Abstract: In this paper we present discretization and decomposition methods for a multi-component transport model of a chemical vapor deposition (CVD) process. CVD processes are used to manufacture deposition layers or bulk materials. In our transport model we simulate the deposition of thin layers. The microscopic model is based on the heavy particles, which are derived by approximately solving a linearized multicomponent Boltzmann equation. For the drift-process of the particles we propose diffusionreaction equations as well as for the effects of heat conduction. We concentrate on solving the diffusion-reaction equation with analytical and numerical methods. For the chemical processes, modelled with reaction equations, we propose decomposition methods and decouple the multi-component models to simpler systems of differential equations. In the numerical experiments we present the computational results of our proposed models.
Abstract: Direct fermentation of 226 white rose tapioca stem to
ethanol by Fusarium oxysporum was studied in a batch reactor.
Fermentation of ethanol can be achieved by sequential pretreatment
using dilute acid and dilute alkali solutions using 100 mesh tapioca
stem particles. The quantitative effects of substrate concentration, pH
and temperature on ethanol concentration were optimized using a full
factorial central composite design experiment. The optimum process
conditions were then obtained using response surface methodology.
The quadratic model indicated that substrate concentration of 33g/l,
pH 5.52 and a temperature of 30.13oC were found to be optimum for
maximum ethanol concentration of 8.64g/l. The predicted optimum
process conditions obtained using response surface methodology was
verified through confirmatory experiments. Leudeking-piret model
was used to study the product formation kinetics for the production
of ethanol and the model parameters were evaluated using
experimental data.
Abstract: In this study, synthesis of biomemitic patterned nano
hydroxyapatite-starch biocomposites using different concentration of
starch to evaluate effect of polymer alteration on biocomposites
structural properties has been reported. Formation of hydroxyapatite
nano particles was confirmed by X-ray diffraction (XRD) and Fourier
transform infrared spectroscopy (FT-IR). Size and morphology of the
samples were characterized using scanning and transmission electron
microscopy (SEM and TEM). It seems that by increasing starch
content, the more active site of polymer (oxygen atoms) can be
provided for interaction with Ca2+ followed by phosphate and
hydroxyl group.
Abstract: We developed a new method based on quasimolecular
modeling to simulate the cavity flow in three cavity
shapes: rectangular, half-circular and bucket beer in cgs units. Each
quasi-molecule was a group of particles that interacted in a fashion
entirely analogous to classical Newtonian molecular interactions.
When a cavity flow was simulated, the instantaneous velocity vector
fields were obtained by using an inverse distance weighted
interpolation method. In all three cavity shapes, fluid motion was
rotated counter-clockwise. The velocity vector fields of the three
cavity shapes showed a primary vortex located near the upstream
corners at time t ~ 0.500 s, t ~ 0.450 s and t ~ 0.350 s, respectively.
The configurational kinetic energy of the cavities increased as time
increased until the kinetic energy reached a maximum at time t ~
0.02 s and, then, the kinetic energy decreased as time increased. The
rectangular cavity system showed the lowest kinetic energy, while
the half-circular cavity system showed the highest kinetic energy.
The kinetic energy of rectangular, beer bucket and half-circular
cavities fluctuated about stable average values 35.62 x 103, 38.04 x
103 and 40.80 x 103 ergs/particle, respectively. This indicated that the
half-circular shapes were the most suitable shape for a shrimp pond
because the water in shrimp pond flows best when we compared with
rectangular and beer bucket shape.
Abstract: The dissolution of spherical particles in liquids is analyzed dynamically. Here, we consider the case the dissolution of solute yields a solute-free solid phase in the outer portion of a particle. As dissolution proceeds, the interface between the undissolved solid phase and the solute-free solid phase moves towards the center of the particle. We assume that there exist two resistances for the diffusion of solute molecules: the resistance due to the solute-free portion of the particle and that due to a surface layer near solid-liquid interface. In general, the equation governing the dynamic behavior of dissolution needs to be solved numerically. However, analytical expressions for the temporal variation of the size of the undissoved portion of a particle and the variation of dissolution time can be obtained in some special cases. The present analysis takes the effect of variable bulk solute concentration on dissolution into account.
