Abstract: Water is essential for life and fresh water is a finite
resource that is becoming scarce day by day even though it is
recycled by hydrological cycle. The fresh water reserves are being
polluted due to expanding irrigation, industries, urban population and
its development. Contaminated water leads to several health
problems. With the increasing demand of fresh water, solar
distillation is an alternate solution which uses solar energy to
evaporate water and then to condense it, thereby collecting distilled
water within or outside the same system to use it as potable water.
The structure that houses the process is known as a 'solar still'. In this
paper, ‘Modified double slope solar still (MDSSS)’ & 'Modified
double slope basin type multiwick solar still (MDSBMSS)' have been
designed to convert saline, brackish water into drinking water. In this
work two different modified solar stills are fabricated to study the
performance of these solar stills. For modification of solar stills,
Fibre Reinforced Plastic (FRP) and Acrylic sheets are used. The
experiments in MDSBMSS and MDSSS was carried on 10
September 2015 & 5 November 2015 respectively. Performances of
the stills were investigated. The amount of distillate has been found
3624 Ml/day in MDSBMSS on 10 September 2015 and 2400 Ml/day
in MDSSS on 5 November 2015.
Abstract: This work studies the effect of thickness on structural
and electrical properties of CuAlS2 thin films grown by two stage
vacuum thermal evaporation technique. CuAlS2 thin films of
thicknesses 50nm, 100nm and 200nm were deposited on suitably
cleaned corning 7059 glass substrate at room temperature (RT). In
the first stage Cu-Al precursors were grown at room temperature by
thermal evaporation and in the second stage Cu-Al precursors were
converted to CuAlS2 thin films by sulfurisation under sulfur
atmosphere at the temperature of 673K. The structural properties of
the films were examined by X-ray diffraction (XRD) technique while
electrical properties of the specimens were studied using four point
probe method. The XRD studies revealed that the films are of
crystalline in nature having tetragonal structure. The variations of the
micro-structural parameters, such as crystallite size (D), dislocation
density ( ), and micro-strain ( ), with film thickness were
investigated. The results showed that the crystallite sizes increase as
the thickness of the film increases. The dislocation density and
micro-strain decreases as the thickness increases. The resistivity ( )
of CuAlS2 film is found to decrease with increase in film thickness,
which is related to the increase of carrier concentration with film
thickness. Thus thicker films exhibit the lowest resistivity and high
carrier concentration, implying these are the most conductive films.
Low electrical resistivity and high carrier concentration are widely
used as the essential components in various optoelectronic devices
such as light-emitting diode and photovoltaic cells.
Abstract: We investigate the performance of an integrated cascade (IC) refrigeration system which uses environment friendly zeotropic mixtures. Computational calculation has been carried out by varying pressure level at the evaporator and the condenser of the system. Effects of mass flow rate of the refrigerant on the coefficient of performance (COP) are presented. We show that the integrated cascade system produces ultra-low temperatures in the evaporator by using environment friendly zeotropic mixture.
Abstract: The combination of multi–walled carbon nanotubes
(MWCNTs) with polymers offers an attractive route to reinforce the
macromolecular compounds as well as the introduction of new
properties based on morphological modifications or electronic
interactions between the two constituents. As they are only a few
nanometers in dimension, it offers ultra-large interfacial area per
volume between the nano-element and polymer matrix. Nevertheless,
the use of MWCNTs as a rough material in different applications has
been largely limited by their poor processability, insolubility, and
infusibility. Studies concerning the nanofiller reinforced polymer
composites are justified in an attempt to overcome these limitations.
This work presents one preliminary study of MWCNTs dispersion
into the PVDF homopolymer. For preparation, the composite
components were diluted in n,n-dimethylacetamide (DMAc) with
mechanical agitation assistance. After complete dilution, followed by
slow evaporation of the solvent at 60°C, the samples were dried.
