Abstract: The draw solute separation process in Forward
Osmosis desalination was simulated in Aspen Plus chemical process
modeling software, to estimate the energy consumption and compare
it with other desalination processes, mainly the Reverse Osmosis
process which is currently most prevalent. The electrolytic chemistry
for the system was retrieved using the Elec – NRTL property method
in the Aspen Plus database. Electrical equivalent of energy required
in the Forward Osmosis desalination technique was estimated and
compared with the prevalent desalination techniques.
Abstract: In this paper, we present a vertical nanowire thin film transistor with gate-all-around architecture, fabricated using CMOS compatible processes. A novel method of fabricating polysilicon vertical nanowires of diameter as small as 30 nm using wet-etch is presented. Both n-type and p-type vertical poly-silicon nanowire transistors exhibit superior electrical characteristics as compared to planar devices. On a poly-crystalline nanowire of 30 nm diameter, high Ion/Ioff ratio of 106, low drain-induced barrier lowering (DIBL) of 50 mV/V, and low sub-threshold slope SS~100mV/dec are demonstrated for a device with channel length of 100 nm.
Abstract: This paper proposes new algorithms for the computeraided
design and manufacture (CAD/CAM) of 3D woven multi-layer
textile structures. Existing commercial CAD/CAM systems are often
restricted to the design and manufacture of 2D weaves. Those
CAD/CAM systems that do support the design and manufacture of
3D multi-layer weaves are often limited to manual editing of design
paper grids on the computer display and weave retrieval from stored
archives. This complex design activity is time-consuming, tedious
and error-prone and requires considerable experience and skill of a
technical weaver. Recent research reported in the literature has
addressed some of the shortcomings of commercial 3D multi-layer
weave CAD/CAM systems. However, earlier research results have
shown the need for further work on weave specification, weave
generation, yarn path editing and layer binding. Analysis of 3D
multi-layer weaves in this research has led to the design and
development of efficient and robust algorithms for the CAD/CAM of
3D woven multi-layer textile structures. The resulting algorithmically
generated weave designs can be used as a basis for lifting plans that
can be loaded onto looms equipped with electronic shedding
mechanisms for the CAM of 3D woven multi-layer textile structures.
Abstract: A newly designed gas-distributor for granulation of powdery materials in equilibrated fluidized bed and a system for collecting the granules prepared are suggested. The aim of these designs is to solve the problems arising by the granulation of powdery materials in fluidized bed devices. The gasdistributor and the collection system proved to be reliable at operation; they reduce the size of still zones, effectively disperse the binding solution in the bed and ensure the collection of granules of given diameter
Abstract: Environmental awareness and depletion of the
petroleum resources are among vital factors that motivate a number
of researchers to explore the potential of reusing natural fiber as an
alternative composite material in industries such as packaging,
automotive and building constructions. Natural fibers are available in
abundance, low cost, lightweight polymer composite and most
importance its biodegradability features, which often called “ecofriendly"
materials. However, their applications are still limited due
to several factors like moisture absorption, poor wettability and large
scattering in mechanical properties. Among the main challenges on
natural fibers reinforced matrices composite is their inclination to
entangle and form fibers agglomerates during processing due to
fiber-fiber interaction. This tends to prevent better dispersion of the
fibers into the matrix, resulting in poor interfacial adhesion between
the hydrophobic matrix and the hydrophilic reinforced natural fiber.
Therefore, to overcome this challenge, fiber treatment process is one
common alternative that can be use to modify the fiber surface
topology by chemically, physically or mechanically technique.
Nevertheless, this paper attempt to focus on the effect of
mercerization treatment on mechanical properties enhancement of
natural fiber reinforced composite or so-called bio composite. It
specifically discussed on mercerization parameters, and natural fiber
reinforced composite mechanical properties enhancement.
Abstract: Computational fluid dynamics (CFD) simulations
carried out in this paper show that spacer orientation has a major
influence on temperature patterns and on the heat transfer rates. The
local heat flux values significantly vary from high to very low values
at each filament when spacer touches the membrane surface. The
heat flux profile is more uniform when spacer filaments are not in
contact with the membrane thus making this arrangement more
beneficial. The temperature polarization is also found to be less in
this case when compared to the empty channel.
