Abstract: In recent research copper and manganese systems
were found to be the most active in CO and organic compounds
oxidation among the base catalysts. The mixed copper manganese
oxide has been widely studied in oxidation reactions because of their
higher activity at low temperatures in comparison with single oxide
catalysts. The results showed that the formation of spinel
CuxMn3−xO4 in the oxidized catalyst is responsible for the activity
even at room temperature. That is why the most of the investigations
are focused on the hopcalite catalyst (CuMn2O4) as the best coppermanganese
catalyst. Now it’s known that this is true only for CO
oxidation, but not for mixture of CO and VOCs. The purpose of this
study is to investigate the alumina supported copper-manganese
catalysts with different Cu/Mn molar ratio in terms of oxidation of
CO, methanol and dimethyl ether. The catalysts were prepared by impregnation of γ-Al2O3 with
copper and manganese nitrates and the catalytic activity
measurements were carried out in two stage continuous flow
equipment with an adiabatic reactor for simultaneous oxidation of all
compounds under the conditions closest possible to the industrial. Gas
mixtures on the input and output of the reactor were analyzed with a
gas chromatograph, equipped with FID and TCD detectors. The
texture characteristics were determined by low-temperature (- 196oС)
nitrogen adsorption in a Quantachrome Instruments NOVA 1200e
(USA) specific surface area & pore analyzer. Thermal, XRD and
TPR analyses were performed. It was established that the active component of the mixed Cu-
Mn/γ–alumina catalysts strongly depends on the Cu/Mn molar ratio.
Highly active alumina supported Cu-Mn catalysts for CO, methanol
and DME oxidation were synthesized. While the hopcalite is the best
catalyst for CO oxidation, the best compromise for simultaneous
oxidation of all components is the catalyst with Cu/Mn molar ratio
1:5.
Abstract: The literature on language teaching and second
language acquisition has been largely driven by monolingual
ideology with a common assumption that a second language (L2) is
best taught and learned in the L2 only. The current study challenges
this assumption by reporting learners' positive perceptions of tertiary
level teachers' code switching practices in Vietnam. The findings of
this study contribute to our understanding of code switching practices
in language classrooms from a learners' perspective.
Data were collected from student participants who were working
towards a Bachelor degree in English within the English for Business
Communication stream through the use of focus group interviews.
The literature has documented that this method of interviewing has a
number of distinct advantages over individual student interviews. For
instance, group interactions generated by focus groups create a more
natural environment than that of an individual interview because they
include a range of communicative processes in which each individual
may influence or be influenced by others - as they are in their real
life. The process of interaction provides the opportunity to obtain the
meanings and answers to a problem that are "socially constructed
rather than individually created" leading to the capture of real-life
data. The distinct feature of group interaction offered by this
technique makes it a powerful means of obtaining deeper and richer
data than those from individual interviews. The data generated
through this study were analysed using a constant comparative
approach. Overall, the students expressed positive views of this
practice indicating that it is a useful teaching strategy. Teacher code
switching was seen as a learning resource and a source supporting
language output. This practice was perceived to promote student
comprehension and to aid the learning of content and target language
knowledge. This practice was also believed to scaffold the students'
language production in different contexts. However, the students
indicated their preference for teacher code switching to be
constrained, as extensive use was believed to negatively impact on
their L2 learning and trigger cognitive reliance on the L1 for L2
learning. The students also perceived that when the L1 was used to a
great extent, their ability to develop as autonomous learners was
negatively impacted.
This study found that teacher code switching was supported in
certain contexts by learners, thus suggesting that there is a need for
the widespread assumption about the monolingual teaching approach
to be re-considered.
