Abstract: The paper deals with the development of portable aerosol concentrator and its application for the determination of nitrites and nitrates. The device enables the continuous trapping of pollutants in the air. An extensive literature search has been elaborated which aims at the development of samplers and the possibilities of their application in the continuous determination of volatile organic compounds. The practical part of the paper is focused on the development of the portable aerosol concentrator. The device using the Aerosol Enrichment Unit has been experimentally verified and subsequently realized. It operates on the principle of equilibrium accumulation of pollutants from the gaseous phase using absorption liquid polydisperse aerosol. The device has been applied for monitoring nitrites and nitrates in the air. The chemiluminescence detector was used for detection; the achieved detection limit for nitrites was 28 ng/m3 and for nitrates 78 ng/m3.
Abstract: This article reports on the studies of porous GaN prepared by ultra-violet (UV) assisted electrochemical etching in a solution of 4:1:1 HF: CH3OH:H2O2 under illumination of an UV lamp with 500 W power for 10, 25 and 35 minutes. The optical properties of porous GaN sample were compared to the corresponding as grown GaN. Porosity induced photoluminescence (PL) intensity enhancement was found in these samples. The resulting porous GaN displays blue shifted PL spectra compared to the as-grown GaN. Appearance of the blue shifted emission is correlated with the development of highly anisotropic structures in the morphology. An estimate of the size of the GaN nanostructure can be obtained with the help of a quantized state effective mass theory.
Abstract: The research was designed to examine the relationship
between the development of muscle fatigue and the effect it has on
sport performance, specifically during maximal voluntary
contraction. This kind of this investigation using simultaneous
electrophysiological and mechanical recordings, based on advanced
mathematical processing, allows us to get parameters, and indexes in
a short time, and finally, the mapping to use for the thorough
investigation of the muscle contraction force, respectively the
phenomenon of local muscle fatigue, both for athletes and other
subjects.
Abstract: In recent years, it has been proposed security
architecture for sensor network.[2][4]. One of these, TinySec by Chris
Kalof, Naveen Sastry, David Wagner had proposed Link layer security
architecture, considering some problems of sensor network. (i.e :
energy, bandwidth, computation capability,etc). The TinySec employs
CBC_mode of encryption and CBC-MAC for authentication based on
SkipJack Block Cipher. Currently, This TinySec is incorporated in the
TinyOS for sensor network security.
This paper introduces TinyHash based on general hash algorithm.
TinyHash is the module in order to replace parts of authentication and
integrity in the TinySec. it implies that apply hash algorithm on
TinySec architecture. For compatibility about TinySec, Components
in TinyHash is constructed as similar structure of TinySec. And
TinyHash implements the HMAC component for authentication and
the Digest component for integrity of messages. Additionally, we
define the some interfaces for service associated with hash algorithm.
Abstract: The construction of original functional sample of the portable device for fast analysis of energetic materials has been described in the paper. The portable device consisting of two parts – an original miniaturized microcolumn liquid chromatograph and a unique chemiluminescence detector – has been proposed and realized. In a very short time, this portable device is capable of identifying selectively most of military nitramine- and nitroesterbased explosives as well as inorganic nitrates occurring in trace concentrations in water or in soil. The total time required for the identification of extracts is shorter than 8 minutes.
Abstract: Acute toxicity of nano SiO2, ZnO, MCM-41 (Meso
pore silica), Cu, Multi Wall Carbon Nano Tube (MWCNT), Single
Wall Carbon Nano Tube (SWCNT) , Fe (Coated) to bacteria Vibrio
fischeri using a homemade luminometer , was evaluated. The values
of the nominal effective concentrations (EC), causing 20% and 50%
inhibition of biouminescence, using two mathematical models at two
times of 5 and 30 minutes were calculated. Luminometer was
designed with Photomultiplier (PMT) detector. Luminol
chemiluminescence reaction was carried out for the calibration graph.
