Abstract: In this paper we present discretization and decomposition methods for a multi-component transport model of a chemical vapor deposition (CVD) process. CVD processes are used to manufacture deposition layers or bulk materials. In our transport model we simulate the deposition of thin layers. The microscopic model is based on the heavy particles, which are derived by approximately solving a linearized multicomponent Boltzmann equation. For the drift-process of the particles we propose diffusionreaction equations as well as for the effects of heat conduction. We concentrate on solving the diffusion-reaction equation with analytical and numerical methods. For the chemical processes, modelled with reaction equations, we propose decomposition methods and decouple the multi-component models to simpler systems of differential equations. In the numerical experiments we present the computational results of our proposed models.
Abstract: Vernonia divergens Benth., commonly known as
“Insulin Plant” (Fam: Asteraceae) is a potent sugar killer. Locally the
leaves of the plant, boiled in water are successfully administered to a
large number of diabetic patients. The present study evaluates the
putative anti-diabetic ingredients, isolated from the in vivo and in
vitro grown plantlets of V. divergens for their antimicrobial and
anticancer activities. Sterilized explants of nodal segments were
cultured on MS (Musashige and Skoog, 1962) medium in presence of
different combinations of hormones. Multiple shoots along with
bunch of roots were regenerated at 1mg l-1 BAP and 0.5 mg l-1 NAA.
Micro-plantlets were separated and sub-cultured on the double
strength (2X) of the above combination of hormones leading to
increased length of roots and shoots. These plantlets were
successfully transferred to soil and survived well in nature. The
ethanol extract of plantlets from both in vivo & in vitro sources were
prepared in soxhlet extractor and then concentrated to dryness under
reduced pressure in rotary evaporator. Thus obtainedconcentrated
extracts showed significant inhibitory activity against gram
negative bacteria like Escherichia coli and Pseudomonas
aeruginosa but no inhibition was found against gram positive
bacteria. Further, these ethanol extracts were screened for in vitro
percentage cytotoxicity at different time periods (24 h, 48 h and 72 h)
of different dilutions. The in vivo plant extract inhibited the growth of
EAC mouse cell lines in the range of 65, 66, 78, and 88% at 100, 50,
25 & 12.5μg mL-1 but at 72 h of treatment. In case of the extract of in
vitro origin, the inhibition was found against EAC cell lines even at
48h. During spectrophotometric scanning, the extracts exhibited
different maxima (ʎ) - four peaks in in vitro extracts as against single
in in vivo preparation suggesting the possible change in the nature of
ingredients during micropropagation through tissue culture
techniques.
Abstract: The mesoporous MoO3/γ-Al2O3 catalyst was prepared
by incipient wetness impregnation method aiming to investigate the
effect of drying method and molybdenum content on the catalyst
property and performance towards the oxidation of benzothiophene
(BT), dibenzothiophene (DBT) and 4,6-dimethyle dibenzothiophene
(4,6-DMDBT) with H2O2 for deep oxidative desulfurization of diesel
fuel. The catalyst was characterized by XRD, BET, BJH and SEM
method. The catalyst with 10wt.% and 15wt.% Mo content represent
same optimum performance for DBT and 4,6-DMDBT removal, but
a catalyst with 10wt.% Mo has higher efficiency than 15wt.% Mo for
BT conversion. The SEM images show that use of rotary evaporator
in drying step reaches a more homogenous impregnation. The
oxidation reactivity of different sulfur compounds was studied which
followed the order of DBT>4,6-DMDBT>>BT.
Abstract: The importance for manipulating an incorporated
scaffold and directing cell behaviors is well appreciated for tissue
engineering. Here, we developed newly nano-topographic oxidized
silicon nanosponges capable of being various chemical modifications
to provide much insight into the fundamental biology of how cells
interact with their surrounding environment in vitro. A wet etching
technique is exerted to allow us fabricated the silicon nanosponges in a
high-throughput manner. Furthermore, various organo-silane
chemicals enabled self-assembled on the surfaces by vapor deposition.
We have found that Chinese hamster ovary (CHO) cells displayed
certain distinguishable morphogenesis, adherent responses, and
biochemical properties while cultured on these chemical modified
nano-topographic structures in compared with the planar oxidized
silicon counterparts, indicating that cell behaviors can be influenced
by certain physical characteristic derived from nano-topography in
addition to the hydrophobicity of contact surfaces crucial for cell
adhesion and spreading. Of particular, there were predominant
nano-actin punches and slender protrusions formed while cells were
cultured on the nano-topographic structures. This study shed potential
applications of these nano-topographic biomaterials for controlling
cell development in tissue engineering or basic cell biology research.
