Abstract: We successfully developed and tested a new
separation layer solving problems with unmanageable deposits inside the boilers of Zluticka Heating Plant. The deposits are mainly created
by glass-forming melts. We plotted straw ash compositions in K2OCaO-
SiO2 phase diagram and illustrated that they are in the area of low-melting eutectic points. To prevent the melting of ash and the
formation of deposits, we modified ash compositions by injecting additives into biomass fuel, and thus effectively suppressed deposits in a burner.
Abstract: Effect of temperature and light was investigated on a
thin film of organic semiconductor formyl-TIPPCu(II) deposited on a
glass substrate with preliminary evaporated gold electrodes. The
electrical capacitance and resistance of the fabricated device were
evaluated under the effect of temperature and light. The relative
capacitance of the fabricated sensor increased by 4.3 times by rising
temperature from 27 to 1870C, while under illumination up to 25000
lx, the capacitance of the Au/formyl-TIPPCu(II)/Au photo capacitive
sensor increased continuously by 13.2 times as compared to dark
conditions.
Abstract: Membrane distillation (MD) is a rising technology for
seawater or brine desalination process. In this work, an air gap
membrane distillation (AGMD) performance was investigated for
aqueous NaCl solution along with natural ground water and seawater.
In order to enhance the performance of the AGMD process in
desalination, that is, to get more flux, it is necessary to study the
effect of operating parameters on the yield of distillate water. The
influence of operational parameters such as feed flow rate, feed
temperature, feed salt concentration, coolant temperature and air gap
thickness on the membrane distillation (MD) permeation flux have
been investigated for low and high salt solution. the natural
application of ground water and seawater over 90 h continuous
operation, scale deposits observed on the membrane surface and
reduction in flux represents 23% for ground water and 60% for
seawater, in 90 h. This reduction was eliminated (less than 14 %) by
acidification of feed water. Hence, promote the research attention in
apply of AGMD for the ground water as well as seawater
desalination over today-s conventional RO operation.
Abstract: A facile vapour deposition method of synthesis of vertically aligned ZnO nanowires on carbon seed layer was developed. The received samples were investigated on electronic microscope JSM-6490 LA JEOL and x-ray diffractometer X, pert MPD PRO. The photoluminescence spectra (PL) of obtained ZnO samples at a room temperature were studied using He-Cd laser (325 nm line) as excitation source.
Abstract: Technology of thin film deposition is of interest in
many engineering fields, from electronic manufacturing to corrosion
protective coating. A typical deposition process, like that developed
at the University of Eindhoven, considers the deposition of a thin,
amorphous film of C:H or of Si:H on the substrate, using the
Expanding Thermal arc Plasma technique. In this paper a computing
procedure is proposed to simulate the flow field in a deposition
chamber similar to that at the University of Eindhoven and a
sensitivity analysis is carried out in terms of: precursor mass flow
rate, electrical power, supplied to the torch and fluid-dynamic
characteristics of the plasma jet, using different nozzles. To this
purpose a deposition chamber similar in shape, dimensions and
operating parameters to the above mentioned chamber is considered.
Furthermore, a method is proposed for a very preliminary evaluation
of the film thickness distribution on the substrate. The computing
procedure relies on two codes working in tandem; the output from
the first code is the input to the second one. The first code simulates
the flow field in the torch, where Argon is ionized according to the
Saha-s equation, and in the nozzle. The second code simulates the
flow field in the chamber. Due to high rarefaction level, this is a
(commercial) Direct Simulation Monte Carlo code. Gas is a mixture
of 21 chemical species and 24 chemical reactions from Argon plasma
and Acetylene are implemented in both codes. The effects of the
above mentioned operating parameters are evaluated and discussed
by 2-D maps and profiles of some important thermo-fluid-dynamic
parameters, as per Mach number, velocity and temperature. Intensity,
position and extension of the shock wave are evaluated and the
influence of the above mentioned test conditions on the film
thickness and uniformity of distribution are also evaluated.
Abstract: Air quality in Setapak district of Kuala Lumpur was
studied by analysing the rainwater chemical composition using ion
chromatography method. Twelve sampling sites were selected and
120 rainwater samples were collected in the period of 10 weeks. The
results of this study were compared to the earlier published data and
the evaluation showed that the NO3
- ion concentration increased from
0.41 to 3.32 ppm, while SO4
2- ion concentration increased from 0.39
to 3.26 ppm over the past two decades that is mostly due to rapid
urban development of the city. However, it was found that the
chemical composition for both residential and industrial areas does
not have significant difference. Most of the rainwater samples
showed alkaline pH (pH > 5.6). The possible factors for such alkaline
pH in rainwater samples are assumed to be the marine sources,
biomass burning and alkaline character of soil particles.
