Abstract: In this paper, the Lennard -Jones potential is applied
to molecules of liquid argon as well as its vapor and platinum as solid
surface in order to perform a non-equilibrium molecular dynamics
simulation to study the microscopic aspects of liquid-vapor-solid
interactions. The channel is periodic in x and y directions and along z
direction it is bounded by atomic walls. It was found that density of
the liquids near the solid walls fluctuated greatly and that the
structure was more like a solid than a liquid. This indicates that the
interactions of solid and liquid molecules are very strong. The
resultant surface tension, liquid density and vapor density are found
to be well predicted when compared with the experimental data for
argon. Liquid and vapor densities were found to depend on the cutoff
radius which induces the use of P3M (particle-particle particle-mesh)
method which was implemented for evaluation of force and surface
tension.
Abstract: The changes in quality properties and nutritional
components in two fermented mugworts (Artemisia capillaries
Thumberg, Artemisiaeasiaticae Nakai) were characterized followed
by the rapid pattern analysis of volatile flavor compounds by Electric
Nose based on SAW(Surface Acoustic Wave) sensor in GC system.
There were remarkable decreases in the pH and small changes in the
total soluble solids after fermentation. The L (lightness) and b
(yellowness) values in Hunter's color system were shown to be
decreased, whilst the a (redness) value was increased by fermentation.
The HPLC analysis demonstrated that total amino acids were
increased in quantity and the essential amino acids were contained
higher in A. asiaticaeNakai than in A. capillaries Thumberg. While
the total polyphenol contents were not affected by fermentation, the
total sugar contents were dramatically decreased. Scopoletinwere
highly abundant in A. capillarisThumberg, however, it was not
detected in A. asiaticaeNakai. Volatile flavor compounds by Electric
Nose showed that the intensity of several peaks were increased much
and seven additional flavor peaks were newly produced after
fermentation. The flavor differences of two mugworts were clearly
distinguished from the image patterns of VaporPrintTM which indicate
that the fermentation enables the two mugworts to have subtle flavor
differences.
Abstract: This paper aims to perform the second law analysis of
thermodynamics on the laminar film condensation of pure saturated
vapor flowing in the direction of gravity on an ellipsoid with variable
wall temperature. The analysis provides us understanding how the
geometric parameter- ellipticity and non-isothermal wall temperature
variation amplitude “A." affect entropy generation during film-wise
condensation heat transfer process. To understand of which
irreversibility involved in this condensation process, we derived an
expression for the entropy generation number in terms of ellipticity
and A. The result indicates that entropy generation increases with
ellipticity. Furthermore, the irreversibility due to finite temperature
difference heat transfer dominates over that due to condensate film
flow friction and the local entropy generation rate decreases with
increasing A in the upper half of ellipsoid. Meanwhile, the local
entropy generation rate enhances with A around the rear lower half of
ellipsoid.
Abstract: This research evaluated and compared the thermodynamic performance of heat pump systems which can be run under two different modes as air to air and air to water by using only one compressor. To achieve this comparison an experimental performance study was made on a traditional vapor compressed heat pump system that can be run air to air mode and air to water mode by help of a valve. The experiments made under different thermal conditions. Thermodynamic performance of the systems are presented and compared with each other for different working conditions.
Abstract: Localized surface plasmon resonance (LSPR) is the
coherent oscillation of conductive electrons confined in noble
metallic nanoparticles excited by electromagnetic radiation, and
nanosphere lithography (NSL) is one of the cost-effective methods to
fabricate metal nanostructures for LSPR. NSL can be categorized
into two major groups: dispersed NSL and closely pack NSL. In
recent years, gold nanocrescents and gold nanoholes with vertical
sidewalls fabricated by dispersed NSL, and silver nanotriangles and
gold nanocaps on silica nanospheres fabricated by closely pack NSL,
have been reported for LSPR biosensing. This paper introduces
several novel gold nanostructures fabricated by NSL in LSPR
applications, including 3D nanostructures obtained by evaporating
gold obliquely on dispersed nanospheres, nanoholes with slant
sidewalls, and patchy nanoparticles on closely packed nanospheres,
all of which render satisfactory sensitivity for LSPR sensing. Since
the LSPR spectrum is very sensitive to the shape of the metal
nanostructures, formulas are derived and software is developed for
calculating the profiles of the obtainable metal nanostructures by
NSL, for different nanosphere masks with different fabrication
conditions. The simulated profiles coincide well with the profiles of
the fabricated gold nanostructures observed under scanning electron
microscope (SEM) and atomic force microscope (AFM), which
proves that the software is a useful tool for the process design of
different LSPR nanostructures.
