Abstract: In this research work, poly (acrylonitrile-butadienestyrene)/
polypropylene (ABS/PP) blends were processed by melt
compounding in a twin-screw extruder. Upgrading of the thermal
characteristics of the obtained materials was attempted by the
incorporation of organically modified montmorillonite (OMMT), as
well as, by the addition of two types of compatibilizers;
polypropylene grafted with maleic anhydride (PP-g-MAH) and ABS
grafted with maleic anhydride (ABS-g-MAH). The effect of the
above treatments was investigated separately and in combination.
Increasing the PP content in ABS matrix seems to increase the
thermal stability of their blend and the glass transition temperature
(Tg) of SAN phase of ABS. From the other part, the addition of ABS
to PP promotes the formation of its β-phase, which is maximum at 30
wt% ABS concentration, and increases the crystallization temperature
(Tc) of PP. In addition, it increases the crystallization rate of PP.The
β-phase of PP in ABS/PP blends is reduced by the addition of
compatibilizers or/and organoclay reinforcement. The incorporation
of compatibilizers increases the thermal stability of PP and reduces
its melting (ΔΗm) and crystallization (ΔΗc) enthalpies. Furthermore it
decreases slightly the Tgs of PP and SAN phases of ABS/PP blends.
Regarding the storage modulus of the ABS/PP blends, it presents a
change in their behavior at about 10°C and return to their initial
behavior at ~110°C. The incorporation of OMMT to no compatibilized
and compatibilized ABS/PP blends enhances their storage modulus.
Abstract: Plastics occupy wide place in the applications of
automotive, electronics and house goods. Especially reinforced
plastics become popular because of their high strength besides their
advantages of low weight and easy manufacturability. In this study,
mechanical and morphological properties of polypropylene (PP) and
high density polyethylene (HDPE) matrix composites reinforced with
surface modified nano titan dioxide (TiO2) particles were
investigated. Surface modification was made by coating the nano
powders with maleic anhydride grafted styrene ethylene butylene
styrene (SEBS-g-MA) and silane, respectively. After surface
modification, PP/TiO2 and HDPE/TiO2 composites were obtained by
using twin screw extruder at titan dioxide loading of 1 wt.%, 3 wt.%
and 5 wt.%. Effects of surface modification were determined by
thermal and morphological analysis. SEBS-g-MA provided bridging
effect between TiO2 particles and polymer matrix while silane was
effective as a dispersant. Depending on that, homogenous structures
without agglomeration were obtained. Mechanical tests were
performed on the injection moldings of the composites for obtaining
the impact strength, tensile strength, stress at break, elongation and
elastic modulus. Reinforced HDPE and PP moldings gave higher
tensile strength and elastic modulus due to the rigid structure of TiO2.
Slight increment was seen in stress at break. Elongation and impact
strength decreased due to the stiffness of the nano titan dioxide.
Abstract: In the Lost Foam Casting process, melting point
temperature of metal, as well as volume and rate of the foam
degradation have significant effect on the mold filling pattern.
Therefore, gas generation capacity and gas gap length are two
important parameters for modeling of mold filling time of the lost
foam casting processes. In this paper, the gas gap length at the liquidfoam
interface for a low melting point (aluminum) alloy and a high
melting point (Carbon-steel) alloy are investigated by the
photography technique. Results of the photography technique
indicated, that the gas gap length and the mold filling time are
increased with increased coating thickness and density of the foam.
The Gas gap lengths measured in aluminum and Carbon-steel,
depend on the foam density, and were approximately 4-5 and 25-60
mm, respectively. By using a new system, the gas generation
capacity for the aluminum and steel was measured. The gas
generation capacity measurements indicated that gas generation in
the Aluminum and Carbon-steel lost foam casting was about 50 CC/g
and 3200 CC/g polystyrene, respectively.
Abstract: This paper presents the results of an experimental study on the performance of a triboelectric separator of plastic mixtures used for recycling. The separator consists of four cylindrical electrodes. The principle behind the separation technique is based on the difference in the Coulomb force acting on the plastic particles after triboelectric charging. The separation of mixtures of acrylonitrile butadiene styrene (ABS) and polystyrene (PS) using this method was studied. The effects of the triboelectric charging time and applied voltage on the separation efficiency were investigated. The experimental results confirm that it is possible to obtain a high purity and recovery rate for the initial compositions considered in this study.
