Abstract: Mercury is a natural occurring element and present in
various concentrations in the environment. Due to its toxic effects, it
is desirable to research mercury sensitive materials to adsorb
mercury. This paper describes the preparation of Au nanoparticles for
mercury adsorption by using a microwave (MW)-polyol method in
the presence of three different Sodium Chloride (NaCl)
concentrations (10, 20 and 30 mM). Mixtures of spherical, triangular,
octahedral, decahedral particles and 1-D product were obtained using
this rapid method. Sizes and shapes was found strongly depend on the
concentrations of NaCl. Without NaCl concentration, spherical,
triangular plates, octahedral, decahedral nanoparticles and 1D
product were produced. At the lower NaCl concentration (10 mM),
spherical, octahedral and decahedral nanoparticles were present,
while spherical and decahedral nanoparticles were preferentially form
by using 20 mM of NaCl concentration. Spherical, triangular plates,
octahedral and decahedral nanoparticles were obtained at the highest
NaCl concentration (30 mM). The amount of mercury adsorbed using
20 ppm mercury solution is the highest (67.5 %) for NaCl
concentration of 30 mM. The high yield of polygonal particles will
increase the mercury adsorption. In addition, the adsorption of
mercury is also due to the sizes of the particles. The sizes of particles
become smaller with increasing NaCl concentrations (size ranges, 5-
16 nm) than those synthesized without addition of NaCl (size ranges
11-32 nm). It is concluded that NaCl concentrations affects the
formation of sizes and shapes of Au nanoparticles thus affects the
mercury adsorption.
Abstract: A steady two-phase flow model has been developed to simulate the drying process of porous particle in a pneumatic conveying dryer. The model takes into account the momentum, heat and mass transfer between the continuous phase and the dispersed phase. A single particle model was employed to calculate the evaporation rate. In this model the pore structure is simplified to allow the dominant evaporation mechanism to be readily identified at all points within the duct. The predominant mechanism at any time depends upon the pressure, temperature and the diameter of pore from which evaporating is occurring. The model was validated against experimental studies of pneumatic transport at low and high speeds as well as pneumatic drying. The effects of operating conditions on the dryer parameters are studied numerically. The present results show that the drying rate is enhanced as the inlet gas temperature and the gas flow rate increase and as the solid mass flow rate deceases. The present results also demonstrate the necessity of measuring the inlet gas velocity or the solid concentration in any experimental analysis.
Abstract: Plastics occupy wide place in the applications of
automotive, electronics and house goods. Especially reinforced
plastics become popular because of their high strength besides their
advantages of low weight and easy manufacturability. In this study,
mechanical and morphological properties of polypropylene (PP) and
high density polyethylene (HDPE) matrix composites reinforced with
surface modified nano titan dioxide (TiO2) particles were
investigated. Surface modification was made by coating the nano
powders with maleic anhydride grafted styrene ethylene butylene
styrene (SEBS-g-MA) and silane, respectively. After surface
modification, PP/TiO2 and HDPE/TiO2 composites were obtained by
using twin screw extruder at titan dioxide loading of 1 wt.%, 3 wt.%
and 5 wt.%. Effects of surface modification were determined by
thermal and morphological analysis. SEBS-g-MA provided bridging
effect between TiO2 particles and polymer matrix while silane was
effective as a dispersant. Depending on that, homogenous structures
without agglomeration were obtained. Mechanical tests were
performed on the injection moldings of the composites for obtaining
the impact strength, tensile strength, stress at break, elongation and
elastic modulus. Reinforced HDPE and PP moldings gave higher
tensile strength and elastic modulus due to the rigid structure of TiO2.
Slight increment was seen in stress at break. Elongation and impact
strength decreased due to the stiffness of the nano titan dioxide.
Abstract: Silver nanoparticles were prepared by chemical reduction method. Silver nitrate was taken as the metal precursor and hydrazine hydrate as a reducing agent. The formation of the silver nanoparticles was monitored using UV-Vis absorption spectroscopy. The UV-Vis spectroscopy revealed the formation of silver nanopart├¡cles by exhibing the typical surface plasmon absorption maxima at 418-420 nm from the UV–Vis spectrum. Comparison of theoretical (Mie light scattering theory) and experimental results showed that diameter of silver nanoparticles in colloidal solution is about 60 nm. We have used energy-dispersive spectroscopy (EDX), X-ray diffraction (XRD), transmission electron microscopy (TEM) and, UV–Vis spectroscopy to characterize the nanoparticles obtained. The energy-dispersive spectroscopy (EDX) of the nanoparticles dispersion confirmed the presence of elemental silver signal no peaks of other impurity were detected. The average size and morphology of silver nanoparticles were determined by transmission electron microscopy (TEM). TEM photographs indicate that the nanopowders consist of well dispersed agglomerates of grains with a narrow size distribution (40 and 60 nm), whereas the radius of the individual particles are between 10 and 20 nm. The synthesized nanoparticles have been structurally characterized by X-ray diffraction and transmission high-energy electron diffraction (HEED). The peaks in the XRD pattern are in good agreement with the standard values of the face-centered-cubic form of metallic silver (ICCD-JCPDS card no. 4-0787) and no peaks of other impurity crystalline phases were detected. Additionally, the antibacterial activity of the nanopart├¡culas dispersion was measured by Kirby-Bauer method. The nanoparticles of silver showed high antimicrobial and bactericidal activity against gram positive bacteria such as Escherichia Coli, Pseudimonas aureginosa and staphylococcus aureus which is a highly methicillin resistant strain.
