Abstract: The increasing demand of thermoplastic elastomers is related to the wide range of applications, such as automotive, footwear, wire and cable industries, adhesives and medical devices, cell phones, sporting goods, toys and others. These materials are susceptible to microbial attack. Moisture and organic matter present in some areas (such as shower area and sink), provide favorable conditions for microbial proliferation, which contributes to the spread of diseases and reduces the product life cycle. Compounds based on SEBS copolymers, poly(styrene-b-(ethylene-co-butylene)-b-styrene, are a class of thermoplastic elastomers (TPE), fully recyclable and largely used in domestic appliances like bath mats and tooth brushes (soft touch). Zinc oxide and zinc ions loaded in personal and home care products have become common in the last years due to its biocidal effect. In that sense, the aim of this study was to evaluate the effect of zinc as antimicrobial agent in compounds based on SEBS/polypropylene/oil/ calcite for use as refrigerator seals (gaskets), bath mats and sink squeegee. Two zinc oxides from different suppliers (ZnO-Pe and ZnO-WR) and one masterbatch of zinc ions (M-Zn-ion) were used in proportions of 0%, 1%, 3% and 5%. The compounds were prepared using a co-rotating double screw extruder (L/D ratio of 40/1 and 16 mm screw diameter). The extrusion parameters were kept constant for all materials. Tests specimens were prepared using the injection molding machine. A compound with no antimicrobial additive (standard) was also tested. Compounds were characterized by physical (density), mechanical (hardness and tensile properties) and rheological properties (melt flow rate - MFR). The Japan Industrial Standard (JIS) Z 2801:2010 was applied to evaluate antibacterial properties against Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli). The Brazilian Association of Technical Standards (ABNT) NBR 15275:2014 were used to evaluate antifungal properties against Aspergillus niger (A. niger), Aureobasidium pullulans (A. pullulans), Candida albicans (C. albicans), and Penicillium chrysogenum (P. chrysogenum). The microbiological assay showed a reduction over 42% in E. coli and over 49% in S. aureus population. The tests with fungi showed inconclusive results because the sample without zinc also demonstrated an inhibition of fungal development when tested against A. pullulans, C. albicans and P. chrysogenum. In addition, the zinc loaded samples showed worse results than the standard sample when tested against A. niger. The zinc addition did not show significant variation in mechanical properties. However, the density values increased with the rise in ZnO additives concentration, and had a little decrease in M-Zn-ion samples. Also, there were differences in the MFR results in all compounds compared to the standard.
Abstract: Lightweight concrete is being used in the construction industry as a building material in its own right. Ultra-lightweight concrete can be applied as a filler and support material for the manufacturing of composite building materials. This paper is about the development of a stable and reproducible ultra-lightweight concrete with the inclusion of poly-lactic acid (PLA) beads and assessing the feasibility of PLA as a lightweight aggregate that will deliver advantages such as a more eco-friendly concrete and a non-petroleum polymer aggregate. In total, sixty-three samples were prepared and the effectiveness of mineral admixture, curing conditions, water-cement ratio, PLA ratio, EPS ratio and perlite ratio on compressive strength of perlite concrete are studied. The results show that PLA particles are sensitive to alkali environment of cement paste and considerably shrank and lost their strength. A higher compressive strength and a lower density was observed when expanded polystyrene (EPS) particles replaced PLA beads. In addition, a set of equations is proposed to estimate the water-cement ratio, cement content and compressive strength of perlite concrete.
Abstract: Accurate prediction of the cooling/heating load and consequently, the sizing of the heating, ventilating, and air-conditioning equipment require precise calculation of the heat transfer mainly by conduction through envelope components of a building. The thermal resistance of most thermal insulation materials depends on the operating temperature. The temperature to which the insulation materials are exposed varies, depending on the thermal resistance of the materials, the location of the insulation layer within the assembly system, and the effective temperature which depends on the amount of solar radiation received on the surface of the assembly. The main objective of this paper is to investigate the change of the thermal conductivity of polystyrene insulation material in terms of the temperature at the mid-thickness of the material and its effect on the cooling load required by the building.
Abstract: The great majority of the applications of thermal isolation in the strip of drops and averages temperatures (up to 200ºC), it is made of materials aggressive nature, such an as glass wool, rock wool, polystyrene, EPS among others. Such materials, in spite of the effectiveness in the retention of the flow of heat, possess considerable cost and when discarded they are long years to be to decompose. In that context, trying to adapt the world politics the about of the preservation of the environment, a study began with intention of developing a material composite, with properties of thermal, originating from insulating industrial residues. In this research, the behavior of the composite was analyzed, as submitted the fire. For this, the reaction rehearsals were accomplished to the fire for the composites 2:1; 1:1; 1:2 and for the Latex, based in the "con" experiment in agreement with the norm ASTM - E 1334 - 90. As consequence, in function of the answers of the system was possible to be observed to the acting of each mixture proportion.
