Abstract: The aim of this work was to study the in vitro effects
of δ-lactam 1 and its 4-chlorophenyl derivative 2, on the proliferative
responses of human lymphocytes and Th1 and Th2 cytokine
secretion. The possible protective role of vitamin E on intracellular
stress oxidative induced by these compounds was also investigated.
Peripheral blood lymphocytes were isolated using differential
centrifugation on a density gradient of Histopaque. They were
cultured with mitogen concanavalin A, vitamin E (10 μM) and with
different concentrations of the compounds 1 and 2 (0.1 to 10 μM).
Proliferation (MTT assay), IL-2, INFγ and IL-4 (Elisa kits),
intracellular superoxide anion were determined. 1 and 2 were
immunostimulant and increased cytokine secretion with a shift away
from Th1 response to Th2. These properties were however
accompanied by an increase in intracellular oxidative stress. The
presence of vitamin E exhibited protective effects by reducing δ-
lactam-induced superoxide anion generation in lymphocytes.
Abstract: In this paper, removal of chromium(VI) from aqueous
solution has been researched using reverse osmosis. The influence of
transmembrane pressure and feed concentration on permeate flux,
water recovery, permeate concentration, and salt rejection was
studied. The results showed that according to the variation of
transmembrane pressure and feed concentration, the permeate flux
and salt rejection were in the range 19.17 to 58.75 l/m2.min and
99.51 to 99.8 %, respectively. The highest permeate flux, 58.75
l/m2.min, and water recovery, 42.47 %, were obtained in the highest
pressure and the lowest feed concentration. On the other hand, the
lowest permeate concentration, 0.01 mg/l, and the highest salt
rejection, 99.8 %, were obtained in the highest pressure and the
lowest feed concentration.
Abstract: The objectives of this research are to produce
prototype coconut oil based solvent offset printing inks and to
analyze a basic quality of printing work derived from coconut oil
based solvent offset printing inks, by mean of bringing coconut oil
for producing varnish and bringing such varnish to produce black
offset printing inks. Then, analysis of qualities i.e. CIELAB value,
density value, and dot gain value of printing work from coconut oil
based solvent offset printing inks which printed on gloss-coated
woodfree paper weighs 130 grams were done. The research result of
coconut oil based solvent offset printing inks indicated that the
suitable varnish formulation is using 51% of coconut oil, 36% of
phenolic resin, and 14% of solvent oil 14%, while the result of
producing black offset ink displayed that the suitable formula of
printing ink is using varnish mixed with 20% of coconut oil, and the
analyzing printing work of coconut oil based solvent offset printing
inks which printed on paper, the results were as follows: CIELAB
value of black offset printing ink is at L* = 31.90, a* = 0.27, and b* =
1.86, density value is at 1.27 and dot gain value was high at mid tone
area of image area.
Abstract: Energetic and structural results for ethanol-water mixtures as a function of the mole fraction were calculated using Monte Carlo methodology. Energy partitioning results obtained for equimolar water-ethanol mixture and ether organic liquids are compared. It has been shown that at xet=0.22 the RDFs for waterethanol and ethanol-ethanol interactions indicated strong hydrophobic interactions between ethanol molecules and the local structure of solution is less structured at this concentration as at ether ones. Results obtained for ethanol-water mixture as a function of concentration are in good agreement with the experimental data.
Abstract: The present paper reports the removal of Cd(II) and
Zn(II) ions using synthetic Zeolit NaA. The adsorption capacity of
the sorbent (Zeolite NaA) strongly depends on simultaneous or not
simultaneous (concurrent) presence of Cd(II) and Zn(II) in the
sorbate. When Cd(II) and Zn(II) are present simultaneously
(concurrently) in the sorbate, Zn(II) ions were sorbed at higher rate.
Equilibrium data fitted Langmuir, Freundlich and Tempkin isotherms
well. The applicability of the isotherm equation to describe the
adsorption process was judged by the correlation coefficients R2. The
Langmuir model yielded the best fit with R2 values equal to or higher
than 0.970, as compared to the Freundlich and Tempkin models. The
fact that 1/n values range from 0.322 to 0.755 indicates that the
adsorption of Cd(II) and Zn(II) ions from aqueous solutions also
favored by the Freundlich model.