Films of about 80 μm were obtained. FTIR and UV-Vis
spectroscopic techniques were used to characterize the
nanocomposites. The appearance of absorption bands in the FTIR
spectra of nanofilled samples, when compared to the spectrum of
pristine PVDF samples, are discussed and compared with the UV-Vis
measurements.
Abstract: The beginning of 21st century has witnessed new
advancements in the design and use of new materials for biosensing
applications, from nano to macro, protein to tissue. Traditional
analytical methods lack a complete toolset to describe the
complexities introduced by living systems, pathological relations,
discrete hierarchical materials, cross-phase interactions, and
structure-property dependencies. Materiomics – via systematic
molecular dynamics (MD) simulation – can provide structureprocess-
property relations by using a materials science approach
linking mechanisms across scales and enables oriented biosensor
design. With this approach, DNA biosensors can be utilized to detect
disease biomarkers present in individuals’ breath such as acetone for
diabetes. Our wireless sensor array based on single-stranded DNA
(ssDNA)-decorated single-walled carbon nanotubes (SWNT) has
successfully detected trace amount of various chemicals in vapor
differentiated by pattern recognition. Here, we present how MD
simulation can revolutionize the way of design and screening of DNA
aptamers for targeting biomarkers related to oral diseases and oral
health monitoring. It demonstrates great potential to be utilized to
build a library of DNDA sequences for reliable detection of several
biomarkers of one specific disease, and as well provides a new
methodology of creating, designing, and applying of biosensors.
Abstract: Concrete is an essential building material which is
widely used in construction industry all over the world due to its
compressible strength. Curing of concrete plays a vital role in
durability and other performance necessities. Improper curing can
affect the concrete performance and durability easily. When areas
like scarcity of water, structures is not accessible by humans external
curing cannot be performed, so we opt for internal curing. Internal
curing (or) self curing plays a major role in developing the concrete
pore structure and microstructure. The concept of internal curing is to
enhance the hydration process to maintain the temperature uniformly.
The evaporation of water in the concrete is reduced by self curing
agent (Super Absorbing Polymer – SAP) there by increasing the
water retention capacity of the concrete. The research work was
carried out to reduce water, which is prime material used for concrete
in the construction industry. Concrete curing plays a major role in
developing hydration process. Concept of self curing will reduce the
evaporation of water from concrete. Self curing will increase water
retention capacity as compared to the conventional concrete. Proper
self curing (or) internal curing increases the strength, durability and
performance of concrete. Super absorbing Polymer (SAP) used as
internal curing agent. In this study 0.2% to 0.4% of SAP was varied
in different grade of high strength concrete. In the experiment
replacement of cement by silica fumes with 5%, 10% and 15% are
studied. It is found that replacement of silica fumes by 10 % gives
more strength and durability when compared to others.
Abstract: Searching the “Island of stability” is a topic of
extreme interest in theoretical as well as experimental modern
physics today. This “island of stability” is spanned by superheavy
elements (SHE's) that are produced in the laboratory. SHE's are
believed to exist primarily due to the “magic” stabilizing effects of
nuclear shell structure. SHE synthesis is extremely difficult due to
their very low production cross section, often of the order of pico
barns or less. Stabilizing effects of shell closures at proton number
Z=82 and neutron number N=126 are predicted theoretically. Though
stabilizing effects of Z=82 have been experimentally verified, no
concluding observations have been made with N=126, so far. We
measured and analyzed the total evaporation residue (ER) cross
sections for a number of systems with neutron number around 126 to
explore possible shell closure effects in ER cross sections, in this
work.
Abstract: The transesterification of dimethyl malonate (DMM)
with phenol has been studied in vapour phase over cordierite
honeycomb coated with solid acid catalysts such as ZrO2,
Mo(VI)/ZrO2 and SO42-/ZrO2. The catalytic materials were prepared
honeycomb coated, powder forms, and characterized for their total
surface acidity by NH3-TPD and crystalinity by powder XRD
methods. Phenyl methyl malonate (PMM) and diphenyl malonate
(DPM) were obtained as the reaction products. A good conversion of
DMM (up to 82%) of MPM with 95% selectivity was observed when
the reactions were carried out at a catalyst bed temperature of 200 °C
and flow-rate of 10 mL/h in presence of Mo(VI)/ZrO2 as catalyst.