Abstract: In this paper, the unstable angle of attack of a
FOXTROT aircraft is controlled by using Genetic Algorithm based
flight controller and the result is compared with the conventional
techniques like Tyreus-Luyben (TL), Ziegler-Nichols (ZN) and
Interpolation Rule (IR) for tuning the PID controller. In addition, the
performance indices like Mean Square Error (MSE), Integral Square
Error (ISE), and Integral Absolute Time Error (IATE) etc. are
improved by using Genetic Algorithm. It was established that the
error by using GA is very less as compared to the conventional
techniques thereby improving the performance indices of the
dynamic system.
Abstract: Asphalt concrete pavements have a short life cycle,
failing mainly due to temperature changes, traffic loading and ageing.
Modified asphalt mixtures provide the technology to produce a
bituminous binder with improved viscoelastic properties, which
remain in balance over a wider temperature range and loading
conditions. In this research, 60/70 penetration grade asphalt binder
was modified by adding 2, 4, 6, 8 and 10 percent by weight of asphalt
binder following the wet process and the mineral aggregate was
modified by adding 1, 2, 3, 4 and 5 percent crumb rubber by volume
of the mineral aggregate following the dry process. The LDPE
modified asphalt binder rheological properties were evaluated. The
laboratory results showed an increase in viscosity, softening point
and stiffness of the binder. The modified asphalt was then used in
preparing asphalt mixtures by Marshall Mix design procedure. The
Marshall Stability values for mixes containing 2% crumb rubber and
4% LDPE were found to be 30% higher than the conventional asphalt
concrete mix.
Abstract: Polymeric micro-cantilevers (Cs) are rapidly
becoming popular for MEMS applications such as chemo- and biosensing
as well as purely electromechanical applications such as
microrelays. Polymer materials present suitable physical and
chemical properties combined with low-cost mass production. Hence,
micro-cantilevers made of polymers indicate much more
biocompatibility and adaptability of rapid prototyping along with
mechanical properties. This research studies the effects of three
process and one size factors on the filling behaviour in micro cavity,
and the role of each in the replication of micro parts using different
polymer materials i.e. polypropylene (PP) SABIC 56M10 and
acrylonitrile butadiene styrene (ABS) Magnum 8434 . In particular,
the following factors are considered: barrel temperature, mould
temperature, injection speed and the thickness of micro features. The
study revealed that the barrel temperature and the injection speed are
the key factors affecting the flow length of micro features replicated
in PP and ABS. For both materials, an increase of feature sizes
improves the melt flow. However, the melt fill of micro features does
not increase linearly with the increase of their thickness.
Abstract: In this study, the feasibility of incorporating ceramic
waste from bricks (perforated brick and double hollow brick) and
extruded polystyrene (XPS) waste, is analysed.
Results show that it is possible to incorporate up to 25% of
ceramic waste and 4% of XPS waste over the weight of gypsum in a
gypsum matrix. Furthermore, with the addition of ceramic waste an
8% of surface hardness increase and a 25% of capillary water
absorption reduction can be obtained. On the other hand, with the
addition of XPS, a 26% reduction of density and a 37% improvement
of thermal conductivity can be obtained.
The obtained results are favorable to use these materials in order to
produce prefabricated gypsum and also as material for interior
cladding walls.
Abstract: In order to use bitumen in hot mix asphalt, it must
have specific characteristics. There are some methods to reach these
properties. Using polymer modifiers are one of the methods to
modify the bitumen properties. In this paper the effect of Styrene-
Butadiene-Rubber that is one of the bitumen polymer modifiers on
rheology properties of bitumen is studied. In this regard, the
rheological properties of base bitumen and the modified bitumen with
3, 4, and 5 percent of Styrene-Butadiene-Rubber (SBR) were
analysed. The results show that bitumen modified with 5 percent of
SBR has the best performance than the other samples.
Abstract: The present work analyses different parameters of end
milling to minimize the surface roughness for AISI D2 steel. D2 Steel
is generally used for stamping or forming dies, punches, forming
rolls, knives, slitters, shear blades, tools, scrap choppers, tyre
shredders etc. Surface roughness is one of the main indices that
determines the quality of machined products and is influenced by
various cutting parameters. In machining operations, achieving
desired surface quality by optimization of machining parameters, is a
challenging job. In case of mating components the surface roughness
become more essential and is influenced by the cutting parameters,
because, these quality structures are highly correlated and are
expected to be influenced directly or indirectly by the direct effect of
process parameters or their interactive effects (i.e. on process
environment). In this work, the effects of selected process parameters
on surface roughness and subsequent setting of parameters with the
levels have been accomplished by Taguchi’s parameter design
approach. The experiments have been performed as per the
combination of levels of different process parameters suggested by
L9 orthogonal array. Experimental investigation of the end milling of
AISI D2 steel with carbide tool by varying feed, speed and depth of
cut and the surface roughness has been measured using surface
roughness tester. Analyses of variance have been performed for mean
and signal-to-noise ratio to estimate the contribution of the different
process parameters on the process.