Abstract: In this paper, the energy saving and human thermal
comfort in a typical office room are investigated. The impact of a
combined system of exhaust inlet air with light slots located at the
ceiling level in a room served by displacement ventilation system is
numerically modelled. Previous experimental data are used to
validate the Computational Fluid Dynamic (CFD) model. A case
study of simulated office room includes two seating occupants, two
computers, two data loggers and four lamps. The combined system is
located at the ceiling level above the heat sources. A new method of
calculation for the cooling coil load in Stratified Air Distribution
(STRAD) system is used in this study. The results show that 47.4%
energy saving of space cooling load can be achieved by combing the
exhaust inlet air with light slots at the ceiling level above the heat
sources.
Abstract: A dip-coating process has been used to form an
asymmetric silica membrane with improved membrane performance
and reproducibility. First, we deposited repeatedly silica on top of a
commercial alumina membrane support to improve its structural
make up. The membrane is further processed under clean room
conditions to avoid dust impurity and subsequent drying in an oven
for high thermal, chemical and physical stability. The resulting
asymmetric membrane exhibits a gradual change in the membrane
layer thickness. Compared to the support, the dual-layer process
improves the gas flow rates. For the scientific applications for natural
gas purification, CO2, CH4 and H2 gas flow rates were. In addition,
the membrane selectively separated hydrogen.
Abstract: Reticence is a prominent and complex phenomenon
which occurs in foreign language classrooms and influences students’
oral passivity. The present study investigated the extent in which
students experience reticence in the EFL classrooms and explored the
underlying factors triggering reticence. The participants were 104
Iranian freshmen undergraduate male and female EFL students, who
enrolled in listening and speaking courses, all majoring in English
studying at Islamic Azad University Isfahan (Khorasgan) Branch and
University of Isfahan, Isfahan, Iran. To collect the data, the Reticence
Scale-12 (RS-12) questionnaire which measures the level of reticence
consisting of six dimensions (anxiety, knowledge, timing,
organization, skills, and memory) was administered to the
participants. The statistical analyses showed that the reticent level
was high among the Iranian EFL undergraduate students, and their
major problems were feelings of anxiety and delivery skills.
Moreover, the results revealed that factors such as low English
proficiency, the teaching method, and lack of confidence contributed
to the students’ reticence in Iranian EFL classrooms. It can be
implied that language teachers’ awareness of learners’ reticence can
help them choose more appropriate activities and provide a friendly
environment enhancing hopefully more effective participation of EFL
learners. The findings can have implications for EFL teachers,
learners and policy makers.
Abstract: To ensure student success in a non-majors biology course, a flipped classroom pedagogical approach was developed and implemented. All students were assigned online lectures to listen to before they come to class. A three hour lecture was split into one hour of online component, one hour of in class lecture and one hour of worksheets done by students in the classroom. This deviation from a traditional 3 hour in class lecture has resulted in increased student interest in science as well as better understanding of difficult scientific concepts. A pre and post survey was given to measure the interest in the subject and grades were used to measure the success rates. While the overall grade average did not change dramatically, students reported a much better appreciation of biology. Also, students overwhelmingly like the use of worksheets in class to help them understand the concepts. They liked the fact that they could listen to lectures at their own pace on line and even repeat if needed. The flipped classroom approach turned out to work really well our non-science majors and the author is ready to implement this in other classrooms.
Abstract: Chitosan functionalized Fe3O4-Au core shell
nanoparticles have been prepared using a two-step wet chemical
approach using NaBH4 as reducing agent for formation of Au in
ethylene glycol. X-ray diffraction studies shows individual phases of
Fe3O4 and Au in the as prepared samples with crystallite size of 5.9
and 11.4 nm respectively. The functionalization of the core-shell
nanostructure with Chitosan has been confirmed using Fourier
transform infrared spectroscopy along with signatures of octahedral
and tetrahedral sites of Fe3O4 below 600cm-1. Mössbauer
spectroscopy shows decrease in particle-particle interaction in
presence of Au shell (72% sextet) than pure oleic coated Fe3O4
nanoparticles (88% sextet) at room temperature. At 80K, oleic acid
coated Fe3O4 shows only sextets whereas the Chitosan functionalized
Fe3O4 and Chitosan functionalized Fe3O4@Au core shell show
presence of 5 and 11% doublet, respectively.
