Abstract: TiO2 nanoparticles were synthesized by hydrothermal
method at 180°C from TiOSO4 aqueous solution with1m/l
concentration. The obtained products were coated with silica by
means of a seeded polymerization technique for a coating time of
1440 minutes to obtain well defined TiO2@SiO2 core-shell structure.
The uncoated and coated nanoparticles were characterized by using
X-Ray diffraction technique (XRD), Fourier Transform Infrared
Spectroscopy (FT-IR) to study their physico-chemical properties.
Evidence from XRD and FTIR results show that SiO2 is
homogenously coated on the surface of titania particles. FTIR spectra
show that there exists an interaction between TiO2 and SiO2 and
results in the formation of Ti-O-Si chemical bonds at the interface of
TiO2 particles and SiO2 coating layer. The non linear optical limiting
properties of TiO2 and TiO2@SiO2 nanoparticles dispersed in
ethylene glycol were studied at 532nm using 5ns Nd:YAG laser
pulses. Three-photon absorption is responsible for optical limiting
characteristics in these nanoparticles and it is seen that the optical
nonlinearity is enhanced in core-shell structures when compared with
single counterparts. This effective three-photon type absorption at
this wavelength, is of potential application in fabricating optical
limiting devices.
Abstract: Embedded hardware simulator is a valuable computeraided
tool for embedded application development. This paper focuses
on the ARM926EJ-S MMU, builds state transition models and
formally verifies critical properties for the models. The state transition
models include loading instruction model, reading data model, and
writing data model. The properties of the models are described by
CTL specification language, and they are verified in VIS. The results
obtained in VIS demonstrate that the critical properties of MMU are
satisfied in the state transition models. The correct models can be
used to implement the MMU component in our simulator. In the
end of this paper, the experimental results show that the MMU can
successfully accomplish memory access requests from CPU.
Abstract: The typical coupled-tanks process that is TITO
plant has the difficulty in controller design because changing
of system dynamics and interacting of process. This paper
presents design methodology of auto-adjustable PI controller
using MRAC technique. The proposed method can adjust the
controller parameters in response to changes in plant and
disturbance real time by referring to the reference model that
specifies properties of the desired control system.
Abstract: Asphalt surfaces are exposed to various weather
conditions and dynamic loading caused by passing trucks and
vehicles. In such situations, asphalt cement shows so different
rheological-mechanical behavior. If asphalt cement isn-t compatible
enough, asphalt layer will be damaged immediately and expensive
repairing procedures should be performed then. To overcome this
problem, researchers study on mechanical improved asphalt cement.
In this study, bentonite was used in order to modify bitumen
characteristics and the modified bitumen's characteristics were
investigated by asphalt cement tests. Then, the optimal bitumen
content in various compounds was determined and asphalt samples
with different contents of additives were prepared and tested. Results
show using this kind of additive not only has caused improvement in
bitumen mechanical properties, but also improvement in Marshall
Parameters was achieved.
Abstract: There are a many of needs for the development of
SiC-based hydrogen sensor for harsh environment applications. We
fabricated and investigated Pd/Ta2O5/SiC-based hydrogen sensors
with MOS capacitor structure for high temperature process monitoring
and leak detection applications in such automotive, chemical and
petroleum industries as well as direct monitoring of combustion
processes. In this work, we used silicon carbide (SiC) as a substrate to
replace silicon which operating temperatures are limited to below
200°C. Tantalum oxide was investigated as dielectric layer which has
high permeability for hydrogen gas and high dielectric permittivity,
compared with silicon dioxide or silicon nitride. Then, electrical
response properties, such as I-V curve and dependence of capacitance
on hydrogen concentrations were analyzed in the temperature ranges
of room temperature to 500°C for performance evaluation of the
sensor.
