Abstract: Ontology is widely being used as a tool for organizing
information, creating the relation between the subjects within the
defined knowledge domain area. Various fields such as Civil,
Biology, and Management have successful integrated ontology in
decision support systems for managing domain knowledge and to
assist their decision makers. Gross pollutant traps (GPT) are devices
used in trapping and preventing large items or hazardous particles in
polluting and entering our waterways. However choosing and
determining GPT is a challenge in Malaysia as there are inadequate
GPT data repositories being captured and shared. Hence ontology is
needed to capture, organize and represent this knowledge into
meaningful information which can be contributed to the efficiency of
GPT selection in Malaysia urbanization. A GPT Ontology framework
is therefore built as the first step to capture GPT knowledge which
will then be integrated into the decision support system. This paper
will provide several examples of the GPT ontology, and explain how
it is constructed by using the Protégé tool.
Abstract: In the present work, we have developed a symmetric electrochemical capacitor based on the nanostructured iron oxide (Fe3O4)-activated carbon (AC) nanocomposite materials. The physical properties of the nanocomposites were characterized by Scanning Electron Microscopy (SEM) and Brunauer-Emmett-Teller (BET) analysis. The electrochemical performances of the composite electrode in 1.0 M Na2SO3 and 1.0 M Na2SO4 aqueous solutions were evaluated using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The composite electrode with 4 wt% of iron oxide nanomaterials exhibits the highest capacitance of 86 F/g. The experimental results clearly indicate that the incorporation of iron oxide nanomaterials at low concentration to the composite can improve the capacitive performance, mainly attributed to the contribution of the pseudocapacitance charge storage mechanism and the enhancement on the effective surface area of the electrode. Nevertheless, there is an optimum threshold on the amount of iron oxide that needs to be incorporated into the composite system. When this optimum threshold is exceeded, the capacitive performance of the electrode starts to deteriorate, as a result of the undesired particle aggregation, which is clearly indicated in the SEM analysis. The electrochemical performance of the composite electrode is found to be superior when Na2SO3 is used as the electrolyte, if compared to the Na2SO4 solution. It is believed that Fe3O4 nanoparticles can provide favourable surface adsorption sites for sulphite (SO3 2-) anions which act as catalysts for subsequent redox and intercalation reactions.
Abstract: Hydraulic conductivity is one parameter important for predicting the movement of water and contaminants dissolved in the water through the soil. The hydraulic conductivity is measured on soil samples in the lab and sometimes tests carried out in the field. The hydraulic conductivity has been related to soil particle diameter by a number of investigators. In this study, 25 set of soil samples with sand texture. The results show approximately success in predicting hydraulic conductivity from particle diameters data. The following relationship obtained from multiple linear regressions on data (R2 = 0.52): Where d10, d50 and d60, are the soil particle diameter (mm) that 10%, 50% and 60% of all soil particles are finer (smaller) by weight and Ks, saturated hydraulic conductivity is expressed in m/day. The results of regression analysis showed that d10 play a more significant role with respect to Ks, saturated hydraulic conductivity (m/day), and has been named as the effective parameter in Ks calculation.
Abstract: Simulations of magnetic microstructure in elliptical
Permalloy elements used for controlled motion of magnetic particles
are discussed. The saturating field of the elliptical elements was
studied with respect to lateral dimensions for one-vortex, cross-tie,
diamond and double-diamond states as initial zero-field domain
configurations. With aspect ratio of 1:3 the short axis was varied
from 125 nm to 1000 nm, whereas the thickness was kept constant at
50 nm.
Abstract: A biocompatible ferrofluid have been prepared by coprecipitation
of FeCl2.4H2O and FeCl3.6H2O under ultrasonic
irradiation and with NaOH as alkaline agent. Cystein was also used
as capping agent in the solution. Magnetic properties of the produced
ferrofluid were then determined by VSM test and magnetite
nanoparticles were characterized by XRD and TEM techniques. The
effect of surfactant to Fe ion weight ratio was also studied during this
project by using two different amount of Dextran. Results showed the
presence of a biocompatible superparamagnetic ferrofluid including
magnetite nanoparticles with particle size ranging under 20 nm. The
increase in the surfactant content results in the narrowing of the size
distribution and reduction of the particle size and more solution
stability.
Abstract: In the paper the research of flat textile products for use
as electrodes was presented. Material-s resistance measurements were
carried out to determine the suitability of the textiles. Based on the received results of studies different types of textile electrodes were
designed. Textile electrodes tests were carried out on human
phantoms. The electro-conductive properties of human forearm
phantom were also described. Based on this results special electroconductive
hydrogels with electro-conductive particles were feasible. The hydrogel is an important element of the forearm-s phantom
model of a survey of electrodes for muscle electrostimulation. The
hydrogel is an equivalent human skin and tissue. The hydrogel should
have a permanence and recurrence of the electro-conductive properties.
