Abstract: The aim of this study was to synthesize the single
walled carbon nanotubes (SWCNTs) and determine their hydrogen
storage capacities. SWCNTs were firstly synthesized by chemical
vapor deposition (CVD) of acetylene (C2H2) on a magnesium oxide
(MgO) powder impregnated with an iron nitrate (Fe(NO3)3·9H2O)
solution. The synthesis parameters were selected as: the synthesis
temperature of 800°C, the iron content in the precursor of 5% and the
synthesis time of 30 min. Purification process of SWCNTs was
fulfilled by microwave digestion at three different temperatures (120,
150 and 200 °C), three different acid concentrations (0.5, 1 and 1.5
M) and for three different time intervals (15, 30 and 60 min). Nitric
acid (HNO3) was used in the removal of the metal catalysts. The
hydrogen storage capacities of the purified materials were measured
using volumetric method at the liquid nitrogen temperature and gas
pressure up to 100 bar. The effects of the purification conditions such
as temperature, time and acid concentration on hydrogen adsorption
were investigated.
Abstract: Snow cover is an important phenomenon in
hydrology, hence modeling the snow accumulation and melting is an
important issue in places where snowmelt significantly contributes to
runoff and has significant effect on water balance. The physics-based
models are invariably distributed, with the basin disaggregated into
zones or grid cells. Satellites images provide valuable data to verify
the accuracy of spatially distributed model outputs. In this study a
spatially distributed physically based model (WetSpa) was applied to
predict snow cover and melting in the Latyan dam watershed in Iran.
Snowmelt is simulated based on an energy balance approach. The
model is applied and calibrated with one year of observed daily
precipitation, air temperature, windspeed, and daily potential
evaporation. The predicted snow-covered area is compared with
remotely sensed images (MODIS). The results show that simulated
snow cover area SCA has a good agreement with satellite image
snow cover area SCA from MODIS images. The model performance
is also tested by statistical and graphical comparison of simulated and
measured discharges entering the Latyan dam reservoir.
Abstract: In this study, the conversion of n-pentane to aromatics is investigated on HZSM-5 zeolites modified by Ga ion-exchange and silylation using tetraethyl orthosilicate (TEOS) via chemical liquid deposition (CLD). The effect of SiO2/Al2O3 ratios of HZSM-5 was also studied. Parameters in preparing catalysts i.e. TEOS loading and cycles of deposition were varied to obtain the optimal condition for enhancing p-xylene selectivity. The highest p-xylene selectivity 99.7% was achieved when the amount of TEOS was 20 vol.%.The catalysts were characterized by TPD, TPO, XRF, and BET. Results show that the conversion of n-pentane was influenced remarkably by the SiO2/Al2O3 ratios of HZSM-5. The highest p-xylene selectivity 99.7% was achieved when the amount of TEOS was 20 vol.%. And cycles of deposition greatly improves HZSM-5 shape-selectivity.
Abstract: This research were investigated, determined, and
analyzed of the climate characteristically change in the provincial
Udon Thani in the period of 60 surrounding years from 1951 to 2010
A.D. that it-s transferred to effects of climatologically data for
determining global warming. Statistically significant were not found
for the 60 years- data (R2
Abstract: In this study, direct numerical simulation for the bubble condensation in the subcooled boiling flow was performed. The main goal was to develop the CFD modeling for the bubble condensation and to evaluate the accuracy of the VOF model with the developed CFD modeling. CFD modeling for the bubble condensation was developed by modeling the source terms in the governing equations of VOF model using UDF. In the modeling, the amount of condensation was determined using the interfacial heat transfer coefficient obtained from the bubble velocity, liquid temperature and bubble diameter every time step. To evaluate the VOF model using the CFD modeling for the bubble condensation, CFD simulation results were compared with SNU experimental results such as bubble volume and shape, interfacial area, bubble diameter and bubble velocity. Simulation results predicted well the behavior of the actual condensing bubble. Therefore, it can be concluded that the VOF model using the CFD modeling for the bubble condensation will be a useful computational fluid dynamics tool for analyzing the behavior of the condensing bubble in a wide range of the subcooled boiling flow.