Abstract: In this study, the dispersion of heavy particles line in
an isotropic and incompressible three-dimensional turbulent flow has
been studied using the Kinematic Simulation techniques to find out
the evolution of the line fractal dimension. The fractal dimension of
the line is found in the case of different particle gravity (in practice,
different values of particle drift velocity) in the presence of small
particle inertia with a comparison with that obtained in the diffusion
case of material line at the same Reynolds number. It can be
concluded for the dispersion of heavy particles line in turbulent flow
that the particle gravity affect the fractal dimension of the line for
different particle gravity velocities in the range 0.2 < W < 2. With
the increase of the particle drift velocity, the fractal dimension of the
line decreases which may be explained as the particles pass many
scales in their journey in the direction of the gravity and the particles
trajectories do not affect by these scales at high particle drift
velocities.
Abstract: With the presence of a uniform vertical magnetic field and suspended particles, thermocapillary instability in a horizontal liquid layer is investigated. The resulting eigenvalue is solved by the Galerkin technique for various basic temperature gradients. It is found that the presence of magnetic field always has a stability effect of increasing the critical Marangoni number.
Abstract: Adhesion strength of exterior or interior coating of
steel pipes is too important. Increasing of coating adhesion on
surfaces can increase the life time of coating, safety factor of
transmitting line pipe and decreasing the rate of corrosion and costs.
Preparation of steel pipe surfaces before doing the coating process is
done by shot and grit blasting. This is a mechanical way to do it.
Some effective parameters on that process, are particle size of
abrasives, distance to surface, rate of abrasive flow, abrasive physical
properties, shapes, selection of abrasive, kind of machine and its
power, standard of surface cleanness degree, roughness, time of
blasting and weather humidity. This search intended to find some
better conditions which improve the surface preparation, adhesion
strength and corrosion resistance of coating. So, this paper has
studied the effect of varying abrasive flow rate, changing the
abrasive particle size, time of surface blasting on steel surface
roughness and over blasting on it by using the centrifugal blasting
machine. After preparation of numbers of steel samples (according to
API 5L X52) and applying epoxy powder coating on them, to
compare strength adhesion of coating by Pull-Off test. The results
have shown that, increasing the abrasive particles size and flow rate,
can increase the steel surface roughness and coating adhesion
strength but increasing the blasting time can do surface over blasting
and increasing surface temperature and hardness too, change,
decreasing steel surface roughness and coating adhesion strength.
Abstract: This paper presents the results of an experimental study on the performance of a triboelectric separator of plastic mixtures used for recycling. The separator consists of four cylindrical electrodes. The principle behind the separation technique is based on the difference in the Coulomb force acting on the plastic particles after triboelectric charging. The separation of mixtures of acrylonitrile butadiene styrene (ABS) and polystyrene (PS) using this method was studied. The effects of the triboelectric charging time and applied voltage on the separation efficiency were investigated. The experimental results confirm that it is possible to obtain a high purity and recovery rate for the initial compositions considered in this study.
Abstract: In this researcha particle swarm optimization (PSO)
algorithm is proposedfor no-wait flowshopsequence dependent
setuptime scheduling problem with weighted earliness-tardiness
penalties as the criterion (|,
|Σ
"
).The
smallestposition value (SPV) rule is applied to convert the continuous
value of position vector of particles in PSO to job permutations.A
timing algorithm is generated to find the optimal schedule and
calculate the objective function value of a given sequence in PSO
algorithm. Twodifferent neighborhood structures are applied to
improve the solution quality of PSO algorithm.The first one is based
on variable neighborhood search (VNS) and the second one is a
simple one with invariable structure. In order to compare the
performance of two neighborhood structures, random test problems
are generated and solved by both neighborhood
approaches.Computational results show that the VNS algorithmhas
better performance than the other one especially for the large sized
problems.