Abstract: The state of melt viscosity in injection process is significantly influenced by the setting parameters due to that the shear rate of injection process is higher than other processes. How to determine plastic melt viscosity during injection process is important to understand the influence of setting parameters on the melt viscosity. An apparatus named as pressure sensor bushing (PSB) module that is used to evaluate the melt viscosity during injection process is developed in this work. The formulations to coupling melt viscosity with fill time and injection pressure are derived and then the melt viscosity is determined. A test mold is prepared to evaluate the accuracy on viscosity calculations between the PSB module and the conventional approaches. The influence of melt viscosity on the tensile strength of molded part is proposed to study the consistency of injection quality.
Abstract: Highly ordered arrays of TiO2 nanotubes (TiNTs) were grown vertically on Ti foil by electrochemical anodization. We controlled the lengths of these TiNTs from 2.4 to 26.8 ¶üÇóμm while varying the water contents (1, 3, and 6 wt%) of the electrolyte in ethylene glycol in the presence of 0.5 wt% NH4F with anodization for various applied voltages (20–80 V), periods (10–240 min) and temperatures (10–30 oC). For vertically aligned TiNT arrays, not only the increase in their tube lengths, but also their geometric (wall thickness and surface roughness) and crystalline structure lead to a significant influence on photocatalytic activity. The length optimization for methylene blue (MB) photodegradation was 18 μm. Further extending the TiNT length yielded lower photocatalytic activity presumably related to the limited MB diffusion and light-penetration depth into the TiNT arrays. The results indicated that a maximum MB photodegradation rate was obtained for the discrete anatase TiO2 nanotubes with thick and rough walls.
Abstract: Crystallization has been used for the separation of
chloronitrobenzene or CNBs, which are isomeric substances (o-, mand
p-CNB) and important intermediates in chemical productions. Effects of feed composition on the crystallization of m- and p-CNB was first studied. The results conform to the binary phase diagram of
m- and p-CNB. After that, effects of FAU zeolites (NaX, CaX, BaX, NaY and CaY) above the eutectic composition (63.5 and 65.0 wt% m-CNB in the feed) was also investigated. The results showed that
the FAU zeolites significantly affected the precipitates, the
composition of which was shifted from being rich in m-CNB to rich
in p-CNB. Effects of the number of FAU zeolites on the precipitate composition was then studied. The results revealed that the
precipitates from the lower number of the zeolites had higher p-CNB purity than those from the higher number of zeolite.
Abstract: Team distillation assisted by microwave extraction
(SDAM) considered as accelerated technique extraction is a
combination of microwave heating and steam distillation, performed
at atmospheric pressure. SDAM has been compared with the same
technique coupled with the cryogrinding of seeds (SDAM -CG).
Isolation and concentration of volatile compounds are performed by a
single stage for the extraction of essential oil from Cuminum
cyminum seeds. The essential oils extracted by these two methods for
5 min were quantitatively (yield) and qualitatively (aromatic profile)
no similar. These methods yield an essential oil with higher amounts
of more valuable oxygenated compounds, and allow substantial
savings of costs, in terms of time, energy and plant material. SDAM
and SDAM-CG is a green technology and appears as a good
alternative for the extraction of essential oils from aromatic plants.
Abstract: Isobaric vapor-liquid equilibrium measurements are reported for the binary mixtures of Mesitylene + 1-Heptanol and Mesitylene + 1-Octanol at 97.3 kPa. The measurements have been performed using a vapor recirculating type (modified Othmer's) equilibrium still. Both the mixtures show positive deviation from ideality. The Mesitylene + 1-Heptanol mixture forms an azeotrope whereas Mesitylene + 1- Octanol form a non – azeotropic mixture. The activity coefficients have been calculated taking into consideration the vapor phase nonideality. The data satisfy the thermodynamic consistency tests of Herington, and Hirata. The activity coefficients have been satisfactorily correlated by means of the Margules, Redlich-Kister, Wilson, Black, and NRTL equations. The activity coefficient values have also been obtained by UNIFAC method.
Abstract: Recently, a growing interest has emerged on the
development of new and efficient energy sources, due to the inevitable extinction of the nonrenewable energy reserves. One of
these alternative sources which has a great potential and sustainability to meet up the energy demand is biomass energy. This
significant energy source can be utilized with various energy
conversion technologies, one of which is biomass gasification in
supercritical water.