In the linear calibration range, the correlation coefficients and
coefficient of Variation (CV) were 0.988 and 3.21% respectively
which demonstrate the accuracy and reproducibility of the instrument
that are suitable. The important part of this research depends on how
to optimize the best condition for maximum bioluminescence. The
culture of Vibrio fischeri with optimal conditions in liquid media,
were stirring at 120 rpm at a temperature of 150C to 180C and were
incubated for 24 to 72 hours while solid medium was held at 180C
and for 48 hours. Suspension of nanoparticles ZnO, after 30 min
contact time to bacteria Vibrio fischeri, showed the highest toxicity
while SiO2 nanoparticles showed the lowest toxicity. After 5 min
exposure time, the toxicity of ZnO was the strongest and MCM-41
was the weakest toxicant component.
Abstract: The possibility of intrinsic electromagnetic fields
within living cells and their resonant self-interaction and interaction
with ambient electromagnetic fields is suggested on the basis of a
theoretical and experimental study. It is reported that intrinsic
electromagnetic fields are produced in the form of radio-frequency
and infra-red photons within atoms (which may be coupled or
uncoupled) in cellular structures, such as the cell cytoskeleton and
plasma membrane. A model is presented for the interaction of these
photons among themselves or with atoms under a dipole-dipole
coupling, induced by single-photon or two-photon processes. This
resonance is manifested by conspicuous field amplification and it is
argued that it is possible for these resonant photons to undergo
tunnelling in the form of evanescent waves to a short range (of a few
nanometers to micrometres). This effect, suggested as a resonant
photon tunnelling mechanism in this report, may enable these fields
to act as intracellular signal communication devices and as bridges
between macromolecules or cellular structures in the cell
cytoskeleton, organelles or membrane. A brief overview of an
experimental technique and a review of some preliminary results are
presented, in the detection of these fields produced in living cell
membranes under physiological conditions.
Abstract: Polystyrene particles of different sizes are optically
trapped with a gaussian beam from a He-Cd laser operating at 442
nm. The particles are observed to exhibit luminescence after a certain
trapping time followed by an escape from the optical trap. The
observed luminescence is explained in terms of the photodegradation
of the polystyrene backbone. It is speculated that these chemical
modifications also play a role for the escape of the particles from the
trap. Variations of the particle size and the laser power show that
these parameters have a great influence on the observed phenomena.
Abstract: Optical Coherence Tomography (OCT) combined
with the Confocal Microscopy, as a noninvasive method, permits the
determinations of materials defects in the ceramic layers depth. For
this study 256 anterior and posterior metal and integral ceramic fixed
partial dentures were used, made with Empress (Ivoclar), Wollceram
and CAD/CAM (Wieland) technology. For each investigate area 350
slices were obtain and a 3D reconstruction was perform from each
stuck. The Optical Coherent Tomography, as a noninvasive method,
can be used as a control technique in integral ceramic technology,
before placing those fixed partial dentures in the oral cavity. The
purpose of this study is to evaluate the capability of En face Optical
Coherence Tomography (OCT) combined with a fluorescent method
in detection and analysis of possible material defects in metalceramic
and integral ceramic fixed partial dentures. As a conclusion,
it is important to have a non invasive method to investigate fixed
partial prostheses before their insertion in the oral cavity in order to
satisfy the high stress requirements and the esthetic function.
Abstract: In this paper, the application of the Mode Matching
(MM) method in the case of photonic crystal waveguide
discontinuities is presented. The structure under consideration is
divided into a number of cells, which supports a number of guided
and evanescent modes. These modes can be calculated numerically
by an alternative formulation of the plane wave expansion method
for each frequency. A matrix equation is then formed relating the
modal amplitudes at the beginning and at the end of the structure.
The theory is highly efficient and accurate and can be applied to
study the transmission sensitivity of photonic crystal devices due to
fabrication tolerances. The accuracy of the MM method is compared
to the Finite Difference Frequency Domain (FDFD) and the Adjoint
Variable Method (AVM) and good agreement is observed.