Abstract: The expression of LFA-1 diverges from the
physiological condition, thus active targeting carrier can provide the
benefits from difference into LFA-1 expression in various conditions.
Here, the selectivity of cIBR-conjugated nanoparticles (cIBR-NPs),
in terms of uptake, was investigated using PBMCs, Mixed PBMCMolt-
3 cells and Molt-3 cells. The expressions of LFA-1 on Molt-3
cells, from flow cytometry and Western blot, possessed the highest
level whereas PBMCs showed the lowest level. The kinetic uptake
profiles of cIBR-NPs were obtained by flow cytometry, which the
degree of cellular uptake presented a similar trend with the level of
LFA-1 indicating the influence of LFA-1 expression on the cellular
uptake of cIBR-NPs. The conformation of LFA-1 had a slight effect
on the cellular uptake of cIBR-NPs. Overall we demonstrated that
cIBR-NPs enhanced cellular uptake and improved the selectivity of
drug carriers to LFA-1 on the leukemia cells, which related with the
order of LFA-1 expression.
Abstract: In this study, Friction Stir Processing (FSP) a recent grain refinement technique was employed to disperse micron-sized (2 *m) SiCp particles into aluminum alloy AA6063. The feasibility to fabricate bulk composites through FSP was analyzed and experiments were conducted at different traverse speeds and wider volumes of the specimens. Micro structural observation were carried out by employing optical microscopy test of the cross sections in both parallel and perpendicular to the tool traverse direction. Mechanical property including micro hardness was evaluated in detail at various regions on the specimen. The composites had an excellent bonding with aluminum alloy substrate and a significant increase of 30% in the micro hardness value of metal matrix composite (MMC) as to that of the base metal has observed. The observations clearly indicate that SiC particles were uniformly distributed within the aluminum matrix.
Abstract: Biological evolution has generated a rich variety of
successful solutions; from nature, optimized strategies can be
inspired. One interesting example is the ant colonies, which are able
to exhibit a collective intelligence, still that their dynamic is simple.
The emergence of different patterns depends on the pheromone trail,
leaved by the foragers. It serves as positive feedback mechanism for
sharing information.
In this paper, we use the dynamic of TASEP as a model of
interaction at a low level of the collective environment in the ant-s
traffic flow. This work consists of modifying the movement rules of
particles “ants" belonging to the TASEP model, so that it adopts with
the natural movement of ants. Therefore, as to respect the constraints
of having no more than one particle per a given site, and in order to
avoid collision within a bidirectional circulation, we suggested two
strategies: decease strategy and waiting strategy. As a third work
stage, this is devoted to the study of these two proposed strategies-
stability. As a final work stage, we applied the first strategy to the
whole environment, in order to get to the emergence of traffic flow,
which is a way of learning.
Abstract: The stab resistance performance of newly developed
fabric composites composed of hexagonal paper honeycombs, filled
with shear thickening fluid (STF), and woven Kevlar® fabric or
UHMPE was investigated in this study. The STF was prepared by
dispersing submicron SiO2 particles into polyethylene glycol (PEG).
Our results indicate that the STF-Kevlar composite possessed lower
penetration depth than that of neat Kevlar. In other words, the
STF-Kevlar composite can attain the same energy level in
stab-resistance test with fewer layers of Kevlar fabrics than that of the
neat Kevlar fabrics. It also indicates that STF can be used for the
fabrication of flexible body armors and can provide improved
protection against stab threats. We found that the stab resistance of the
STF-Kevlar composite increases with the increase of SiO2
concentration in STF. Moreover, the silica particles functionalized
with silane coupling agent can further improve the stab resistance.
Abstract: Low silica type X (LSX) Zeolite is one of useful
material in many manufacturing due to the advantage properties
including high surface area, stability, microporous crystalline
aluminosilicates and positive ion in an extra–framework. The LSX
was used rice husk silica source which obtained by leaching with
hydrochloric acid and calcination at 500 C. To improve the
synthesis method, the LSX was crystallizated in Teflon–lined
autoclave will expedite deceasing of the amorphous particles. The
mixed gel with composition of 5.5 Na2O : 1.65 K2O : Al2O3 : 2.2
SiO2 : 122 H2O was crystallized in different container
(Polypropylene bottom and Teflon–lined autoclave). The obtained
powder was characterized by X–ray diffraction (XRD), X–ray
fluorescence spectrometry, N2 adsorption-desorption analysis BET
surface area Scanning electron microscopy (SEM) and Fourier
transform infrared spectroscopy to justify the quality of zeolite. The
results showed the crystallized zeolite in Teflon lined autoclave has
102.8 nm of crystal size, 286 m2/g of surface area and fewer amounts
of round amorphous particles when compared with the crystallized
zeolite in Polypropylene.