Abstract: Polycyclic aromatic hydrocarbons (PAHs) are formed
during the pyrolysis of scrap tyres to produce tyre pyrolytic oil
(TPO). Due to carcinogenic, mutagenic, and toxic properties PAHs
are priority pollutants. Hence it is essential to remove PAHs from
TPO before utilising TPO as a petroleum fuel alternative (to run the
engine). Agricultural wastes have promising future to be utilized as
biosorbent due to their cost effectiveness, abundant availability, high
biosorption capacity and renewability. Various low cost adsorbents
were prepared from natural sources. Uptake of PAHs present in tyre
pyrolytic oil was investigated using various low-cost adsorbents of
natural origin including sawdust (shisham), coconut fiber, neem bark,
chitin, activated charcoal. Adsorption experiments of different PAHs
viz. naphthalene, acenaphthalene, biphenyl and anthracene have been
carried out at ambient temperature (25°C) and at pH 7. It was
observed that for any given PAH, the adsorption capacity increases
with the lignin content. Freundlich constant Kf and 1/n have been
evaluated and it was found that the adsorption isotherms of PAHs
were in agreement with a Freundlich model, while the uptake
capacity of PAHs followed the order: activated charcoal> saw dust
(shisham) > coconut fiber > chitin. The partition coefficients in
acetone-water, and the adsorption constants at equilibrium, could be
linearly correlated with octanol–water partition coefficients. It is
observed that natural adsorbents are good alternative for PAHs
removal. Sawdust of Dalbergia sissoo, a by-product of sawmills was
found to be a promising adsorbent for the removal of PAHs present in
TPO. It is observed that adsorbents studied were comparable to those
of some conventional adsorbents.
Abstract: A series of polystyrene (PS) nanoparticles were
prepared by grafting polystyrene from both aggregated silica and
colloidally dispersed silica nanoparticles using atom-transfer radical
polymerisation (ATRP). Cross-linking and macroscopic gelation
were minimised by using a miniemulsion system. The thermal and
mechanical behaviour of the nanocomposites have been examined by
differential scanning calorimetry (DSC) and dynamic mechanical
thermal analysis (DMTA).
Abstract: The majority of contemporary insulation materials
commonly used in the building industry is made from non-renewable
raw materials; furthermore, their production often brings high energy
costs. A long-term trend as far as sustainable development is
concerned has been the reduction of energy and material demands of
building material production. One of the solutions is the possibility of
using easily renewable natural raw material sources which are
considerably more ecological and their production is mostly less
energy-consuming compared to the production of normal insulations
(mineral wool, polystyrene). The paper describes the results of
research focused on the development of thermal and acoustic
insulation materials based on natural fibres intended for floor
constructions. Given the characteristic open porosity of natural fibre
materials, the hygrothermal behaviour of the developed materials was
studied. Especially the influence of relative humidity and temperature
on thermal insulation properties was observed.
Abstract: Virtual reality (VR) is a rapidly emerging computer
interface that attempts to immerse the user completely within an
experimental recreation; thereby, greatly enhancing the overall
impact and providing a much more intuitive link between the
computer and the human participants. The main objective of this
study is to design tractor trailer capable of meeting the customers’
requirements and suitable for rough conditions to be used in
combination with a farm tractor in India. The final concept is capable
of providing arrangements for attaching the trailer to the tractor easily
by pickup hitch, stronger and lighter supporting frame, option of
spare tyre etc. Furthermore, the resulting product design can be sent
via the Internet to customers for comments or marketing purposes.
The virtual prototyping (VP) system therefore facilitates advanced
product design and helps reduce product development time and cost
significantly.
Abstract: The aluminum impregnated catalysts of Al-alumina (Al-Al2O3), Al-montmorillonite (Al-Mmn) and Al-activated charcoal (Al-AC) of various percent loadings were prepared by wet impregnation method and characterized by SEM, XRD and N2 adsorption/desorption (BET). The catalytic properties were investigated in the degradation of waste polystyrene (WPS). The results of catalytic degradation of Al metal, 20% Al-Al2O3, 5% Al-Mmn and 20% Al-AC were compared with each other for optimum conditions. Among the catalyst used 20% Al-Al2O3 was found the most effective catalyst. The BET surface area of 20% Al-Al2O3 determined was 70.2 m2/g. The SEM data revealed the catalyst with porous structure throughout the frame work with small nanosized crystallites. The yield of liquid products with 20% Al-Al2O3 (91.53 ± 2.27 wt%) was the same as compared to Al metal (91.20 ± 0.35 wt%) but the selectivity of hydrocarbons and yield of styrene monomer (56.32 wt%) was higher with 20% Al-Al2O3 catalyst.