Abstract: We investigated a modified thermal evaporation
method in the growth process of ZnO nanowires. ZnO nanowires
were fabricated on p-type silicon substrates without using a metal
catalyst. A simple horizontal double-tube system along with
chemical vapor diffusion of the precursor was used to grow the ZnO
nanowires. The substrates were placed in different temperature
zones, and ZnO nanowires with different diameters were obtained for
the different substrate temperatures. In addition to the nanowires,
ZnO microdiscs with different diameters were obtained on another
substrate, which was placed at a lower temperature than the other
substrates. The optical properties and crystalline quality of the ZnO
nanowires and microdiscs were characterized by room temperature
photoluminescence (PL) and Raman spectrometers. The PL and
Raman studies demonstrated that the ZnO nanowires and microdiscs
grown using such set-up had good crystallinity with excellent optical
properties. Rectifying behavior of ZnO/Si heterostructures was
characterized by a simple DC circuit.
Abstract: The effect of chemical treatment in CdCl2 on the
compositional changes and defect structures of potentially useful ZnS
solar cell thin films prepared by vacuum deposition method was
studied using the complementary Rutherford backscattering (RBS)
and Thermoluminesence (TL) techniques. A series of electron and
hole traps are found in the various as deposited samples studied.
After treatment, perturbation on the intensity is noted; mobile defect
states and charge conversion and/or transfer between defect states are
found.
Abstract: Efficient luminescence is reported for the first time in Eu2+ activated double Chlorides A2BCl4 (A=Alkali metal, B=Alkaline earth element). A simple wet-chemical preparation is described. Emission intensities are comparable to that of the commercial phosphor. Excitation covers near UV region. These phosphors may be useful for applications like solid state lighting, scintillation detectors and X-ray storage using photo-stimulable phosphors.
Abstract: In this paper, we introduce an effective strategy for
subgoal division and ordering based upon recursive subgoals and
combine this strategy with a genetic-based planning approach. This
strategy can be applied to domains with conjunctive goals. The main
idea is to recursively decompose a goal into a set of serializable
subgoals and to specify a strict ordering among the subgoals.
Empirical results show that the recursive subgoal strategy reduces the
size of the search space and improves the quality of solutions to
planning problems.
Abstract: As German companies roll out their standardized
production systems to offshore manufacturing plants, they face the
challenge of implementing them in different cultural environments.
Studies show that the local adaptation is one of the key factors for a
successful implementation. Thus the question arises of where the line
between standardization and adaptation can be drawn. To answer
this question the influence of culture on production systems is
analysed in this paper. The culturally contingent components of
production systems are identified. Also the contingency factors are
classified according to their impact on the necessary adaptation
changes and implementation effort. Culturally specific decision
making, coordination, communication and motivation patterns
require one-time changes in organizational and process design. The
attitude towards rules requires more intense coaching and controlling.
Lastly a framework is developed to depict standardization and
adaption needs when transplanting production systems into different
cultural environments.
Abstract: The dynamic speckle or biospeckle is an interference
phenomenon generated at the reflection of a coherent light by an
active surface or even by a particulate or living body surface. The
above mentioned phenomenon gave scientific support to a method
named biospeckle which has been employed to study seed viability,
biological activity, tissue senescence, tissue water content, fruit
bruising, etc. Since the above mentioned method is not invasive and
yields numerical values, it can be considered for possible automation
associated to several processes, including selection and sorting.
Based on these preliminary considerations, this research work
proposed to study the interaction of a laser beam with vegetative
samples by measuring the incident light intensity and the transmitted
light beam intensity at several vegetative slabs of varying thickness.
Tests were carried on fifteen slices of apple tissue divided into three
thickness groups, i.e., 4 mm, 5 mm, 18 mm and 22 mm. A diode laser
beam of 10mW and 632 nm wavelength and a Samsung digital
camera were employed to carry the tests. Outgoing images were
analyzed by comparing the gray gradient of a fixed image column of
each image to obtain a laser penetration scale into the tissue,
according to the slice thickness.