Abstract: This paper presents the exergy analysis of a
desalination unit using humidification-dehumidification process.
Here, this unit is considered as a thermal system with three main
components, which are the heating unit by using a solar collector, the
evaporator or the humidifier, and the condenser or the dehumidifier.
In these components the exergy is a measure of the quality or grade
of energy and it can be destroyed in them. According to the second
law of thermodynamics this destroyed part is due to irreversibilities
which must be determined to obtain the exergetic efficiency of the
system.
In the current paper a computer program has been developed using
visual basic to determine the exergy destruction and the exergetic
efficiencies of the components of the desalination unit at variable
operation conditions such as feed water temperature, outlet air
temperature, air to feed water mass ratio and salinity, in addition to
cooling water mass flow rate and inlet temperature, as well as
quantity of solar irradiance.
The results obtained indicate that the exergy efficiency of the
humidifier increases by increasing the mass ratio and decreasing the
outlet air temperature. In the other hand the exergy efficiency of the
condenser increases with the increase of this ratio and also with the
increase of the outlet air temperature.
Abstract: This paper addresses one important aspect of
combustion system analysis, the spray evaporation and
dispersion modeling. In this study we assume an empty
cylinder which is as a simulator for a ramjet engine and the
cylinder has been studied by cold flow. Four nozzles have the
duties of injection which are located in the entrance of
cylinder. The air flow comes into the cylinder from one side
and injection operation will be done. By changing injection
velocity and entrance air flow velocity, we have studied
droplet sizing and efficient mass fraction of fuel vapor near
and at the exit area. We named the mass of fuel vapor inside
the flammability limit as the efficient mass fraction. Further,
we decreased the initial temperature of fuel droplets and we
have repeated the investigating again. To fulfill the calculation
we used a modified version of KIVA-3V.
Abstract: Gas turbine air inlet cooling is a useful method for
increasing output for regions where significant power demand and
highest electricity prices occur during the warm months. Inlet air
cooling increases the power output by taking advantage of the gas
turbine-s feature of higher mass flow rate when the compressor inlet
temperature decreases. Different methods are available for reducing
gas turbine inlet temperature. There are two basic systems currently
available for inlet cooling. The first and most cost-effective system is
evaporative cooling. Evaporative coolers make use of the evaporation
of water to reduce the gas turbine-s inlet air temperature. The second
system employs various ways to chill the inlet air. In this method, the
cooling medium flows through a heat exchanger located in the inlet
duct to remove heat from the inlet air. However, the evaporative
cooling is limited by wet-bulb temperature while the chilling can cool
the inlet air to temperatures that are lower than the wet bulb
temperature. In the present work, a thermodynamic model of a gas
turbine is built to calculate heat rate, power output and thermal
efficiency at different inlet air temperature conditions. Computational
results are compared with ISO conditions herein called "base-case".
Therefore, the two cooling methods are implemented and solved for
different inlet conditions (inlet temperature and relative humidity).
Evaporative cooler and absorption chiller systems results show that
when the ambient temperature is extremely high with low relative
humidity (requiring a large temperature reduction) the chiller is the
more suitable cooling solution. The net increment in the power output
as a function of the temperature decrease for each cooling method is
also obtained.
Abstract: Perturbed-Chain Statistical Association Fluid Theory (PC-SAFT) equation of state (EOS) is a modified SAFT EOS with three pure component specific parameters: segment number (m), diameter (σ) and energy (ε). These PC-SAFT parameters need to be determined for each component under the conditions of interest by fitting experimental data, such as vapor pressure, density or heat capacity. PC-SAFT parameters for propane, ethylene and hydrogen in supercritical region were successfully estimated by fitting experimental density data available in literature. The regressed PCSAFT parameters were compared with the literature values by means of estimating pure component density and calculating average absolute deviation between the estimated and experimental density values. PC-SAFT parameters available in literature especially for ethylene and hydrogen estimated density in supercritical region reasonably well. However, the regressed PC-SAFT parameters performed better in supercritical region than the PC-SAFT parameters from literature.
Abstract: This research deals with techno economic analysis to select the most economic desalination method for Asalouyeh combined cycle power plant . Due to lack of fresh water, desalination of sea water is necessary to provide required DM water of Power Plant. The most common desalination methods are RO, MSF, MED, and MED–TVC. In this research, methods of RO, MED, and MED– TVC have been compared. Simulation results show that recovery of heat of exhaust gas of main stack is optimum case for providing DM water required for injected steam of MED desalination. This subject is very important because of improving thermal efficiency of power plant using extra heat recovery. Also, it has been shown that by adding 3 rows of finned tube to de-aerator evaporator, which is very simple and low cost, required steam for generating 5200 m3/day of desalinated water is obtainable.