Abstract: Double heterogeneity of randomly located pebbles in
the core and Coated Fuel Particles (CFPs) in the pebbles are specific
features in pebble bed reactors and usually, because of difficulty to
model with MCNP code capabilities, are neglected. In this study,
characteristics of HTR-10, Tsinghua University research reactor, are
used and not only double heterogeneous but also truncated CFPs and
Pebbles are considered.Firstly, 8335 CFPs are distributed randomly
in a pebble and then the core of reactor is filled with those pebbles
and graphite pebbles as moderator such that 57:43 ratio of fuel and
moderator pebbles is established.Finally, four different core
configurations are modeled. They are Simple Cubic (SC) structure
with truncated pebbles,SC structure without truncated pebble, and
Simple Hexagonal(SH) structure without truncated pebbles and SH
structure with truncated pebbles. Results like effective multiplication
factor (Keff), critical height,etc. are compared with available data.
Abstract: In this paper processes including large deformations of a rubber with hyperelastic material behavior are simulated by the RKPM method. Due to the loss of kronecker delta properties in the mesh less shape functions, the imposition of essential boundary conditions consumes significant CPU time in mesh free computations. In this work transformation method is used for imposition of essential boundary conditions. A RKPM material shape function is used in this analysis. The support of the material shape functions covers the same set of particles during material deformation and hence the transformation matrix is formed only once at the initial stages. A computer program in MATLAB is developed for simulations.
Abstract: Blood pulse is an important human physiological signal commonly used for the understanding of the individual physical health. Current methods of non-invasive blood pulse sensing require direct contact or access to the human skin. As such, the performances of these devices tend to vary with time and are subjective to human body fluids (e.g. blood, perspiration and skin-oil) and environmental contaminants (e.g. mud, water, etc). This paper proposes a simulation model for the novel method of non-invasive acquisition of blood pulse using the disturbance created by blood flowing through a localized magnetic field. The simulation model geometry represents a blood vessel, a permanent magnet, a magnetic sensor, surrounding tissues and air in 2-dimensional. In this model, the velocity and pressure fields in the blood stream are described based on Navier-Stroke equations and the walls of the blood vessel are assumed to have no-slip condition. The blood assumes a parabolic profile considering a laminar flow for blood in major artery near the skin. And the inlet velocity follows a sinusoidal equation. This will allow the computational software to compute the interactions between the magnetic vector potential generated by the permanent magnet and the magnetic nanoparticles in the blood. These interactions are simulated based on Maxwell equations at the location where the magnetic sensor is placed. The simulated magnetic field at the sensor location is found to assume similar sinusoidal waveform characteristics as the inlet velocity of the blood. The amplitude of the simulated waveforms at the sensor location are compared with physical measurements on human subjects and found to be highly correlated.
Abstract: The study of effect of laser scanning speed on
material efficiency in Ti6Al4V application is very important because unspent powder is not reusable because of high temperature oxygen
pick-up and contamination. This study carried out an extensive study
on the effect of scanning speed on material efficiency by varying the
speed between 0.01 to 0.1m/sec. The samples are wire brushed and
cleaned with acetone after each deposition to remove un-melted
particles from the surface of the deposit. The substrate is weighed before and after deposition. A formula was developed to calculate the
material efficiency and the scanning speed was compared with the
powder efficiency obtained. The results are presented and discussed.
The study revealed that the optimum scanning speed exists for this study at 0.01m/sec, above and below which the powder efficiency
will drop
Abstract: As a part of the development of a numerical method of
close capture exhausts systems for machining devices, a test rig
recreating a situation similar to a grinding operation, but in a
perfectly controlled environment, is used. The properties of the
obtained spray of solid particles are initially characterized using
particle tracking velocimetry (PTV), in order to obtain input and
validation parameters for numerical simulations. The dispersion of a
tracer gas (SF6) emitted simultaneously with the particle jet is then
studied experimentally, as the dispersion of such a gas is
representative of that of finer particles, whose aerodynamic response
time is negligible. Finally, complete modeling of the test rig is
achieved to allow comparison with experimental results and thus to
progress towards validation of the models used to describe a twophase
flow generated by machining operation.
Abstract: For relatively small particles of aluminum (5%) is observed to
corrode before passivation occurs at moderate temperatures (>50oC)
in de-ionized water within one hour. Physical contact with alumina
powder results in a significant increase in both the rate of corrosion
and the extent of corrosion before passivation. Whereas the resulting
release of hydrogen gas could be of commercial interest for portable
hydrogen supply systems, the fundamental aspects of Al corrosion
acceleration in presence of dispersed alumina particles are equally
important. This paper investigates the effects of various amounts of
alumina on the corrosion rate of aluminum powders in water and the
effect of multiple additions of aluminum into a single reactor.