Water, being the most important solvent in nature, has very important characteristics as a reaction solvent under supercritical
circumstances. At temperatures above its critical point (374.8oC and
22.1 MPa), water becomes more acidic and its diffusivity increases.
Working with water at high temperatures increases the thermal
reaction rate, which in consequence leads to a better dissolving of the
organic matters and a fast reaction with oxygen. Hence, supercritical water offers a control mechanism depending on solubility, excellent
transport properties based on its high diffusion ability and new reaction possibilities for hydrolysis or oxidation.
In this study the gasification of a real biomass, namely olive mill
wastewater (OMW), in supercritical water is investigated with the
use of Pt/Al2O3 and Ni/Al2O3 catalysts. OMW is a by-product
obtained during olive oil production, which has a complex nature
characterized by a high content of organic compounds and
polyphenols. These properties impose OMW a significant pollution
potential, but at the same time, the high content of organics makes
OMW a desirable biomass candidate for energy production.
All of the catalytic gasification experiments were made with five
different reaction temperatures (400, 450, 500, 550 and 600°C),
under a constant pressure of 25 MPa. For the experiments conducted
with Ni/Al2O3 catalyst, the effect of five reaction times (30, 60, 90,
120 and 150 s) was investigated. However, procuring that similar
gasification efficiencies could be obtained at shorter times, the experiments were made by using different reaction times (10, 15, 20,
25 and 30 s) for the case of Pt/Al2O3 catalyst. Through these experiments, the effects of temperature, time and catalyst type on the
gasification yields and treatment efficiencies were investigated.
Abstract: Significant changes in oil and gas drilling have
emphasized the need to verify the integrity and reliability of drill
stem components. Defects are inevitable in cast components,
regardless of application; but if these defects go undetected, any
severe defect could cause down-hole failure.
One such defect is shrinkage porosity. Castings with lower level
shrinkage porosity (CB levels 1 and 2) have scattered pores and do
not occupy large volumes; so pressure testing and helium leak testing
(HLT) are sufficient for qualifying the castings. However, castings
with shrinkage porosity of CB level 3 and higher, behave erratically
under pressure testing and HLT making these techniques insufficient
for evaluating the castings- integrity.
This paper presents a case study to highlight how the radiography
technique is much more effective than pressure testing and HLT.
Abstract: In the present research, steam cracking of two types of
feedstocks i.e., naphtha and ethane is simulated for Pyrocrack1-1 and
2/2 coil configurations considering two key parameters of coil outlet
temperature (COT) and coil capacity using a radical based kinetic
model. The computer model is confirmed using the industrial data
obtained from Amirkabir Petrochemical Complex. The results are in
good agreement with performance data for naphtha cracking in a
wide range of severity (0.4-0.7), and for ethane cracking on various
conversions (50-70). It was found that Pyrocrack2-2 coil type is an
appropriate choice for steam cracking of ethane at reasonable
ethylene yield while resulting in much lower tube wall temperature
while Pyrocrack1-1 coil type is a proper selection for liquid
feedstocks i.e. naphtha. It can be used for cracking of liquid
feedstocks at optimal ethylene yield whereas not exceeding the
allowable maximum tube temperature.
Abstract: Biochemical Oxygen Demand (BOD) is a measure of
the oxygen used in bacteria mediated oxidation of organic substances
in water and wastewater. Theoretically an infinite time is required for
complete biochemical oxidation of organic matter, but the
measurement is made over 5-days at 20 0C or 3-days at 27 0C test
period with or without dilution. Researchers have worked to further
reduce the time of measurement.
The objective of this paper is to review advancement made in
BOD measurement primarily to minimize the time and negate the
measurement difficulties. Survey of literature review in four such
techniques namely BOD-BARTTM, Biosensors, Ferricyanidemediated
approach, luminous bacterial immobilized chip method.
Basic principle, method of determination, data validation and their
advantage and disadvantages have been incorporated of each of the
methods.
