Abstract: Climate change leading to global warming affects the
earth through many different ways such as weather (temperature, precipitation, humidity and the other parameters of weather), snow coverage and ice melting, sea level rise, hydrological cycles, quality of water, agriculture, forests, ecosystems and health. One of the most
affected areas by climate change is hydrology and water resources.
Regions where majority of runoff consists of snow melt are more
sensitive to climate change. The first step of climate change studies
is to establish trends of significant climate variables including precipitation,
temperature and flow data to detect any potential climate
change impacts already happened. Two popular non-parametric trend
analysis methods, Mann-Kendal and Spearman-s Rho were applied
to Upper Euphrates Basin (Turkey) to detect trends of precipitation,
temperatures (maximum, minimum and average) and streamflow.
Abstract: The empirical mode decomposition (EMD) represents any time series into a finite set of basis functions. The bases are termed as intrinsic mode functions (IMFs) which are mutually orthogonal containing minimum amount of cross-information. The EMD successively extracts the IMFs with the highest local frequencies in a recursive way, which yields effectively a set low-pass filters based entirely on the properties exhibited by the data. In this paper, EMD is applied to explore the properties of the multi-year air temperature and to observe its effects on climate change under global warming. This method decomposes the original time-series into intrinsic time scale. It is capable of analyzing nonlinear, non-stationary climatic time series that cause problems to many linear statistical methods and their users. The analysis results show that the mode of EMD presents seasonal variability. The most of the IMFs have normal distribution and the energy density distribution of the IMFs satisfies Chi-square distribution. The IMFs are more effective in isolating physical processes of various time-scales and also statistically significant. The analysis results also show that the EMD method provides a good job to find many characteristics on inter annual climate. The results suggest that climate fluctuations of every single element such as temperature are the results of variations in the global atmospheric circulation.
Abstract: In this work, we incorporated a quartic bond potential
into a coarse-grained bead-spring model to study lubricant adsorption
on a solid surface as well as depletion instability. The surface tension
density and the number density profiles were examined to verify the
solid-liquid and liquid-vapor interfaces during heat treatment. It was
found that both the liquid-vapor interfacial thickness and the
solid-vapor separation increase with the temperatureT* when T*is
below the phase transition temperature Tc
*. At high temperatures
(T*>Tc
*), the solid-vapor separation decreases gradually as the
temperature increases. In addition, we evaluated the lubricant weight
and bond loss profiles at different temperatures. It was observed that
the lubricant desorption is favored over decomposition and is the main
cause of the lubricant failure at the head disk interface in our
simulations.
Abstract: Sulphur dioxide is a harmful gaseous product that
needs to be minimized in the atmosphere. This research work
investigates the use of zeolite as a possible additive that can improve
the sulphur dioxide capture in wet flue gas desulphurisation
dissolution process. This work determines the effect of temperature,
solid to liquid ratio, acid concentration and stirring speed on the
leaching of zeolite using a pH stat apparatus. The atomic absorption
spectrometer was used to measure the calcium ions from the solution.
It was found that the dissolution rate of zeolite decreased with
increase in solid to liquid ratio and increases with increase in
temperature, stirring speed and acid concentration. The activation
energy for the dissolution rate of zeolite in hydrochloric acid was
found to be 9.29kJ/mol. and therefore the product layer diffusion was
the rate limiting step.
Abstract: The tray/multi-tray distillation process is a topic that
has been investigated to great detail over the last decade by many
teams such as Jubran et al. [1], Adhikari et al. [2], Mowla et al. [3],
Shatat et al. [4] and Fath [5] to name a few. A significant amount of
work and effort was spent focusing on modeling and/simulation of
specific distillation hardware designs. In this work, we have focused
our efforts on investigating and gathering experimental data on
several engineering and design variables to quantify their influence
on the yield of the multi-tray distillation process. Our goals are to
generate experimental performance data to bridge some existing gaps
in the design, engineering, optimization and theoretical modeling
aspects of the multi-tray distillation process.
