study,
fibroblasts were cultured from lung parenchyma of bronchial
carcinoma patients with varying degrees of COPD; controls
(non-COPD, n=5), mild COPD (GOLD 1, n=5) and moderate-severe
COPD (GOLD 2-3, n=12). Measurements were made of proliferation,
senescence-associated beta-galactosidase-1, mRNA expression of
IL-6, IL-8, MMP-1, tropoelastin and versican, and protein levels for
IL-6, IL-8, PGE2, tropoelastin, insoluble elastin, and versican. It was
found that GOLD 2-3 fibroblasts proliferated more slowly (p
Abstract: This paper presents a part of research on the
rheological properties of bitumen modified by thermoplastic namely
linear low density polyethylene (LLDPE), high density polyethylene
(HDPE) and polypropylene (PP) and its interaction with 80 pen base
bitumen. As it is known that the modification of bitumen by the use
of polymers enhances its performance characteristics but at the same
time significantly alters its rheological properties. The rheological
study of polymer modified bitumen (PMB) was made through
penetration, ring & ball softening point and viscosity test. The results
were then related to the changes in the rheological properties of
polymer modified bitumen. It was observed that thermoplastic
copolymer shows profound effect on penetration rather than
softening point. The viscoelastic behavior of polymer modified
bitumen depend on the concentration of polymer, mixing
temperature, mixing technique, solvating power of base bitumen and
molecular structure of polymer used. PP offer better blend in
comparison to HDPE and LLDPE. The viscosity of base bitumen was
also enhanced with the addition of polymer. The pseudoplastic
behavior was more prominent for HDPE and LLDPE than PP. Best
results were obtained when polymer concentration was kept below
3%
Abstract: In this paper, a predator-prey model with time delay and habitat complexity is investigated. By analyzing the characteristic equations, the local stability of each feasible equilibria of the system is discussed and the existence of a Hopf bifurcation at the coexistence equilibrium is established. By choosing the sum of two delays as a bifurcation parameter, we show that Hopf bifurcations can occur as crosses some critical values. By deriving the equation describing the flow on the center manifold, we can determine the direction of the Hopf bifurcations and the stability of the bifurcating periodic solutions. Numerical simulations are carried out to illustrate the main theoretical results.
Abstract: Abdominal aortic aneurysms rupture (AAAs) is one of the main causes of death in the world. This is a very complex phenomenon that usually occurs “without previous warning". Currently, criteria to assess the aneurysm rupture risk (peak diameter and growth rate) can not be considered as reliable indicators. In a first approach, the main geometric parameters of aneurysms have been linked into five biomechanical factors. These are combined to obtain a dimensionless rupture risk index, RI(t), which has been validated preliminarily with a clinical case and others from literature. This quantitative indicator is easy to understand, it allows estimating the aneurysms rupture risks and it is expected to be able to identify the one in aneurysm whose peak diameter is less than the threshold value. Based on initial results, a broader study has begun with twelve patients from the Clinic Hospital of Valladolid-Spain, which are submitted to periodic follow-up examinations.
Abstract: In the paper the results of calculations of the dynamic
response of a multi-storey reinforced concrete building to a strong
mining shock originated from the main region of mining activity in
Poland (i.e. the Legnica-Glogow Copper District) are presented. The
representative time histories of accelerations registered in three
directions were used as ground motion data in calculations of the
dynamic response of the structure. Two variants of a numerical model
were applied: the model including only structural elements of the
building and the model including both structural and non-structural
elements (i.e. partition walls and ventilation ducts made of brick). It
turned out that non-structural elements of multi-storey RC buildings
have a small impact of about 10 % on natural frequencies of these
structures. It was also proved that the dynamic response of building
to mining shock obtained in case of inclusion of all non-structural
elements in the numerical model is about 20 % smaller than in case
of consideration of structural elements only. The principal stresses
obtained in calculations of dynamic response of multi-storey building
to strong mining shock are situated on the level of about 30% of
values obtained from static analysis (dead load).
