Abstract: A water treatment technology employing the adsorption of dissolved organic contaminants from water and their electrochemical regeneration has been commercialized by Arvia Technology Ltd, UK. This technology focuses the adsorption of pollutants onto the surface of low surface area graphite based adsorbents followed by the anodic oxidation of adsorbed species in an electrochemical cell. However, some of the adsorbed species may lead to the formation of intermediate breakdown products due to incomplete oxidation. The information regarding the formation of breakdown products during electrochemical regeneration of these adsorbents is important for the effective application of this process to water treatment. In the present paper, the formation of the break down products during electrochemical regeneration of various graphite based adsorbents has been demonstrated.
Abstract: Intercalation imparts interesting features to the host graphite material. Two different types of intercalated compounds called (GIC-bisulphate or Nyex 1000 and GIC-nitrate or Nyex 3000) were tested for their adsorption capacity and ability to undergo electrochemical regeneration. It was found that Nyex 3000 showed comparatively slow kinetics along with reduced adsorption capacity to one half for acid violet 17 as adsorbate. Acid violet 17 was selected as model organic pollutant for evaluating comparative performance of said adsorbents. Both adsorbent materials showed 100% regeneration efficiency as achieved by passing a charge of 36 C g-1 at a current density of 12 mA cm-2 and a treatment time of 60 min.
Abstract: A unique combination of adsorption and
electrochemical regeneration with a proprietary adsorbent material
called Nyex 100 was introduced at the University of Manchester for
waste water treatment applications. Nyex 100 is based on graphite
intercalation compound. It is non porous and electrically conducing
adsorbent material. This material exhibited very small BET surface
area i.e. 2.75 m2g-1, in consequence, small adsorptive capacities for
the adsorption of various organic pollutants were obtained. This work
aims to develop composite adsorbent material essentially capable of
electrochemical regeneration coupled with improved adsorption
characteristics. An organic dye, acid violet 17 was used as standard
organic pollutant. The developed composite material was
successfully electrochemically regenerated using a DC current of 1 A
for 60 minutes. Regeneration efficiency was maintained at around
100% for five adsorption-regeneration cycles.
Abstract: Arvia®, a spin-out company of University of Manchester, UK is commercialising a water treatment technology for the removal of low concentrations of organics from water. This technology is based on the adsorption of organics onto graphite based adsorbents coupled with their electrochemical regeneration in a simple electrochemical cell. In this paper, the potential of the process to adsorb microorganisms and electrochemically disinfect them present in water has been demonstrated. Bench scale experiments have indicated that the process of adsorption using graphite adsorbents with electrochemical regeneration can be used for water disinfection effectively. The most likely mechanisms of disinfection of water through this process include direct electrochemical oxidation and electrochemical chlorination.