Abstract: Applying corona wind as a novel technique can lead
to a great level of heat and mass transfer augmentation by using very
small amount of energy. Enhancement of forced flow evaporation
rate by applying electric field (corona wind) has been experimentally
evaluated in this study. Corona wind produced by a fine wire
electrode which is charged with positive high DC voltage impinges
to water surface and leads to evaporation enhancement by disturbing
the saturated air layer over water surface. The study was focused on
the effect of corona wind velocity, electrode spacing and air flow
velocity on the level of evaporation enhancement. Two sets of
experiments, i.e. with and without electric field, have been
conducted. Data obtained from the first experiment were used as
reference for evaluation of evaporation enhancement at the presence
of electric field. Applied voltages ranged from corona threshold
voltage to spark over voltage at 1 kV increments. The results showed
that corona wind has great enhancement effect on water evaporation
rate, but its effectiveness gradually diminishes by increasing air flow
velocity. Maximum enhancements were 7.3 and 3.6 for air velocities
of 0.125 and 1.75 m/s, respectively.
Abstract: In this paper, the effects of thermodynamic,
hydrodynamic and geometric of an air cooled condenser on COP of
vapor compression cycle are investigated for a fixed condenser facing
surface area. The system is utilized with a scroll compressor,
modeled based on thermodynamic and heat transfer equations
employing Matlab software. The working refrigerant is R134a whose
thermodynamic properties are called from Engineering Equation
Software. This simulation shows that vapor compression cycle can
be designed by different configurations and COPs, economical and
optimum working condition can be obtained via considering these
parameters.
Abstract: Carbon nanotubes (CNTs) with their high mechanical,
electrical, thermal and chemical properties are regarded as promising
materials for many different potential applications. Having unique
properties they can be used in a wide range of fields such as
electronic devices, electrodes, drug delivery systems, hydrogen
storage, textile etc. Catalytic chemical vapor deposition (CCVD) is a
common method for CNT production especially for mass production.
Catalysts impregnated on a suitable substrate are important for
production with chemical vapor deposition (CVD) method. Iron
catalyst and MgO substrate is one of most common catalyst-substrate
combination used for CNT. In this study, CNTs were produced by
CCVD of acetylene (C2H2) on magnesium oxide (MgO) powder
substrate impregnated by iron nitrate (Fe(NO3)3•9H2O) solution. The
CNT synthesis conditions were as follows: at synthesis temperatures
of 500 and 800°C multiwall and single wall CNTs were produced
respectively. Iron (Fe) catalysts were prepared by with Fe:MgO ratio
of 1:100, 5:100 and 10:100. The duration of syntheses were 30 and
60 minutes for all temperatures and catalyst percentages. The
synthesized materials were characterized by thermal gravimetric
analysis (TGA), transmission electron microscopy (TEM) and Raman
spectroscopy.
Abstract: In designing of condensers, the prediction of pressure
drop is as important as the prediction of heat transfer coefficient.
Modeling of two phase flow, particularly liquid – vapor flow under
diabatic conditions inside a horizontal tube using CFD analysis is
difficult with the available two phase models in FLUENT due to
continuously changing flow patterns. In the present analysis, CFD
analysis of two phase flow of refrigerants inside a horizontal tube of
inner diameter, 0.0085 m and 1.2 m length is carried out using
homogeneous model under adiabatic conditions. The refrigerants
considered are R22, R134a and R407C. The analysis is performed at
different saturation temperatures and at different flow rates to
evaluate the local frictional pressure drop. Using Homogeneous
model, average properties are obtained for each of the refrigerants
that is considered as single phase pseudo fluid. The so obtained
pressure drop data is compared with the separated flow models
available in literature.