In the BOD-BARTTM method the time lag is calculated for the
system to change from oxidative to reductive state. BIOSENSORS
are the biological sensing element with a transducer which produces
a signal proportional to the analyte concentration. Microbial species
has its metabolic deficiencies. Co-immobilization of bacteria using
sol-gel biosensor increases the range of substrate. In ferricyanidemediated
approach, ferricyanide has been used as e-acceptor instead
of oxygen. In Luminous bacterial cells-immobilized chip method,
bacterial bioluminescence which is caused by lux genes was
observed. Physiological responses is measured and correlated to
BOD due to reduction or emission.
There is a scope to further probe into the rapid estimation of BOD.
Abstract: Arthrobacter viscosus biomass was used for Cr(VI)
biosorption. The effect of pH on Cr(VI) reduction and removal from
aqueous solution was studied in the range of 1-4. The Cr(VI) removal
involves both redox reaction and adsorption of metal ions on biomass
surface. The removal rate of Cr(VI) was enhanced by very acid
conditions, while higher solution pH values favored the removal of
total chromium. The best removal efficiency and uptake were
reached at pH 4, 72.5 % and 12.6 mgCr/gbiomass, respectively.
Abstract: This current research focused on development of degradable starch based packaging film with enhanced mechanical properties. A series of low density polyethylene (LDPE)/tapioca starch compounds with various tapioca starch contents were prepared by twin screw extrusion with the addition of maleic anhydride grafted polyethylene as compatibilizer. Palm cooking oil was used as processing aid to ease the blown film process, thus, degradable film can be processed via conventional blown film machine. Studies on their characteristics, mechanical properties and biodegradation were carried out by Fourier Transform Infrared (FTIR) spectroscopy and optical properties, tensile test and exposure to fungi environment respectively. The presence of high starch contents had an adverse effect on the tensile properties of LDPE/tapioca starch blends. However, the addition of compatibilizer to the blends improved the interfacial adhesion between the two materials, hence, improved the tensile properties of the films. High content of starch amount also was found to increase the rate of biodegradability of LDPE/tapioca starch films. It can be proved by exposure of the film to fungi environment. A growth of microbes colony can be seen on the surface of LDPE/tapioca starch film indicates that the granular starch present on the surface of the polymer film is attacked by microorganisms, until most of it is assimilated as a carbon source.
Abstract: Pressure driven microscale gas flow-separation has
been investigated by solving the compressible Navier-Stokes (NS)
system of equations. A two dimensional explicit finite volume (FV)
compressible flow solver has been developed using modified
advection upwind splitting methods (AUSM+) with no-slip/first
order Maxwell-s velocity slip conditions to predict the flowseparation
behavior in microdimensions. The effects of scale-factor
of the flow geometry and gas species on the microscale gas flowseparation
have been studied in this work. The intensity of flowseparation
gets reduced with the decrease in scale of the flow
geometry. In reduced dimension, flow-separation may not at all be
present under similar flow conditions compared to the larger flow
geometry. The flow-separation patterns greatly depend on the
properties of the medium under similar flow conditions.
Abstract: The peng-Robinson (PR), a cubic equation of state (EoS), is extended to polymers by using a single set of energy (A1, A2, A3) and co-volume (b) parameters per polymer fitted to experimental volume data. Excellent results for the volumetric behavior of the 11 polymer up to 2000 bar pressure are obtained. The EoS is applied to the correlation and prediction of Henry constants in polymer solutions comprising three polymer and many nonpolar and polar solvents, including supercritical gases. The correlation achieved with two adjustable parameter is satisfactory compared with the experimental data. As a result, the present work provides a simple and useful model for the prediction of Henry's constant for polymer containing systems including those containing polar, nonpolar and supercritical fluids.
Abstract: In this work, Experimental tie-line results and
solubility (binodal) curves were obtained for the ternary systems
(water + acetic acid + methyl isobutyl ketone (MIBK)), (water +
lactic acid+ methyl isobutyl ketone) at T = 294.15K and atmospheric
pressure. The consistency of the values of the experimental tie-lines
was determined through the Othmer-Tobias and Hands correlations.
For the extraction effectiveness of solvents, the distribution and
selectivity curves were plotted. In addition, these experimental tieline
data were also correlated with NRTL model. The interaction
parameters for the NRTL model were retrieved from the obtained
experimental results by means of a combination of the homotopy
method and the genetic algorithms.