Abstract: Carbon nanotubes (CNTs) possess unique structural,
mechanical, thermal and electronic properties, and have been
proposed to be used for applications in many fields. However, to
reach the full potential of the CNTs, many problems still need to be
solved, including the development of an easy and effective
purification procedure, since synthesized CNTs contain impurities,
such as amorphous carbon, carbon nanoparticles and metal particles.
Different purification methods yield different CNT characteristics
and may be suitable for the production of different types of CNTs. In
this study, the effect of different purification chemicals on carbon
nanotube quality was investigated. CNTs were firstly synthesized by
chemical vapor deposition (CVD) of acetylene (C2H2) on a
magnesium oxide (MgO) powder impregnated with an iron nitrate
(Fe(NO3)3·9H2O) solution. The synthesis parameters were selected
as: the synthesis temperature of 800°C, the iron content in the
precursor of 5% and the synthesis time of 30 min. The liquid phase
oxidation method was applied for the purification of the synthesized
CNT materials. Three different acid chemicals (HNO3, H2SO4, and
HCl) were used in the removal of the metal catalysts from the
synthesized CNT material to investigate the possible effects of each
acid solution to the purification step. Purification experiments were
carried out at two different temperatures (75 and 120 °C), two
different acid concentrations (3 and 6 M) and for three different time
intervals (6, 8 and 15 h). A 30% H2O2 : 3M HCl (1:1 v%) solution
was also used in the purification step to remove both the metal
catalysts and the amorphous carbon. The purifications using this
solution were performed at the temperature of 75°C for 8 hours.
Purification efficiencies at different conditions were evaluated by
thermogravimetric analysis. Thermal and electrical properties of
CNTs were also determined. It was found that the obtained electrical
conductivity values for the carbon nanotubes were typical for organic
semiconductor materials and thermal stabilities were changed
depending on the purification chemicals.
Abstract: In the present study, Convective heat transfer
coefficient and pressure drop of Al2O3/water nanofluid in laminar
flow regime under constant heat flux conditions inside a circular tube
were experimentally investigated. Al2O3/water nanofluid with 0.5%
and 1% volume concentrations with 15 nm diameter nanoparticles
were used as working fluid. The effect of different volume
concentrations on convective heat transfer coefficient and friction
factor was studied. The results emphasize that increasing of particle
volume concentration leads to enhance convective heat transfer
coefficient. Measurements show the average heat transfer coefficient
enhanced about 11-20% with 0.5% volume concentration and
increased about 16-27% with 1% volume concentration compared to
distilled water. In addition, the convective heat transfer coefficient of
nanofluid enhances with increase in heat flux. From the results, the
average ratio of (fnf/fbf) was about 1.10 for 0.5% volume
concentration. Therefore, there is no significant increase in friction
factor for nanofluids.
Abstract: Cardiovascular diseases, principally atherosclerosis, are responsible for 30% of world deaths. Atherosclerosis is due to the formation of plaque. The fatty plaque may be at risk of rupture, leading typically to stroke and heart attack. The plaque is usually associated with a high degree of lumen reduction, called a stenosis.It is increasingly recognized that the initiation and progression of disease and the occurrence of clinical events is a complex interplay between the local biomechanical environment and the local vascular biology. The aim of this study is to investigate the flow behavior through a stenosed artery. A physical experiment was performed using an artery model and blood analogue fluid. An axisymmetric model constructed consists of contraction and expansion region that follow a mathematical form of cosine function. A 30% diameter reduction was used in this study. The flow field was measured using particle image velocimetry (PIV). Spherical particles with 20μm diameter were seeded in a water-glycerol-NaCl mixture. Steady flow Reynolds numbers are 250. The area of interest is the region after the stenosis where the flow separation occurs. The velocity field was measured and the velocity gradient was investigated. There was high particle concentration in the recirculation zone. High velocity gradient formed immediately after the stenosis throat created a lift force that enhanced particle migration to the flow separation area.