Abstract: In this work, ionic liquids (ILs) for CO2 capturing in typical absorption/stripper process are considered. The use of ionic liquids is considered to be cost-effective because it requires less energy for solvent recovery compared to other conventional processes. A mathematical model is developed for the process based on Peng-Robinson (PR) equation of state (EoS) which is validated with experimental data for various solutions involving CO2. The model is utilized to study the sorbent and energy demand for three types of ILs at specific CO2 capturing rates. The energy demand is manifested by the vapor-liquid equilibrium temperature necessary to remove the captured CO2 from the used solvent in the regeneration step. It is found that higher recovery temperature is required for solvents with higher solubility coefficient. For all ILs, the temperature requirement is less than that required by the typical monoethanolamine (MEA) solvent. The effect of the CO2 loading in the sorbent stream on the process performance is also examined.
Abstract: This paper addresses one important aspect of
combustion system analysis, the spray evaporation and
dispersion modeling. In this study we assume an empty
cylinder which is as a simulator for a ramjet engine and the
cylinder has been studied by cold flow. Four nozzles have the
duties of injection which are located in the entrance of
cylinder. The air flow comes into the cylinder from one side
and injection operation will be done. By changing injection
velocity and entrance air flow velocity, we have studied
droplet sizing and efficient mass fraction of fuel vapor near
and at the exit area. We named the mass of fuel vapor inside
the flammability limit as the efficient mass fraction. Further,
we decreased the initial temperature of fuel droplets and we
have repeated the investigating again. To fulfill the calculation
we used a modified version of KIVA-3V.
Abstract: This study aimed at developing visualization tools for integrating CloudSat images and Water Vapor Satellite images. KML was used for integrating data from CloudSat Satellite and GMS-6 Water Vapor Satellite. CloudSat 2D images were transformed into 3D polygons in order to achieve 3D images. Before overlaying the images on Google Earth, GMS-6 water vapor satellite images had to be rescaled into linear images. Web service was developed using webMathematica. Shoreline from GMS-6 images was compared with shoreline from LandSat images on Google Earth for evaluation. The results showed that shoreline from GMS-6 images was highly matched with the shoreline in LandSat images from Google Earth. For CloudSat images, the visualizations were compared with GMS-6 images on Google Earth. The results showed that CloudSat and GMS-6 images were highly correlated.
Abstract: If an unsteady heat transfer or heat impulse happens in
part of the cryogenic pipeline system of large space environment
simulation equipment while running in vacuum environment, it will
lead to abnormal flow of the cryogenic fluid in the pipeline. When the
situation gets worse, the cryogenic fluid in the pipeline will have phase
change and a gas block which results in the malfunction of the
cryogenic pipeline system. Referring to the structural parameter of a
typical cryogenic pipeline system and the basic equation, an analytical
model and a calculation model for cryogenic pipeline system can be
built. The various factors which influence the thermal resistance of a
cryogenic pipeline system can be analyzed and calculated by using the
qualitative analysis relation deduced for thermal resistance of pipeline.
The research conclusion could provide theoretical support for the
design and operation of a cryogenic pipeline system
Abstract: ZnO-SnO2 i.e. Zinc-Tin-Oxide (ZTO) thin films were
deposited on glass substrate with varying concentrations (ZnO:SnO2
- 100:0, 90:10, 70:30 and 50:50 wt.%) at room temperature by flash
evaporation technique. These deposited ZTO film were annealed at
450 0C in vacuum. These films were characterized to study the effect
of annealing on the structural, electrical, and optical properties.
Atomic force microscopy (AFM) and Scanning electron microscopy
(SEM) images manifest the surface morphology of these ZTO thin
films. The apparent growth of surface features revealed the formation
of nanostructure ZTO thin films. The small value of surface
roughness (root mean square RRMS) ensures the usefulness in
optical coatings. The sheet resistance was also found to be decreased
for both types of films with increasing concentration of SnO2. The
optical transmittance found to be decreased however blue shift has
been observed after annealing.
Abstract: This paper describes a steady state model of a multiple
effect evaporator system for simulation and control purposes. The
model includes overall as well as component mass balance equations,
energy balance equations and heat transfer rate equations for area
calculations for all the effects. Each effect in the process is
represented by a number of variables which are related by the energy
and material balance equations for the feed, product and vapor flow
for backward, mixed and split feed. For simulation 'fsolve' solver in
MATLAB source code is used. The optimality of three sequences i.e.
backward, mixed and splitting feed is studied by varying the various
input parameters.