However, over SO4^2-/ZrO2 catalyst, the yield of DPM was found to be
higher. The results have been interpreted based on the variation of
acidic properties and powder XRD phases of zirconia on
incorporation of Mo(VI) or SO42– ions. Transesterification reactions
were also carried out over powder forms of the catalytic materials
and the yield of the desired phenyl ester products were compared
with that of the HC coated catalytic materials. The solid acids were
found to be reusable when used for at least 5 reaction cycles.
Abstract: The 1:1 cocrystal of 2-amino-4-chloro-6-
methylpyrimidine (2A4C6MP) with 4-methylbenzoic acid (4MBA)
(I) has been prepared by slow evaporation method in methanol,
which was crystallized in monoclinic C2/c space group, Z = 8, and a
= 28.431 (2) Å, b = 7.3098 (5) Å, c = 14.2622 (10) Å and β =
109.618 (3)°. The presence of unionized –COOH functional group in
cocrystal I was identified both by spectral methods (1H and 13C
NMR, FTIR) and X-ray diffraction structural analysis. The
2A4C6MP molecule interact with the carboxylic group of the
respective 4MBA molecule through N—H⋯O and O—H⋯N
hydrogen bonds, forming a cyclic hydrogen–bonded motif R2
2(8).
The crystal structure was stabilized by Npyrimidine—H⋯O=C and
C=O—H⋯Npyrimidine types hydrogen bonding interactions.
Theoretical investigations have been computed by HF and density
function (B3LYP) method with 6–311+G (d,p)basis set. The
vibrational frequencies together with 1H and 13C NMR chemical
shifts have been calculated on the fully optimized geometry of
cocrystal I. Theoretical calculations are in good agreement with the
experimental results. Solvent–free formation of this cocrystal I is
confirmed by powder X-ray diffraction analysis.
Abstract: Within this paper, latest results on processing of energetic nanomaterials by means of the Spray Flash Evaporation technique are presented. This technology constitutes a highly effective and continuous way to prepare fascinating materials on the nano- and micro-scale. Within the process, a solution is set under high pressure and sprayed into an evacuated atomization chamber. Subsequent ultrafast evaporation of the solvent leads to an aerosol stream, which is separated by cyclones or filters. No drying gas is required, so the present technique should not be confused with spray dying. Resulting nanothermites, insensitive explosives or propellants and compositions are foreseen to replace toxic (according to REACH) and very sensitive matter in military and civil applications. Diverse examples are given in detail: nano-RDX (n-Cyclotrimethylentrinitramin) and nano-aluminum based systems, mixtures (n-RDX/n-TNT - trinitrotoluene) or even cocrystalline matter like n-CL-20/HMX (Hexanitrohexaazaisowurtzitane/ Cyclotetra-methylentetranitramin). These nanomaterials show reduced sensitivity by trend without losing effectiveness and performance. An analytical study for material characterization was performed by using Atomic Force Microscopy, X-Ray Diffraction, and combined techniques as well as spectroscopic methods. As a matter of course, sensitivity tests regarding electrostatic discharge, impact, and friction are provided.
Abstract: In this study, the three-dimensional cavitating
turbulent flow in a complete Francis turbine is simulated using
mixture model for cavity/liquid two-phase flows. Numerical analysis
is carried out using ANSYS CFX software release 12, and standard k-ε
turbulence model is adopted for this analysis. The computational
fluid domain consist of spiral casing, stay vanes, guide vanes, runner
and draft tube. The computational domain is discretized with a threedimensional
mesh system of unstructured tetrahedron mesh. The
finite volume method (FVM) is used to solve the governing equations
of the mixture model. Results of cavitation on the runner’s blades
under three different boundary conditions are presented and
discussed. From the numerical results it has been found that the
numerical method was successfully applied to simulate the cavitating
two-phase turbulent flow through a Francis turbine, and also
cavitation is clearly predicted in the form of water vapor formation
inside the turbine. By comparison the numerical prediction results
with a real runner; it’s shown that the region of higher volume
fraction obtained by simulation is consistent with the region of runner
cavitation damage.