Abstract: Organic Flash Cycle (OFC) has potential of improving
efficiency for recovery of low temperature heat sources mainly due to
reducing temperature mismatch in the heat exchanger. In this work
exergetical performance analysis of ORC is conducted for recovery of
low grade heat source. Effects of system parameters such as flash
evaporation temperature or heating temperature are theoretically
investigated on the exergy destructions (anergies) at various
components of the system as well as exergy efficiency. Results show
that exergy efficiency has a peak with respect to the flash temperature,
and the optimum flash temperature increases with the heating
temperature. The component where the largest exergy destruction
occurs varies with the flash temperature or heating temperature.
Abstract: The composition, vapour pressure, and heat capacity
of nine biodiesel fuels from different sources were measured. The
vapour pressure of the biodiesel fuels is modeled assuming an ideal
liquid phase of the fatty acid methyl esters constituting the fuel. New
methodologies to calculate the vapour pressure and ideal gas and
liquid heat capacities of the biodiesel fuel constituents are proposed.
Two alternative optimization scenarios are evaluated: 1) vapour
pressure only; 2) vapour pressure constrained with liquid heat
capacity. Without physical constraints, significant errors in liquid
heat capacity predictions were found whereas the constrained
correlation accurately fit both vapour pressure and liquid heat
capacity.
Abstract: In this work, we incorporated a quartic bond potential
into a coarse-grained bead-spring model to study lubricant adsorption
on a solid surface as well as depletion instability. The surface tension
density and the number density profiles were examined to verify the
solid-liquid and liquid-vapor interfaces during heat treatment. It was
found that both the liquid-vapor interfacial thickness and the
solid-vapor separation increase with the temperatureT* when T*is
below the phase transition temperature Tc
*. At high temperatures
(T*>Tc
*), the solid-vapor separation decreases gradually as the
temperature increases. In addition, we evaluated the lubricant weight
and bond loss profiles at different temperatures. It was observed that
the lubricant desorption is favored over decomposition and is the main
cause of the lubricant failure at the head disk interface in our
simulations.
Abstract: An Artificial Neural Network based modeling
technique has been used to study the influence of different
combinations of meteorological parameters on evaporation from a
reservoir. The data set used is taken from an earlier reported study.
Several input combination were tried so as to find out the importance
of different input parameters in predicting the evaporation. The
prediction accuracy of Artificial Neural Network has also been
compared with the accuracy of linear regression for predicting
evaporation. The comparison demonstrated superior performance of
Artificial Neural Network over linear regression approach. The
findings of the study also revealed the requirement of all input
parameters considered together, instead of individual parameters
taken one at a time as reported in earlier studies, in predicting the
evaporation. The highest correlation coefficient (0.960) along with
lowest root mean square error (0.865) was obtained with the input
combination of air temperature, wind speed, sunshine hours and
mean relative humidity. A graph between the actual and predicted
values of evaporation suggests that most of the values lie within a
scatter of ±15% with all input parameters. The findings of this study
suggest the usefulness of ANN technique in predicting the
evaporation losses from reservoirs.
Abstract: The theoretical investigation is carried out to describe
the effect of increase of pressure waves amplitude in clean and bubbly liquid. The goal of the work is to capture the regime of multiple magnification of acoustic and shock waves in the liquid,
which enables to get appropriate conditions to enlarge collapses of
micro-bubbles. The influence of boundary conditions and frequency
of the governing acoustic field is studied for the case of the
cylindrical acoustic resonator. It has been observed the formation of
standing waves with large amplitude at resonant frequencies. The
interaction of the compression wave with gas and vapor bubbles is
investigated for the convergent channel. It is shown theoretically that
the chemical reactions, which occur inside gas bubbles, provide additional impulse to the wave, that affect strongly on the collapses
of the vapor bubbles
Abstract: Climate change is a phenomenon has been based on
the available evidence from a very long time ago and now its
existence is very probable. The speed and nature of climate
parameters changes at the middle of twentieth century has been
different and its quickness more than the before and its trend changed
to some extent comparing to the past. Climate change issue now
regarded as not only one of the most common scientific topic but also
a social political one, is not a new issue. Climate change is a
complicated atmospheric oceanic phenomenon on a global scale and
long-term. Precipitation pattern change, fast decrease of snowcovered
resources and its rapid melting, increased evaporation, the
occurrence of destroying floods, water shortage crisis, severe
reduction at the rate of harvesting agricultural products and, so on are
all the significant of climate change. To cope with this phenomenon,
its consequences and events in which public instruction is the most
important but it may be climate that no significant cant and effective
action has been done so far. The present article is included a part of
one surrey about climate change in Fars. The study area having
annually mean temperature 14 and precipitation 320 mm .23 stations
inside the basin with a common 37 year statistical period have been
applied to the meteorology data (1974-2010). Man-kendal and
change factor methods are two statistical methods, applying them, the
trend of changes and the annual mean average temperature and the
annual minimum mean temperature were studied by using them.