Abstract: Utilization of waste material in asphalt pavement
would be beneficial in order to find an alternative solution to increase
service life of asphalt pavement and reduce environmental pollution
as well. One of these waste materials is Polyethylene Terephthalate
(PET) which is a type of polyester material and is produced in a large
extent. This research program is investigating the effects of adding
waste PET particles into the asphalt mixture with a maximum size of
2.36 mm. Different percentages of PET were added into the mixture
during dry process. Gap-graded mixture (SMA 14) and PG 80-100
asphalt binder have been used for this study. To evaluate PET
reinforced asphalt mixture different laboratory investigations have
been conducted on specimens. Marshall Stability test was carried
out. Besides, stiffness modulus test and indirect tensile fatigue test
were conducted on specimens at optimum asphalt content. It was
observed that in many cases PET reinforced SMA mixture had better
mechanical properties in comparison with control mixture.
Abstract: The effects of irrigation with dairy factory wastewater
on soil properties were investigated at two sites that had received
irrigation for > 60 years. Two adjoining paired sites that had never
received DFE were also sampled as well as another seven fields from
a wider area around the factory. In comparison with paired sites that
had not received effluent, long-term wastewater irrigation resulted in
an increase in pH, EC, extractable P, exchangeable Na and K and
ESP. These changes were related to the use of phosphoric acid,
NaOH and KOH as cleaning agents in the factory. Soil organic C
content was unaffected by DFE irrigation but the size (microbial
biomass C and N) and activity (basal respiration) of the soil
microbial community were increased. These increases were
attributed to regular inputs of soluble C (e.g. lactose) present as milk
residues in the wastewater. Principal component analysis (PCA) of
the soils data from all 11sites confirmed that the main effects of DFE
irrigation were an increase in exchangeable Na, extractable P and
microbial biomass C, an accumulation of soluble salts and a liming
effect. PCA analysis of soil bacterial community structure, using
PCR-DGGE of 16S rDNA fragments, generally separated individual
sites from one another but did not group them according to irrigation
history. Thus, whilst the size and activity of the soil microbial
community were increased, the structure and diversity of the
bacterial community remained unaffected.
Abstract: In the present analysis an unsteady laminar
forced convection water boundary layer flow is considered.
The fluid properties such as viscosity and Prandtl number are
taken as variables such that those are inversely proportional to
temperature. By using quasi-linearization technique the nonlinear
coupled partial differential equations are linearized and
the numerical solutions are obtained by using implicit finite
difference scheme with the appropriate selection of step sizes.
Non-similar solutions have been obtained from the starting
point of the stream-wise coordinate to the point where skin
friction value vanishes. The effect non-uniform mass transfer
along the surface of the cylinder through slot is studied on the
skin friction and heat transfer coefficients.
Abstract: The study was designed to evaluate the use of low
concentrations of separan flocculent (Less than 3 ppm) on
physicochemical properties of sugar cane juice. Colour, pH, purity,
turbidity, pol, brix, reducing sugars tannins and polyphenols of
crushed cane (green and burned) juice, mixed juice and clarified
juice were studied. The results showed that pol, brix, reducing sugar
and turbidity are higher in crushed cane juice. Clarified burned juice
had low turbidity, reducing sugars, pol and brix but had significantly
lower pH, purity and colour when compared to crushed juice.
Polyphenols of the crushed juice (1.19%) decreased significantly in
the clarified juice to 0.006%. Addition of separan at a concentration
of 0.015 ppm reduced significantly colour, polyphenols and tannins
and reducing sugar compared to the control.
Abstract: The kinetic properties of enzymes are often reported
using the apparent KM and Vmax appropriate to the standard
Michaelis-Menten enzyme. However, this model is inappropriate to
enzymes that have more than one substrate or where the rate
expression does not apply for other reasons. Consequently, it is
desirable to have a means of estimating the appropriate kinetic
parameters from the apparent values of KM and Vmax reported for each
substrate. We provide a means of estimating the range within which
the parameters should lie and apply the method to data for glutamate
dehydrogenase from the nematode parasite of sheep Teladorsagia
circumcincta.
Abstract: We investigate the ZnO role in the inherent protection
of old manuscripts to protect them against environmental damaging
effect of ultraviolet radiation, pollutant gasses, mold and bacteria. In
this study a cellulosic nanocomposite of ZnO were used as protective
coating on the surface of paper fibers. This layered nanocomposite
can act as a consolidate materials too. Furthermore, to determine how
well paper works screen objects from the damaging effects, two
accelerated aging mechanisms due to light and heat are discussed.