Abstract: This research work proposed a study of fruit bruise detection by means of a biospeckle method, selecting the papaya fruit (Carica papaya) as testing body. Papaya is recognized as a fruit of outstanding nutritional qualities, showing high vitamin A content, calcium, carbohydrates, exhibiting high popularity all over the world, considering consumption and acceptability. The commercialization of papaya faces special problems which are associated to bruise generation during harvesting, packing and transportation. Papaya is classified as climacteric fruit, permitting to be harvested before the maturation is completed. However, by one side bruise generation is partially controlled once the fruit flesh exhibits high mechanical firmness. By the other side, mechanical loads can set a future bruise at that maturation stage, when it can not be detected yet by conventional methods. Mechanical damages of fruit skin leave an entrance door to microorganisms and pathogens, which will cause severe losses of quality attributes. Traditional techniques of fruit quality inspection include total soluble solids determination, mechanical firmness tests, visual inspections, which would hardly meet required conditions for a fully automated process. However, the pertinent literature reveals a new method named biospeckle which is based on the laser reflectance and interference phenomenon. The laser biospeckle or dynamic speckle is quantified by means of the Moment of Inertia, named after its mechanical counterpart due to similarity between the defining formulae. Biospeckle techniques are able to quantify biological activities of living tissues, which has been applied to seed viability analysis, vegetable senescence and similar topics. Since the biospeckle techniques can monitor tissue physiology, it could also detect changes in the fruit caused by mechanical damages. The proposed technique holds non invasive character, being able to generate numerical results consistent with an adequate automation. The experimental tests associated to this research work included the selection of papaya fruit at different maturation stages which were submitted to artificial mechanical bruising tests. Damages were visually compared with the frequency maps yielded by the biospeckle technique. Results were considered in close agreement.
Abstract: The fixed partial dentures are mainly used in the frontal
part of the dental arch because of their great esthetics. There are
several factors that are associated with the stress state created in
ceramic restorations, including: thickness of ceramic layers,
mechanical properties of the materials, elastic modulus of the
supporting substrate material, direction, magnitude and frequency of
applied load, size and location of occlusal contact areas, residual
stresses induced by processing or pores, restoration-cement
interfacial defects and environmental defects. The purpose of this
study is to evaluate the capability of Polarization Sensitive Optical
Coherence Tomography (PSOCT) in detection and analysis of
possible material defects in metal-ceramic and integral ceramic fixed
partial dentures. As a conclusion, it is important to have a non
invasive method to investigate fixed partial prostheses before their
insertion in the oral cavity in order to satisfy the high stress
requirements and the esthetic function.
Abstract: This paper reports on the enhanced photoluminescence
(PL) of nanocomposites through the layered structuring of phosphor
and quantum dot (QD). Green phosphor of Sr2SiO4:Eu, red QDs of
CdSe/CdS/CdZnS/ZnS core-multishell, and thermo-curable resin
were used for this study. Two kinds of composite (layered and mixed)
were prepared, and the schemes for optical energy transfer between
QD and phosphor were suggested and investigated based on PL decay
characteristics. It was found that the layered structure is more effective
than the mixed one in the respects of PL intensity, PL decay and
thermal loss. When this layered nanocomposite (QDs on phosphor) is
used to make white light emitting diode (LED), the brightness is
increased by 37 %, and the color rendering index (CRI) value is raised
to 88.4 compared to the mixed case of 80.4.
Abstract: An electric power system includes a generating, a
transmission, a distribution, and consumers subsystems. An electrical
power network in Tanzania keeps growing larger by the day and
become more complex so that, most utilities have long wished for
real-time monitoring and remote control of electrical power system
elements such as substations, intelligent devices, power lines,
capacitor banks, feeder switches, fault analyzers and other physical
facilities. In this paper, the concept of automation of management of
power systems from generation level to end user levels was
determined by using Power System Simulator for Engineering
(PSS/E) version 30.3.2.