Abstract: Batch fermentation of 5, 10 and 25 g/L biodiesel
derived crude glycerol was carried out at 30, 37 and 450C by
Clostridium pasteurianum cells immobilized on silica. Maximum
yield of 1,3-propanediol (PDO) (0.60 mol/mol), and ethanol (0.26
mol/mol) were obtained from 10 g/L crude glycerol at 30 and 370C
respectively. Maximum yield of butanol (0.28 mol/mol substrate
added) was obtained at 370C with 25 g/L substrate. None of the three
products were detected at 45oC even after 10 days of fermentation.
Only traces of ethanol (0.01 mol/mol) were detected at 450C with 5
g/L substrate. The results obtained for 25 g/L substrate utilization
were fitted in first order rate equation to obtain the values of rate
constant at three different temperatures for bioconversion of glycerol.
First order rate constants for bioconversion of glycerol at 30, 37 and
45oC were found to be 0.198, 0.294 and 0.029/day respectively.
Activation energy (Ea) for crude glycerol bioconversion was
calculated to be 57.62 kcal/mol.
Abstract: Spherical shaped magnetite (Fe3O4) and Au@Fe3O4
nanoparticles were successfully synthesized from Fe electrodes
immersed in water with CTAB surfactant and HAuCl4 solution using
simple method-pulsed plasma in liquid, without the use of dopants or
special conditions for stabilization. Vibrating sample magnetometer
indicated ferromagnetic behavior of particles at room temperature with
coercivity and saturation magnetization of (Hc=105 Oe, Ms=6.83
emu/g) for Fe3O4 and (Hc=175, Ms=3.56emu/g) for Au@Fe3O4
nanoparticles. Structure and morphology of nanoparticles were
characterized by X-ray Diffraction analysis and HR-TEM
measurements. The cytotoxicity of nanoparticles was indicated using a
XTT assay to be very low (cell viability: 98-89% with Fe3O4 and
99-91% for Au@Fe3O4 NPs).
Abstract: Experimental liquid-liquid equilibra of butan-2-ol -
ethanol -water; pentan-1-ol - ethanol - water and toluene - acetone -
water ternary systems were investigated at (25oC). The reliability of
the experimental tie-line data was ascertained by using Othmer-Tobias
and Hand plots. The distribution coefficients (D) and separation
factors (S) of the immiscibility region were evaluated for the three
systems.
Abstract: In this work, several ASP solutions were flooded into
fractured models initially saturated with heavy oil at a constant flow
rate and different geometrical characteristics of fracture. The ASP
solutions are constituted from 2 polymers i.e. a synthetic polymer,
hydrolyzed polyacrylamide as well as a biopolymer, a surfactant and
2types of alkaline. The results showed that using synthetic
hydrolyzed polyacrylamide polymer increases ultimate oil recovery;
however, type of alkaline does not play a significant rule on oil
recovery. In addition, position of the injection well respect to the
fracture system has remarkable effects on ASP flooding. For instance
increasing angle of fractures with mean flow direction causes more
oil recovery and delays breakthrough time. This work can be
accounted as a comprehensive survey on ASP flooding which
considers most of effective factors in this chemical EOR method.
Abstract: Arvia®, a spin-out company of University of Manchester, UK is commercialising a water treatment technology for the removal of low concentrations of organics from water. This technology is based on the adsorption of organics onto graphite based adsorbents coupled with their electrochemical regeneration in a simple electrochemical cell. In this paper, the potential of the process to adsorb microorganisms and electrochemically disinfect them present in water has been demonstrated. Bench scale experiments have indicated that the process of adsorption using graphite adsorbents with electrochemical regeneration can be used for water disinfection effectively. The most likely mechanisms of disinfection of water through this process include direct electrochemical oxidation and electrochemical chlorination.
Abstract: The results of the two-phase gas-solid jet in pneumatic
powder injection process analysis were presented in the paper. The
researches were conducted on model set-up with high speed camera
jet movement recording. Then the recorded material was analyzed to
estimate main particles movement parameters. The values obtained
from this direct measurement were compared to those calculated with
the use of the well-known formulas for the two-phase flows
(pneumatic conveying). Moreover, they were compared to
experimental results previously achieved by authors. The analysis led
to conclusions which to some extent changed the assumptions used
even by authors, regarding the two-phase jet in pneumatic powder
injection process. Additionally, the visual analysis of the recorded
clips supplied data to make a more complete evaluation of the jet
behavior in the lance outlet than before.