Abstract: Polymeric materials have become an integral part of every aspect of today's industry. They have wide applications, inter alia, in areas such as medicine, food industry and agriculture. In agriculture, for example, they are used for the production of pots, irrigation systems and for soil mulching. The aim of this study was the attempt to produce a biodecomposable agricultural mat, by coating cotton fabric with a blend of carboxylated styrene-butadiene latex (LBSK) containing the enzymatic hydrolyzate of keratin from cattle hair, which would serve as a material for mulching.
The production of such material allows the beneficial management of burdensome tannery waste constituted by keratin from cattle hair and at the same time, the production of agricultural mats that much faster undergo decomposition than commonly used polyethylene mats.
Abstract: The measurement of enterprise-university-research
cooperative efficiency has important meanings in improving the
cooperative efficiency, strengthening the effective integration of
regional resource, enhancing the ability of regional innovation and
promoting the development of regional economy. The paper
constructs the DEA method and DEA-Malmquist productivity index
method to research the cooperation efficiency of Hubei by making
comparisons with other provinces in China. The study found out the
index of technology efficiency is 0.52 and the enterprise-universityresearch
cooperative efficiency is Non-DEA efficient. To realize the
DEA efficiency of Hubei province, the amount of 1652.596 R&D
employees and 638.368 R&D employees’ full time equivalence should
be reduced or 137.89 billion yuan of new products’ sales income be
increased. Finally, it puts forward policy recommendations on existing
problems to strengthen the standings of the cooperation, realize the
effective application of the research results, and improve the level of
management of enterprise-university-research cooperation efficiency.
Abstract: The modern energy-efficient houses are often founded on a thermal insulation (TI) layer placed under the building’s RC foundation slab.The purpose of the paper is to identify the potential problems of the buildings founded on TI layer from the seismic point of view. The two main goals of the study were to assess the seismic behavior of such buildings, and to search for the critical structural parameters affecting the response of the superstructure as well as of the extruded polystyrene (XPS) layer. As a test building a multi-storeyed RC frame structure with and without the XPS layer under the foundation slab has been investigated utilizing nonlinear dynamic (time-history) and static (pushover) analyses. The structural response has been investigated with reference to the following performance parameters: i) Building’s lateral roof displacements, ii) Edge compressive and shear strains of the XPS, iii) Horizontal accelerations of the superstructure, iv) Plastic hinge patterns of the superstructure, v) Part of the foundation in compression, and vi) Deformations of the underlying soil and vertical displacements of the foundation slab (i.e. identifying the potential uplift). The results have shown that in the case of higher and stiff structures lying on firm soil the use of XPS under the foundation slab might induce amplified structural peak responses compared to the building models without XPS under the foundation slab. The analysis has revealed that the superstructure as well as the XPS response is substantially affected by the stiffness of the foundation slab.
Abstract: People’s tendency towards living in apartment houses is increasing in a densely populated country. However, some residents living in apartment houses are bothered by noise coming from the houses above. In order to reduce noise pollution, the communities are increasingly imposing a bylaw, including the limitation of floor impact sound, minimum thickness of floors, and floor soundproofing solutions. This research effort focused on the specific long-time deflection of resilient materials in the floor sound insulation systems of apartment houses. The experimental program consisted of testing nine floor sound insulation specimens subjected to sustained load for 45 days. Two main parameters were considered in the experimental investigation: three types of resilient materials and magnitudes of loads. The test results indicated that the structural behavior of the floor sound insulation systems under long-time load was quite different from that the systems under short-time load. The loading period increased the deflection of floor sound insulation systems and the increasing rate of the long-time deflection of the systems with ethylene vinyl acetate was smaller than that of the systems with low density ethylene polystyrene.
Abstract: The main goal of this study was to find simple and industrially applicable production of ion exchangers based on nanofibrous polystyrene matrix and characterization of prepared material. Starting polystyrene nanofibers were sulfonated and crosslinked under appropriate conditions at the same time by sulfuric acid. Strongly acidic cation exchanger was obtained in such a way. The polymer matrix was made from polystyrene nanofibers prepared by NanospiderTM technology.
Various types postpolymerization reactions and other methods of crosslinking were studied. Greatly different behavior between nano- and microsize materials was observed. The final nanofibrous material was characterized and compared to common granular ion exchangers and available microfibrous ion exchangers. The sorption properties of nanofibrous ion exchangers were compared with the granular ion exchangers. For nanofibrous ion exchangers of comparable ion exchange capacity was observed considerably faster adsorption kinetics.