Abstract: In contrast to existing methods which do not take into account multiconnectivity in a broad sense of this term, we develop mathematical models and highly effective combination (BIEM and FDM) numerical methods of calculation of stationary and quasi-stationary temperature field of a profile part of a blade with convective cooling (from the point of view of realization on PC). The theoretical substantiation of these methods is proved by appropriate theorems. For it, converging quadrature processes have been developed and the estimations of errors in the terms of A.Ziqmound continuity modules have been received. For visualization of profiles are used: the method of the least squares with automatic conjecture, device spline, smooth replenishment and neural nets. Boundary conditions of heat exchange are determined from the solution of the corresponding integral equations and empirical relationships. The reliability of designed methods is proved by calculation and experimental investigations heat and hydraulic characteristics of the gas turbine first stage nozzle blade.
Abstract: To study the impact of the inter-module ventilation (IMV) on the space station, the Computational Fluid Dynamic (CFD) model under the influence of IMV, the mathematical model, boundary conditions and calculation method are established and determined to analyze the influence of IMV on cabin air flow characteristics and velocity distribution firstly; and then an integrated overall thermal mathematical model of the space station is used to consider the impact of IMV on thermal management. The results show that: the IMV has a significant influence on the cabin air flow, the flowrate of IMV within a certain range can effectively improve the air velocity distribution in cabin, if too much may lead to its deterioration; IMV can affect the heat deployment of the different modules in space station, thus affecting its thermal management, the use of IMV can effectively maintain the temperature levels of the different modules and help the space station to dissipate the waste heat.
Abstract: This paper presents an optimal design of poly-phase induction motor using Quadratic Interpolation based Particle Swarm Optimization (QI-PSO). The optimization algorithm considers the efficiency, starting torque and temperature rise as objective function (which are considered separately) and ten performance related items including harmonic current as constraints. The QI-PSO algorithm was implemented on a test motor and the results are compared with the Simulated Annealing (SA) technique, Standard Particle Swarm Optimization (SPSO), and normal design. Some benchmark problems are used for validating QI-PSO. From the test results QI-PSO gave better results and more suitable to motor-s design optimization. Cµ code is used for implementing entire algorithms.
Abstract: Optimization of extraction of phenolic compounds
from Avicennia marina using response surface methodology was
carried out during the present study. Five levels, three factors
rotatable design (CCRD) was utilized to examine the optimum
combination of extraction variables based on the TPC of Avicennia
marina leaves. The best combination of response function was 78.41
°C, drying temperature; 26.18°C; extraction temperature and 36.53
minutes of extraction time. However, the procedure can be promptly
extended to the study of several others pharmaceutical processes like
purification of bioactive substances, drying of extracts and
development of the pharmaceutical dosage forms for the benefit of
consumers.
Abstract: Thermal load calculations have been performed for
multi-layered walls that are composed of three different parts; a
common (sand and cement) plaster, and two types of locally
produced soft and hard bricks. The masonry construction of these
layered walls was based on concrete-backed stone masonry made of
limestone bricks joined by mortar. These multilayered walls are
forming the outer walls of the building envelope of a typical Libyan
house. Based on the periodic seasonal weather conditions, within the
Libyan cost region during summer and winter, measured thermal
conductivity values were used to implement such seasonal variation
of heat flow and the temperature variations through the walls. The
experimental measured thermal conductivity values were obtained
using the Hot Disk technique. The estimation of the thermal
resistance of the wall layers ( R-values) is based on measurements
and calculations. The numerical calculations were done using a
simplified analytical model that considers two different wall
constructions which are characteristics of such houses. According to
the obtained results, the R-values were quite low and therefore,
several suggestions have been proposed to improve the thermal
loading performance that will lead to a reasonable human comfort
and reduce energy consumption.
Abstract: The purpose of this research is to establish the experimental conditions for removal of Cibacron Brilliant Yellow 3G-P dye (CBY) from aqueous solutions by sorption onto coffee husks as a low-cost sorbent. The effects of various experimental parameters (e.g. initial CBY dye concentration, sorbent mass, pH, temperature) were examined and the optimal experimental conditions were determined. The results indicated that the removal of the dye was pH dependent and at initial pH of 2, the dye was removed effectively. The CBY dye sorption data were fitted to Langmuir, Freundlich, Temkin and Dubinin-Radushkevich equilibrium models. The maximum sorption capacity of CBY dye ions onto coffee husks increased from 24.04 to 35.04 mg g-1 when the temperature was increased from 293 to 313 K. The calculated sorption thermodynamic parameters including ΔG°, ΔH°, and ΔS° indicated that the CBY dye sorption onto coffee husks is a spontaneous, endothermic and mainly physical in nature.