Abstract: Composites based on a biodegradable polycaprolactone (PCL) containing 0.5, 1.0 and 2.0 wt % of titanium dioxide (TiO2) micro and nanoparticles were prepared by melt mixing and the effect of filler type and contents on the thermal properties, dynamic-mechanical behaviour and morphology were investigated. Measurements of storage modulus and loss modulus by dynamic mechanical analysis (DMA) showed better results for microfilled PCL/TiO2 composites than nanofilled composites, with the same filler content. DSC analysis showed that the Tg and Tc of micro and nanocomposites were slightly lower than those of neat PCL. The crystallinity of the PCL increased with the addition of TiO2 micro and nanoparticles; however, the cc for the PCL was unchanged with micro TiO2 content. The thermal stability of PCL/TiO2 composites were characterized using thermogravimetric analysis (TGA). The initial weight loss (5 wt %) occurs at slightly higher temperature with micro and nano TiO2 addition and with increasing TiO2 content.
Abstract: The purpose of this study was to investigate the
response of the newly released Gafchromic HD-V2 film for alpha
particle of 5.5 MeV. Gafchromic HD-V2 was exposed to alpha
particles of energy 5 MeV from 241Am for different durations. Then
the films were scanned with a flatbed scanner. The dose response
curve up to 2200 Gy has been achieved. The film’s reproducibility
and sensitivity were evaluated. The results obtained show that the net
optical density increases almost exponentially with the increase in the
exposure time, and it becomes saturated after prolonged exposure
times. The red channel shows the highest sensitivity, with a value of
4 x 10-3 Gy-1 at netOD of 0.4. The inter-film reproducibility was
measured and the relative uncertainty found was 1.7 %, 2.1 % and 2.3
% for grey, red and green channels, respectively.
Abstract: The basis of examines is survey of 500 in the years
2002-2010, which was selected according to homogeneity of land
cover and where 1090 revenues were evaluated. For achieved yields
of winter wheat is obtained multicriterial regression function
depending on the major factors influencing the consumption of
nitrogen. The coefficient of discrimination of the established model is
0.722. The increase in efficiency of fertilization is involved in supply
of organic nutrients, tillage, soil pH, past weather, the humus content
in the subsoil and grain content to 0.001 mm. The decrease in
efficiency was mainly influenced by the total dose of mineral
nitrogen, although it was divided into multiple doses, the proportion
loamy particles up to 0.01 mm, rainy, or conversely dry weather
during the vegetation. The efficiency of nitrogen was found to be the
smallest on undeveloped soils and the highest on chernozem and
alluvial soils.
Abstract: We developed a method based on quasi-molecular
modelling to simulate the fall of water drops on horizontally smooth
and rough surfaces. Each quasi-molecule was a group of particles
that interacted in a fashion entirely analogous to classical Newtonian
molecular interactions. When a falling water droplet was simulated at
low impact velocity on both smooth and rough surfaces, the droplets
moved periodically (i.e. the droplets moved up and down for a
certain period, finally they stopped moving and reached a steady
state), spreading and recoiling without splash or break-up. Spreading
rates of falling water droplets increased rapidly as time increased
until the spreading rate reached its steady state at time t ~ 0.25 s for
rough surface and t ~ 0.40 s for smooth surface. The droplet height
above both surfaces decreased as time increased, remained constant
after the droplet diameter attained a maximum value and reached its
steady state at time t ~ 0.4 s. However, rough surface had higher
spreading rates of falling water droplets and lower height on the
surface than smooth one.
Abstract: Sol-gel method has been used to fabricate
nanocomposite films on glass substrates composed halloysite clay
mineral and nanocrystalline TiO2. The methodology for the synthesis
involves a simple chemistry method utilized nonionic surfactant
molecule as pore directing agent along with the acetic acid-based solgel
route with the absence of water molecules. The thermal treatment
of composite films at 450oC ensures elimination of organic material
and lead to the formation of TiO2 nanoparticles onto the surface of
the halloysite nanotubes. Microscopy techniques and porosimetry
methods used in order to delineate the structural characteristics of the
materials. The nanocomposite films produced have no cracks and
active anatase crystal phase with small crystallite size were deposited
on halloysite nanotubes. The photocatalytic properties for the new
materials were examined for the decomposition of the Basic Blue 41
azo dye in solution. These, nanotechnology based composite films
show high efficiency for dye’s discoloration in spite of different
halloysite quantities and small amount of halloysite/TiO2 catalyst
immobilized onto glass substrates. Moreover, we examined the
modification of the halloysite/TiO2 films with silver particles in order
to improve the photocatalytic properties of the films. Indeed, the
presence of silver nanoparticles enhances the discoloration rate of the
Basic Blue 41 compared to the efficiencies obtained for unmodified
films.