Abstract: Oxidative stress is considered to be the cause for onset
and the progression of type 2 diabetes mellitus (T2DM) and
complications including neuropathy. It is a deleterious process that
can be an important mediator of damage to cell structures: protein,
lipids and DNA. Data suggest that in patients with diabetes and
diabetic neuropathy DNA repair is impaired, which prevents effective
removal of lesions. Objective: The aim of our study was to evaluate
the association of the hOGG1 (326 Ser/Cys) and XRCC1 (194
Arg/Trp, 399 Arg/Gln) gene polymorphisms whose protein is
involved in the BER pathway with DNA repair efficiency in patients
with diabetes type 2 and diabetic neuropathy compared to the healthy
subjects. Genotypes were determined by PCR-RFLP analysis in 385
subjects, including 117 with type 2 diabetes, 56 with diabetic
neuropathy and 212 with normal glucose metabolism. The
polymorphisms studied include codon 326 of hOGG1 and 194, 399
of XRCC1 in the base excision repair (BER) genes. Comet assay was
carried out using peripheral blood lymphocytes from the patients and
controls. This test enabled the evaluation of DNA damage in cells
exposed to hydrogen peroxide alone and in the combination with the
endonuclease III (Nth). The results of the analysis of polymorphism
were statistically examination by calculating the odds ratio (OR) and
their 95% confidence intervals (95% CI) using the ¤ç2-tests. Our data
indicate that patients with diabetes mellitus type 2 (including those
with neuropathy) had higher frequencies of the XRCC1 399Arg/Gln
polymorphism in homozygote (GG) (OR: 1.85 [95% CI: 1.07-3.22],
P=0.3) and also increased frequency of 399Gln (G) allele (OR: 1.38
[95% CI: 1.03-1.83], P=0.3). No relation to other polymorphisms
with increased risk of diabetes or diabetic neuropathy. In T2DM
patients complicated by neuropathy, there was less efficient repair of
oxidative DNA damage induced by hydrogen peroxide in both the
presence and absence of the Nth enzyme. The results of our study
suggest that the XRCC1 399 Arg/Gln polymorphism is a significant
risk factor of T2DM in Polish population. Obtained data suggest a
decreased efficiency of DNA repair in cells from patients with
diabetes and neuropathy may be associated with oxidative stress.
Additionally, patients with neuropathy are characterized by even
greater sensitivity to oxidative damage than patients with diabetes,
which suggests participation of free radicals in the pathogenesis of
neuropathy.
Abstract: This study shows palynomorphological description of
pollen grains of Lamium garganicum, species of the family Labiatae.
Fresh material of this plant is taken in Mount Llogara, in Albania. By
comparison made between palinomorphological characteristics of
pollen grains of Lamium garganicum with those of Lamium
maculatum and Lamium purpureum, showed that granules have
similarities in the number of furrows. The pollen grains of Lamium
garganicum were larger in length and width than those of Lamium
maculatum and almost equal with those of Lamium purpureum.
Furrows are longer than those of pollen grains in Lamium maculatum
and shorter than those of Lamium purpureum. The layer of exine of
Lamium garganicum was thinner than that of two others. The
sculpture of exine was fine reticulate, where reticulas were uniform
whereas in Lamium purpureum was verrucate, with small verrucae; in
Lamium maculatum was reticulate.
Abstract: Cement, the most widely used construction material
is very brittle and characterized by low tensile strength and strain
capacity. Macro to nano fibers are added to cement to provide
tensile strength and ductility to it. Carbon Nanotube (CNT), one of
the nanofibers, has proven to be a promising reinforcing material in
the cement composites because of its outstanding mechanical
properties and its ability to close cracks at the nano level. The
experimental investigations for CNT reinforced cement is costly,
time consuming and involves huge number of trials. Mathematical
modeling of CNT reinforced cement can be done effectively and
efficiently to arrive at the mechanical properties and to reduce the
number of trials in the experiments. Hence, an attempt is made to
numerically study the effective mechanical properties of CNT
reinforced cement numerically using Representative Volume
Element (RVE) method. The enhancement in its mechanical
properties for different percentage of CNTs is studied in detail.
Abstract: Restoration research has become important on principle recently in Czech Republic. The reason is simple. More than 70 % of mined brown coal comes from the North Bohemian Basin these days. Open cast brown coal mining has lead to large damage on the landscape. Reclamation of phytotoxic areas is one of the serious problems in the North Bohemian Basin. It mainly concerns the areas with the occurrence of overburden rocks from the coal bed enriched with coal. The presented paper includes the characteristics of the important phytotoxic areas and the methodology of their reclamation. The results are documented with the long term monitoring of physical, mineralogical, chemical and pedological parameters of rocks in the testing areas.
Abstract: In the present work, study of the vibration of thin cylindrical shells made of a functionally gradient material (FGM) composed of stainless steel and nickel is presented. Material properties are graded in the thickness direction of the shell according to volume fraction power law distribution. The objective is to study the natural frequencies, the influence of constituent volume fractions and the effects of boundary conditions on the natural frequencies of the FG cylindrical shell. The study is carried out using third order shear deformation shell theory. The analysis is carried out using Hamilton's principle. The governing equations of motion of FG cylindrical shells are derived based on shear deformation theory. Results are presented on the frequency characteristics, influence of constituent volume fractions and the effects of clamped-free boundary conditions