Abstract: This paper presents the climatic range calculations for
comfort evaporative cooling for Tehran. In this study the minimum
climatic conditions required to achieve an appropriate comfort zone
will be presented.
Physiologically uncomfortable conditions in arid climates are
mainly caused by the extreme heat and dryness. Direct evaporative
cooling adds moisture to the air stream until the air stream is close to
saturation. The dry bulb temperature is reduced, while the wet bulb
temperature stays the same. Evaporative cooling is economical,
effective, environmentally friendly, and healthy.
Comfort cooling by direct evaporative cooling (passive or fan
forced) in the 35. 41 N (such as Tehran) latitude requires design
wet-bulb temperature not over 25.4 C. Evaporative cooling outside
this limit cannot achieve the required 26.7 ET, and is recommended
for relief cooling only.
Abstract: The present work deals with thermodynamic analysis
of cascade refrigeration system using ozone friendly refrigerants pair
R507A and R23. R507A is azeotropic mixture composed of HFC
refrigerants R125/R143a (50%/50% wt.). R23 is a single component
HFC refrigerant used as replacement to CFC refrigerant R13 in low
temperature applications. These refrigerants have zero ozone
depletion potential and are non-flammable and as R507A an
azeotropic mixture there is no problem of temperature glide. This
study thermodynamically analyzed R507A-R23 cascade refrigeration
system to optimize the design and operating parameters of the
system. The design and operating parameters include: Condensing,
evaporating, subcooling and superheating temperatures in the high
temperature circuit, temperature difference in the cascade heat
exchanger, Condensing, evaporating, subcooling and superheating
temperatures in the low temperature circuit.
Abstract: Capacity and efficiency of any refrigerating system
diminish rapidly as the difference between the evaporating and
condensing temperature is increased by reduction in the evaporator
temperature. The single stage vapour compression refrigeration
system is limited to an evaporator temperature of -40 0C. Below
temperature of -40 0C the either cascade refrigeration system or multi
stage vapour compression system is employed. Present work
describes thermal design of main three heat exchangers namely
condenser (HTS), cascade condenser and evaporator (LTS) of
R404A-R508B and R410A-R23 cascade refrigeration system. Heat
transfer area of condenser (HTS), cascade condenser and evaporator
(LTS) for both systems have been compared and the effect of
condensing and evaporating temperature on heat-transfer area for
both systems have been studied under same operating condition. The
results shows that the required heat-transfer area of condenser and
cascade condenser for R410A-R23 cascade system is lower than the
R404A-R508B cascade system but heat transfer area of evaporator is
similar for both the system. The heat transfer area of condenser and
cascade condenser decreases with increase in condensing temperature
(Tc), whereas the heat transfer area of cascade condenser and
evaporator increases with increase in evaporating temperature (Te).
Abstract: In order to investigate water deficit stress on 24 of
soybean (Glycine Max. L) cultivars and lines in temperate climate, an
experiment was conducted in Iran Seed and Plant Improvement
Institute. Stress levels were irrigation after evaporation of 50, 100,
150 mm water from pan, class A. Randomized Completely Block
Design was arranged for each stress levels. Some traits such as, node
number, plant height, pod number per area, grain number per pod,
grain number per area, 1000 grains weight, grain yield and harvest
index were measured. Results showed that water deficit stress had
significant effect on node number, plant height, pod number per area,
grain number per pod, grain number per area, 1000 grains weight and
harvest index. Also all of agronomic traits except harvest index
influenced significantly by cultivars and lines. The least and most
grain yield was belonged to Ronak X Williams and M41 x Clark
respectively.