Abstract: The influence of extrusion parameters on surface
quality and properties of AA6061+x% vol. SiC (x = 0; 2,5; 5; 7,5;10)
composites was discussed in this paper. The averages size of
AA6061 and SiC particles were 10.6 μm and 0.42 μm, respectively.
Two series of composites (I - compacts were preheated at extrusion
temperature through 0.5 h and cooled by water directly after process;
II - compacts were preheated through 3 hours and were not cooled)
were consolidated via powder metallurgy processing and extruded by
KoBo method. High values of density for both series of composites
were achieved. Better surface quality was observed for II series of
composites. Moreover, for these composites lower (compared to I
series) but more uniform strength properties over the cross-section of
the bar were noticed. Microstructure and Young-s modulus
investigations were made.
Abstract: The dispersion of heavy particles line in an isotropic
and incompressible three-dimensional turbulent flow has been
studied using the Kinematic Simulation techniques to find out the
evolution of the line fractal dimension. In this study, the fractal
dimension of the line is found for different cases of heavy particles
inertia (different Stokes numbers) in the absence of the particle
gravity with a comparison with the fractal dimension obtained in the
diffusion case of material line at the same Reynolds number. It can
be concluded for the dispersion of heavy particles line in turbulent
flow that the particle inertia affect the fractal dimension of a line
released in a turbulent flow for Stokes numbers 0.02 < St < 2. At the
beginning for small times, most of the different cases are not affected
by the inertia until a certain time, the particle response time τa, with
larger time as the particles inertia increases, the fractal dimension of
the line increases owing to the particles becoming more sensitive to
the small scales which cause the change in the line shape during its
journey.
Abstract: The use of magnetic and magnetic/gold core/shell
nanoparticles in biotechnology or medicine has shown good promise
due to their hybrid nature which possesses superior magnetic and
optical properties. Some of these potential applications include
hyperthermia treatment, bio-separations, diagnostics, drug delivery
and toxin removal. Synthesis refinement to control geometric and
magnetic/optical properties, and finding functional surfactants for
biomolecular attachment, are requirements to meet application
specifics.
Various high-temperature preparative methods were used for the
synthesis of iron oxide and gold-coated iron oxide nanoparticles.
Different surface functionalities, such as 11-aminoundecanoic and
11-mercaptoundecanoic acid, were introduced on the surface of the
particles to facilitate further attachment of biomolecular functionality
and drug-like molecules. Nanoparticle thermal stability, composition,
state of aggregation, size and morphology were investigated and the
results from techniques such as Fourier Transform-Infra Red
spectroscopy (FT-IR), Ultraviolet visible spectroscopy (UV-vis),
Transmission Electron Microscopy (TEM) and thermal analysis are
discussed.
Abstract: In hydrocyclones, the particle separation efficiency is
limited by the suspended fine particles, which are discharged with the
coarse product in the underflow. It is well known that injecting water
in the conical part of the cyclone reduces the fine particle fraction in
the underflow. This paper presents a mathematical model that
simulates the water injection in the conical component. The model
accounts for the fluid flow and the particle motion. Particle
interaction, due to hindered settling caused by increased density and
viscosity of the suspension, and fine particle entrainment by settling
coarse particles are included in the model. Water injection in the
conical part of the hydrocyclone is performed to reduce fine particle
discharge in the underflow. The model demonstrates the impact of
the injection rate, injection velocity, and injection location on the
shape of the partition curve. The simulations are compared with
experimental data of a 50-mm cyclone.
Abstract: Fly ash is one of the residues generated in
combustion, and comprises the fine particles that rise with the flue
gases. Ash which does not rise is termed bottom ash [1]. In our
country, it is expected that will be occurred 50 million tons of waste
ash per year until 2020. Released waste from the thermal power
plants is caused very significant problems as known. The fly ashes
can be evaluated by using as adsorbent material.