Abstract: The mixture formation prior to the ignition process
plays as a key element in the diesel combustion. Parametric studies of
mixture formation and ignition process in various injection parameter
has received considerable attention in potential for reducing
emissions. Purpose of this study is to clarify the effects of injection
pressure on mixture formation and ignition especially during ignition
delay period, which have to be significantly influences throughout the
combustion process and exhaust emissions. This study investigated
the effects of injection pressure on diesel combustion fundamentally
using rapid compression machine. The detail behavior of mixture
formation during ignition delay period was investigated using the
schlieren photography system with a high speed camera. This method
can capture spray evaporation, spray interference, mixture formation
and flame development clearly with real images. Ignition process and
flame development were investigated by direct photography method
using a light sensitive high-speed color digital video camera. The
injection pressure and air motion are important variable that strongly
affect to the fuel evaporation, endothermic and prolysis process
during ignition delay. An increased injection pressure makes spray tip
penetration longer and promotes a greater amount of fuel-air mixing
occurs during ignition delay. A greater quantity of fuel prepared
during ignition delay period thus predominantly promotes more rapid
heat release.
Abstract: In this paper, the solubility of CO2 in AMP solution
have been measured at temperature range of ( 293, 303 ,313,323)
K.The amine concentration ranges studied are (2.0, 2.8, and 3.4) M.
A solubility apparatus was used to measure the solubility of CO2 in
AMP solution on samples of flue gases from Thermal and Central
Power Plants of Esfahan Steel Company. The modified Kent
Eisenberg model was used to correlate and predict the vapor-liquid
equilibria of the (CO2 + AMP + H2O) system. The model predicted
results are in good agreement with the experimental vapor-liquid
equilibrium measurements.
Abstract: Observations show that power plant efficiency
decreases in hot summer days. Water droplet injection in air
condensers is suggested in order to decrease the inlet air temperature.
Nozzle arrangement, injected water flow rate and droplets diameter
effects on evaporation rate and the resulting air temperature are
investigated using numerical simulation. Decreasing the diameter of
injected droplets and increasing the number of injecting nozzles,
decreases the outlet air temperature. Also a more uniform air
temperature can be obtained using more injecting nozzles. Numerical
results are in good agreement with analytical results.
Abstract: In this article, a high vacuum system for the evaporation of organic semiconductors is introduced and a mathematical model is given. Based on the exact input output linearization a deposition rate controller is designed and tested with different evaporation materials.
Abstract: A steady two-phase flow model has been developed to simulate the drying process of porous particle in a pneumatic conveying dryer. The model takes into account the momentum, heat and mass transfer between the continuous phase and the dispersed phase. A single particle model was employed to calculate the evaporation rate. In this model the pore structure is simplified to allow the dominant evaporation mechanism to be readily identified at all points within the duct. The predominant mechanism at any time depends upon the pressure, temperature and the diameter of pore from which evaporating is occurring. The model was validated against experimental studies of pneumatic transport at low and high speeds as well as pneumatic drying. The effects of operating conditions on the dryer parameters are studied numerically. The present results show that the drying rate is enhanced as the inlet gas temperature and the gas flow rate increase and as the solid mass flow rate deceases. The present results also demonstrate the necessity of measuring the inlet gas velocity or the solid concentration in any experimental analysis.
Abstract: This paper provides an exergy analysis of the multistage refrigeration cycle used for C2+ recovery plant. The behavior of an industrial refrigeration cycle with refrigerant propane has been investigated by the exergy method. A computational model based on the exergy analysis is presented for the investigation of the effects of the valves on the exergy losses, the second law of efficiency, and the coefficient of performance (COP) of a vapor compression refrigeration cycle. The equations of exergy destruction and exergetic efficiency for the main cycle components such as evaporators, condensers, compressors, and expansion valves are developed. The relations for the total exergy destruction in the cycle and the cycle exergetic efficiency are obtained. An ethane recovery unit with its refrigeration cycle has been simulated to prepare the exergy analysis. Using a typical actual work input value; the exergetic efficiency of the refrigeration cycle is determined to be 39.90% indicating a great potential for improvements. The simulation results reveal that the exergetic efficiencies of the heat exchanger and expansion sections get the lowest rank among the other compartments of refrigeration cycle. Refrigeration calculations have been carried out through the analysis of T–S and P–H diagrams where coefficient of performance (COP) was obtained as 1.85. The novelty of this article includes the effect and sensitivity analysis of molar flow, pressure drops and temperature on the exergy efficiency and coefficient of performance of the cycle.