Results show good stability of papers with nanocomposite coating.
Also, a good light stability was shown in the colored paper that
treated with this nanocomposite. Furthermore, to demonstrate the
degree of antifungal and antibacterial properties of coated papers,
papers was treated with four common molds and bacteria and the
good preventive effects of coated paper against molds and bacteria
are described.
Abstract: This paper presents the stabilization potential of Class
F pond ash (PA) from a coal fired thermal power station on tropical
peat soil. Peat or highly organic soils are well known for their high
compressibility, natural moisture content, low shear strength and
long-term settlement. This study investigates the effect of different
amount (i.e., 5, 10, 15 and 20%) of PA on peat soil, collected from
Sarawak, Malaysia, mainly compaction and unconfined compressive
strength (UCS) properties. The amounts of PA added to the peat soil
sample as percentage of the dry peat soil mass. With the increase in
PA content, the maximum dry density (MDD) of peat soil increases,
while the optimum moisture content (OMC) decreases. The UCS
value of the peat soils increases significantly with the increase of PA
content and also with curing periods. This improvement on
compressive strength of tropical peat soils indicates that PA has the
potential to be used as a stabilizer for tropical peat soil. Also, the use
of PA in soil stabilization helps in reducing the pond volume and
achieving environment friendly as well as a sustainable development
of natural resources.
Abstract: Curing of paints by exposure to UV radiations is
emerging as one of the best film forming technique as an alternative
to traditional solvent borne oxidative and thermal curing coatings.
The composition and chemistry of UV curable coatings and role of
multifunctional and monofunctional monomers, oligomers, and
photoinitiators have been discussed. The limitations imposed by
thermodynamic equilibrium and tendency for acrylic double bond
polymerizations during synthesis of multifunctional acrylates have
been presented. Aim of present investigation was thus to explore the
reaction variables associated with synthesis of multifunctional
acrylates. Zirconium oxychloride was evaluated as catalyst against
regular acid functional catalyst. The catalyzed synthesis of glyceryl
acrylate and neopentyl glycol acrylate was conducted by variation of
following reaction parameters: two different reactant molar ratios-
1:4 and 1:6; catalyst usage in % by moles on polyol- 2.5, 5.0 and 7.5
and two different reaction temperatures- 45 and 75 0C. The reaction
was monitored by determination of acid value and hydroxy value at
regular intervals, besides TLC, HPLC, and FTIR analysis of
intermediates and products. On the basis of determination of reaction
progress over 1-60 hrs, the esterification reaction was observed to
follow 2nd order kinetics with rate constant varying from 1*10-4 to
7*10-4. The thermal and catalytic components of second order rate
constant and energy of activation were also determined. Uses of
these kinetic and thermodynamic parameters in design of reactor for
manufacture of multifunctional acrylate ester have been presented.
The synthesized multifunctional acrylates were used to formulate and
apply UV curable clear coat followed by determination of curing
characteristics and mechanical properties of cured film. The overall
curing rates less than 05 min. were easily attained indicating
economical viability of radiation curable system due to faster
production schedules
Abstract: The most suitable Semiconductor detector, Cadmium
Zinc Teloraid , has unique properties because of high Atomic number
and wide Brand Gap . It has been tried in this project with different
processes such as Lead , Diffusion , Produce and Recombination ,
effect of Trapping and injection carrier of CdZnTe , to get hole and
then present a complete answer of it . Then we should investigate the
movement of carrier ( Electron – Hole ) by using above answer.
Abstract: Inspired by the recent experiments [1]-[3] indicating
unusual doubly magic nucleus 24O which lies just at the neutron
drip-line and encouraged by the success of our relativistic mean-field
(RMF) plus state dependent BCS approach for the description of
the ground state properties of the drip-line nuclei [23]-[27], we have
further employed this approach, across the entire periodic table, to
explore the unusual shell closures in exotic nuclei. In our RMF+BCS
approach the single particle continuum corresponding to the RMF is
replaced by a set of discrete positive energy states for the calculations
of pairing energy. Detailed analysis of the single particle spectrum,
pairing energies and densities of the nuclei predict the unusual proton
shell closures at Z = 6, 14, 16, 34, and unusual neutron shell closures
at N = 6, 14, 16, 34, 40, 70, 112.