Abstract: The effect of Alumina nanoparticle size on thermophysical
properties, heat transfer performance and pressure loss characteristics of
Aviation Turbine Fuel (ATF)-Al2O3 nanofluids is studied experimentally for
the proposed application of regenerative cooling of semi-cryogenic rocket
engine thrust chambers. Al2O3 particles with mean diameters of 50 nm or 150
nm are dispersed in ATF. At 500C and 0.3% particle volume concentration,
the bigger particles show increases of 17% in thermal conductivity and 55% in
viscosity, whereas the smaller particles show corresponding increases of 21%
and 22% for thermal conductivity and viscosity respectively. Contrary to these
results, experiments to study the heat transfer performance and pressure loss
characteristics show that at the same pumping power, the maximum
enhancement in heat transfer coefficient at 500C and 0.3% concentration is
approximately 47% using bigger particles, whereas it is only 36% using
smaller particles.
Abstract: The purpose of this investigation is to relate the rain
power and the overland flow power to soil erodibility to assess the
effects of both parameters on soil erosion using variable rainfall
intensity on remoulded agricultural soil. Six rainfall intensities were
used to simulate the natural rainfall and are as follows: 12.4mm/h,
20.3mm/h, 28.6mm/h, 52mm/h, 73.5mm/h and 103mm/h. The results
have shown that the relationship between overland flow power and
rain power is best represented by a linear function (R2=0.99). As
regards the relationships between soil erodibility factor and rain and
overland flow powers, the evolution of both parameters with the
erodibility factor follow a polynomial function with high coefficient
of determination. From their coefficients of determination (R2=0.95)
for rain power and (R2=0.96) for overland flow power, we can
conclude that the flow has more power to detach particles than rain.
This could be explained by the fact that the presence of particles,
already detached by rain and transported by the flow, give the flow
more weight and then contribute to the detachment of particles by
collision.
Abstract: The paper reports the preparation and photocatalytic
activity of ZnO/SnO2 and SnO2 nanoparticles. These nanoparticles
were synthesized by hydrothermal method. The products were
characterized by X-ray diffraction (XRD) and scanning electron
microscopy (SEM). Their grain sizes are about 50-100 nm. The
photocatalytic activities of these materials were investigated for
congo red removal from aqueous solution under UV light irradiation.
It was shown that the use of ZnO/SnO2 as photocatalyst have better
photocatalytic activity for degradation of congo red than SnO2 or
TiO2 (anatase, particle size: 30nm) alone.
Abstract: Polymeric microreactors have emerged as a new
generation of carriers that hold tremendous promise in the areas of
cancer therapy, controlled delivery of drugs, for removal of
pollutants etc. Present work reports a simple and convenient
methodology for synthesis of polystyrene and poly caprolactone
microreactors. An aqueous suspension of carboxylated (1μm)
polystyrene latex particles was mixed with toluene solution followed
by freezing with liquid nitrogen. Freezed particles were incubated at
-20°C and characterized for formation of voids on the surface of
polymer microspheres by Field Emission Scanning Electron
Microscope. The hollow particles were then overnight incubated at
40ºC with unfunctionalized quantum dots (QDs) in 5:1 ratio. QDs
Encapsulated polystyrene microcapsules were characterized by
fluorescence microscopy.
Likewise Poly ε-caprolactone microreactors were prepared by
micro-volcanic rupture of freeze dried microspheres synthesized
using emulsification of polymer with aqueous Poly vinyl alcohol and
freezed with liquid nitrogen. Microreactors were examined with Field
Emission Scanning Electron Microscope for size and morphology.
Current study is an attempt to create hollow polymer particles which
can be employed for microencapsulation of nanoparticles and drug
molecules.
Abstract: Bionanotechnology deals with nanoscopic interactions between nanostructured materials and biological systems. Polymer nanocomposites with optimized biological activity have attracted great attention. Nanoclay is considered as reinforcing nanofiller in manufacturing of high performance nanocomposites. In current study, organomodified-nanoclay with negatively charged silicate layers was incorporated into biomedical grade silicone rubber. Nanoparticle loading has been tailored to enhance cell behavior. Addition of nanoparticles led to improved mechanical properties of substrate with enhanced strength and stiffness while no toxic effects was observed. Results indicated improved viability and proliferation of cells by addition of nanofillers. The improved mechanical properties of the matrix result in proper cell response through adjustment and arrangement of cytoskeletal fibers. Results can be applied in tissue engineering when enhanced substrates are required for improvement of cell behavior for in vivo applications.