Based on time series for each parameter, the annual mean average
temperature and the mean of annual maximum temperature have a
rising trend so that this trend is clearer to the mean of annual
maximum temperature.
Abstract: This paper presents a comparative study on
Vanadyl Phthalocyanine (VOPc) thin films deposited by thermal
evaporation and spin coating techniques. The samples
were prepared on cleaned glass substrates and annealed at
various temperatures ranging form 95oC to 155oC. To obtain
the morphological and structural properties of VOPc thin
films, X-ray diffraction (XRD) technique and atomic force
microscopy (AFM) have been implied. The AFM topographic
images show a very slight difference in the thermally grown
films, before and after annealing, however best results are
achieved for the spin-cast film annealed at 125oC. The XRD
spectra show no existence of the sharp peaks, suggesting the
material to be amorphous. The humps in the XRD patterns
indicate the presence of some crystallites.
Abstract: Natural gas is the most popular fossil fuel in the
current era and future as well. Natural gas is existed in underground
reservoirs so it may contain many of non-hydrocarbon components
for instance, hydrogen sulfide, nitrogen and water vapor. These
impurities are undesirable compounds and cause several technical
problems for example, corrosion and environment pollution.
Therefore, these impurities should be reduce or removed from natural
gas stream. Khurmala dome is located in southwest Erbil-Kurdistan
region. The Kurdistan region government has paid great attention for
this dome to provide the fuel for Kurdistan region. However, the
Khurmala associated natural gas is currently flaring at the field.
Moreover, nowadays there is a plan to recover and trade this gas and
to use it either as feedstock to power station or to sell it in global
market. However, the laboratory analysis has showed that the
Khurmala sour gas has huge quantities of H2S about (5.3%) and CO2
about (4.4%). Indeed, Khurmala gas sweetening process has been
removed in previous study by using Aspen HYSYS. However,
Khurmala sweet gas still contents some quintets of water about 23
ppm in sweet gas stream. This amount of water should be removed or
reduced. Indeed, water content in natural gas cause several technical
problems such as hydrates and corrosion. Therefore, this study aims
to simulate the prospective Khurmala gas dehydration process by
using Aspen HYSYS V. 7.3 program. Moreover, the simulation
process succeeded in reducing the water content to less than 0.1ppm.
In addition, the simulation work is also achieved process
optimization by using several desiccant types for example, TEG and
DEG and it also study the relationship between absorbents type and
its circulation rate with HCs losses from glycol regenerator tower.
Abstract: Isobaric vapor-liquid equilibrium measurements are
reported for the binary mixture of Methyl acetate and
Isopropylbenzene at 97.3 kPa. The measurements have been
performed using a vapor recirculating type (modified Othmer's)
equilibrium still. The mixture shows positive deviation from ideality
and does not form an azeotrope. The activity coefficients have been
calculated taking into consideration the vapor phase nonideality. The
data satisfy the thermodynamic consistency tests of Herington and
Black. The activity coefficients have been satisfactorily correlated by
means of the Margules, NRTL, and Black equations. A comparison
of the values of activity coefficients obtained by experimental data
with the UNIFAC model has been made.
Abstract: Thermal water hammer is a special type of water
hammer which rarely occurs in heat exchangers. In biphasic fluids, if
steam bubbles are surrounded by condensate, regarding lower
condensate temperature than steam, they will suddenly collapse. As a
result, the vacuum caused by an extreme change in volume lead to
movement of the condensates in all directions and their collision the
force produced by this collision leads to a severe stress in the pipe
wall. This phenomenon is a special type of water hammer. According
to fluid mechanics, this phenomenon is a particular type of transient
flows during which abrupt change of fluid leads to sudden pressure
change inside the tube. In this paper, the mechanism of abrupt failure
of 80 tubes of 481 tubes of a methanol heat exchanger is discussed.
Initially, due to excessive temperature differences between heat
transfer fluids and simultaneous failure of 80 tubes, thermal shock
was presupposed as the reason of failure. Deeper investigation on
cross-section of failed tubes showed that failure was, ductile type of
failure, so the first hypothesis was rejected. Further analysis and more
accurate experiments revealed that failure of tubes caused by thermal
water hammer. Finally, the causes of thermal water hammer and
various solutions to avoid such mechanism are discussed.