Abstract: In the present study, a procedure was developed to
determine the optimum reaction rate constants in generalized
Arrhenius form and optimized through the Nelder-Mead method. For
this purpose, a comprehensive mathematical model of a fixed bed
reactor for dehydrogenation of heavy paraffins over Pt–Sn/Al2O3
catalyst was developed. Utilizing appropriate kinetic rate expressions
for the main dehydrogenation reaction as well as side reactions and
catalyst deactivation, a detailed model for the radial flow reactor was
obtained. The reactor model composed of a set of partial differential
equations (PDE), ordinary differential equations (ODE) as well as
algebraic equations all of which were solved numerically to
determine variations in components- concentrations in term of mole
percents as a function of time and reactor radius. It was demonstrated
that most significant variations observed at the entrance of the bed
and the initial olefin production obtained was rather high. The
aforementioned method utilized a direct-search optimization
algorithm along with the numerical solution of the governing
differential equations. The usefulness and validity of the method was
demonstrated by comparing the predicted values of the kinetic
constants using the proposed method with a series of experimental
values reported in the literature for different systems.
Abstract: The mechanism of microwave heating is essentially
that of dielectric heating. After exposing the emulsion to the
microwave Electromagnetic (EM) field, molecular rotation and ionic
conduction due to the penetration of (EM) into the emulsion are
responsible for the internal heating. To determine the capability of
microwave technology in demulsification of crude oil emulsions,
microwave demulsification method was applied in a 50-50 % and 20-
80 % water-in-oil emulsions with microwave exposure time varied
from 20-180 sec. Transient temperature profiles of water-in-oil
emulsions inside a cylindrical container were measured. The
temperature rise at a given location was almost horizontal (linear).
The average rates of temperature increase of 50-50 % and 20-80 %
water-in-oil emulsions are 0.351 and 0.437 oC/sec, respectively. The
rate of temperature increase of emulsions decreased at higher
temperature due to decreasing dielectric loss of water. These results
indicate that microwave demulsification of water-in-oil emulsions
does not require chemical additions. Microwave has the potential to
be used as an alternative way in the demulsification process.
Abstract: In this study, production possibilities of hydrogen and/or methane via SCWG from black grape residues have been investigated. For this aim, grape residues which remain as a byproduct of the wine making process have been used. Since utilization from grape residues is limited due to the high moisture content, supercritical water gasification is the most convenient method. The effect of the gasification temperature and type of catalyst on supercritical water gasification have been investigated. Gasification experiments were performed in a batch autoclave at four different temperatures 300, 400, 500 and 600°C. K2CO3 and Trona (NaHCO3.Na2CO3·2H2O) were used as catalyst. Real biomass types of black grape residues have been successfully gasified and the product gas (hydrogen, methane, carbon dioxide, carbon monoxide and a small amount of ethane and ethylene) were identified by using gas chromatography. A TOC analyzer was used to determine total organic carbon (TOC) content of aqueous phase. The amounts of carboxylic acids, aldehydes, ketones, furfurals and phenols present in the aqueous solutions were analyzed by high performance liquid chromatography. When the temperature increased from 300°C to 600°C, mol% of H2 in gas products increased. The presence of catalysts improves the hydrogen yield. Trona showed gasification activity to be similar to that of K2CO3. It may be concluded that the use of Trona instead of commercially produced catalysts, can be preferably used in the gasification of biomass in supercritical water.
Abstract: Natural gas is defined as gas obtained from a natural underground reservoir. It generally contains a large quantity of methane along with heavier hydrocarbons such as ethane, propane, isobutene, normal butane; also in the raw state it often contains a considerable amount of non hydrocarbons, such as nitrogen and the acid gases (carbon dioxide and hydrogen sulfide). The acid gases must be removed from natural gas before use. One of the processes witch are use in the industry to remove the acid gases from natural gas is the use of alkanolamine process. In this present paper, a simulation study for an industrial gas sweetening plant has been investigated. The aim of the study is to investigate the effect of using mixing amines as solvent on the gas treatment process using the software Hysys.