Abstract: Multidrug resistant organisms have been taunting the
medical world for the last few decades. Even with new antibiotics
developed, resistant strains have emerged soon after. With the
advancement of nanotechnology, we investigated colloidal silver
nanoparticles for its antimicrobial activity against Pseudomonas
aeruginosa. This organism is a multidrug resistant which contributes
to the high morbidity and mortality in immunocompromised patients.
Five multidrug resistant strains were used in this study. The
antimicrobial effect was studied using the disc diffusion and broth
dilution techniques. An inhibition zone of 11 mm was observed with
10 μg dose of the nanoparticles. The nanoparticles exhibited MIC of
50 μg/ml when added at the lag phase and the subinhibitory
concentration was measured as 100 μg/ml. The MIC50 value showed
to be 15 μg/ml. This study suggests that silver nanoparticles can be
further developed as an antimicrobial agent, hence decreasing the
burden of the multidrug resistance phenomena.
Abstract: Tribological behavior and wear regimes of ascast
and heattreted Al-Cu-Mg matrix composites containing SiC
particles were studied using a pin-on-disc wear testing apparatus
against an EN32 steel counterface giving emphasis on wear rate as
a function of applied pressures (0.2, 0.6, 1.0 and 1.4 MPa) at
different sliding distances (1000, 2000, 3000, 4000 and 5000
meters) and at a fixed sliding speed of 3.35m/s. The results showed
that the composite exhibited lower wear rate than that of the matrix
alloy and the wear rate of the composites is noted to be invariant to
the sliding distance and is reducing by heat treatment. Wear
regimes such as low, mild and severe wear were observed as per the
Archard-s wear calculations. It is very interesting to note that the
mild wear is almost constant in all the wear regimes.
Abstract: In this study, a low temperature sensor highly selective to CO in presence of methane is fabricated by using 4 nm SnO2 quantum dots (QDs) prepared by sonication assisted precipitation. SnCl4 aqueous solution was precipitated by ammonia under sonication, which continued for 2 h. A part of the sample was then dried and calcined at 400°C for 1.5 h and characterized by XRD and BET. The average particle size and the specific surface area of the SnO2 QDs as well as their sensing properties were compared with the SnO2 nano-particles which were prepared by conventional sol-gel method. The BET surface area of sonochemically as-prepared product and the one calcined at 400°C after 1.5 hr are 257 m2/gr and 212 m2/gr respectively while the specific surface area for SnO2 nanoparticles prepared by conventional sol-gel method is about 80m2/gr. XRD spectra revealed pure crystalline phase of SnO2 is formed for both as-prepared and calcined samples of SnO2 QDs. However, for the sample prepared by sol-gel method and calcined at 400°C SnO crystals are detected along with those of SnO2. Quantum dots of SnO2 show exceedingly high sensitivity to CO with different concentrations of 100, 300 and 1000 ppm in whole range of temperature (25- 350°C). At 50°C a sensitivity of 27 was obtained for 1000 ppm CO, which increases to a maximum of 147 when the temperature rises to 225°C and then drops off while the maximum sensitivity for the SnO2 sample prepared by the sol-gel method was obtained at 300°C with the amount of 47.2. At the same time no sensitivity to methane is observed in whole range of temperatures for SnO2 QDs. The response and recovery times of the sensor sharply decreases with temperature, while the high selectivity to CO does not deteriorate.
Abstract: Three reactor types were explored and successfully
used for pigment production by Monascus: shake flasks, and shaken
and stirred miniaturized reactors. Also, the use of dielectric
spectroscopy for the on-line measurement of biomass levels was
explored. Shake flasks gave good pigment yields, but scale up is
difficult, and they cannot be automated. Shaken bioreactors were less
successful with pigment production than stirred reactors.
Experiments with different impeller speeds in different volumes of
liquid in the reactor confirmed that this is most likely due oxygen
availability. The availability of oxygen appeared to affect biomass
levels less than pigment production; red pigment production in
particular needed very high oxygen levels. Dielectric spectroscopy
was effectively used to continuously measure biomass levels during
the submerged fungal fermentation in the shaken and stirred
miniaturized bioreactors, despite the presence of the solid substrate
particles. Also, the capacitance signal gave useful information about
the viability of the cells in the culture.