Abstract: Carboneous catalytical methane decomposition is an
attractive process because it produces two valuable products:
hydrogen and carbon. Furthermore, this reaction does not emit any
green house or hazardous gases. In the present study, experiments
were conducted in a thermo gravimetric analyzer using Fluka 05120
as carboneous catalyst to analyze its effectiveness in methane
decomposition. Various temperatures and methane partial pressures
were chosen and carbon mass gain was observed as a function of
time. Results are presented in terms of carbon formation rate,
hydrogen production and catalytical activity. It is observed that there
is linearity in carbon deposition amount by time at lower reaction
temperature (780 °C). On the other hand, it is observed that carbon
and hydrogen formation rates are increased with increasing
temperature. Finally, we observed that the carbon formation rate is
highest at 950 °C within the range of temperatures studied.
Abstract: This paper is a continuation of our interest in the influence of temperature on specific retention volumes and the resulting infinite dilution activity coefficients. This has a direct effect in the design of absorption and stripping columns for the abatement of volatile organic compounds. The interaction of 13 volatile organic compounds (VOCs) with polydimethylsiloxane (PDMS) at varying temperatures was studied by gas liquid chromatography (GLC). Infinite dilution activity coefficients and specific retention volumes obtained in this study were found to be in agreement with those obtained from static headspace and group contribution methods by the authors as well as literature values for similar systems. Temperature variation also allows for transport calculations for different seasons. The results of this work confirm that PDMS is well suited for the scrubbing of VOCs from waste gas streams. Plots of specific retention volumes against temperature gave linear van-t Hoff plots.
Abstract: An Artificial Neural Network based modeling
technique has been used to study the influence of different
combinations of meteorological parameters on evaporation from a
reservoir. The data set used is taken from an earlier reported study.
Several input combination were tried so as to find out the importance
of different input parameters in predicting the evaporation. The
prediction accuracy of Artificial Neural Network has also been
compared with the accuracy of linear regression for predicting
evaporation. The comparison demonstrated superior performance of
Artificial Neural Network over linear regression approach. The
findings of the study also revealed the requirement of all input
parameters considered together, instead of individual parameters
taken one at a time as reported in earlier studies, in predicting the
evaporation. The highest correlation coefficient (0.960) along with
lowest root mean square error (0.865) was obtained with the input
combination of air temperature, wind speed, sunshine hours and
mean relative humidity. A graph between the actual and predicted
values of evaporation suggests that most of the values lie within a
scatter of ±15% with all input parameters. The findings of this study
suggest the usefulness of ANN technique in predicting the
evaporation losses from reservoirs.
Abstract: An aqueous methanol sensor for use in direct
methanol fuel cells (DMFCs) applications is demonstrated; the
methanol sensor is built using dispersed single-walled carbon
nanotubes (SWCNTs) with Nafion117 solution to detect the methanol
concentration in water. The study is aimed at the potential use of the
carbon nanotubes array as a methanol sensor for direct methanol fuel
cells (DMFCs). The concentration of methanol in the fuel circulation
loop of a DMFC system is an important operating parameter, because
it determines the electrical performance and efficiency of the fuel cell
system. The sensor is also operative even at ambient temperatures
and responds quickly to changes in the concentration levels of the
methanol. Such a sensor can be easily incorporated into the methanol
fuel solution flow loop in the DMFC system.
Abstract: Hydrogen is an important chemical in many industries
and it is expected to become one of the major fuels for energy
generation in the future. Unfortunately, hydrogen does not exist in its
elemental form in nature and therefore has to be produced from
hydrocarbons, hydrogen-containing compounds or water.
Above its critical point (374.8oC and 22.1MPa), water has lower
density and viscosity, and a higher heat capacity than those of
ambient water. Mass transfer in supercritical water (SCW) is
enhanced due to its increased diffusivity and transport ability. The
reduced dielectric constant makes supercritical water a better solvent
for organic compounds and gases. Hence, due to the aforementioned
desirable properties, there is a growing interest toward studies
regarding the gasification of organic matter containing biomass or
model biomass solutions in supercritical water.
In this study, hydrogen and biofuel production by the catalytic
gasification of 2-Propanol in supercritical conditions of water was
investigated. Pt/Al2O3and Ni/Al2O3were the catalysts used in the
gasification reactions. All of the experiments were performed under a
constant pressure of 25MPa. The effects of five reaction temperatures
(400, 450, 500, 550 and 600°C) and five reaction times (10, 15, 20,
25 and 30 s) on the gasification yield and flammable component
content were investigated.