Abstract: Ipomoea batatas (Sweetpotato) is currently ranked
sixth in the total world food production and are planted mainly for
their storage roots. The present study was undertaken to evaluate and
compare the antioxidant properties of the leaf and carotenoids extract
from the Ipomoea batatas var. Oren leaves. Total flavonoids in the
leaf extract was 144.6 ± 40.5 μg/g compared to 114.86 ± 4.35 μg/g
catechin equivalent in the carotenoids extract. Total polyphenols in
the leaf extracts (3.470 ± 0.024 GAE g/100g DW) was slightly higher
compared to carotenoids extract (2.994 ± 0.078 GAE g/100g DW).
The carotenoids extract marked a higher radical scavenging capacity
with the IC50= 491.86 μg/ml compared to leaf extract (IC50= 545.39
μg/ml). Concentration-dependent reducing activity was observed for
both extracts. Thus, the carotenoids extraction process retained most
of the antioxidant capacity from the leaves and can be made into
potential natural yellow dye with antioxidant property.
Abstract: The textural parameters, together with appearance and
flavor, are sensory attributes of great importance for the product to be
accepted by the consumer. The objective of the present study was the
evaluation of the textural attributes of Packhams pears in the fresh
state, after drying in a chamber with forced convection at 50ºC,
lyophilized and re-hydrated. In texture analysis it was used the
method of Texture Profile Analysis (TPA). The parameters analyzed
were hardness, cohesiveness, adhesiveness, elasticity and chewiness.
From the results obtained is possible to see that the drying operation
greatly affected some textural properties of the pears, so that the
hardness diminished very much with drying, for both drying
methods.
Abstract: Coloured Petri net (CPN) has been widely adopted in various areas in Computer Science, including protocol specification, performance evaluation, distributed systems and coordination in multi-agent systems. It provides a graphical representation of a system and has a strong mathematical foundation for proving various properties. This paper proposes a novel representation of a coloured Petri net using an extension of logic programming called abductive logic programming (ALP), which is purely based on classical logic. Under such a representation, an implementation of a CPN could be directly obtained, in which every inference step could be treated as a kind of equivalence preserved transformation. We would describe how to implement a CPN under such a representation using common meta-programming techniques in Prolog. We call our framework CPN-LP and illustrate its applications in modeling an intelligent agent.
Abstract: Porcine production in China represents approximately
the 50% of the worldwide pig production. Information about pig
husbandry characteristics in China and manure properties from sows
to fatteners in intensive pig farms are not broadly available for
scientific studies as it is a time consuming, expensive task and highly
inaccessible. This study provides a report about solid pig manures
(28% dry matter) in a commercial pig farm located in the peri-urban
area of Beijing as well as a general overview of the current pig
husbandry techniques including pig breeds, feeds, diseases, housing as
well as pig manure and wastewater disposal. The main results are
intended to serve as a literature source for young scientists in order to
understand the main composition of pig manures as well as to identify
the husbandry techniques applied in an intensive pig farm in Beijing.
Abstract: A SnO2/CdS/CdTe heterojunction was fabricated by
thermal evaporation technique. The fabricated cells were annealed at
573K for periods of 60, 120 and 180 minutes. The structural
properties of the solar cells have been studied by using X-ray
diffraction. Capacitance- voltage measurements were studied for the
as-prepared and annealed cells at a frequency of 102 Hz. The
capacitance- voltage measurements indicated that these cells are
abrupt. The capacitance decreases with increasing annealing time.
The zero bias depletion region width and the carrier concentration
increased with increasing annealing time. The carrier transport
mechanism for the CdS/CdTe heterojunction in dark is tunneling
recombination. The ideality factor is 1.56 and the reverse bias
saturation current is 9.6×10-10A. The energy band lineup for the n-
CdS/p-CdTe heterojunction was investigated using current - voltage
and capacitance - voltage characteristics.