The purpose of this study is to investigate the possibility of use of
Tuncbilek fly ash like low-cost adsorbents for heavy metal
adsorption. First of all, Tuncbilek fly ash was characterized. For this
purpose; analysis such as sieve analysis, XRD, XRF, SEM and FT-IR
were performed.
Abstract: An embedded system for SEU(single event upset) test
needs to be designed to prevent system failure by high-energy particles
during measuring SEU. SEU is a phenomenon in which the data is changed temporary in semiconductor device caused by high-energy particles. In this paper, we present an embedded system for
SRAM(static random access memory) SEU test. SRAMs are on the DUT(device under test) and it is separated from control board which
manages the DUT and measures the occurrence of SEU. It needs to
have considerations for preventing system failure while managing the
DUT and making an accurate measurement of SEUs. We measure the occurrence of SEUs from five different SRAMs at three different
cyclotron beam energies 30, 35, and 40MeV. The number of SEUs of SRAMs ranges from 3.75 to 261.00 in average.
Abstract: The objective of the present investigation was to
evaluate the morphology of Escherchia coli bacteria in interaction
with SiO2 nanoparticles.
This study was made by atomic force microscopy and quartz
crystal microbalance using SiO2 nanoparticles with 10nm, 50nm and
100nm diameter and bacteria immobilized on polyelectrolyte
multilayer films obtained by spin coating or by “layer by layer”
(LbL) method.
Abstract: Free convection effects and heat transfer due to a pulsating point heat source embedded in an infinite, fluid saturated, porous dusty medium are studied analytically. Both velocity and temperature fields are discussed in the form of series expansions in the Rayleigh number, for both the fluid and particle phases based on the mean heat generation rate from source and on the permeability of the porous dusty medium. This study is carried out by assuming the Rayleigh number small and the validity of Darcy-s law. Analytical expressions for both phases are obtained for second order mean in both velocity and temperature fields and evolution of different wave patterns are observed in the fluctuating part. It has been observed that, at the vicinity of the origin, the second order mean flow is influenced only by relaxation time of dust particles and not by dust concentration.
Abstract: Antimosy-doped tin oxide (ATO) particles were
prepared via chemical coprecipitation and reverse emulsion. The size
and size distribution of ATO particles were obviously decreased via
reverse microemulsion method. At the relatively high yield the ATO
particles were nearly spherical in shape, meanwhile the crystalline
structure and excellent conductivity were reserved, which could satisfy
the requirement as composite fillers, such as dielectric filler of
polyimide film.
Abstract: There have been widespread applications of fluidized beds in industries which are related to the combination of gas-solid particles during the last decade. For instance, in order to crack the catalyses in petrochemical industries or as a drier in food industries. High capacity of fluidized bed in heat and mass transfer has made this device very popular. In order to achieve a higher efficiency of fluidized beds, a particular attention has been paid to beds with pulsating air flow. In this paper, a fluidized bed device with pulsating flow has been designed and constructed. Size of particles have been used during the test are in the range of 40 to 100μm. The purpose of this experimental test is to investigate the air flow regime, observe the particles- movement and measure the pressure loss along the bed. The effects of pulsation can be evaluated by comparing the results for both continuous and pulsating flow. Results of both situations are compared for various gas speeds. Moreover the above experiment is numerically simulated by using Fluent software and its numerical results are compared with the experimental results.
Abstract: This paper presents a novel approach for tuning unified power flow controller (UPFC) based damping controller in order to enhance the damping of power system low frequency oscillations. The design problem of damping controller is formulated as an optimization problem according to the eigenvalue-based objective function which is solved using iteration particle swarm optimization (IPSO). The effectiveness of the proposed controller is demonstrated through eigenvalue analysis and nonlinear time-domain simulation studies under a wide range of loading conditions. The simulation study shows that the designed controller by IPSO performs better than CPSO in finding the solution. Moreover, the system performance analysis under different operating conditions show that the δE based controller is superior to the mB based controller.