Abstract: In this paper a numerical simulation of electric and
hydrodynamic fields distribution in an electrofilter for dielectric
liquids cell is made. The simulation is made with the purpose to
determine the trajectory of particles that moves under the action of
external force in an electric and hydrodynamic field created inside of
an electrofilter for dielectric liquids. Particle trajectory is analyzed
for a dielectric liquid-solid particles suspension.
Abstract: A 3D simulation study for an incompressible
slip flow around a spherical aerosol particle was performed.
The full Navier-Stokes equations were solved and the velocity
jump at the gas-particle interface was treated numerically by
imposition of the slip boundary condition. Analytical solution
to the Stokesian slip flow past a spherical particle was used as
a benchmark for code verification, and excellent agreement
was achieved. The Simulation results showed that in addition
to the Knudsen number, the Reynolds number affects the slip
correction factor. Thus, the Cunningham-based slip corrections
must be augmented by the inclusion of the effect of
Reynolds number for application to Lagrangian tracking of
fine particles. A new expression for the slip correction factor
as a function of both Knudsen number and Reynolds number
was developed.
Abstract: The aims of this paper are to study the efficacy of
chitosan nanoparticles in stimulating specific antibody against
A/H1N1 influenza antigen in mice. Chitosan nanoparticles (CSN)
were characterized by TEM. The results showed that the average size
of CSN was from 80nm to 106nm. The efficacy of A/H1N1 influenza
vaccine loaded on the surface of CSN showed that loading efficiency
of A/H1N1 influenza antigen on CSN was from 93.75 to 100%. Safe
property of the vaccine were tested. In 10 days post vaccination,
group of CSN 30 kDa and 300 kDa loaded A/H1N1 influenza antigen
were the rate of immune response on mice to be 100% (9/9) higher
than Al(OH)3 and other adjuvant. 100% mice in the experiment of all
groups had immune response in 20 days post vaccination. The results
also showed that HI titer of the group using CSN 300 kDa as an
adjuvant increased significantly up to 3971 HIU, over three-fold
higher than the Al(OH)3 adjuvant, chitosan (CS), and one hundredfold
than the A/H1N1 antigen only. Stability of the vaccine
formulation was investigated.
Abstract: We estimate snow velocity and snow drift density on hilly terrain under the assumption that the drifting snow mass can be represented using a micro-continuum approach (i.e. using a nonclassical mechanics approach assuming a class of fluids for which basic equations of mass, momentum and energy have been derived). In our model, the theory of coupled stress fluids proposed by Stokes [1] has been employed for the computation of flow parameters. Analyses of bulk drift velocity, drift density, drift transport and mass transport of snow particles have been carried out and computations made, considering various parametric effects. Results are compared with those of classical mechanics (logarithmic wind profile). The results indicate that particle size affects the flow characteristics significantly.
Abstract: In this study we applied thermal lens (TL) technique
to study the effect of size on thermal diffusivity of cadmium sulphide
(CdS) nanofluid prepared by using γ-radiation method containing
particles with different sizes. In TL experimental set up a diode laser
of wavelength 514 nm and intensity stabilized He-Ne laser were used
as the excitation source and the probe beam respectively,
respectively. The experimental results showed that the thermal
diffusivity value of CdS nanofluid increases when the of particle size
increased.
Abstract: Fly ash is a significant waste that is released of
thermal power plants and defined as very fine particles that are drifted upward with up taken by the flue gases due to the burning of
used coal [1]. The fly-ash is capable of removing organic
contaminants in consequence of high carbon content, a large surface area per unit volume and contained heavy metals. Therefore, fly ash
is used as an effective coagulant and adsorbent by pelletization [2, 3].
In this study, the possibility of use of fly ash taken from Turkey like low-cost adsorbent for adsorption of zinc ions found in waste
water was investigated. The fly ash taken from Turkey was pelletized with bentonite and molass to evaluate the adsorption capaticity. For
this purpose; analyses such as sieve analysis, XRD, XRF, FTIR and SEM were performed. As a result, it was seen that pellets prepared
from fly ash, bentonite and molass would be used for zinc adsorption.