Abstract: This paper discuss the separation of the miscible
liquids by means of fractional distillation. For complete separation of
liquids, the process of heating, condensation, separation and storage
is done automatically to achieve the objective. PIC micro-controller
has been used to control each and every process of the work. The
controller also controls the storage process by activating and deactivating
the conveyors. The liquids are heated which on reaching
their respective boiling points evaporate and enter the condensation
chamber where they convert into liquid. The liquids are then directed
to their respective tanks by means of stepper motor which moves in
three directions, each movement into different tank. The tank on
filling sends the signal to controller which then opens the solenoid
valves. The tank is emptied into the beakers below the nozzle. As the
beaker filled, the nozzle closes and the conveyors come into
operation. The filled beaker is replaced by an empty beaker from
behind. The work can be used in oil industries, chemical industries
and paint industries.
Abstract: We present the development of a new underwater laser
cutting process in which a water-jet has been used along with the
laser beam to remove the molten material through kerf. The
conventional underwater laser cutting usually utilizes a high pressure
gas jet along with laser beam to create a dry condition in the cutting
zone and also to eject out the molten material. This causes a lot of gas
bubbles and turbulence in water, and produces aerosols and waste
gas. This may cause contamination in the surrounding atmosphere
while cutting radioactive components like burnt nuclear fuel. The
water-jet assisted underwater laser cutting process produces much
less turbulence and aerosols in the atmosphere. Some amount of
water vapor bubbles is formed at the laser-metal-water interface;
however, they tend to condense as they rise up through the
surrounding water. We present the design and development of a
water-jet assisted underwater laser cutting head and the parametric
study of the cutting of AISI 304 stainless steel sheets with a 2 kW
CW fiber laser. The cutting performance is similar to that of the gas
assist laser cutting; however, the process efficiency is reduced due to
heat convection by water-jet and laser beam scattering by vapor. This
process may be attractive for underwater cutting of nuclear reactor
components.
Abstract: Due to the stringent legislation for emission of diesel
engines and also increasing demand on fuel consumption, the
importance of detailed 3D simulation of fuel injection, mixing and
combustion have been increased in the recent years. In the present
work, FIRE code has been used to study the detailed modeling of
spray and mixture formation in a Caterpillar heavy-duty diesel
engine. The paper provides an overview of the submodels
implemented, which account for liquid spray atomization, droplet
secondary break-up, droplet collision, impingement, turbulent
dispersion and evaporation. The simulation was performed from
intake valve closing (IVC) to exhaust valve opening (EVO). The
predicted in-cylinder pressure is validated by comparing with
existing experimental data. A good agreement between the predicted
and experimental values ensures the accuracy of the numerical
predictions collected with the present work. Predictions of engine
emissions were also performed and a good quantitative agreement
between measured and predicted NOx and soot emission data were
obtained with the use of the present Zeldowich mechanism and
Hiroyasu model. In addition, the results reported in this paper
illustrate that the numerical simulation can be one of the most
powerful and beneficial tools for the internal combustion engine
design, optimization and performance analysis.
Abstract: In turning hardened steel, polycrystalline cubic boron
nitride (cBN) compacts are widely used, due to their higher hardness
and higher thermal conductivity. However, in milling hardened steel,
fracture of cBN cutting tools readily occurs because they have poor
fracture toughness. Therefore, coated cemented carbide tools, which
have good fracture toughness and wear resistance, are generally
widely used. In this study, hardened steel (ASTM D2, JIS SKD11,
60HRC) was milled with three physical vapor deposition
(PVD)-coated cemented carbide end mill cutters in order to determine
effective tool materials for cutting hardened steel at high cutting
speeds. The coating films used were (Ti,W)N/(Ti,W,Si)N and
(Ti,W)N/(Ti,W,Si,Al)N coating films. (Ti,W,Si,Al)N is a new type of
coating film. The inner layer of the (Ti,W)N/(Ti,W,Si)N and
(Ti,W)N/(Ti,W,Si,Al)N coating system is (Ti,W)N coating film, and
the outer layer is (Ti,W,Si)N and (Ti,W,Si,Al)N coating films,
respectively. Furthermore, commercial (Ti,Al)N-based coating film
was also used. The following results were obtained: (1) In milling
hardened steel at a cutting speed of 3.33 m/s, the tool wear width of the
(Ti,W)N/(Ti,W,Si,Al)N-coated tool was smaller than that of the
(Ti,W)N/(Ti,W,Si)N-coated tool. And, compared with the commercial
(Ti,Al)N, the tool wear width of the (Ti,W)N/(Ti,W,Si,Al)N-coated
tool was smaller than that of the (Ti,Al)N-coated tool. (2) The tool
wear of the (Ti,W)N/(Ti,W,Si,Al)N-coated tool increased with an
increase in cutting speed. (3) The (Ti,W)N/(Ti,W,Si,Al)N-coated
cemented carbide was an effective tool material for high-speed cutting
below a cutting speed of 3.33 m/s.