Abstract: Moulded parts contribute to more than 70% of
components in products. However, common defects particularly in
plastic injection moulding exist such as: warpage, shrinkage, sink
marks, and weld lines. In this paper Taguchi experimental design
methods are applied to reduce the warpage defect of thin plate
Acrylonitrile Butadiene Styrene (ABS) and are demonstrated in two
levels; namely, orthogonal arrays of Taguchi and the Analysis of
Variance (ANOVA). Eight trials have been run in which the optimal
parameters that can minimize the warpage defect in factorial
experiment are obtained. The results obtained from ANOVA
approach analysis with respect to those derived from MINITAB
illustrate the most significant factors which may cause warpage in
injection moulding process. Moreover, ANOVA approach in
comparison with other approaches like S/N ratio is more accurate and
with the interaction of factors it is possible to achieve higher and the
better outcomes.
Abstract: This work describes the aerodynamic characteristic for
aircraft wing model with and without bird feather like winglet. The
aerofoil used to construct the whole structure is NACA 653-218
Rectangular wing and this aerofoil has been used to compare the
result with previous research using winglet. The model of the
rectangular wing with bird feather like winglet has been fabricated
using polystyrene before design using CATIA P3 V5R13 software
and finally fabricated in wood. The experimental analysis for the
aerodynamic characteristic for rectangular wing without winglet,
wing with horizontal winglet and wing with 60 degree inclination
winglet for Reynolds number 1.66×105, 2.08×105 and 2.50×105 have
been carried out in open loop low speed wind tunnel at the
Aerodynamics laboratory in Universiti Putra Malaysia. The
experimental result shows 25-30 % reduction in drag coefficient and
10-20 % increase in lift coefficient by using bird feather like winglet
for angle of attack of 8 degree.
Abstract: This work proposes an optical fiber system (OF) for
sensing various volatile organic compounds (VOCs) in human breath
for the diagnosis of some metabolic disorders as a non-invasive
methodology. The analyzed VOCs are alkanes (i.e., ethane, pentane,
heptane, octane, and decane), and aromatic compounds (i.e., benzene,
toluene, and styrene). The OF displays high analytical performance
since it provides near real-time responses, rapid analysis, and low
instrumentation costs, as well as it exhibits useful linear range and
detection limits; the developed OF sensor is also comparable to a
reference methodology (gas chromatography-mass spectrometry) for
the eight tested VOCs.
Abstract: Thermo-chemical treatment (TCT) such as pyrolysis
is getting recognized as a valid route for (i) materials and valuable
products and petrochemicals recovery; (ii) waste recycling; and (iii)
elemental characterization. Pyrolysis is also receiving renewed
attention for its operational, economical and environmental
advantages. In this study, samples of polyethylene terephthalate
(PET) and polystyrene (PS) were pyrolysed in a microthermobalance
reactor (using a thermogravimetric-TGA setup). Both
polymers were prepared and conditioned prior to experimentation.
The main objective was to determine the kinetic parameters of the
depolymerization reactions that occur within the thermal degradation
process. Overall kinetic rate constants (ko) and activation energies
(Eo) were determined using the general kinetics theory (GKT)
method previously used by a number of authors. Fitted correlations
were found and validated using the GKT, errors were within ± 5%.
This study represents a fundamental step to pave the way towards the
development of scaling relationship for the investigation of larger
scale reactors relevant to industry.