Abstract: The heavy metal contamination of the technogenous
sediments and soils at the investigated dump-field show irregular
planar distribution. Also the heavy metal content in the surface water,
drainage water and in the groundwater was studied both in the dry as
well as during the rainy periods. The cementation process causes
substitution of iron by copper. Natural installation and development
of plant species was observed at the old mine waste dumps, specific
to the local chemical conditions such as low content of essential
nutrients and high content of heavy metals. The individual parts of
the plant tissues (roots, branches/stems, leaves/needles, flowers/
fruits) are contaminated by heavy metals and tissues are damaged
differently, respectively.
Abstract: ZnO nanostructures including nanowires, nanorods,
and nanoneedles were successfully deposited on GaAs substrates,
respectively, by simple two-step chemical method for the first time. A
ZnO seed layer was firstly pre-coated on the O2-plasma treated
substrate by sol-gel process, followed by the nucleation of ZnO
nanostructures through hydrothermal synthesis. Nanostructures with
different average diameter (15-250 nm), length (0.9-1.8 μm), density
(0.9-16×109 cm-2) were obtained via adjusting the growth time and
concentration of precursors. From the reflectivity spectra, we
concluded ordered and taper nanostructures were preferential for
photovoltaic applications. ZnO nanoneedles with an average diameter
of 106 nm, a moderate length of 2.4 μm, and the density of 7.2×109
cm-2 could be synthesized in the concentration of 0.04 M for 18 h.
Integrated with the nanoneedle array, the power conversion efficiency
of single junction solar cell was increased from 7.3 to 12.2%,
corresponding to a 67% improvement.
Abstract: This paper presents a spectroscopic study on doping
of Vanadyl pathalocyanine (VOPc) by [6,6]-phenyl C61 butyric acid
methyl ester (PCBM). The films are characterized by UV/Vis/NIR
spectroscopy. A drastic increase in the absorption coefficient has
been observed with increasing dopant concentration. Optical
properties of VOPc:PCBM films deposited by spin coating technique
were studied in detail. Optical band gap decreased with the PCBM
incorporation in the VOPc film. Optical band gap calculated from the
absorption spectra decreased from 3.32 eV to 3.26 eV with a
variation of 0–75 % of PCBM concentration in the VOPC films.
Abstract: The study of the fouling deposition of pink guava
juice (PGJ) is relatively new research compared to milk fouling
deposit. In this work, a new experimental set-up was developed to
imitate the fouling formation in heat exchanger, namely a continuous
flow experimental set-up heat exchanger. The new experimental setup
was operated under industrial pasteurization temperature of PGJ,
which was at 93°C. While the flow rate and pasteurization period
were based on the experimental capacity, which were 0.5 and 1
liter/min for the flow rate and the pasteurization period was set for 1
hour. Characterization of the fouling deposit was determined by
using various methods. Microstructure of the deposits was carried
out using ESEM. Proximate analyses were performed to determine
the composition of moisture, fat, protein, fiber, ash and carbohydrate
content. A study on the hardness and stickiness of the fouling deposit
was done using a texture analyzer. The presence of seedstone in pink
guava juice was also analyzed using a particle analyzer. The findings
shown that seedstone from pink guava juice ranging from 168 to
200μm and carbohydrate was found to be a major composition
(47.7% of fouling deposit consists of carbohydrate). Comparison
between the hardness and stickiness of the deposits at two different
flow rates showed that fouling deposits were harder and denser at
higher flow rate. Findings from this work provide basis knowledge
for further study on fouling and cleaning of PGJ.
Abstract: In the present investigation, H13 tool steel has been
deposited on copper alloy substrate using both CO2 and diode laser.
A detailed parametric analysis has been carried out in order to find
out optimum processing zone for coating defect free H13 tool steel
on copper alloy substrate. Followed by parametric optimization, the
microstructure and microhardness of the deposited clads have been
evaluated. SEM micrographs revealed dendritic microstructure in
both clads. However, the microhardness of CO2 laser deposited clad
was much higher compared to diode laser deposited clad.