Abstract: We have developed a microfluidic device system for the continuous producting of nanoparticles, and we have clarified the relationship between the mixing performance of reactors and the particle size. First, we evaluated the mixing performance of reactors by carring out the Villermaux–Dushman reaction and determined the experimental conditions for producing AgCl nanoparticles. Next, we produced AgCl nanoparticles and evaluated the mixing performance and the particle size. We found that as the mixing performance improves the size of produced particles decreases and the particle size distribution becomes sharper. We produced AgCl nanoparticles with a size of 86 nm using the microfluidic device that had the best mixing performance among the three reactors we tested in this study; the coefficient of variation (Cv) of the size distribution of the produced nanoparticles was 26.1%.
Abstract: Silver nano-particles have been used for antibacterial
purpose and it is also believed to have removal of odorous compounds,
oxidation capacity as a metal catalyst. In this study, silver
nano-particles in nano sizes (5-30 nm) were prepared on the surface of
NaHCO3, the supporting material, using a sputtering method that
provided high silver content and minimized conglomerating problems
observed in the common AgNO3 photo-deposition method. The silver
nano-particles were dispersed by dissolving Ag-NaHCO3 into water,
and the dispersed silver nano-particles in the aqueous phase were
applied to remove inorganic odor compounds, H2S, in a scrubbing
reactor. Hydrogen sulfide in the gas phase was rapidly removed by the
silver nano-particles, and the concentration of sulfate (SO4
2-) ion
increased with time due to the oxidation reaction by silver as a
catalyst. Consequently, the experimental results demonstrated that the
silver nano-particles in the aqueous solution can be successfully
applied to remove odorous compounds without adding additional
energy sources and producing any harmful byproducts
Abstract: Soil stabilization has been widely used to improve
soil strength and durability or to prevent erosion and dust generation.
Generally to reduce problems of clayey soils in engineering work and
to stabilize these soils additional materials are used. The most
common materials are lime, fly ash and cement. Using this materials,
although improve soil property , but in some cases due to financial
problems and the need to use special equipment are limited .One of
the best methods for stabilization clayey soils is neutralization the
clay particles. For this purpose we can use ion exchange materials.
Ion exchange solution like CBR plus can be used for soil
stabilization. One of the most important things in using CBR plus is
determination the amount of this solution for various soils with
different properties. In this study a laboratory experiment is conduct
to evaluate the ion exchange capacity of three soils with various
plasticity index (PI) to determine amount or required CBR plus
solution for soil stabilization.
Abstract: Iron ore and coal are the two major important raw
materials being used in Iron making industries. Usually ore fines
containing around 5% Alumina are rejected due to higher proportion
of alumina. Therefore, a technology or process which may reduce
the alumina content by 2% by beneficiation process will be highly
attractive . In addition fine coals with ash content is used nearly 12%
is directly injected in blast furnace. Fast fluidization is a technology
by using dry beneficiation of coal and iron ore can be done. During
the fluidization process the iron ore band coal is fluidized at high
velocity in the riser of a fast fluidized bed, the heavier and coarse
particles is generally settled at the bottom in a dense zone of the riser
while the finer and lighter particle are entrained to the top dilute zone
and then via a cyclone is fed back to the bottom of the riser column.
Most of the alumina and low ash fine size coals being lighter are
expected to move up to the riser and by a natural beneficiation of
ores is expected to take place in the riser. Therefore in this study an
attempt has been made for dry beneficiation of iron ore and coal in a
fluidized bed and its hydrodynamic characterization.
Abstract: A numerical study has been carried out to investigate
the heat transfer by natural convection of nanofluid taking Cu as
nanoparticles and the water as based fluid in a three dimensional
annulus enclosure filled with porous media (silica sand) between two
horizontal concentric cylinders with 12 annular fins of 2.4mm
thickness attached to the inner cylinder under steady state conditions.