Abstract: Microstructural and hardening changes of
Fe-0.2wt.%V alloy and pure Fe irradiated with 100 keV hydrogen ions
at room temperature were investigated. It was found that dislocation
density varies dramatically after irradiation, ranging from dislocation
free to dense areas with tangled and complex dislocation
configuration. As the irradiated Fe-0.2wt.%V samples were annealed
at 773 K, the irradiation-induced dislocation loops disappear, while
many small precipitates with enriched C distribute in the matrix. Some
large precipitates with enriched V were also observed. The hardness of
Fe-0.2wt.%V alloy and pure Fe increases after irradiation, which
ascribes to the formation of dislocation loops in the irradiated
specimens. Compared with pure Fe, the size of the
irradiation-introduced dislocation loops in Fe-0.2wt.%V alloy
decreases and the density increases, the change of the hardness also
decreases.
Abstract: Dielectric ceramic samples in the BaO-Re2O3-TiO2
ternary system were synthesized with structural formula Ba2-
xRe4+2x/3Ti8O24 where Re= rare earth metal and Re= Sm and La where
x varies from 0.0 to 0.6 with step size 0.1. Polycrystalline samples
were prepared by the conventional solid state reaction technique. The
dielectric, electrical and impedance analysis of all the samples in the
frequency range 1KHz- 1MHz at room temperature (25°C) have been
done to get the understanding of electrical conduction and dielectric
relaxation and their correlation. Dielectric response of the samples at
lower frequencies shows dielectric dispersion while at higher
frequencies it shows dielectric relaxation. The ac conductivity is well
fitted by the Jonscher law. The spectroscopic data in the impedance
plane confirms the existence of grain contribution to the relaxation.
All the properties are found out to be function of frequency as well as
the amount of substitution.
Abstract: The changes of the optical and structural properties of
Bismuth-Boro-Tellurite glasses pre and post gamma irradiation were
studied. Six glass samples, with different composition [(TeO2)0.7
(B2O3)0.3]1-x (Bi2O3)x prepared by melt quenching method were
irradiated with 25kGy gamma radiation at room temperature. The
Fourier Transform Infrared Spectroscopy (FTIR) was used to explore
the structural bonding in the prepared glass samples due to exposure,
while UV-VIS Spectrophotometer was used to evaluate the changes
in the optical properties before and after irradiation. Gamma
irradiation causes profound changes in the peak intensity as shown by
FTIR spectra which is due to the breaking of the network bonding.
Before gamma irradiation, the optical band gap, Eg value decreased
from 2.44 eV to 2.15 eV with the addition of Bismuth content. The
value kept decreasing (from 2.18 eV to 2.00 eV) following exposure
to gamma radiation due to the increase of non-bridging oxygen
(NBO) and the increase of defect in the glass. In conclusion, the glass
with high content of Bi2O3 (0.30Bi) give smallest Eg and show less
changes in FTIR spectra after gamma irradiation which indicate that
this glass is more resistant to gamma radiation compared to other
glasses.
Abstract: An unconventional composite inorganic ceramic
membrane capable of enhancing carbon dioxide emission decline was
fabricated and tested at laboratory scale in conformism to various
environmental guidelines and also to mitigate the effect of global
warming. A review of the existing membrane technologies for carbon
capture including the relevant gas transport mechanisms is presented.
Single gas permeation experiments using silica modified ceramic
membrane with internal diameter 20mm, outside diameter 25mm and
length of 368mm deposited on a macro porous support was carried
out to investigate individual gas permeation behaviours at different
pressures at room temperature. Membrane fabrication was achieved
using after a dip coating method. Nitrogen, Carbon dioxide, Argon,
Oxygen and Methane pure gases were used to investigate their
individual permeation rates at various pressures. Results show that
the gas flow rate increases with pressure drop. However above a
pressure of 3bar, CO2 permeability ratio to that of the other gases
indicated control of a more selective surface adsorptive transport
mechanism.