Abstract: The photocatalytic activity efficiency of TiO2 for the degradation of Toluene in photoreactor can be enhanced by nano- TiO2/LDPE composite film. Since the amount of TiO2 affected the efficiency of the photocatalytic activity, this work was mainly concentrated on the effort to embed the high amount of TiO2 in the Polyethylene matrix. The developed photocatalyst was characterized by XRD, UV-Vis spectrophotometer and SEM. The SEM images revealed the high homogeneity of the deposition of TiO2 on the polyethylene matrix. The XRD patterns interpreted that TiO2 embedded in the PE matrix exhibited mainly in anatase form. In addition, the photocatalytic results show that the toluene removal efficiencies of 30±5%, 49±4%, 68±5%, 42±6% and 33±5% were obtained when using the catalyst loading at 0%, 10%, 15%, 25% and 50% (wt. cat./wt. film), respectively.
Abstract: In this paper we present discretization and decomposition methods for a multi-component transport model of a chemical vapor deposition (CVD) process. CVD processes are used to manufacture deposition layers or bulk materials. In our transport model we simulate the deposition of thin layers. The microscopic model is based on the heavy particles, which are derived by approximately solving a linearized multicomponent Boltzmann equation. For the drift-process of the particles we propose diffusionreaction equations as well as for the effects of heat conduction. We concentrate on solving the diffusion-reaction equation with analytical and numerical methods. For the chemical processes, modelled with reaction equations, we propose decomposition methods and decouple the multi-component models to simpler systems of differential equations. In the numerical experiments we present the computational results of our proposed models.
Abstract: We succeeded to produce a high performance and flexible graphene/Manganese dioxide (G/MnO2) electrode coated on flexible polyethylene terephthalate (PET) substrate. The graphene film is initially synthesized by drop-casting the graphene oxide (GO) solution on the PET substrate, followed by simultaneous reduction and patterning of the dried film using carbon dioxide (CO2) laser beam with power of 1.8 W. Potentiostatic Anodic Deposition method was used to deposit thin film of MnO2 with different loading mass 10 – 50 and 100 μg.cm-2 on the pre-prepared graphene film. The electrodes were fully characterized in terms of structure, morphology, and electrochemical performance. A maximum specific capacitance of 973 F.g-1 was attributed when depositing 50μg.cm-2 MnO2 on the laser reduced graphene oxide rGO (or G/50MnO2) and over 92% of its initial capacitance was retained after 1000 cycles. The good electrochemical performance and long-term cycling stability make our proposed approach a promising candidate in the supercapacitor applications.
Abstract: The importance for manipulating an incorporated
scaffold and directing cell behaviors is well appreciated for tissue
engineering. Here, we developed newly nano-topographic oxidized
silicon nanosponges capable of being various chemical modifications
to provide much insight into the fundamental biology of how cells
interact with their surrounding environment in vitro. A wet etching
technique is exerted to allow us fabricated the silicon nanosponges in a
high-throughput manner. Furthermore, various organo-silane
chemicals enabled self-assembled on the surfaces by vapor deposition.
We have found that Chinese hamster ovary (CHO) cells displayed
certain distinguishable morphogenesis, adherent responses, and
biochemical properties while cultured on these chemical modified
nano-topographic structures in compared with the planar oxidized
silicon counterparts, indicating that cell behaviors can be influenced
by certain physical characteristic derived from nano-topography in
addition to the hydrophobicity of contact surfaces crucial for cell
adhesion and spreading. Of particular, there were predominant
nano-actin punches and slender protrusions formed while cells were
cultured on the nano-topographic structures. This study shed potential
applications of these nano-topographic biomaterials for controlling
cell development in tissue engineering or basic cell biology research.
Abstract: The paper describes the carbonate microfacies identified in the Sinjar Formation (Late Paleocene–Early Eocene) cropping out in Qara Dagh Mountain, near Sulekan Village approximately 20km south–west of Sulaimani (Iraq). One section (62m thick) has been measured in the field and closely sampled to undertake detailed microfaciesal and micropalaeontological studies to determine the formation-s age and environment of deposition. A samples were collected illustrating all the lithological changes along the section. The limestone in the studied area is hard and extremely rich in large foraminifers (soritids, rotaliids, nummulites, miliolids) and green algae (dasycladales). The investigation of the thin sections allowed us to identify the carbonate microfacies (18 types and subtypes) and the micropaleontological association (foraminifers and green algae), to determine the age of formation and to reconstruct the paleoenvironment of deposition (fore-reef, reef, back-reef). Based on the field observations and the studied thin sections, we determined three Units of a carbonate platform (I, II and III) from the base to the top of the section: Unit I with coralgal associations, Unit II is dominated by larger foraminifers and haracterized by the absence of coralgal associations, while Unit III is dominated by small foraminifers (mostly miliolids), peloids and green algae. It is partially dolomitized.