Abstract: People, throughout the history, have made estimates
and inferences about the future by using their past experiences.
Developing information technologies and the improvements in the
database management systems make it possible to extract useful
information from knowledge in hand for the strategic decisions.
Therefore, different methods have been developed. Data mining by
association rules learning is one of such methods. Apriori algorithm,
one of the well-known association rules learning algorithms, is not
commonly used in spatio-temporal data sets. However, it is possible
to embed time and space features into the data sets and make Apriori
algorithm a suitable data mining technique for learning spatiotemporal
association rules. Lake Van, the largest lake of Turkey, is a
closed basin. This feature causes the volume of the lake to increase or
decrease as a result of change in water amount it holds. In this study,
evaporation, humidity, lake altitude, amount of rainfall and
temperature parameters recorded in Lake Van region throughout the
years are used by the Apriori algorithm and a spatio-temporal data
mining application is developed to identify overflows and newlyformed
soil regions (underflows) occurring in the coastal parts of
Lake Van. Identifying possible reasons of overflows and underflows
may be used to alert the experts to take precautions and make the
necessary investments.
Abstract: Wicking and evaporation of water in porous knitted fabrics is investigated by combining experimental and analytical approaches: The standard wicking model from Lucas and Washburn is enhanced to account for evaporation and gravity effects. The goal is to model the effect of gravity and evaporation on wicking using simple analytical expressions and investigate the influence of fabrics geometrical parameters, such as porosity and thickness on evaporation impact on maximum reachable height values. The results show that fabric properties have a significant influence on evaporation effect. In this paper, an experimental study of determining water kinetics from different knitted fabrics were gravimetrically investigated permitting the measure of the mass and the height of liquid rising in fabrics in various atmospheric conditions. From these measurements, characteristic pore parameters (capillary radius and permeability) can be determined.
Abstract: An industrial system for the production of white
liquor of a paper industry, Klabin Paraná Papéis, formed by ten
reactors was modeled, simulated, and analyzed. The developed model
considered possible water losses by evaporation and reaction, in
addition to variations in volumetric flow of lime mud across the
reactors due to composition variations. The model predictions agreed
well with the process measurements at the plant and the results
showed that the slaking reaction is nearly complete at the third
causticizing reactor, while causticizing ends by the seventh reactor.
Water loss due to slaking reaction and evaporation occurs more
pronouncedly in the slaking reaction than in the final causticizing
reactors; nevertheless, the lime mud flow remains nearly constant
across the reactors.
Abstract: This paper reports on the response of a fiber-optic
sensing probe to small concentrations of hydrogen peroxide (H2O2)
vapor at room temperature. H2O2 has extensive applications in industrial and medical
environments. Conversely, H2O2 can be a health hazard by itself. For
example, H2O2 induces cellular damage in human cells and its
presence can be used to diagnose illnesses such as asthma and human
breast cancer. Hence, development of reliable H2O2 sensor is of vital
importance to detect and measure this species. Ferric ferrocyanide, referred to as Prussian Blue (PB), was
deposited on the tip of a multimode optical fiber through the single
source precursor technique and served as an indicator of H2O2 in a
spectroscopic manner. Sensing tests were performed in H2O2-H2O
vapor mixtures with different concentrations of H2O2. The results of sensing tests show the sensor is able to detect H2O2
concentrations in the range of 50.6 ppm to 229.5 ppm. Furthermore,
the sensor response to H2O2 concentrations is linear in a log-log scale
with the adjacent R-square of 0.93. This sensing behavior allows us
to detect and quantify the concentration of H2O2 in the vapor phase.