Abstract: Pipa is one of the most important Chinese traditional
plucked instruments, but its directivity has never been measured
systematically. In western, directivity of loudness for western
instruments is deeply researched through analysis of sound pressure
level, whereas the directivity of timbre is seldom studied. In this paper,
a new method for directivity of timbre was proposed, and horizontal
directivity patterns of loudness and timbre of Pipa were measured.
Directivity of Pipa radiation was measured in an anechoic room. The
sound of Pipa played by a musician was recorded simultaneously by
32 microphones with Pipa in the center. The measuring results were
examined through listening test. According to the measurement of
Pipa directivity radiation, we put forward the best localization of Pipa
in the Chinese traditional orchestra and the optimal recording region.
Abstract: The distribution of a single global clock across a chip
has become the major design bottleneck for high performance VLSI
systems owing to the power dissipation, process variability and multicycle
cross-chip signaling. A Network-on-Chip (NoC) architecture
partitioned into several synchronous blocks has become a promising
approach for attaining fine-grain power management at the system
level. In a NoC architecture the communication between the blocks is
handled asynchronously. To interface these blocks on a chip
operating at different frequencies, an asynchronous FIFO interface is
inevitable. However, these asynchronous FIFOs are not required if
adjacent blocks belong to the same clock domain. In this paper, we
have designed and analyzed a 16-bit asynchronous micropipelined
FIFO of depth four, with the awareness of place and route on an
FPGA device. We have used a commercially available Spartan 3
device and designed a high speed implementation of the
asynchronous 4-phase micropipeline. The asynchronous FIFO
implemented on the FPGA device shows 76 Mb/s throughput and a
handshake cycle of 109 ns for write and 101.3 ns for read at the
simulation under the worst case operating conditions (voltage =
0.95V) on a working chip at the room temperature.
Abstract: Taiwan is a hyper endemic area for the Hepatitis B
virus (HBV). The estimated total number of HBsAg carriers in the
general population who are more than 20 years old is more than 3
million. Therefore, a case record review is conducted from January
2003 to June 2007 for all patients with a diagnosis of acute hepatitis
who were admitted to the Emergency Department (ED) of a
well-known teaching hospital. The cost for the use of medical
resources is defined as the total medical fee. In this study, principal
component analysis (PCA) is firstly employed to reduce the number of
dimensions. Support vector regression (SVR) and artificial neural
network (ANN) are then used to develop the forecasting model. A total
of 117 patients meet the inclusion criteria. 61% patients involved in
this study are hepatitis B related. The computational result shows that
the proposed PCA-SVR model has superior performance than other
compared algorithms. In conclusion, the Child-Pugh score and
echogram can both be used to predict the cost of medical resources for
patients with acute hepatitis in the ED.
Abstract: In this paper, the effects of fiber types and elevated
temperatures on compressive strength, modulus of rapture and the
bond characteristics of fiber reinforced concretes (FRC) are
presented. By using the three different types of fibers (steel fiber-SF,
polypropylene-PPF and polyvinyl alcohol-PVA), FRC specimens
were produced and exposed to elevated temperatures up to 800 ºC for
1.5 hours. In addition, a plain concrete (without fiber) was produced
and used as a control. Test results obtained showed that the steel fiber
reinforced concrete (SFRC) had the highest compressive strength,
modulus of rapture and bond stress values at room temperatures, the
residual bond, flexural and compressive strengths of both FRC and
plain concrete dropped sharply after exposure to high temperatures.
The results also indicated that the reduction of bond, flexural and
compressive strengths with increasing the exposed temperature was
relatively less for SFRC than for plain, and FRC with PPF and PVA.