Abstract: Traditionally, wind tunnel models are made of metal
and are very expensive. In these years, everyone is looking for ways
to do more with less. Under the right test conditions, a rapid
prototype part could be tested in a wind tunnel. Using rapid prototype
manufacturing techniques and materials in this way significantly
reduces time and cost of production of wind tunnel models. This
study was done of fused deposition modeling (FDM) and their ability
to make components for wind tunnel models in a timely and cost
effective manner. This paper discusses the application of wind tunnel
model configuration constructed using FDM for transonic wind
tunnel testing. A study was undertaken comparing a rapid
prototyping model constructed of FDM Technologies using
polycarbonate to that of a standard machined steel model. Testing
covered the Mach range of Mach 0.3 to Mach 0.75 at an angle-ofattack
range of - 2° to +12°. Results from this study show relatively
good agreement between the two models and rapid prototyping
Method reduces time and cost of production of wind tunnel models.
It can be concluded from this study that wind tunnel models
constructed using rapid prototyping method and materials can be
used in wind tunnel testing for initial baseline aerodynamic database
development.
Abstract: The possibility of producing drinking water from
brackish ground water using Vacuum membrane distillation (VMD)
process was studied. It is a rising technology for seawater or brine
desalination process. The process simply consists of a flat sheet
hydrophobic micro porous PTFE membrane and diaphragm vacuum
pump without a condenser for the water recovery or trap. In this
work, VMD performance was investigated for aqueous NaCl solution
and natural ground water. The influence of operational parameters
such as feed flow rate (30 to 55 l/h), feed temperature (313 to 333 K),
feed salt concentration (5000 to 7000 mg/l) and permeate pressure
(1.5 to 6 kPa) on the membrane distillation (MD) permeation flux
have been investigated. The maximum flux reached to 28.34 kg/m2 h
at feed temperature, 333 K; vacuum pressure, 1.5 kPa; feed flow rate,
55 l/h and feed salt concentration, 7000 mg/l. The negligible effects
in the reduction of permeate flux found over 150 h experimental run
for salt water. But for the natural ground water application over 75 h,
scale deposits observed on the membrane surface and 29% reduction
in the permeate flux over 75 h. This reduction can be eliminated by
acidification of feed water. Hence, promote the research attention in
apply of VMD for the ground water purification over today-s
conventional RO operation.
Abstract: Carbon nanotubes (CNTs) with their high mechanical,
electrical, thermal and chemical properties are regarded as promising
materials for many different potential applications. Having unique
properties they can be used in a wide range of fields such as
electronic devices, electrodes, drug delivery systems, hydrogen
storage, textile etc. Catalytic chemical vapor deposition (CCVD) is a
common method for CNT production especially for mass production.
Catalysts impregnated on a suitable substrate are important for
production with chemical vapor deposition (CVD) method. Iron
catalyst and MgO substrate is one of most common catalyst-substrate
combination used for CNT. In this study, CNTs were produced by
CCVD of acetylene (C2H2) on magnesium oxide (MgO) powder
substrate impregnated by iron nitrate (Fe(NO3)3•9H2O) solution. The
CNT synthesis conditions were as follows: at synthesis temperatures
of 500 and 800°C multiwall and single wall CNTs were produced
respectively. Iron (Fe) catalysts were prepared by with Fe:MgO ratio
of 1:100, 5:100 and 10:100. The duration of syntheses were 30 and
60 minutes for all temperatures and catalyst percentages. The
synthesized materials were characterized by thermal gravimetric
analysis (TGA), transmission electron microscopy (TEM) and Raman
spectroscopy.
Abstract: Intermetallic Ni3Al – based alloys belong to a group
of advanced materials characterized by good chemical and physical
properties (such as structural stability, corrosion resistance) which
offer advenced technological applications. The paper presents the
study of catalytic properties of Ni3Al foils (thickness approximately
50 &m) in the methanol and hexane decomposition. The egzamined
material posses microcrystalline structure without any additional
catalysts on the surface. The better catalytic activity of Ni3Al foils
with respect to quartz plates in both methanol and hexane
decomposition was confirmed. On thin Ni3Al foils the methanol
conversion reaches approximately 100% above 480 oC while the
hexane conversion reaches approximately 100% (98,5%) at 500 oC.
Deposit formed during the methanol decomposition is built up of
carbon nanofibers decorated with metal-like nanoparticles.