The governing equations which used are continuity, momentum and
energy equations under an assumptions used Darcy law and
Boussinesq-s approximation which are transformed to dimensionless
equations. The finite difference approach is used to obtain all the
computational results using the MATLAB-7. The parameters affected
on the system are modified Rayleigh number (10 ≤Ra*≤ 1000), fin
length Hf (3, 7 and 11mm), radius ratio Rr (0.293, 0.365 and 0.435)
and the volume fraction(0 ≤ ¤ò ≤ 0 .35). It was found that the
average Nusselt number depends on (Ra*, Hf, Rr and φ). The results
show that, increasing of fin length decreases the heat transfer rate and
for low values of Ra*, decreasing Rr cause to decrease Nu while for
Ra*
greater than 100, decreasing Rr cause to increase Nu and adding
Cu nanoparticles with 0.35 volume fraction cause 27.9%
enhancement in heat transfer. A correlation for Nu in terms of Ra*,
Hf and φ, has been developed for inner hot cylinder.
Abstract: In the present study, the pressure drop and laminar convection heat transfer characteristics of nanofluids in microchannel heat sink with square duct are numerically investigated. The water based nanofluids created with Al2O3 and CuO particles in four different volume fractions of 0%, 0.5%, 1%, 1.5% and 2% are used to analyze their effects on heat transfer and the pressure drop. Under the laminar, steady-state flow conditions, the finite volume method is used to solve the governing equations of heat transfer. Mixture Model is considered to simulate the nanofluid flow. For verification of used numerical method, the results obtained from numerical calculations were compared with the results in literature for both pure water and the nanofluids in different volume fractions. The distributions of the particles in base fluid are assumed to be uniform. The results are evaluated in terms of Nusselt number, the pressure drop and heat transfer enhancement. Analysis shows that the nanofluids enhance heat transfer while the Reynolds number and the volume fractions are increasing. The best overall enhancement was obtained at φ=%2 and Re=100 for CuO-water nanofluid.
Abstract: Samples of CoFe2-xCrxO4 where x varies from 0.0 to 0.5 were prepared by co-precipitation route. These samples were sintered at 750°C for 2 hours. These particles were characterized by X-ray diffraction (XRD) at room temperature. The FCC spinel structure was confirmed by XRD patterns of the samples. The crystallite sizes of these particles were calculated from the most intense peak by Scherrer formula. The crystallite sizes lie in the range of 37-60 nm. The lattice parameter was found decreasing upon substitution of Cr. DC electrical resistivity was measured as a function of temperature. The room temperature thermoelectric power was measured for the prepared samples. The magnitude of Seebeck coefficient depends on the composition and resistivity of the samples.
Abstract: Heavy rainfall greatly affects the aerodynamic performance of the aircraft. There are many accidents of aircraft caused by aerodynamic efficiency degradation by heavy rain.
In this Paper we have studied the heavy rain effects on the aerodynamic efficiency of cambered NACA 64-210 and symmetric
NACA 0012 airfoils. Our results show significant increase in drag and decrease in lift. We used preprocessing software gridgen for creation of geometry and mesh, used fluent as solver and techplot as postprocessor. Discrete phase modeling called DPM is used to model the rain particles using two phase flow approach. The rain particles are assumed to be inert.
Both airfoils showed significant decrease in lift and increase in drag in simulated rain environment. The most significant difference between these two airfoils was the NACA 64-210 more sensitivity than NACA 0012 to liquid water content (LWC). We believe that the results showed in this paper will be useful for the designer of the commercial aircrafts and UAVs, and will be helpful for training of the pilots to control the airplanes in heavy rain.