Abstract: Irradiated material is a typical example of a complex
system with nonlinear coupling between its elements. During
irradiation the radiation damage is developed and this development
has bifurcations and qualitatively different kinds of behavior.
The accumulation of primary defects in irradiated crystals is
considered in frame work of nonlinear evolution of complex system.
The thermo-concentration nonlinear feedback is carried out as a
mechanism of self-oscillation development.
It is shown that there are two ways of the defect density evolution
under stationary irradiation. The first is the accumulation of defects;
defect density monotonically grows and tends to its stationary state
for some system parameters. Another way that takes place for
opportune parameters is the development of self-oscillations of the
defect density.
The stationary state, its stability and type are found. The
bifurcation values of parameters (environment temperature, defect
generation rate, etc.) are obtained. The frequency of the selfoscillation
and the conditions of their development is found and
rated. It is shown that defect density, heat fluxes and temperature
during self-oscillations can reach much higher values than the
expected steady-state values. It can lead to a change of typical
operation and an accident, e.g. for nuclear equipment.
Abstract: Simultaneous transient conduction and radiation heat
transfer with heat generation is investigated. Analysis is carried out
for both steady and unsteady situations. two-dimensional gray
cylindrical enclosure with an absorbing, emitting, and isotropically
scattering medium is considered. Enclosure boundaries are assumed
at specified temperatures. The heat generation rate is considered
uniform and constant throughout the medium. The lattice Boltzmann
method (LBM) was used to solve the energy equation of a transient
conduction-radiation heat transfer problem. The control volume finite
element method (CVFEM) was used to compute the radiative
information. To study the compatibility of the LBM for the energy
equation and the CVFEM for the radiative transfer equation, transient
conduction and radiation heat transfer problems in 2-D cylindrical
geometries were considered. In order to establish the suitability of the
LBM, the energy equation of the present problem was also solved
using the the finite difference method (FDM) of the computational
fluid dynamics. The CVFEM used in the radiative heat transfer was
employed to compute the radiative information required for the
solution of the energy equation using the LBM or the FDM (of the
CFD). To study the compatibility and suitability of the LBM for the
solution of energy equation and the CVFEM for the radiative
information, results were analyzed for the effects of various
parameters such as the boundary emissivity. The results of the LBMCVFEM
combination were found to be in excellent agreement with
the FDM-CVFEM combination. The number of iterations and the
steady state temperature in both of the combinations were found
comparable. Results are found for situations with and without heat
generation. Heat generation is found to have significant bearing on
temperature distribution.
Abstract: Toughening of polyamide 6 (PA6)/ Nanoclay (NC) nanocomposites with styrene-ethylene/butadiene-styrene copolymer (SEBS) using maleated styrene-ethylene/butadiene-styrene copolymer (mSEBS)/ as a compatibilizer were investigated by blending them in a co-rotating twin-screw extruder. Response surface method of experimental design was used for optimizing the material and processing parameters. Effect of four factors, including SEBS, mSEBS and NC contents as material variables and order of mixing as a processing factor, on toughness of hybrid nanocomposites were studied. All the prepared samples showed ductile behavior and low temperature Izod impact toughness of some of the hybrid nanocomposites demonstrated 900% improvement compared to the PA6 matrix while the modulus showed maximum enhancement of 20% compared to the pristine PA6 resin.
Abstract: In this work the numerical simulation of transient heat
transfer in a cylindrical probe is done. An experiment was conducted
introducing a steel cylinder in a heating chamber and registering its
surface temperature along the time during one hour. In parallel, a
mathematical model was solved for one dimension transient heat
transfer in cylindrical coordinates, considering the boundary
conditions of the test. The model was solved using finite difference
method, because the thermal conductivity in the cylindrical steel bar
and the convection heat transfer coefficient used in the model are
considered temperature dependant functions, and both conditions
prevent the use of the analytical solution. The comparison between
theoretical and experimental results showed the average deviation is
below 2%. It was concluded that numerical methods are useful in
order to solve engineering complex problems. For constant k and h,
the experimental methodology used here can be used as a tool for
teaching heat transfer in mechanical engineering, using mathematical
simplified models with analytical solutions.