Abstract: After the internet explosion in the 90’s, technology
was immediately integrated into the school system. Technology
which symbolizes advancement in human knowledge was seen as a
setback by many educators. Efforts have been made to help stem this
erroneous believes and help educators realize the benefits of
technology and ways of implementing it in the classrooms especially
in the sciences. This advancement created a constantly expanding gap
between the pupil’s perception on the use of technology within the
learning atmosphere and the teacher’s perception and limitations
hence, the focus of this paper is on the need to refocus on the use of
Science and Technology in enhancing children’s potentials in
learning at school especially in Science for sustainable development
in Nigeria. The paper recommended measures for facilitating the
sustenance of science and technology in Nigerian schools so as to
enhance the potentials of our children in Science and Technology for
a better tomorrow.
Abstract: Taking into account the significance of measuring the
daily use of the study space in the libraries in order to develop and
reorganize the space for enhancing the efficiency of the study space,
the current study aimed to apply GIS in analyzing the study halls of
the Central Library and Document Center of Tehran University in
order to determine how study desks and chairs were used by the
students. The study used a combination of survey-descriptive and
system design method. In order to gather the required data, surveydescriptive
method was used. For implementing and entering data
into ArcGIS and analyzing the data and displaying the results on the
maps of the study halls of the library, system design method was
utilized. The design of the spatial database of the use of the study
halls was measured through the extent of occupancy of the space by
the library users and the maps of the study halls of the central library
of Tehran University as the case study. The results showed that
Abooreyhan hall had the highest rate of occupancy of the desks and
chairs compared to the other halls. The Hall of Science and
Technology, with an average occupancy rate of 0.39 for the tables
represented the lowest number of users and Rashid al-Dins hall, and
Science and Technology hall with an average occupancy rate (0.40)
had the lowest number of users for seats. In this study, the
comparison of the space occupied at different periods in the morning,
evenings, afternoons, and several months was performed through
GIS. This system analyzed the space relationships effectively and
efficiently. The output of this study would be used by administrators
and librarians to determine the exact extent of use of the equipment
of the study halls and librarians can use the output map to design the
space more efficiently at the library.
Abstract: This paper presents effects of distilled water, seawater
and sustained bending strains of 30% and 50% ultimate strain at
room temperature, on the durability of unidirectional pultruded
carbon fiber reinforced polymer (CFRP) plates. In this study,
dynamic mechanical analyzer (DMA) was used to investigate the
synergic effects of the immersions and bending strains on the viscoelastic
properties of (CFRP) such as storage modulus, tan delta and
glass transition temperature. The study reveals that the storage
modulus and glass transition temperature increase while tan delta
peak decreases in the initial stage of both immersions due to the
progression of curing. The storage modulus and Tg subsequently
decrease and tan delta increases due to the matrix plasticization. The
blister induced damages in the unstrained seawater samples enhance
water uptake and cause more serious degradation of Tg and storage
modulus than in water immersion. Increasing sustained bending
decreases Tg and storage modulus in a long run for both immersions
due to resin matrix cracking and debonding. The combined effects of
immersions and strains are not clearly reflected due to the statistical
effects of DMA sample sizes and competing processes of molecular
reorientation and postcuring.
Abstract: The adaptation of social networking sites within
higher education has garnered significant interest in the recent years
with numerous researches considering it as a possible shift from the
traditional classroom based learning paradigm. Notwithstanding this
increase in research and conducted studies however, the adaption of
SNS based modules have failed to proliferate within Universities.
This paper commences its contribution by analyzing the various
models and theories proposed in literature and amalgamate together
various effective aspects for the inclusion of social technology within
e-Learning. A three phased framework is further proposed which
details the necessary considerations for the successful adaptation of
SNS in enhancing the students learning experience. This proposal
outlines the theoretical foundations which will be analyzed in
practical implementation across international university campuses.
Abstract: In a multi-cultural learning context, where ties are
weak and dynamic, combining qualitative with quantitative research
methods may be more effective. Such a combination may also allow
us to answer different types of question, such as about people’s
perception of the network. In this study the use of observation,
interviews and photos were explored as ways of enhancing data from
social network questionnaires. Integrating all of these methods was
found to enhance the quality of data collected and its accuracy, also
providing a richer story of the network dynamics and the factors that
shaped these changes over time.