Abstract: The present paper discusses the selection of process
parameters for obtaining optimal nanocrystallites size in the CuOZrO2
catalyst. There are some parameters changing the inorganic
structure which have an influence on the role of hydrolysis and
condensation reaction. A statistical design test method is
implemented in order to optimize the experimental conditions of
CuO-ZrO2 nanoparticles preparation. This method is applied for the
experiments and L16 orthogonal array standard. The crystallites size
is considered as an index. This index will be used for the analysis in
the condition where the parameters vary. The effect of pH, H2O/
precursor molar ratio (R), time and temperature of calcination,
chelating agent and alcohol volume are particularity investigated
among all other parameters. In accordance with the results of
Taguchi, it is found that temperature has the greatest impact on the
particle size. The pH and H2O/ precursor molar ratio have low
influences as compared with temperature. The alcohol volume as
well as the time has almost no effect as compared with all other
parameters. Temperature also has an influence on the morphology
and amorphous structure of zirconia. The optimal conditions are
determined by using Taguchi method. The nanocatalyst is studied by
DTA-TG, XRD, EDS, SEM and TEM. The results of this research
indicate that it is possible to vary the structure, morphology and
properties of the sol-gel by controlling the above-mentioned
parameters.
Abstract: Nanotechnology is the science of creating, using and
manipulating objects which have at least one dimension in range of
0.1 to 100 nanometers. In other words, nanotechnology is
reconstructing a substance using its individual atoms and arranging
them in a way that is desirable for our purpose.
The main reason that nanotechnology has been attracting
attentions is the unique properties that objects show when they are
formed at nano-scale. These differing characteristics that nano-scale
materials show compared to their nature-existing form is both useful
in creating high quality products and dangerous when being in
contact with body or spread in environment.
In order to control and lower the risk of such nano-scale particles,
the main following three topics should be considered:
1) First of all, these materials would cause long term diseases that
may show their effects on body years after being penetrated in human
organs and since this science has become recently developed in
industrial scale not enough information is available about their
hazards on body.
2) The second is that these particles can easily spread out in
environment and remain in air, soil or water for very long time,
besides their high ability to penetrate body skin and causing new
kinds of diseases.
3) The third one is that to protect body and environment against
the danger of these particles, the protective barriers must be finer than
these small objects and such defenses are hard to accomplish.
This paper will review, discuss and assess the risks that human and
environment face as this new science develops at a high rate.
Abstract: Magnesium alloys have gained increased attention in recent years in automotive, electronics, and medical industry. This because of magnesium alloys have better properties than aluminum alloys and steels in respects of their low density and high strength to weight ratio. However, the main problems of magnesium alloy welding are the crack formation and the appearance of porosity during the solidification. This paper proposes a unique technique to weld two thin sheets of AZ31B magnesium alloy using a paste containing Ag nanoparticles. The paste containing Ag nanoparticles of 5 nm in average diameter and an organic solvent was used to coat the surface of AZ31B thin sheet. The coated sheet was heated at 100 °C for 60 s to evaporate the solvent. The dried sheet was set as a lower AZ31B sheet on the jig, and then lap fillet welding was carried out by using a pulsed Nd:YAG laser in a closed box filled with argon gas. The characteristics of the microstructure and the corrosion behavior of the joints were analyzed by opticalmicroscopy (OM), energy dispersive spectrometry (EDS), electron probe micro-analyzer (EPMA), scanning electron microscopy (SEM), and immersion corrosion test. The experimental results show that the wrought AZ31B magnesium alloy can be joined successfully using Ag nanoparticles. Ag nanoparticles insert promote grain refinement, narrower the HAZ width and wider bond width compared to weld without and insert. Corrosion rate of welded AZ31B with Ag nanoparticles reduced up to 44 % compared to base metal. The improvement of corrosion resistance of welded AZ31B with Ag nanoparticles due to finer grains and large grain boundaries area which consist of high Al content. β-phase Mg17Al12 could serve as effective barrier and suppressed further propagation of corrosion. Furthermore, Ag distribution in fusion zone provide much more finer grains and may stabilize the magnesium solid solution making it less soluble or less anodic in aqueous