Abstract: Fluids are used for heat transfer in many engineering
equipments. Water, ethylene glycol and propylene glycol are some
of the common heat transfer fluids. Over the years, in an attempt to
reduce the size of the equipment and/or efficiency of the process,
various techniques have been employed to improve the heat transfer
rate of these fluids. Surface modification, use of inserts and
increased fluid velocity are some examples of heat transfer
enhancement techniques. Addition of milli or micro sized particles
to the heat transfer fluid is another way of improving heat transfer
rate. Though this looks simple, this method has practical problems
such as high pressure loss, clogging and erosion of the material of
construction. These problems can be overcome by using nanofluids,
which is a dispersion of nanosized particles in a base fluid.
Nanoparticles increase the thermal conductivity of the base fluid
manifold which in turn increases the heat transfer rate. In this work,
the heat transfer enhancement using aluminium oxide nanofluid has
been studied by computational fluid dynamic modeling of the
nanofluid flow adopting the single phase approach.
Abstract: A simple and dexterous in situ method was introduced to load CdS nanocrystals into organofunctionalized mesoporous, which used an ion-exchange method. The products were extensively characterized by combined spectroscopic methods. X- ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM) demonstrated both the maintenance of pore symmetry (space group p6mm) of SBA-15 and the presence of CdS nanocrystals with uniform sizes of about 6 - 8 nm inside the functionalized SBA-15 channels. These mesoporous silica-supported CdS composites showed room temperature photoluminescence properties with a blue shift, indicating the quantum size effect of nanocrystalline CdS.
Abstract: There are many kinds of metal borates found not only
in nature but also synthesized in the laboratory such as magnesium
borates. Due to its excellent properties, as remarkable ceramic
materials, they have also application areas in anti-wear and friction
reducing additives as well as electro-conductive treating agents. The
synthesis of magnesium borate powders can be fulfilled simply with
two different methods, hydrothermal and thermal synthesis.
Microwave assisted method, also another way of producing
magnesium borate, can be classified into thermal synthesis because of
using the principles of solid state synthesis. It also contributes
producing particles with small size and high purity in nano-size
material synthesize. In this study the production of magnesium
borates, are aimed using MgCl2.6H2O and H3BO3. The identification
of both starting materials and products were made by the equipments
of, X-Ray Diffraction (XRD) and Fourier Transform Infrared
Spectroscopy (FT-IR). After several synthesis steps magnesium
borates were synthesized and characterized by XRD and FT-IR, as
well.
Abstract: Addition of milli or micro sized particles to the heat
transfer fluid is one of the many techniques employed for improving
heat transfer rate. Though this looks simple, this method has
practical problems such as high pressure loss, clogging and erosion
of the material of construction. These problems can be overcome by
using nanofluids, which is a dispersion of nanosized particles in a
base fluid. Nanoparticles increase the thermal conductivity of the
base fluid manifold which in turn increases the heat transfer rate.
Nanoparticles also increase the viscosity of the basefluid resulting in
higher pressure drop for the nanofluid compared to the base fluid. So
it is imperative that the Reynolds number (Re) and the volume
fraction have to be optimum for better thermal hydraulic
effectiveness. In this work, the heat transfer enhancement using
aluminium oxide nanofluid using low and high volume fraction
nanofluids in turbulent pipe flow with constant wall temperature has
been studied by computational fluid dynamic modeling of the
nanofluid flow adopting the single phase approach. Nanofluid, up till
a volume fraction of 1% is found to be an effective heat transfer
enhancement technique. The Nusselt number (Nu) and friction factor
predictions for the low volume fractions (i.e. 0.02%, 0.1 and 0.5%)
agree very well with the experimental values of Sundar and Sharma
(2010). While, predictions for the high volume fraction nanofluids
(i.e. 1%, 4% and 6%) are found to have reasonable agreement with
both experimental and numerical results available in the literature.
So the computationally inexpensive single phase approach can be
used for heat transfer and pressure drop prediction of new nanofluids.