Abstract: Bicycle usage for exercise, recreation, and commuting
to work in Australia shows that pedal cycling is the fourth most
popular activity with 10.6% increase in participants between 2001
and 2007. As with other means of transport, accident and injury
becomes common although mandatory bicycle helmet wearing has
been introduced. The research aims to develop a face surrogate made
of sandwich of rigid foam and rubber sheets to represent human
facial bone under blunt impact. The facial surrogate will serve as an
important test device for further development of facial-impact
protection for cyclist. A test procedure was developed to simulate the
energy of impact and record data to evaluate the effect of impact on
facial bones. Drop tests were performed to establish a suitable
combination of materials. It was found that the sandwich structure of
rigid extruded-polystyrene foam (density of 40 kg/m3 with a pattern
of 6-mm-holes), Neoprene rubber sponge, and Abrasaflex rubber
backing, had impact characteristics comparable to that of human
facial bone. In particular, the foam thickness of 30 mm and 25 mm
was found suitable to represent human zygoma (cheekbone) and
maxilla (upper-jaw bone), respectively.
Abstract: spherical porous carbon particles with
controllable porosity with a mean size of 2.5m have been
prepared using a spray drying method with organic particle
colloidal template. As a precursor, a mixing solution of carbon
nanopowder and polystyrene (PS) particles as a template was
used. The result showed that the particles with a good porous
structure could be obtained. The pore size and shape (spherical)
were identical to the initial template, giving a potential way for
further developments. The control of particle porosity was also
possible and reported in this paper, in which this control could
be achieved by means of PS concentration.
Abstract: This study has applied the L16 orthogonal array of the
Taguchi method to determine the optimized polymeric
Nanocomposite asphalt binder. Three control factors are defined as
polypropylene plastomer (PP), styrene-butadiene-styrene elastomer
(SBS) and Nanoclay. Four level of concentration contents are
introduced for prepared asphalt binder samples. all samples were
prepared with 4.5% of bitumen 60/70 content. Compressive strength
tests were carried out for defining the optimized sample via
QUALITEK-4 software. SBS with 3%, PP with 5 % and Nanoclay
with 1.5% of concentrations are defined as the optimized
Nanocomposite asphalt binders. The confirmation compressive
strength and also softening point tests showed that modification of
asphalt binders with this method, improved the compressive strength
and softening points of asphalt binders up to 55%.
Abstract: Toughening of polyamide 6 (PA6)/ Nanoclay (NC) nanocomposites with styrene-ethylene/butadiene-styrene copolymer (SEBS) using maleated styrene-ethylene/butadiene-styrene copolymer (mSEBS)/ as a compatibilizer were investigated by blending them in a co-rotating twin-screw extruder. Response surface method of experimental design was used for optimizing the material and processing parameters. Effect of four factors, including SEBS, mSEBS and NC contents as material variables and order of mixing as a processing factor, on toughness of hybrid nanocomposites were studied. All the prepared samples showed ductile behavior and low temperature Izod impact toughness of some of the hybrid nanocomposites demonstrated 900% improvement compared to the PA6 matrix while the modulus showed maximum enhancement of 20% compared to the pristine PA6 resin.
Abstract: Hydrogen is regarded to play an important role in
future energy systems because it can be produced from abundant
resources and its combustion only generates water. The disposal of
waste tyres is a major problem in environmental management
throughout the world. The use of waste materials as a source of
hydrogen is particularly of interest in that it would also solve a waste
treatment problem. There is much interest in the use of alternative
feedstocks for the production of hydrogen since more than 95% of
current production is from fossil fuels. The pyrolysis of waste tyres
for the production of liquid fuels, activated carbons and gases has
been extensively researched. However, combining pyrolysis with
gasification is a novel process that can gasify the gaseous products
from pyrolysis. In this paper, an experimental investigation into the
production of hydrogen and other gases from the bench scale
pyrolysis-gasification of tyres has been investigated. Experiments
were carried using a two stage system consisting of pyrolysis of the
waste tyres followed by catalytic steam gasification of the evolved
gases and vapours in a second reactor. Experiments were conducted
at a pyrolysis temperature of 500 °C using Ni/Al2O3 as a catalyst. The
results showed that there was a dramatic increase in gas yield and the
potential H2 production when the gasification temperature was
increased from 600 to 900 oC. Overall, the process showed that high
yields of hydrogen can be produced from waste tyres.
Abstract: The lubricating properties of commercially available
mucins originating from different animal organs, namely bovine
submaxillary mucin (BSM) and porcine gastric mucin (PGM), have
been characterized at polymeric surfaces for biomedical applications.