Abstract: This study determines the effect of naked and heparinbased
super-paramagnetic iron oxide nanoparticles on the human
cancer cell lines of A2780. Doxorubicin was used as the anticancer
drug, entrapped in the SPIO-NPs. This study aimed to decorate
nanoparticles with heparin, a molecular ligand for 'active' targeting
of cancerous cells and the application of modified-nanoparticles in
cancer treatment. The nanoparticles containing the anticancer drug
DOX were prepared by a solvent evaporation and emulsification
cross-linking method. The physicochemical properties of the
nanoparticles were characterized by various techniques, and uniform
nanoparticles with an average particle size of 110±15 nm with high
encapsulation efficiencies (EE) were obtained. Additionally, a
sustained release of DOX from the SPIO-NPs was successful.
Cytotoxicity tests showed that the SPIO-DOX-HP had higher cell
toxicity than the individual HP and confocal microscopy analysis
confirmed excellent cellular uptake efficiency. These results indicate
that HP based SPIO-NPs have potential uses as anticancer drug
carriers and also have an enhanced anticancer effect.
Abstract: Heat powered solid sorption is a feasible alternative to
electrical vapor compression refrigeration systems. In this paper,
activated carbon (powder type Maxsorb and fiber type ACF-A10)-
CO2 based adsorption cooling cycles are studied using the pressuretemperature-
concentration (P-T-W) diagram. The specific cooling
effect (SCE) and the coefficient of performance (COP) of these two
cooling systems are simulated for the driving heat source
temperatures ranging from 30 ºC to 90 ºC in terms of different
cooling load temperatures with a cooling source temperature of 25
ºC. It is found from the present analysis that Maxsorb-CO2 couple
shows higher cooling capacity and COP. The maximum COPs of
Maxsorb-CO2 and ACF(A10)-CO2 based cooling systems are found
to be 0.15 and 0.083, respectively. The main innovative feature of
this cooling cycle is the ability to utilize low temperature waste heat
or solar energy using CO2 as the refrigerant, which is one of the best
alternative for applications where flammability and toxicity are not
allowed.
Abstract: Capacity and efficiency of any refrigerating system
diminish rapidly as the difference between the evaporating and
condensing temperature is increased by a reduction in the evaporator
temperature. The single stage vapour compression refrigeration
system using various refrigerants are limited to an evaporator
temperature of -40 0C. Below temperature of -40 0C the either
cascade refrigeration system or multi stage vapour compression
system is employed. Present work describes thermal design of
condenser (HTS), cascade condenser and evaporator (LTS) of
R404A-R508B and R410A-R23 cascade refrigeration system. Heat
transfer area of condenser, cascade condenser and evaporator for
both systems are compared and the effect of condenser and
evaporator temperature on heat-transfer area for both systems is
studied under same operating condition. The results shows that the
required heat-transfer area of condenser and cascade condenser for
R410A-R23 cascade system is lower than the R404A-R508B cascade
system but heat transfer area of evaporator is similar for both the
system. The heat transfer area of condenser and cascade condenser
decreases with increase in condenser temperature (Tc), whereas the
heat transfer area of cascade condenser and evaporator increases with
increase in evaporator temperature (Te).