Abstract: This study intends to show the influence of the
hydrolytic degradation on the properties of the e-PTFE/NOMEX®
membranes used in fire-protective clothing. The modification of
water vapour permeability, morphology and chemical structure was
examined by MOCON Permatran, electron microscopy scanning
(SEM), and ATR-FTIR, respectively. A decrease in permeability to
water vapour of the aged samples was observed following closure of
transpiration pores. Analysis of fiber morphology indicates the
appearance of defects at the fibers surface with the presence of micro
cavities. ATR-FTIR analysis reveals the presence of a new absorption
band attributed to carboxylic acid terminal groups generated during
the amide bond hydrolysis.
Abstract: Determination of genetic variation is useful for plant
breeding and hence production of more efficient plant species under
different conditions, like drought stress. In this study a sample of 28
recombinant inbred lines (RILs) of wheat developed from the cross of
Norstar and Zagross varieties, together with their parents, were
evaluated for two years (2010-2012) under normal and water stress
conditions using split plot design with three replications. Main plots
included two irrigation treatments of 70 and 140 mm evaporation
from Class A pan and sub-plots consisted of 30 genotypes. The effect
of genotypes and interaction of genotypes with years and water
regimes were significant for all characters. Significant genotypic
effect implies the existence of genetic variation among the lines
under study. Heritability estimates were high for 1000 grain weight
(0.87). Biomass and grain yield showed the lowest heritability values
(0.42 and 0.50, respectively). Highest genotypic and phenotypic
coefficients of variation (GCV and PCV) belonged to harvest index.
Moderate genetic advance for most of the traits suggested the
feasibility of selection among the RILs under investigation. Some
RILs were higher yielding than either parent at both environments.
Abstract: Liquid-Liquid Equilibrium (LLE) data are measured
for the ternary mixtures of water + 1-butanol + butyl acetate and
quaternary mixtures of water + 1-butanol + butyl acetate + glycerol at
atmospheric pressure at 313.15 K. In addition, isothermal
vapor–liquid–liquid equilibrium (VLLE) data are determined
experimentally at 333.15 K. The region of heterogeneity is found to
increase as the hydrophilic agent (glycerol) is introduced into the
aqueous mixtures. The experimental data are correlated with the
NRTL model. The predicted results from the solution model with the
model parameters determined from the constituent binaries are also
compared with the experimental values.
Abstract: The development of electric vehicle batteries have
resulted in very high energy density lithium-ion batteries. However,
this progress is accompanied by the risk of thermal runaway, which
can result in serious accidents. Heat pipes are heat exchangers that
are suitable to be applied in electric vehicle battery thermal
management for their lightweight, compact size and do not require
external power supply. This paper aims to examine experimentally a
Flat Plate Loop Heat Pipe (FPLHP) performance as a heat exchanger
in thermal management system of lithium-ion battery for electric
vehicle application. The heat generation of the battery was simulated
using a cartridge heater. Stainless steel screen mesh was used as the
capillary wick. Distilled water, alcohol and acetone were used as
working fluids with a filling ratio of 60%. It was found that acetone
gives the best performance that produces thermal resistance of 0.22
W/°C with 50°C evaporator temperature at heat flux load of 1.61
W/cm2.
Abstract: These Monolayer and multilayer coatings of CrN and
AlCrN deposited on 100Cr6 (AISI 52100) substrate by PVD
magnetron sputtering system. The microstructures of the coatings
were characterized using atomic force microscopy (AFM). The AFM
analysis revealed the presence of domes and craters that are
uniformly distributed over all surfaces of the various layers.
Nanoindentation measurement of CrN coating showed maximum
hardness (H) and modulus (E) of 14 GPa and 190 GPa, respectively.
The measured H and E values of AlCrN coatings were found to be 30
GPa and 382 GPa, respectively. The improved hardness in both the
coatings was attributed mainly to a reduction in crystallite size and
decrease in surface roughness. The incorporation of Al into the CrN
coatings has improved both hardness and Young’s modulus.