Abstract: An artificial neural network (ANN) model is
presented for the prediction of kinematic viscosity of binary mixtures
of poly (ethylene glycol) (PEG) in water as a function of temperature,
number-average molecular weight and mass fraction. Kinematic
viscosities data of aqueous solutions for PEG (0.55419×10-6 –
9.875×10-6 m2/s) were obtained from the literature for a wide range
of temperatures (277.15 - 338.15 K), number-average molecular
weight (200 -10000), and mass fraction (0.0 – 1.0). A three layer
feed-forward artificial neural network was employed. This model
predicts the kinematic viscosity with a mean square error (MSE) of
0.281 and the coefficient of determination (R2) of 0.983. The results
show that the kinematic viscosity of binary mixture of PEG in water
could be successfully predicted using an artificial neural network
model.
Abstract: In this work, the precipitation of asphaltene from a Malaysian light oil reservoir was studies. A series of experiments were designed and carried out to examine the effect of CO2 injection on asphaltene precipitation. Different pressures of injections were used in Dynamic flooding experiment in order to investigate the effect of pressure versus injection pore volume of CO2. These dynamic displacement tests simulate reservoir condition. Results show that by increasing the pore volume of injected gas asphaltene precipitation will increases, also rise in injection pressure causes less precipitation. Sandstone core plug was used to represent reservoir formation during displacement test; therefore it made it possible to study the effect of present of asphaltene on formation. It is found out that the precipitated asphaltene can reduce permeability and porosity which is not favorable during oil production.
Abstract: A kinetic model for propane dehydrogenation in an
industrial moving bed reactor is developed based on the reported
reaction scheme. The kinetic parameters and activity constant are
fine tuned with several sets of balanced plant data. Plant data at
different operating conditions is applied to validate the model and
the results show a good agreement between the model
predictions and plant observations in terms of the amount of main
product, propylene produced. The simulation analysis of key
variables such as inlet temperature of each reactor (Tinrx) and
hydrogen to total hydrocarbon ratio (H2/THC) affecting process
performance is performed to identify the operating condition to
maximize the production of propylene. Within the range of operating
conditions applied in the present studies, the operating condition to
maximize the propylene production at the same weighted average
inlet temperature (WAIT) is ΔTinrx1= -2, ΔTinrx2= +1, ΔTinrx3= +1 ,
ΔTinrx4= +2 and ΔH2/THC= -0.02. Under this condition, the surplus
propylene produced is 7.07 tons/day as compared with base case.
Abstract: This paper describes a one-dimensional numerical model for natural gas production from the dissociation of methane hydrate in hydrate-capped gas reservoir under depressurization and thermal stimulation. Some of the hydrate reservoirs discovered are overlying a free-gas layer, known as hydrate-capped gas reservoirs. These reservoirs are thought to be easiest and probably the first type of hydrate reservoirs to be produced. The mathematical equations that can be described this type of reservoir include mass balance, heat balance and kinetics of hydrate decomposition. These non-linear partial differential equations are solved using finite-difference fully implicit scheme. In the model, the effect of convection and conduction heat transfer, variation change of formation porosity, the effect of using different equations of state such as PR and ER and steam or hot water injection are considered. In addition distributions of pressure, temperature, saturation of gas, hydrate and water in the reservoir are evaluated. It is shown that the gas production rate is a sensitive function of well pressure.
Abstract: Prediction of benzene transport in soil and volatilization from soil to the atmosphere is important for the preservation of human health and management of contaminated soils. The adequacy of a simple numerical model, assuming two-phase diffusion and equilibrium of liquid/solid adsorption, was investigated by experimental data of benzene concentration in a flux chamber (with headspace) where Andosol and sand were filled. Adsorption experiment for liquid phase was performed to determine an adsorption coefficient. Furthermore, adequacy of vapor phase adsorption was also studied through two runs of experiment using sand with different water content. The results show that the model adequately predicted benzene transport and volatilization from Andosol and sand with water content of 14.0%. In addition, the experiment additionally revealed that vapor phase adsorption should be considered in diffusion model for sand with very low water content.