Atomic force microscopy (AFM) and pin-on-disk tribometry have
been employed for tribological studies at nanoscale and macroscale
contacts, respectively. Polystyrene (PS) was employed to represent
‘rigid’ contacts, whereas poly(dimethylsiloxane) (PDMS) was
employed to represent ‘soft contacts’. To understand the lubricating
properties of mucins in correlation with the coverage on surfaces,
adsorption properties of mucins onto the polymeric substrates have
been characterized by means of optical waveguide light-mode
spectroscopy (OWLS). Both mucins showed facile adsorption onto
both polymeric substrates, but the lubricity was highly dependent
upon the pH change between 2 and 7.
Abstract: One of the important factors of cracks on the asphalt
pavements is bitumen aging that associated with the loss of volatile
components and oxidation of asphalt binder. This paper is about
effect of Styrene-Butadiene-Styrene (SBS) polymer on asphalt aging
In order to decrease asphalt aging effects. For this purpose samples of
base bitumen and SBS modified bitumen aged according to the
rolling thin film oven test (RTFOT) and pressure aging vessel (PAV),
respectively. Properties of each sample were evaluated using Fourier
Transform Infrared (FTIR) spectroscopy, n-heptane precipitation,
viscosity test, softening point test and penetration test. FT-IR
Analysis, showed lower oxidation of SBS modified bitumen than
base bitumen, after aging.
Abstract: Traffic density, an indicator of traffic
conditions, is one of the most critical characteristics to
Intelligent Transport Systems (ITS). This paper investigates
recursive traffic density estimation using the information
provided from inductive loop detectors. On the basis of the
phenomenological relationship between speed and density, the
existing studies incorporate a state space model and update the
density estimate using vehicular speed observations via the
extended Kalman filter, where an approximation is made
because of the linearization of the nonlinear observation
equation. In practice, this may lead to substantial estimation
errors. This paper incorporates a suitable transformation to
deal with the nonlinear observation equation so that the
approximation is avoided when using Kalman filter to
estimate the traffic density. A numerical study is conducted. It
is shown that the developed method outperforms the existing
methods for traffic density estimation.
Abstract: Paper presents knowledge about types of test in area
of materials properties of selected methods of rapid prototyping
technologies. In today used rapid prototyping technologies for
production of models and final parts are used materials in initial state
as solid, liquid or powder material structure. In solid state are used
various forms such as pellets, wire or laminates. Basic range
materials include paper, nylon, wax, resins, metals and ceramics. In
Fused Deposition Modeling (FDM) rapid prototyping technology are
mainly used as basic materials ABS (Acrylonitrile Butadiene
Styrene), polyamide, polycarbonate, polyethylene and polypropylene.
For advanced FDM applications are used special materials as silicon
nitrate, PZT (Piezoceramic Material - Lead Zirconate Titanate),
aluminium oxide, hydroxypatite and stainless steel.
Abstract: Polymeric microreactors have emerged as a new
generation of carriers that hold tremendous promise in the areas of
cancer therapy, controlled delivery of drugs, for removal of
pollutants etc. Present work reports a simple and convenient
methodology for synthesis of polystyrene and poly caprolactone
microreactors. An aqueous suspension of carboxylated (1μm)
polystyrene latex particles was mixed with toluene solution followed
by freezing with liquid nitrogen. Freezed particles were incubated at
-20°C and characterized for formation of voids on the surface of
polymer microspheres by Field Emission Scanning Electron
Microscope. The hollow particles were then overnight incubated at
40ºC with unfunctionalized quantum dots (QDs) in 5:1 ratio. QDs
Encapsulated polystyrene microcapsules were characterized by
fluorescence microscopy.
Likewise Poly ε-caprolactone microreactors were prepared by
micro-volcanic rupture of freeze dried microspheres synthesized
using emulsification of polymer with aqueous Poly vinyl alcohol and
freezed with liquid nitrogen. Microreactors were examined with Field
Emission Scanning Electron Microscope for size and morphology.
Current study is an attempt to create hollow polymer particles which
can be employed for microencapsulation of nanoparticles and drug
molecules.